Search

Eleven phase change materials (PCMs) for cooling humans in heat-stressed conditions were evaluated for their cooling characteristics. Effects of packaging material and segmentation were also investigated. Sample packs with a different type PCM (water- and oil-based PCMs, cooling gels, inorganic salts) or different packaging (aluminum, TPU, TPU + neoprene) were investigated on a hotplate. Cooling capacity, duration, and power were determined. Secondly, a PCM pack with hexagon compartments was compared to an unsegmented version with similar content. Cooling power decreased whereas cooling duration increased with increasing melting temperature. The water-based PCMs showed a >2x higher cooling power than other PCMs, but were relatively short-lived. The flexible gels and salts did not demonstrate a phase change plateau in cooling power, compromising their cooling potential. Using a TPU or aluminum packaging was indifferent. Adding neoprene considerably extended cooling duration, while decreasing power. Segmentation has practical benefits, but substantially lowered contact area and therefore cooling power.

There are different thermal perception models linked to a mathematical thermophysiological human model, with which the thermal sensation under stationary and/or dynamic conditions can be evaluated. Each of these perception and thermophysiological models have their own field of application. Stolwijk developed a thermophysiological human model without an associated thermal perception model, which today is still the basis for other mathematical thermophysiological models. Fiala developed the FPC model, also based on the Stolwijk model, and is one of the latest developments in the field of thermophysiological human models. In the FPC model, an equation is included with which the thermal sensation under stationary and dynamic conditions can be assessed; the so-called Dynamic Thermal Sensation (DTS). The DTS equation is, however, specifically developed for use in combination with the FPC model. In contrast to the Stolwijk model, the source code of the computer programs of the later developed thermophysiological human models is not freely available, which limits the use and applicability of the models in practice. It is precise because of the availability of the source code that the Stolwijk model is still used in industry and the research world. The question, therefore, arises: ‘To what extent can a human transient thermal sensation equation be derived, combined with the Stolwijk model, in a similar way to that used for the DTS equation in the FPC model?’.

Contains fulltext : 238809.pdf (Publisher’s version ) (Open Access) The environmental conditions during the Tokyo Olympic and Paralympic Games are expected to be challenging, which increases the risk for participating athletes to develop heat-related illnesses and experience performance loss. To allow safe and optimal exercise performance of Dutch elite athletes, the Thermo Tokyo study aimed to determine thermoregulatory responses and performance loss among elite athletes during exercise in the heat, and to identify personal, sports-related, and environmental factors that contribute to the magnitude of these outcomes. For this purpose, Dutch Olympic and Paralympic athletes performed two personalized incremental exercise tests in simulated control (15°C, relative humidity (RH) 50%) and Tokyo (32°C, RH 75%) conditions, during which exercise performance and (thermo)physiological parameters were obtained. Thereafter, athletes were invited for an additional visit to conduct anthropometric, dual-energy X-ray absorptiometry (DXA), and 3D scan measurements. Collected data also served as input for a thermophysiological computer simulation model to estimate the impact of a wider range of environmental conditions on thermoregulatory responses. Findings of this study can be used to inform elite athletes and their coaches on how heat impacts their individual (thermo)physiological responses and, based on these data, advise which personalized countermeasures (i.e. heat acclimation, cooling interventions, rehydration plan) can be taken to allow safe and maximal performance in the challenging environmental conditions of the Tokyo 2020 Olympic and Paralympic Games.

We propose an approach to designing smart wearables that act as partners to help people cope with stress in daily life. Our approach contributes to the developing field of smart wearables by addressing how technological capabilities can be designed to establish partnerships that consider the person, the situation, and the appropriate type of support. As such, this study also contributes to healthcare by opening up novel technology-supported routes to stress treatment and care. We present the results of a phenomenological study conducted with three war veterans who suffer from chronic posttraumatic stress disorder. We describe how their experiences of dealing with their stress informed our design approach, and discuss the implications of these results on smart wearables and stress management in general. We conclude by reflecting on the limitations of this study and directions for future work.

