Search

We present a charge distribution-based emission model that calculates the infrared spectrum of fullerenes (C60). Analysis of the modelled spectrum of C60 in various charge states shows that the relative intensity of the features in the 5–10 μm versus 15–20 μm can be used to probe the C60 charge state in interstellar spectra. We further used our model to simulate emission from polycyclic aromatic hydrocarbons (PAHs) and C60 at five positions in the cavity of reflection nebula NGC 7023. Specifically, we modelled the 6.2/11.2 band ratio for circumcoronene and circumcircumcoronene and the 7.0/19.0 band ratio for C60 as a function of the ionization parameter γ. A comparison of the model results with the observed band ratios shows that the γ values in the cavity do not vary significantly, suggesting that the emission in the cavity does not originate from locations at the projected distances. Furthermore, we find that the C60-derived γ values are lower than the PAH-derived values by an order of magnitude. We discuss likely scenarios for this discrepancy. In one scenario, we attribute the differences in the derived γ values to the uncertainties in the electron recombination rates of PAHs and C60. In the other scenario, we suggest that PAHs and C60 are not co-spatial resulting in different γ values from their respective models. We highlight that experiments to determine necessary rates will be required in validating either one of the scenarios.

22 pags., 8 figs., 1 tab., Massive stars disrupt their natal molecular cloud material through radiative and mechanical feedback processes. These processes have profound effects on the evolution of interstellar matter in our Galaxy and throughout the universe, from the era of vigorous star formation at redshifts of 1-3 to the present day. The dominant feedback processes can be probed by observations of the Photo-Dissociation Regions (PDRs) where the far-ultraviolet photons of massive stars create warm regions of gas and dust in the neutral atomic and molecular gas. PDR emission provides a unique tool to study in detail the physical and chemical processes that are relevant for most of the mass in inter-and circumstellar media including diffuse clouds, proto-planetary disks, and molecular cloud surfaces, globules, planetary nebulae, and star-forming regions. PDR emission dominates the infrared (IR) spectra of star-forming galaxies. Most of the Galactic and extragalactic observations obtained with the James Webb Space Telescope (JWST) will therefore arise in PDR emission. In this paper we present an Early Release Science program using the MIRI, NIRSpec, and NIRCam instruments dedicated to the observations of an emblematic and nearby PDR: the Orion Bar. These early JWST observations will provide template data sets designed to identify key PDR characteristics in JWST observations. These data will serve to benchmark PDR models and extend them into the JWST era. We also present the Science-Enabling products that we will provide to the community. These template data sets and Science-Enabling products will guide the preparation of future proposals on star-forming regions in our Galaxy and beyond and will facilitate data analysis and interpretation of forthcoming JWST observations., Support for JWST-ERS program ID 1288 was provided through grants from the STScI under NASA contract NAS5-03127 to STScI (K.G., D.V.D.P., M.R.), Univ. of Maryland (M.W., M.P.), Univ. of Michigan (E.B., F.A.), and Univ. of Toledo (T.S.-Y.L.). O.B. and E.H. are supported by the Programme National “Physique et Chimie du Milieu Interstellaire” (PCMI) of CNRS/INSU with INC/INP co-funded by CEA and CNES, and through APR grants 6315 and 6410 provided by CNES. E. P. and J.C. acknowledge support from the National Science and Engineering Council of Canada (NSERC) Discovery Grant program (RGPIN-2020-06434 and RGPIN-2021-04197 respectively). E.P. acknowledges support from a Western Strategic Support Accelerator Grant (ROLA ID 0000050636). J.R.G. and S.C. thank the Spanish MCINN for funding support under grant PID2019-106110GB-I00. Work by M.R. and Y.O. is carried out within the Collaborative Research Centre 956, subproject C1, funded by the Deutsche Forschungsgemeinschaft (DFG)—project ID 184018867. T.O. acknowledges support from JSPS Bilateral Program, grant No. 120219939. M.P. and M.W. acknowledge support from NASA Astrophysics Data Analysis Program award #80NSSC19K0573. C.B. is grateful for an appointment at NASA Ames Research Center through the San José State University Research Foundation (NNX17AJ88A) and acknowledges support from the Internal Scientist Funding Model (ISFM) Directed Work Package at NASA Ames titled: “Laboratory Astrophysics—The NASA Ames PAH IR Spectroscopic Database.”