Current athlete monitoring practice in team sports is mainly based on positional data measured by global positioning or local positioning systems. The disadvantage of these measurement systems is that they do not register lower extremity kinematics, which could be a useful measure for identifying injury-risk factors. Rapid development in sensor technology may overcome the limitations of the current measurement systems. With inertial measurement units (IMUs) securely fixed to body segments, sensor fusion algorithms and a biomechanical model, joint kinematics could be estimated. The main purpose of this article is to demonstrate a sensor setup for estimating hip and knee joint kinematics of team sport athletes in the field. Five male subjects (age 22.5 +/- 2.1 years; body mass 77.0 +/- 3.8 kg; height 184.3 +/- 5.2 cm; training experience 15.3 +/- 4.8 years) performed a maximal 30-meter linear sprint. Hip and knee joint angles and angular velocities were obtained by five IMUs placed on the pelvis, both thighs and both shanks. Hip angles ranged from 195 degrees (+/- 8 degrees) extension to 100.5 degrees (+/- 8 degrees) flexion and knee angles ranged from 168.6 degrees (+/- 12 degrees) minimal flexion and 62.8 degrees (+/- 12 degrees) maximal flexion. Furthermore, hip angular velocity ranged between 802.6 degrees.s(-1) (+/- 192 degrees.s(-1)) and -674.9 degrees.s(-1) (+/- 130 degrees.s(-1)). Knee angular velocity ranged between 1155.9 degrees.s(-1) (+/- 200 degrees.s(-1)) and -1208.2 degrees.s(-1) (+/- 264 degrees.s(-1)). The sensor setup has been validated and could provide additional information with regard to athlete monitoring in the field. This may help professionals in a daily sports setting to evaluate their training programs, aiming to reduce injury and optimize performance.

This paper presents experimental testing of a new semi-active vibration control device comprising a shape memory polymer (SMP) core that is reinforced by an SMP-aramid composite skin. This control device works as a load-transfer component that can be integrated into truss and frame structures in the form of a joint. At the material level, thermal actuation from ambient (25 degrees C) to transition temperature (65 degrees C) causes a significant 40fold increase in damping due to viscoelastic effects. At the component level, uniaxial tensile and four-point bending tests have shown that tensile strength depends primarily on the bond strength between the reinforcement skin and the structural element while flexural strength depends on the strength of the reinforcement skin fibers. Through cyclic testing, it has been observed that material viscoelasticity is beneficial to ductility and energy dissipation. When the joint core is actuated to the SMP transition temperature, axial and flexural stiffness decrease by up to 50% and 90%, respectively. The property change at material and component levels enable tuning the frequency and damping ratio at the structure level, which has been successfully employed to mitigate the dynamic response of a 1/10 scale three-story prototype frame under resonance and earthquake loadings.

ObjectivesTo evaluate how separate and combined climatic parameters affect peak core temperature during exercise in the heat using computer simulations fed with individual data.MethodsThe impact of eight environmental conditions on rectal temperature (Tre) was determined for exercise under heat stress using the Fiala-thermal-Physiology-and-Comfort simulation model. Variations in ambient temperature (Ta±6°C), relative humidity (RH±15%) and solar radiation (SR+921 W/m2) were assessed in isolation and combination (worst-case/best-case scenarios) and compared with baseline (Ta32°C, RH 75%, SR 0 W/m2). The simulation model was fed with personal, anthropometric and individual exercise characteristics.Results54 athletes exercised for 46±10 min at baseline conditions and achieved a peak core temperature of 38.9±0.5°C. Simulations at a higher Ta (38°C) and SR (921 W/m2) resulted in a higher peak Tre compared with baseline (+0.6±0.3°C and +0.5±0.2°C, respectively), whereas a higher RH (90%) hardly affected peak Tre (+0.1±0.1°C). A lower Ta (26°C) and RH (60%) reduced peak Tre by −0.4±0.2°C and a minor −0.1±0.1°C, respectively. The worst-case simulation yielded a 1.5±0.4°C higher Tre than baseline and 2.0±0.7°C higher than the best-case condition.ConclusionCombined unfavourable climatic conditions produce a greater increase in peak core temperature than the sum of its parts in elite athletes exercising in the heat.

Sweat sensors allow for new unobtrusive ways to continuously monitor an athlete's performance and health status. Significant advances have been made in the optimization of sensitivity, selectivity, and durability of electrochemical sweat sensors. However, comparing the in situ performance of these sensors in detail remains challenging because standardized sweat measurement methods to validate sweat sensors in a physiological setting do not yet exist. Current collection methods, such as the absorbent patch technique, are prone to contamination and are labor-intensive, which limits the number of samples that can be collected over time for offline reference measurements. We present an easy-to-fabricate sweat collection system that allows for continuous electrochemical monitoring, as well as chronological sampling of sweat for offline analysis. The patch consists of an analysis chamber hosting a conductivity sensor and a sequence of 5 to 10 reservoirs that contain level indicators that monitor the filling speed. After testing the performance of the patch in the laboratory, elaborate physiological validation experiments (3 patch locations, 6 participants) were executed. The continuous sweat conductivity measurements were compared with laboratory [Na+] and [Cl-] measurements of the samples, and a strong linear relationship (R2 = 0.97) was found. Furthermore, sweat rate derived from ventilated capsule measurement at the three locations was compared with patch filling speed and continuous conductivity readings. As expected from the literature, sweat conductivity was linearly related to sweat rate as well. In short, a successfully validated sweat collection patch is presented that enables sensor developers to systematically validate novel sweat sensors in a physiological setting.

The environmental conditions during the Tokyo Olympic and Paralympic Games are expected to be challenging, which increases the risk for participating athletes to develop heat-related illnesses and experience performance loss. To allow safe and optimal exercise performance of Dutch elite athletes, the Thermo Tokyo study aimed to determine thermoregulatory responses and performance loss among elite athletes during exercise in the heat, and to identify personal, sports-related, and environmental factors that contribute to the magnitude of these outcomes. For this purpose, Dutch Olympic and Paralympic athletes performed two personalized incremental exercise tests in simulated control (15°C, relative humidity (RH) 50%) and Tokyo (32°C, RH 75%) conditions, during which exercise performance and (thermo)physiological parameters were obtained. Thereafter, athletes were invited for an additional visit to conduct anthropometric, dual-energy X-ray absorptiometry (DXA), and 3D scan measurements. Collected data also served as input for a thermophysiological computer simulation model to estimate the impact of a wider range of environmental conditions on thermoregulatory responses. Findings of this study can be used to inform elite athletes and their coaches on how heat impacts their individual (thermo)physiological responses and, based on these data, advise which personalized countermeasures (i.e. heat acclimation, cooling interventions, rehydration plan) can be taken to allow safe and maximal performance in the challenging environmental conditions of the Tokyo 2020 Olympic and Paralympic Games.

Shape-shifting materials are a powerful tool for the fabrication of reconfigurable materials. Upon activation, not only a change in their shape but also a large shift in their material properties can be realized. As compared with the 4D printing of 2D-to-3D shape-shifting materials, the 4D printing of reconfigurable (i.e., 3D-to-3D shape-shifting) materials remains challenging. That is caused by the intrinsically 2D nature of the layer-by-layer manner of fabrication, which limits the possible shape-shifting modes of 4D printed reconfigurable materials. Here, we present a single-step production method for the fabrication and programming of 3D-to-3D shape-changing materials, which requires nothing more than a simple modification of widely available fused deposition modeling (FDM) printers. This simple modification allows the printer to print on curved surfaces. We demonstrate how this modified printer can be combined with various design strategies to achieve high levels of complexity and versatility in the 3D-to-3D shape-shifting behavior of our reconfigurable materials and devices. We showcase the potential of the proposed approach for the fabrication of deployable medical devices including deployable bifurcation stents that are otherwise extremely challenging to create. Shape-shifting structures are important building blocks in the design of reconfigurable materials and devices with advanced functionalities. Here, versatile metamaterials with 3D-to-3D shape-shifting behavior upon thermal activation are fabricated by adapting a 3D printer to print on curved surfaces.