Full list of authors: De Marco, Orsola; Akashi, Muhammad; Akras, Stavros; Alcolea, Javier; Aleman, Isabel; Amram, Philippe; Balick, Bruce; De Beck, Elvire; Blackman, Eric G.; Boffin, Henri M. J.; Boumis, Panos; Bublitz, Jesse; Bucciarelli, Beatrice; Bujarrabal, Valentin; Cami, Jan; Chornay, Nicholas; Chu, You-Hua; Corradi, Romano L. M.; Frank, Adam; García-Hernández, D. A.; García-Rojas, Jorge; García-Segura, Guillermo; Gómez-Llanos, Veronica; Gonçalves, Denise R.; Guerrero, Martín A.; Jones, David; Karakas, Amanda I.; Kastner, Joel H.; Kwok, Sun; Lykou, Foteini; Manchado, Arturo; Matsuura, Mikako; McDonald, Iain; Miszalski, Brent; Mohamed, Shazrene S.; Monreal-Ibero, Ana; Monteiro, Hektor; Montez, Rodolfo; Baez, Paula Moraga; Morisset, Christophe; Nordhaus, Jason; Mendes de Oliveira, Claudia; Osborn, Zara; Otsuka, Masaaki; Parker, Quentin A.; Peeters, Els; Quint, Bruno C.; Quintana-Lacaci, Guillermo; Redman, Matt; Ruiter, Ashley J.; Sabin, Laurence; Sahai, Raghvendra; Contreras, Carmen Sánchez; Santander-García, Miguel; Seitenzahl, Ivo; Soker, Noam; Speck, Angela K.; Stanghellini, Letizia; Steffen, Wolfgang; Toalá, Jesús A.; Ueta, Toshiya; Van de Steene, Griet; Van Winckel, Hans; Ventura, Paolo; Villaver, Eva; Vlemmings, Wouter; Walsh, Jeremy R.; Wesson, Roger; Zijlstra, Albert A., Planetary nebulae—the ejected envelopes of red giant stars—provide us with a history of the last, mass-losing phases of 90% of stars initially more massive than the Sun. Here we analyse images of the planetary nebula NGC 3132 from the James Webb Space Telescope (JWST) Early Release Observations. A structured, extended hydrogen halo surrounding an ionized central bubble is imprinted with spiral structures, probably shaped by a low-mass companion orbiting the central star at about 40–60 au. The images also reveal a mid-infrared excess at the central star, interpreted as a dusty disk, which is indicative of an interaction with another closer companion. Including the previously known A-type visual companion, the progenitor of the NGC 3132 planetary nebula must have been at least a stellar quartet. The JWST images allow us to generate a model of the illumination, ionization and hydrodynamics of the molecular halo, demonstrating the power of JWST to investigate complex stellar outflows. Furthermore, new measurements of the A-type visual companion allow us to derive the value for the mass of the progenitor of a central star with excellent precision: 2.86 ± 0.06 M⊙. These results serve as pathfinders for future JWST observations of planetary nebulae, providing unique insight into fundamental astrophysical processes including colliding winds and binary star interactions, with implications for supernovae and gravitational-wave systems. © 2022, The Author(s), under exclusive licence to Springer Nature Limited., We acknowledge the International Astronomical Union that oversees the work of Commission H3 on Planetary Nebulae. It is through the coordinating activity of this committee that this paper came together. S.A. acknowledges support under the grant 5077 financed by IAASARS/NOA. J.A. and V.B. acknowledge support from the EVENTs/Nebulae-Web research programme, Spanish AEI grant PID2019-105203GB-C21. I.A. acknowledges the support of CAPES, Brazil (Finance Code 001). E.D.B. acknowledges financial support from the Swedish National Space Agency. E.G.B. acknowledges NSF grants AST-1813298 and PHY-2020249. J.C. and E.P. acknowledge support from an NSERC Discovery Grant. G.G.-S. thanks M. L. Norman and the Laboratory for Computational Astrophysics for the use of ZEUS-3D. D.A.G.-H. and A.M. acknowledge support from the ACIISI, Gobierno de Canarias and the European Regional Development Fund (ERDF) under grant with reference PROID2020010051 as well as from the State Research Agency (AEI) of the Spanish Ministry of Science and Innovation (MICINN) under grant PID2020-115758GB-I00. J.G.-R. acknowledges support from Spanish AEI under Severo Ochoa Centres of Excellence Programme 2020-2023 (CEX2019-000920-S). J.G.-R. and V.G.-L. acknowledge support from ACIISI and ERDF under grant ProID2021010074. D.R.G. acknowledges the CNPq grant 313016/2020-8. M.A.G. acknowledges support of grant PGC2018-102184-B-I00 of the Ministerio de Educación, Innovación y Universidades cofunded with FEDER funds and from the State Agency for Research of the Spanish MCIU through the ‘Center of Excellence Severo Ochoa’ award to the Instituto de Astrofísica de Andalucía (SEV-2017-0709). D.J. acknowledges support from the Erasmus+ programme of the European Union under grant number 2020-1-CZ01-KA203-078200. A.I.K. and Z.O. were supported by the Australian Research Council Centre of Excellence for All Sky Astrophysics in 3 Dimensions (ASTRO 3D), through project number CE170100013. This research is/was supported by an Australian Government Research Training Program (RTP) Scholarship. M.M. and R.W. acknowledge support from STFC Consolidated grant (2422911). C.M. acknowledges support from UNAM/DGAPA/PAPIIT under grant IN101220. S.S.M. acknowledges funding from UMiami, the South African National Research Foundation and the University of Cape Town VC2030 Future Leaders Award. J.N. acknowledges support from NSF grant AST-2009713. C.M.d.O. acknowledges funding from FAPESP through projects 2017/50277-0, 2019/11910-4 e 2019/26492-3 and CNPq, process number 309209/2019-6. J.H.K. and P.M.B. acknowledge support from NSF grant AST-2206033 and a NRAO Student Observing Support grant to Rochester Institute of Technology. M.O. was supported by JSPS Grants-in-Aid for Scientific Research(C) (JP19K03914 and 22K03675). Q.A.P. acknowledges support from the HKSAR Research grants council. Vera C. Rubin Observatory is a Federal project jointly funded by the National Science Foundation (NSF) and the Department of Energy (DOE) Office of Science, with early construction funding received from private donations through the LSST Corporation. The NSF-funded LSST (now Rubin Observatory) Project Office for construction was established as an operating centre under the management of the Association of Universities for Research in Astronomy (AURA). The DOE-funded effort to build the Rubin Observatory LSST Camera (LSSTCam) is managed by SLAC National Accelerator Laboratory (SLAC). A.J.R. was supported by the Australian Research Council through award number FT170100243. L.S. acknowledges support from PAPIIT UNAM grant IN110122. C.S.C.’s work is part of I+D+i project PID2019-105203GB-C22 funded by the Spanish MCIN/AEI/10.13039/501100011033. M.S.-G. acknowledges support by the Spanish Ministry of Science and Innovation (MICINN) through projects AxIN (grant AYA2016-78994-P) and EVENTs/Nebulae-Web (grant PID2019-105203GB-C21). R.S.’s contribution to the research described here was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with NASA. J.A.T. thanks the Marcos Moshisnky Fundation (Mexico) and UNAM PAPIIT project IA101622. E.V. acknowledges support from the ‘On the rocks II project’ funded by the Spanish Ministerio de Ciencia, Innovación y Universidades under grant PGC2018-101950-B-I00. A.A.Z. acknowledges support from STFC under grant ST/T000414/1. This research made use of Photutils, an Astropy package for detection and photometry of astronomical sources83, of the Spanish Virtual Observatory (https://svo.cab.inta-csic.es) project funded by MCIN/AEI/10.13039/501100011033/ through grant PID2020-112949GB-I00 and of the computing facilities available at the Laboratory of Computational Astrophysics of the Universidade Federal de Itajubá (LAC-UNIFEI, which is maintained with grants from CAPES, CNPq and FAPEMIG).

We carried out a principal component analysis (PCA) of the fluxes of five polycyclic aromatic hydrocarbon (PAH) bands at 6.2, 7.7, 8.6, 11.0, and 11.2 $\mu$m in the reflection nebula NGC 7023 comprising of the photodissociation region (PDR) and a cavity. We find that only two principal components (PCs) are required to explain the majority of the observed variance in PAH fluxes (98 %). The first PC ($PC_{1}$), which is the primary driver of the variance, represents the total PAH emission. The second PC ($PC_{2}$) is related to the ionization state of PAHs across the nebula. This is consistent with the results of a similar analysis of the PAH emission in NGC 2023. The biplots and the correlations of PCs with the various PAH ratios show that there are two subsets of ionic bands with the 6.2 and 7.7 $\mu$m bands forming one subset and the 8.6 and 11.0 $\mu$m bands the other. However, the distinction between these subsets is only present in the PDR. We have also carried out a separate PCA analysis of the PAH fluxes, this time only considering variations in the cavity. This shows that in the cavity, $PC_{2}$ is not related to the charge state of PAHs, but possibly to structural molecular changes., Comment: 15 pages, 12 figures, accepted for publication in MNRAS

Several diffuse interstellar bands (DIBs) have profiles with resolved sub-peaks that resemble rotational bands of large molecules. Analysis of these profiles can constrain the sizes and geometries of the DIB carriers, especially if the profiles exhibit clear variations along lines of sight probing different physical conditions. Using the extensive data set from the EDIBLES survey we searched for systematic variations in the peak-to-peak separation of these sub-peaks for the $\lambda\lambda$5797, 6379, and 6614 DIBs in lines of sight with a single dominant interstellar cloud. We used the spectra of twelve single-cloud sight lines to measure the peak-to-peak separation in the band profile substructures for these DIBs. We adopted the rotational contour formalism to infer the rotational constant for each DIB carrier and the rotational excitation temperature in the sight lines. We compared these to rotational constants for linear and spherical molecules to estimate the DIB carrier sizes. All three DIBs have peak separations that vary systematically between lines of sight, indicating correlated changes in the rotational excitation temperatures. We derived $B_{6614}$=$(22.2\pm8.9)\times 10^{-3}$ cm$^{-1}$, consistent with previous estimates. Assuming a similar rotational temperature for the $\lambda$6614 DIB carrier and assuming a linear carrier, we found B$_{5797}^{\rm linear}=(5.1\pm2.0)\times10^{-3}~{\rm cm}^{-1}$ and B$_{6379}^{\rm linear} =(2.3\pm0.9)\times10^{-3}~{\rm cm}^{-1}$. If the carriers of those DIBs however are spherical species, their rotational constants are half that value, $B_{5797}^{\rm spherical} = (2.6\pm1.0)\times10^{-3}~{\rm cm}^{-1}$ and $B_{6379}^{\rm spherical} = (1.1\pm0.4)\times10^{-3}~{\rm cm}^{-1}$. We estimate molecule sizes that range from 7--9 carbon atoms ($\lambda$6614 carrier, linear) to 77--114 carbon atoms ($\lambda$6379, spherical)., Comment: 21 pages, 56 figures. Accepted for publication in Astronomy & Astrophysics

We present a charge distribution based model that computes the infrared spectrum of polycyclic aromatic hydrocarbon (PAH) molecules using recent measurements or quantum chemical calculations of specific PAHs. The model is applied to a sample of well-studied photodissociation regions (PDRs) with well-determined physical conditions (the radiation field strength, $G_{0}$, electron density $n_{e}$, and the gas temperature, $T_{\rm gas}$). Specifically, we modelled the emission of five PAHs ranging in size from 18 to 96 carbon atoms, over a range of physical conditions characterized by the ionization parameter $\gamma = G_{0}\times T_{\rm gas}^{1/2}/n_{e}$. The anions emerge as the dominant charge carriers in low $\gamma $ ($< 2\times 10^{2}$) environments, neutrals in the intermediate $\gamma$ ($10^{3} - 10^{4}$) environments, and cations in the high $\gamma$ ($ > 10^{5}$) environments. Furthermore, the PAH anions and cations exhibit similar spectral characteristics. The similarity in the cationic and anionic spectra translates into the interpretation of the 6.2/(11.0+11.2) band ratio, with high values of this ratio associated with large contributions from either cations or anions. The model's predicted values of 6.2/(11.0+11.2) and 3.3/6.2 compared well to the observations in the PDRs NGC 7023, NGC 2023, the horsehead nebula, the Orion bar, and the diffuse ISM, demonstrating that changes in the charge state can account for the variations in the observed PAH emission. We also reassess the diagnostic potential of the 6.2/(11.0+11.2) vs 3.3/(11.0+11.2) ratios and show that without any prior knowledge about $\gamma$, the 3.3/(11.0+11.2) can predict the PAH size, but the 6.2/(11.0+11.2) cannot predict the $\gamma$ of the astrophysical environment., Comment: 27 pages, 24 figures, Accepted for publication in MNRAS

We report the first spectroscopic observations of a background star seen through the region between the ionization front and the dissociation front of the nebula IC 63. This photodissociation region (PDR) exhibits intense extended red emission (ERE) attributed to fluorescence by large molecules/ions. We detected strong diffuse interstellar bands (DIB) in the stellar spectrum, including an exceptionally strong and broad DIB at $\lambda$4428. The detection of strong DIBs in association with ERE could be consistent with the suggestion that the carriers of DIBs and ERE are identical. The likely ERE process is recurrent fluorescence, enabled by inverse internal conversions from highly excited vibrational levels of the ground state to low-lying electronic states with subsequent transitions to ground. This provides a path to rapid radiative cooling for molecules/molecular ions, greatly enhancing their ability to survive in a strongly irradiated environment. The ratio of the equivalent widths (EW) of DIBs $\lambda$5797 and $\lambda$5780 in IC 63 is the same as that observed in the low-density interstellar medium with UV interstellar radiation fields (ISRF) weaker by at least two orders of magnitude. This falsifies suggestions that the ratio of these two DIBs can serve as a measure of the UV strength of the ISRF. Observations of the nebular spectrum of the PDR of IC 63 at locations immediately adjacent to where DIBs were detected failed to reveal any presence of sharp emission features seen in the spectrum of the Red Rectangle nebula. This casts doubts upon proposals that the carriers of these features are the same as those of DIBs seen at slightly shorter wavelengths., Comment: 13 pages, 9 figures

We report a computational study of the stability and infrared (IR) vibrational spectra of neutral and singly ionised fullerene cages containing between 44 and 70 carbon atoms. The stability is characterised in terms of the standard enthalpy of formation per CC bond, the HOMO-LUMO gap, and the energy required to eliminate a C$_2$ fragment. We compare the simulated IR spectra of these fullerene species to the observed emission spectra of several planetary nebulae (Tc 1, SMP SMC 16, and SMP LMC 56) where strong C$_{60}$ emission has been detected. Although we could not conclusively identify fullerenes other than C$_{60}$ and C$_{70}$, our results point to the possible presence of smaller (44, 50, and 56-atom) cages in those astronomical objects. Observational confirmation of our prediction should become possible when the James Webb Space Telescope comes online., 11 pages, 13 figures, 1 table. Accepted for publication on MNRAS

The Diffuse Interstellar Bands (DIBs) are absorption features seen in the spectra of astronomical objects, that arise in the interstellar medium. Today more than 500 DIBs have been observed mostly in the optical and near-infrared wavelengths. The origin of the DIBs are unclear; only ionized buckminsterfullerene C$_{60}^+$ has been identified as a viable candidate for two strong and three weaker DIBs. In this study, we investigate the correlations between the strengths of the two strongest C$_{60}^+$ DIBs as well as their environmental behaviour. Therefore, we analysed measurements of the strengths of the two C$_{60}^+$ DIBs at 9577 and 9633 $\r{A}$ for 26 lines of sight. We used two different methods, including Monte Carlo simulations, to study their correlations and the influence of measurement errors on the correlation coefficients. Furthermore, we examined how the strength of the C$_{60}^+$ DIBs changes as a result of different environmental conditions, as measured by the concentration of H/H$_2$ and the strength of the ambient UV radiation. In contrast to results recently reported by Galazutdinov et al. (2021), we find a high correlation between the strengths of the C$_{60}^+$ DIBs. We also discovered that the behaviour of the correlated C$_{60}^+$ bands is quite distinct from other DIBs at 5780, 5797 and 6203 $\r{A}$ in different environments., Comment: 6 pages, 3 figures, 2 tables. Accepted for publication in A&A Letters