An innovative deicing system for aircraft leading edges has been developed which integrates heater elements into fibre metal laminates. Such an electrical system can lead to weight reductions and more efficient performances compared to conventional bleed air systems. However, the combination of thermal and mechanical loadings also raises new questions on the durability of such a structure, in particular due to the repeated heating to elevated temperature. The linear viscoelastic creep behaviour, including the effects of temperature and ageing, is therefore investigated for manufactured FM906 glass-fibre epoxy composite as used in heated GLARE. A master curve is derived based on the time–temperature and time–age superposition. The effect of physical ageing during loading is included in a long-term creep prediction.

Prolonged exposure to solar radiation can cause considerable heat stress. The application of reflective materials in garments or sunscreens is generally considered as an appropriate protective strategy. In this study, we aimed to compare a range of reflective and control fabrics on their ability to reduce the thermal impact of solar radiation. We evaluated 16 reflective and 5 control fabrics, varying in applicability for garments and/or sunscreens. Transmission of ultraviolet, visible light and infrared radiation was studied using artificial solar light. Thermal impact reduction was first studied using artificial infrared light and secondly using natural sunlight, measuring temperature right at the back and 10 cm behind the fabric after a 10-minute exposure. Most samples showed comparably low radiation transmission (

This paper presents numerical and experimental studies on semi-active seismic response control of structures equipped with variable stiffness and damping structural joints. Such adaptive joints, which are comprised of a shape memory polymer (SMP) core reinforced by an SMP-aramid composite skin, function as load-transfer components as well as semi-active control devices. The SMP core material can transition from a glassy to a rubbery state through thermal actuation resulting in a shift of the structural natural frequencies and a parallel increase of damping ratio, which enables a new semi-active control strategy. Control performance has been evaluated on a three-story frame equipped with 12 adaptive joints and subjected to seismic excitations. Full-transient analysis has shown that when the joints are thermally actuated to the transition temperature (65 degrees C), acceleration and base shear are reduced by up to 62% and 65%, respectively. Shake-table tests have been carried out on a 1/10-scale prototype, confirming that through thermal actuation of the adaptive joints the structural damping ratio increases from 2.6% to 11.3% and the first natural frequency shifts by up to 37%. As the structure becomes more flexible, an increase of displacements and interstory drift might occur. However, depending on the seismic excitation, top-story acceleration and base shear are significantly reduced in the range 43%-50% and 35%-51%, respectively. These results confirm that semi-active control through thermal actuation of variable stiffness and damping structural joints is effective to mitigate the structure response under seismic excitation.

This article presents a novel smart sensor garment with integrated miniaturized inertial measurements units (IMUs) that can be used to monitor lower body kinematics during daily training activities, without the need of extensive technical assistance throughout the measurements. The smart sensor tights enclose five ultra-light sensor modules that measure linear accelerations, angular velocities, and the earth magnetic field in three directions. The modules are located at the pelvis, thighs, and shanks. The garment enables continuous measurement in the field at high sample rates (250 Hz) and the sensors have a large measurement range (32 g, 4,000°/s). They are read out by a central processing unit through an SPI bus, and connected to a centralized battery in the waistband. A fully functioning prototype was built to perform validation studies in a lab setting and in a field setting. In the lab validation study, the IMU data (converted to limb orientation data) were compared with the kinematic data of an optoelectronic measurement system and good validity (CMCs >0.8) was shown. In the field tests, participants experienced the tights as comfortable to wear and they did not feel restricted in their movements. These results show the potential of using the smart sensor tights on a regular base to derive lower limb kinematics in the field.

For sedentary activities, the PMV equation, derived by Fanger, is mainly based on the research of Nevins et al. (720 test subjects). Nevins' experiments were later on repeated by Fanger, but with 128 college-age Danish subjects and 128 elderly Danish subjects, instead of American subjects. Rohles did the research from Nevins et al. again, but over a more extensive temperature range and more, namely 1600, test subjects. Rohles' research results have been partly included in the derivation of the PPD equation, but not in the derivation for the PMV equation. Rohles' experimental results are published at a later time than the publication of the thesis of Fanger. The question arises: ‘If Rohles' experimental results were included in the derivation of the PMV equation, instead of Nevins' experimental results, to what extent does that change the PMV equation and the application area of the PMV equation, with regard of validity, for sedentary activities?'. In the same way, as Fanger described in his thesis, and using the results of Rohles’ experiment, this study is limited to the derivation of a PMV equation with a wider PMV range than −2 to 2, for sedentary activities.

By embedding conductive yarns in, or onto, knitted textile fabrics, simple but robust stretch sensor garments can be manufactured. In that way resistance based sensors can be fully integrated in textiles without compromising wearing comfort, stretchiness, washability, and ease of use in daily life. The many studies on such textile strain sensors that have been published in recent years show that these sensors work in principle, but closer inspection reveals that many of them still have severe practical limitations like a too narrow working range, lack of sensitivity, and undesired time-dependent and hysteresis effects. For those that intend to use this technology it is difficult to determine which manufacturing parameters, shape, stitch type, and materials to apply to realize a functional sensor for a given application. This paper therefore aims to serve as a guideline for the fashion designers, electronic engineers, textile researchers, movement scientists, and human–computer interaction specialists planning to create stretch sensor garments. The paper is limited to textile based sensors that can be constructed using commercially available conductive yarns and existing knitting and embroidery equipment. Within this subtopic, relevant literature is discussed, and a detailed quantitative comparison is provided focusing on sensor characteristics like the gauge factor, working range, and hysteresis.

This paper introduces a new semi-active strategy for vibration control of truss and frame structures equipped with variable stiffness and damping joints which consist of a shape memory polymer (SMP) core reinforced by an SMP-aramid composite skin. When the joints are actuated to the transition temperature through thermal actuation, the SMP core transitions from a glassy to a rubbery state through a viscoelastic region, which causes a stiffness reduction and an increase of damping. The mechanic behavior of the joint can be thought of as transitioning from a moment to a pin connection. This way, it is possible to cause a shift of the structure natural frequencies and to increase damping, which is employed to obtain a significant reduction of the dynamic response. This paper comprises two parts: (1) characterization of a variable stiffness and damping material model through experimental testing; (2) numerical simulations of a truss bridge and a four-story frame, which are equipped with variable stiffness and damping joints. The truss bridge (case A) is subjected to a resonance and a moving load while the four-story frame (case B) is subjected to El Centro earthquake loading. For case A under resonance loading, the dynamic response can be reduced exclusively through a frequency shift and ignoring viscoelastic effects. For case A under moving load and case B under earthquake loading, vibration suppression is mostly caused by the increase of damping due to viscoelastic effects. Control time delays due to joint heating have been included in the analysis. When the joints are actuated to the transition range 55°C–65°C, which is specific to the SMP adopted in this study, the acceleration peak amplitude reduces by up to 95% and 87%, for case A and case B, respectively. For both cases, damping increases by up to 2.2% from undamped conditions (25°C). This work has shown that the adoption of variable stiffness and damping structural joints has great potential to enable a new and effective semi-active control strategy to significantly reduce the structure response under a wide range of dynamic loading conditions.

Voice is a rich modality for conveying emotions, however emotional prosody production can be situationally or medically impaired. Since thermal displays have been shown to evoke emotions, we explore how thermal stimulation can augment perception of neutrally-spoken voice messages with affect. We designed ThermalWear, a wearable on-chest thermal display, then tested in a controlled study (N=12) the effects of fabric, thermal intensity, and direction of change. Thereafter, we synthesized 12 neutrally-spoken voice messages, validated (N=7) them, then tested (N=12) if thermal stimuli can augment their perception with affect. We found warm and cool stimuli (a) can be perceived on the chest, and quickly without fabric (4.7-5s) (b) do not incur discomfort (c) generally increase arousal of voice messages and (d) increase / decrease message valence, respectively. We discuss how thermal displays can augment voice perception, which can enhance voice assistants and support individuals with emotional prosody impairments.

Sweat sensor patches offer new opportunities for unobtrusive monitoring of an athlete’s physical status. This paper presents a novel sweat rate and sweat conductivity patch that is easy to prototype and can be made with common low-cost production techniques: laser cutting and standard printed circuit board (PCB) manufacturing. The device consists of a patch made from hydrophilic PET foil, a double-sided adhesive and a thin PCB with gold electrodes. Two electrodes, which are continuously in contact with the inflowing fluid, measure the sweat conductivity and a separate system with interdigitated electrodes measures the filling process of the reservoirs. Impedance measurement results of both systems demonstrate the working of the concept.