We report new spectroscopic observations of the magnetic Of?p star HD 148937 obtained since 2015 that differ qualitatively from its extensive historical record of weak, periodic spectral variations. This remarkable behaviour represents clear evidence for an unprecedented change in the character of variability of the star. In this paper we describe the new spectral properties and compare them to the previous line profiles. Based on measurements of the radial velocities of the C iii/N iii} emission lines near 4640 \AA\ and the C iv absorption lines near 5800 \AA, we infer that HD 148937 is likely a high-mass, double-lined spectroscopic binary. Combining the spectroscopic orbit with an archival interferometric measurement of the apparent separation of the equal-brightness components, we tentatively conclude that HD 148937 consists of two O-type stars with masses of approximately 34 and $49~M_\odot$, orbiting in an eccentric ($e=0.75$), long-period ($P_{\rm orb}\sim 26$ y) orbit. We discuss the potential relationship of the binary system to the peculiar properties of HD 148937, and propose future observations to refine the orbital and stellar properties., Comment: 12 pages, accepted by MNRAS

Helium has a unique phase diagram and below 25 bar it does not form a solid even at the lowest temperatures. Electrostriction leads to the formation of a solid layer of helium around charged impurities at much lower pressures in liquid and superfluid helium. These so-called ‘Atkins snowballs' have been investigated for several simple ions. Here we form HenC60+ complexes with n exceeding 100 via electron ionization of helium nanodroplets doped with C60. Photofragmentation of these complexes is measured by merging a tunable narrow-bandwidth laser beam with the ions. A switch from red- to blueshift of the absorption frequency of HenC60+ on addition of He atoms at n=32 is associated with a phase transition in the attached helium layer from solid to partly liquid (melting of the Atkins snowball). Elaborate molecular dynamics simulations using a realistic force field and including quantum effects support this interpretation., 'Atkins snowballs', solid layers of helium around an ion core in bulk superfluid He, have been investigated for simple ions but many properties remain unknown. Here, the authors show via photofragmentation experiments that a phase transition occurs in C60-doped He droplets depending on the number of He atoms.

We performed a detailed spectroscopic analysis of the fullerene C60-containing planetary nebula (PN) Lin49 in the Small Magellanic Cloud (SMC). Lin49 is a C-rich and metal-deficient PN (Z~0.0006) and its nebular abundances are in agreement with the AGB model for the initially 1.25 M⊙ stars with the metallicity Z = 0.001. By stellar absorption fitting with TLUSTY, we derived stellar abundances, effective temperature, and surface gravity. We constructed the photoionization model with CLOUDY in order to investigate physical conditions of Lin49. The model with the 0.005-0.1 μm radius graphite and a constant hydrogen density shell could not fit the ~1-5 μm spectral energy distribution (SED) owing to the strong near-IR excess. We propose that the near-IR excess indicates (1) the presence of extremely small carbon molecules or (2) the presence of high-density structure surrounding the central star.

The astronomical emission features, formerly known as the unidentified infrared bands, are now commonly ascribed to polycyclic aromatic hydrocarbons (PAHs). The laboratory experiments and computational modeling performed at NASA Ames Research Center generated a collection of PAH IR spectra that have been used to test and refine the PAH model. These data have been assembled into the NASA Ames PAH IR Spectroscopic Database (PAHdb). PAHdb’s library of computed spectra, currently at version 3.20, contains data on more than 4000 species and the library of laboratory-measured spectra, currently at version 3.00, contains data on 84 species. The spectra can be perused and are available for download at www.astrochemistry.org/pahdb/. This paper introduces the library of laboratory-measured spectra. Although it has been part of PAHdb since its inception, the library of laboratory-measured spectra lacked a proper description in the literature. Here, the experimental methods used to obtain the data are described in detail, an overview of the contents of the experimental library is given, and specific tools developed to analyze and interpret astronomical spectra with the laboratory data are discussed. In addition, updates to the website, documentation and software tools since our last reporting are presented. Software tools to work with the spectroscopic libraries are being developed actively and are available at GitHub. Lastly, a comprehensive demonstration showing how the laboratory-measured data can be applied to explore absorption features in observations toward embedded sources is presented. This demonstration suggests that PAHs very likely contribute to interstellar absorption spectra associated with dense clouds and underscores the need for further IR spectroscopic studies of PAHs trapped in water ice.

We report cosmic ray ionization rates toward ten reddened stars studied within the framework of the EDIBLES (ESO Diffuse Interstellar Bands Large Exploration Survey) program, using the VLT-UVES. For each sightline, between two and ten individual rotational lines of OH+ have been detected in its (0,0) and (1,0) A3Π − X3Σ− electronic band system. This allows constraining of OH+ column densities toward different objects. Results are also presented for 28 additional sightlines for which only one or rather weak signals are found. An analysis of these data makes it possible to derive the primary cosmic ray ionization rate ζp in the targeted diffuse interstellar clouds. For the ten selected targets, we obtain a range of values for ζp equal to (3.9–16.4) × 10−16 s−1. These values are higher than the numbers derived in previous detections of interstellar OH+ in the far-infrared/submillimeter-wave regions and in other near-ultraviolet studies. This difference is a result of using new OH+ oscillator strength values and a more complete picture of all relevant OH+ formation and destruction routes (including the effect of proton recombinations on PAHs), and the relatively high N(OH+) seen toward those ten targets.