In this paper we propose a new multistep characterisation method to be able to map out the dependency of moisture diffusion parameters of a polymeric material over a range of temperature and humidity conditions in a limited amount of time. We do that by (1) using a moisture sorption analyser which can continuously monitor weight changes with microgram accuracy, (2) using thin samples which speeds up the diffusion process and (3) already switch to the next humidity level at 90 or 95% completion of a diffusion step. A multistep diffusion model was developed to account for the overlapping diffusion steps. This model showed to be extremely accurate for fitting experiments consisting of five absorption and one desorption steps. We show that for temperatures up to 85 °C and humidity level between 0 and 85% RH the diffusion of our material was essentially Fickian with a diffusion coefficient ranging from 3.8 × 10−7 mm2/s at 20 °C to 3.6 × 10−6 mm2/s at 85 °C. The moisture saturation concentrations showed a slightly non-linear variation with the applied humidity level.

A wide variety of electrochemical sweat sensors are recently being developed for real-time monitoring of biomarkers. However, from a physiological perspective, little is known about how sweat biomarkers change over time. This paper presents a method to collect and analyze sweat to identify inter and intraindividual variations of electrolytes during exercise. A new microfluidic sweat collection system is developed which consists of a patch covering the collection surface and a sequence of reservoirs. Na+, Cl- and K+ are measured with ion chromatography afterwards. The measurements show that with the new collector, variations in these ion concentrations can be measured reliably over time.

Alkaline water electrolysis becomes increasingly important for the supply of renewable energy, and of raw material for the chemical industry. An attractive choice for the encapsulation of the electrolyte cell is an (advanced) engineering polymer. The objective of this paper is to find a suitable one that can withstand for many years: 30 wt% KOH solution and pure oxygen at a high pressure of 50 bar and at an elevated temperature of 90°C. Using CES EduPack, 12 possible thermoplastic polymers were selected, of which polyphenylene sulfide (PPS) and polysulfone (PSU) were further investigated using accelerated testing. The polymers have been exposed to three KOH concentrations (15, 30 and 45 wt%), two oxygen pressures (pure O2at 5 bar and air with pO2= 20%), and three temperatures (90°C, 120°C, and 170°C). Extensive characterization of the exposed samples has been carried out using various techniques, including weight, tensile, DMA, and creep-recovery measurements, as well as DSC, FTIR, XRD and SEM. After 12 weeks of aging, glass fiber reinforced PPS failed in a strong alkaline solution at high temperatures, due to the dissolution of the glass fibers. The PPS matrix itself and PSU turned out to be resistant to thermo-oxidative and chemical degradation under the conditions tested. Only marginal changes in mechanical, visco-elastic and thermal behavior were observed, which can be ascribed to physical rather than chemical aging. In view of the brittle nature of PPS, it could be concluded that PSU is the most promising candidate for the long-term application in alkaline electrolysis. Extrapolating the data using time-temperature superposition, it is predicted that PSU will retain its integrity and mechanical properties for a period of 20 years of operation.

Filamentous fungi colonize substrates by forming a mycelium. This network of hyphae can be used as a bio-based material. Here, we assessed the impact of environmental growth conditions and deletion of the hydrophobin gene sc3 on material properties of the mycelium of the mushroom forming fungus Schizophyllum commune. Thermogravimetric analysis showed that Δsc3 mycelium retained more water with increasing temperature when compared to the wild type. The Young’s modulus (E) of the mycelium ranged between 438 and 913 MPa when the wild type strain was grown in the dark or in the light at low or high CO2 levels. This was accompanied by a maximum tensile strength (σ) of 5.1–9.6 MPa. In contrast, E and σ of the Δsc3 strain were 3–4- fold higher with values of 1237–2727 MPa and 15.6–40.4 MPa, respectively. These values correlated with mycelium density, while no differences in chemical composition of the mycelia were observed as shown by ATR-FTIR. Together, genetic modification and environmental growth conditions impact mechanical properties of the mycelium by affecting the density of the mycelium. As a result, mechanical properties of wild type mycelium were similar to those of natural materials, while those of Δsc3 were more similar to thermoplastics.