We present a detailed analysis of deep VLT/X-Shooter observations of the planetary nebula Tc 1. We calculate gas temperature, density, extinction, and abundances for several species from the empirical analysis of the total line fluxes. In addition, a spatially resolved analysis of the most intense lines provides the distribution of such quantities across the nebula. The new data reveal that several lines exhibit a double peak spectral profile consistent with the blue- and red-shifted components of an expanding spherical shell. The study of such components allowed us to construct for the first time a three-dimensional morphological model, which reveals that Tc 1 is a slightly elongated spheroid with an equatorial density enhancement seen almost pole on. A few bright lines present extended wings (with velocities up to a few hundred km/s), but the mechanism producing them is not clear. We constructed photoionization models for the main shell of Tc 1. The models predict the central star temperature and luminosity, as well as the nebular density and abundances similar to previous studies. Our models indicate that Tc 1 is located at a distance of approximately 2 kpc. We report the first detection of the [Kr III] 6825 A emission line, from which we determine the Krypton abundance. Our model indicates that the main shell of Tc 1 is matter bounded; leaking H ionizing photons may explain the ionization of its faint AGB-remnant halo., Comment: Accepted for publication in MNRAS. 27 pages, 20 figures

Recent advances in laboratory spectroscopy lead to the claim of ionized Buckminsterfullerene (C60+) as the carrier of two diffuse interstellar bands (DIBs) in the near-infrared. However, irrefutable identification of interstellar C60+ requires a match between the wavelengths and the expected strengths of all absorption features detectable in the laboratory and in space. Here we present Hubble Space Telescope (HST) spectra of the region covering the C60+ 9348, 9365, 9428 and 9577 {\AA} absorption bands toward seven heavily-reddened stars. We focus in particular on searching for the weaker laboratory C60+ bands, the very presence of which has been a matter for recent debate. Using the novel STIS-scanning technique to obtain ultra-high signal-to-noise spectra without contamination from telluric absorption that afflicted previous ground-based observations, we obtained reliable detections of the (weak) 9365, 9428 {\AA} and (strong) 9577 {\AA} C60+ bands. The band wavelengths and strength ratios are sufficiently similar to those determined in the latest laboratory experiments that we consider this the first robust identification of the 9428 {\AA} band, and a conclusive confirmation of interstellar C60+., Comment: Published in ApJ Letters, April 2019, 875, L28

We present the highest resolution single-dish submillimetre observations of the detached shell source U Antliae to date. The observations were obtained at $450~\micron$ and $850~\micron$ with SCUBA-2 instrument on the James Clerk Maxwell Telescope as part of the Nearby Evolved Stars Survey. The emission at $850~\micron$ peaks at $40\arcsec$ with hints of a second peak seen at $\sim 20\arcsec$. The emission can be traced out to a radius of $56\arcsec$ at a $3\sigma$ level. The outer peak observed at $850~\micron$ aligns well with the peak observed at Herschel/PACS wavelengths. With the help of spectral energy distribution fitting and radiative transfer calculations of multiple-shell models for the circumstellar envelope, we explore the various shell structures and the variation of grain sizes along the in the circumstellar envelope. We determine a total shell dust mass of $(2.0 \pm 0.3) \times 10^{-5}$ M$_{\odot}$ and established that the thermal pulse which gave rise to the detached shell occurred 3500 $\pm$ 500 years ago., Comment: Accepted for publication in MNRAS

Emission bands from polycyclic aromatic hydrocarbons (PAHs) dominate the mid-infrared spectra of a wide variety of astronomical sources, encompassing nearly all stages of stellar evolution. Despite their similarities, details in band positions and shapes have allowed a classification of PAH emission to be developed. It has been suggested that this classification is in turn associated with the degree of photoprocessing of PAHs. Over the past decade, a more complete picture of the PAH interstellar life-cycle has emerged, in which a wide range of PAH species are formed during the later stages of stellar evolution. After this they are photoprocessed, increasing the relative abundance of the more stable (typically larger and compact) PAHs. For this work we have tested the effect of the symmetry, size, and structure of PAHs on their fragmentation pattern and infrared spectra by combining experiments at the free electron laser for infrared experiments (FELIX) and quantum chemical computations. Applying this approach to the cations of four molecular species, perylene (C20H12), peropyrene (C26H14), ovalene (C32H14) and isoviolanthrene (C34H18), we find that a reduction of molecular symmetry causes the activation of vibrational modes in the 7–9 μm range. We show that the IR characteristics of less symmetric PAHs can help explain the broad band observed in the class D spectra, which are typically associated with a low degree of photoprocessing. Such large, nonsymmetrical irregular PAHs are currently largely missing from the NASA Ames PAH database. The band positions and shapes of the largest more symmetric PAH measured here, show the best resemblance with class A and B sources, representative of regions with high radiation fields and thus heavier photoprocessing. Furthermore, the dissociation patterns observed in the mass spectra hint to an enhanced stability of the carbon skeleton in more symmetric PAHs with respect to the irregular and less symmetric species, which tend to loose carbon containing units. Although not a direct proof, these findings are fully in line with the grandPAH hypothesis, which claims that symmetric large PAHs can survive as the radiation field increases, while their less symmetric counterparts are destroyed or converted to symmetric PAHs.

We present JCMT SCUBA-2 $450\mu$m and $850\mu$m observations of 14 Asymptotic Giant Branch (AGB) stars (9 O--rich, 4 C-rich and 1 S--type) and one Red Supergiant (RSG) in the Solar Neighbourhood. We combine these observations with \emph{Herschel}/PACS observations at $70\mu$m and $160\mu$m and obtain azimuthally-averaged surface-brightness profiles and their PSF subtracted residuals. The extent of the SCUBA-2 850 $\mu$m emission ranges from 0.01 to 0.16 pc with an average of $\sim40\%$ of the total flux being emitted from the extended component. By fitting a modified black-body to the four-point SED at each point along the radial profile we derive the temperature ($T$), spectral index of dust emissivity ($\beta$) and dust column density ($\Sigma$) as a function of radius. For all the sources, the density profile deviates significantly from what is expected for a constant mass-loss rate, showing that all the sources have undergone variations in mass-loss during this evolutionary phase. In combination with results from CO line emission, we determined the dust-to-gas mass ratio for all the sources in our sample. We find that, when sources are grouped according to their chemistry, the resulting average dust-to-gas ratios are consistent with the respective canonical values. However we see a range of values with significant scatter which indicate the importance of including spatial information when deriving these numbers., Comment: 18 pages plus 13 pages of supplementary figures. Accepted for publication on MNRAS on 24/05/2018. Updated 05/07/2018: Fixed secondary axes (pc axes) on Radial Profiles in all figures

We examine polycyclic aromatic hydrocarbon (PAH), dust and atomic/molecular emission toward the Galactic bulge using Spitzer Space Telescope observations of four fields: C32, C35, OGLE and NGC 6522. These fields are approximately centered on (l, b) = (0.0{\deg}, 1.0{\deg}), (0.0{\deg}, -1.0{\deg}), (0.4{\deg}, -2.1{\deg}) and (1.0{\deg}, -3.8{\deg}), respectively. Far-infrared photometric observations complement the Spitzer/IRS spectroscopic data and are used to construct spectral energy distributions. We find that the dust and PAH emission are exceptionally similar between C32 and C35 overall, in part explained due to their locations---they reside on or near boundaries of a 7 Myr-old Galactic outflow event and are partly shock-heated. Within the C32 and C35 fields, we identify a region of elevated H{\alpha} emission that is coincident with elevated fine-structure and [O IV] line emission and weak PAH feature strengths. We are likely tracing a transition zone of the outflow into the nascent environment. PAH abundances in these fields are slightly depressed relative to typical ISM values. In the OGLE and NGC 6522 fields, we observe weak features on a continuum dominated by zodiacal dust. SED fitting indicates that thermal dust grains in C32 and C35 have comparable temperatures to those of diffuse, high-latitude cirrus clouds. Little variability is detected in the PAH properties between C32 and C35, indicating that a stable population of PAHs dominates the overall spectral appearance. In fact, their PAH features are exceptionally similar to that of the M82 superwind, emphasizing that we are probing a local Galactic wind environment., Comment: Accepted for publication in the Astrophysical Journal

Gas phase spectroscopic laboratory experiments for the buckminsterfullerene cation C60+ have resulted in accurate rest wavelengths for five C60+ transitions that have been compared with diffuse interstellar bands (DIBs) in the near infra-red. Detecting these in astronomical spectra is difficult because of the strong contamination of ground-based spectra by atmospheric water vapor, to the presence of weak and shallow stellar lines and/or blending with other weak DIBs. The detection of the two strong bands has been claimed by several teams, and the three additional and weaker bands have been detected in a few sources. Certain recent papers have argued against the identification of C60+ based on spectral analyses claiming (i) a large variation in the ratio of the equivalent widths of the 9632 and 9577 Å bands, (ii) a large redshift of the 9632 Å band for the Orion star HD 37022, and (iii) the non-detection of the weaker 9428 Å DIB. Here we address these three points: (i) We show that the model stellar line correction for the 9632 Å DIB overestimates the difference between the strengths of the lines in giant and dwarf star spectra, casting doubts on the conclusions about the ratio variability. (ii) Using high quality stellar spectra from the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES), recorded with the ESO/Paranal Ultraviolet Echelle Spectrograph (UVES) in about the same atmospheric conditions, we find no wavelength shift in the 9632 Å band toward HD 37022. (iii) Using EDIBLES spectra and data from the Echelle SpectroPolarimetric Device for the Observation of Stars (ESPaDOnS) at CFHT we show that the presence of a weak 9428 Å band cannot be ruled out, even in the same observations that a previous study claimed it was not present.

The carriers of the diffuse interstellar bands (DIBs) are largely unidentified molecules ubiquitously present in the interstellar medium (ISM). After decades of study, two strong and possibly three weak near-infrared DIBs have recently been attributed to the C60+ fullerene based on observational and laboratory measurements. There is great promise for the identification of the over 400 other known DIBs, as this result could provide chemical hints towards other possible carriers. In an effort to systematically study the properties of the DIB carriers, we have initiated a new large-scale observational survey: the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES). The main objective is to build on and extend existing DIB surveys to make a major step forward in characterising the physical and chemical conditions for a statistically significant sample of interstellar lines-of-sight, with the goal to reverse-engineer key molecular properties of the DIB carriers. EDIBLES is a filler Large Programme using the Ultraviolet and Visual Echelle Spectrograph at the Very Large Telescope at Paranal, Chile. It is designed to provide an observationally unbiased view of the presence and behaviour of the DIBs towards early-spectral-type stars whose lines-of-sight probe the diffuse-to-translucent ISM. Such a complete dataset will provide a deep census of the atomic and molecular content, physical conditions, chemical abundances and elemental depletion levels for each sightline. Achieving these goals requires a homogeneous set of high-quality data in terms of resolution (R ~ 70000 -- 100000), sensitivity (S/N up to 1000 per resolution element), and spectral coverage (305--1042 nm), as well as a large sample size (100+ sightlines). In this first paper the goals, objectives and methodology of the EDIBLES programme are described and an initial assessment of the data is provided., 29 pages (including 14 pages appendix), 15 figures, accepted by A&A

We present a principal component analysis of 23 line of sight parameters (including the strengths of 16 diffuse interstellar bands, DIBs) for a well-chosen sample of single-cloud sightlines representing a broad range of environmental conditions. Our analysis indicates that the majority ($\sim$93\%) of the variations in the measurements can be captured by only four parameters The main driver (i.e., the first principal component) is the amount of DIB-producing material in the line of sight, a quantity that is extremely well traced by the equivalent width of the $\lambda$5797 DIB. The second principal component is the amount of UV radiation, which correlates well with the $\lambda$5797/$\lambda$5780 DIB strength ratio. The remaining two principal components are more difficult to interpret, but are likely related to the properties of dust in the line of sight (e.g., the gas-to-dust ratio). With our PCA results, the DIBs can then be used to estimate these line of sight parameters., Comment: 29 pages, 17 figures; accepted for publication in The Astrophysical Journal

In 2019 it was exactly 100 years ago that the first two DIBs, diffuse interstellar bands, were discovered by Mary Lea Heger. Today some 500 + DIBs are known. In numerous observational, modelling and laboratory studies, efforts have been made to identify the carriers of these absorption features that are observed in the light of reddened stars crossing diffuse and translucent clouds. Despite several claims over the years that specific DIBs could be assigned to specific species, not one of these withstood dedicated follow-up studies. An exception is C 60 + . In 2015, Campbell et al. showed that two strong bands, recorded in the laboratory around 960 nm, coincided precisely with known DIBs and in follow-up studies three more matches between C 60 + transitions and new observational DIB studies were claimed. Over the last four years the evidence for C 60 + as the first identified DIB carrier – including new laboratory data and Hubble Space Telescope observations – has been accumulating, but not all open issues have been solved yet. This article summarizes 6 spectroscopic achievements that sequentially contributed to what seems to become the first DIB story with a happy end.

We have selected a homogeneous sample of asymptotic giant branch (AGB) stars in the Galactic bulge population from the ISOGAL survey. Our target stars cover a wide range of mass-loss rates (∼10−8-10−4 M⊙ yr−1) and differ primarily by their age on the AGB. This homogeneous sample is thus ideally suited to study the dust formation process as a function of age on the AGB. We observed our sample with Spitzer-Infrared Spectrograph, and studied the overall properties of the infrared spectra of these targets. The analysis is complicated by the presence of strong and variable background emission, and the extracted infrared AGB star spectra are affected by interstellar extinction. Several stars in our sample have no detectable dust emission, and we used these ‘naked stars’ to characterize the stellar and molecular contributions to the infrared spectra of our target stars. The resulting dust spectra of our targets do indeed show significant variety in their spectral appearance, pointing to differing dust compositions for the targets. We classify the spectra based on the shape of their 10-μm emission following the scheme by Sloan & Price. We find that the early silicate emission classes associated with oxide dust are generally under-represented in our sample due to extinction effects. We also find a weak 13-μm dust feature in two of our otherwise naked star spectra, suggesting that the carrier of this feature could potentially be the first condensate in the sequence of dust condensation.

Establishing the stability of cosmic fullerenes and fullerenic aggregates is extremely relevant for a variety of reasons. For instance, the emission features of C60 and C70 fall in the same spectral region as the Un-identified InfraRed (UIR) bands, which they could contribute to. To be able to contribute to the UIR emission, however, fullerenes must be able to survive long enough against the destruction mechanisms operating in the interstellar medium. In this study we focus on the effects of collisional processing, i.e., the bombardment by energetic ions and electrons. A recent experimental/theoretical study has shown that ion collisions with C60 clusters result in the dissociation of the cluster with the simultaneous formation of covalent fullerene dimers, which could play a role as DIBs carriers. We present here our first results about the collisional processing of C60 molecules and clusters by H, He and C ions in interstellar shocks. We have adapted the models that have previously been developed to successfully treat the collisional processing of PAHs in space. The nature of the interaction and the similarities between PAHs and fullerenes make this approach appropriate. In addition, our study shows that the formation of covalent dimers following ion collisions with C60 clusters is compatible with the astrophysical conditions under consideration.

We recently identified several emission bands in the Spitzer-IRS spectrum of the unusual planetary nebula Tc 1 with the infrared active vibrational modes of the neutral fullerene species C60 and C70. Since then, the fullerene bands have been detected in a variety of sources representing circumstellar and interstellar environments. Abundance estimates suggest that C60 represents ~0.1%-1.5% of the available carbon in those sources. The observed relative band intensities in various sources are not fully compatible with single-photon heating and fluorescent cooling, and are better reproduced by a thermal distribution at least in some sources. The observational data suggests that fullerenes form in the circumstellar environments of evolved stars, and survive in the interstellar medium. Precisely how they form is still a matter of debate., 12 pages, 5 figures. To appear in the proceedings of IAU symposium 280 "The Molecular Universe"

Polycyclic Aromatic Hydrocarbons (PAHs) are widespread across the Universe and influence many stages of the Galactic lifecycle. The presence of PAHs has been well established and the rich mid-IR PAH spectrum is now commonly used as a probe into (inter)stellar envi- ronments. The NASA Ames PAH IR Spectroscopic Database has been key to test and refine the "PAH hypothesis". This database is a large coherent set (>600 spectra) of laboratory measured and DFT computed infrared spectra of PAHs from C10H8 to C130H28 and has been made available on the web at (http://www.astrochem.org/pahdb). With a new spectral window opening up; the far-IR, the study of PAH far-IR spectra and the quest for identifying a unique member of the interstel- lar PAH family has begun. To guide this research, the far-IR (>20 µm) spectra of different sets of PAHs are investigated using the NASA Ames PAH IR Spectroscopic Database. These sets explore the influence of size, shape, charge and composition on the far-IR PAH spectrum. The far-IR is also the domain of the so-called "drumhead" modes and other molecular vibrations involving low order bending vibrations of the car- bon skeleton as a whole. As with drums, these are molecule and shape specific and promise to be a key diagnostic for specific PAHs. Here, the sensitivity of these "drumhead" modes to size and shape is assessed by comparing the frequencies of the lowest drumhead modes of a family of circular shaped (the coronene "family") and rhombus shaped (the pyrene "family") PAH molecules. From this study, some consequences for an observing strategy are drawn.

We use the NASA Ames Polycyclic Aromatic Hydrocarbon (PAH) infrared spectroscopic database to model infared emission of PAHs following absorption of a UV photon. We calculate emission spectra resulting from the full cooling cascade for each species in the database. Using a least squares approach, we can find out what PAH mixtures best reproduce a few typical astronomical observations representing the different classes of UIR spectra. We find that we can reproduce the observed UIR spectra in the wavelength range 6–14 μ m, offering support for the hypothesis that the UIR bands are indeed due to vibrational modes of PAHs and related molecular species. Spectral decompositions of our best fit models confirm and reinforce several earlier results: (i) the 6.2 μ m band requires a significant contribution of nitrogen-substituted PAHs (PANHs); (ii) the reported components and their variations in the 7.7 μ m band are indicative of changes in the size distribution of the contributing molecules; (iii) there is a significant contribution of anions to the 7.7 μ m band; (iv) the 11.2 μ m band is due to large, neutral and pure PAHs; (v) the 11.0 μ m band is due to large PAH cations.

The so-called C2-DIBs are a class of very weak bands that fall in the blue part of the optical spectrum and are associated with high column densities of the C2 molecule. DIB profile structures constrain potential molecular carriers, but their measurement requires high S/N and spectra and the use of sightlines without Doppler splitting, as typical for a single-cloud situation. Spectra from the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) conducted at the VLT (ESO/Paranal) were explored to identify single-cloud and high C2 column sightlines, extract the corresponding C2-DIBs and study their strengths and profiles, and to investigate in detail any sub-structures. The target selection was made based on profile-fitting of the Sodium doublets and the detection of C2 lines. The C2 (2-0) Phillips system was fitted using a physical model of the host cloud. C2 column densities, temperatures as well as gas densities were derived for each sightline. 18 known C2-DIBs and 8 strong non-C2 DIBs were extracted towards 8 targets, comprising 7 single-cloud and one multi-cloud line-of-sights. Correlational studies revealed a tight association of the former group with the C2 columns, whereas the non-C2 DIBs are primarily correlated with reddening. We report three new weak diffuse band candidates. We show for the first time that at least 14 C2-DIBs exhibit spectral sub-structures which are consistent with unresolved rotational branches of molecular carriers. The variability of their peak separations among the bands for a given sightline implies that their carriers are different molecules with quite different sizes. We also illustrate how profiles of the same DIB vary among targets and as a function of physical parameters and provide tables defining the sub-structures to be compared with future models and experimental results., 19 pages, 15 figures, accepted for publication in A&A

It is well known that the dust properties of the diffuse interstellar medium exhibit variations towards different sight-lines on a large scale. We have investigated the variability of the dust characteristics on a small scale, and from cloud-to-cloud. We use low-resolution spectro-polarimetric data obtained in the context of the Large Interstellar Polarisation Survey (LIPS) towards 59 sight-lines in the Southern Hemisphere, and we fit these data using a dust model composed of silicate and carbon particles with sizes from the molecular to the sub-micrometre domain. Large (> 6 nm) silicates of prolate shape account for the observed polarisation. For 32 sight-lines we complement our data set with UVES archive high-resolution spectra, which enable us to establish the presence of single-cloud or multiple-clouds towards individual sight-lines. We find that the majority of these 35 sight-lines intersect two or more clouds, while eight of them are dominated by a single absorbing cloud. We confirm several correlations between extinction and parameters of the Serkowski law with dust parameters, but we also find previously undetected correlations between these parameters that are valid only in single-cloud sight-lines. We find that interstellar polarisation from multiple-clouds is smaller than from single-cloud sight-lines, showing that the presence of a second or more clouds depolarises the incoming radiation. We find large variations of the dust characteristics from cloud-to-cloud. However, when we average a sufficiently large number of clouds in single-cloud or multiple-cloud sight-lines, we always retrieve similar mean dust parameters. The typical dust abundances of the single-cloud cases are [C]/[H] = 92 ppm and [Si]/[H] = 20 ppm., A&A accepted

We present Spitzer spectra of S stars, which are cool evolved stars with a C/O ratio near unity, some of which have enhanced s-process abundances. We present the detection of a strong and unusual band in themid- infrared, at 13 mu m, within the N-band window. Using quantum-chemically calculated line lists, and model spectra, we identify this band as the fundamental rovibrational band of SiS. Detection of the overtone band at 6.7 mu m confirms the identification. Fitting the line profile shows that the molecule is located in relatively cool layers, at T similar to 1500 K. We discuss these results in the context of chemical equilibrium models. The observed strength of these bands in the cool S stars makes them a promising observational diagnostic tool for studying the atmospheres of brown dwarfs and exoplanets.

We performed a detailed spectroscopic analysis of the fullerene C60-containing planetary nebula (PN) Lin49 in the Small Magellanic Cloud using XSHOOTER at the ESO VLT and the Spitzer/IRS instruments. We derived nebular abundances for nine elements. We used TLUSTY to derive photospheric parameters for the central star. Lin49 is C-rich and metal-deficient PN (Z~0.0006). The nebular abundances are in good agreement with Asymptotic Giant Branch nucleosynthesis models for stars with initial mass 1.25 Msun and metallicity Z = 0.001. Using the TLUSTY synthetic spectrum of the central star to define the heating and ionising source, we constructed the photoionisation model with CLOUDY that matches the observed spectral energy distribution (SED) and the line fluxes in the UV to far-IR wavelength ranges simultaneously. We could not fit the ~1-5 um SED using a model with 0.005-0.1 um-sized graphite grains and a constant hydrogen density shell owing to the prominent near-IR excess, while at other wavelengths the model fits the observed values reasonably well. We argue that the near-IR excess might indicate either (1) the presence of very small particles in the form of small carbon clusters, small graphite sheets, or fullerene precursors, or (2) the presence of a high-density structure surrounding the central star. We found that SMC C60 PNe show a near-IR excess component to lesser or greater degree. This suggests that these C60 PNe might maintain a structure nearby their central star., 24 pages, 17 figures, 17 tables, Accepted for publication by MNRAS

Photodissociation regions (PDRs) contain a large fraction of all of the interstellar matter in galaxies. Classical examples include the boundaries between ionized regions and molecular clouds in regions of massive star formation, marking the point where all of the photons energetic enough to ionize hydrogen have been absorbed. In this paper we determine the physical properties of the PDRs associated with the star forming regions IRAS 23133+6050 and S 106 and present them in the context of other Galactic PDRs associated with massive star forming regions. We employ Herschel PACS and SPIRE spectroscopic observations to construct a full 55-650 ��m spectrum of each object from which we measure the PDR cooling lines, other fine- structure lines, CO lines and the total far-infrared flux. These measurements are then compared to standard PDR models. Subsequently detailed numerical PDR models are compared to these predictions, yielding additional insights into the dominant thermal processes in the PDRs and their structures. We find that the PDRs of each object are very similar, and can be characterized by a two-phase PDR model with a very dense, highly UV irradiated phase (n $\sim$ 10^6 cm^(-3), G$_0$ $\sim$ 10^5) interspersed within a lower density, weaker radiation field phase (n $\sim$ 10^4 cm^(-3), G$_0$ $\sim$ 10^4). We employed two different numerical models to investigate the data, firstly we used RADEX models to fit the peak of the $^{12}$CO ladder, which in conjunction with the properties derived yielded a temperature of around 300 K. Subsequent numerical modeling with a full PDR model revealed that the dense phase has a filling factor of around 0.6 in both objects. The shape of the $^{12}$CO ladder was consistent with these components with heating dominated by grain photoelectric heating. An extra excitation component for the highest J lines (J > 20) is required for S 106., 20 pages, 10 figures, A&A Accepted

We present the first mid-infrared spectra of SMP LMC 11 in the Large Magellanic Cloud. While this object resembles a planetary nebula in the optical, its infrared properties are more similar to an object in transition from the asymptotic giant branch to the planetary nebula phase. A warm dust continuum dominates the infrared spectrum. The peak emission corresponds to a mean dust temperature of 330 K. The spectrum shows overlapping molecular absorption bands from 12 to 17 um corresponding to acetylene and polyacetylenic chains and benzene. This is the first detection of C4H2, C6H2, C6H6 and other molecules in an extragalactic object. The infrared spectrum of SMP LMC 11 is similar in many ways to that of the pre-planetary nebula AFGL 618. The IRS spectrum shows little evidence of nitrogen-based molecules which are commonly seen in Galactic AGB stars. Polycyclic aromatic hydrocarbons are also absent from the spectrum. The detection of the [NeII] 12.8 um line in the infrared and other forbidden emission lines in the optical indicates that an ionized region is present., 5 pages (in emulateapj), 1 table, 2 figures. Accepted for publication in ApJ Letters

The Large Magellanic Cloud (LMC) offers a unique laboratory to study the diffuse interstellar bands (DIBs) under conditions that are profoundly different from those in the Galaxy. DIB carrier abundances depend on several environmental factors, in particular the local UV radiation field. In this paper we present measurements of twelve DIBs in five lines of sight to early-type stars in the LMC, including the 30 Doradus region. From the high resolution spectra obtained with VLT/UVES we also derive environmental parameters that characterise the local interstellar medium (ISM) in the probed LMC clouds. These include the column density components (including total column density) for the atomic resonance lines of Na I, Ca II, Ti II, K I. In addition, we derive the H I column density from 21 cm line profiles, the total-to-selective visual extinction RV and the gas-to-dust ratio N(H I)/A_V. Furthermore, from atomic line ratios we derive the ionisation balance and relative UV field strength in these environments. We discuss the properties of the LMC ISM in the context of DIB carrier formation. The behaviour of DIBs in the LMC is compared to that of DIBs in different local environmental conditions in the Milky Way. A key result is that in most cases the diffuse band strengths are weak (up to factor 5) with respect to Galactic lines of sight of comparable reddening, EB-V. In the line of sight towards Sk -69 223 the 5780 and 5797 �DIBs are very similar in strength and profile to those observed towards HD 144217, which is typical of an environment exposed to a strong

In this paper we study the extended atmosphere of the late-type supergiant Alpha Orionis. Infrared spectroscopy of red supergiants reveals strong molecular bands, some of which do not originate in the photosphere but in a cooler layer of molecular material above it. Lately, these layers have been spatially resolved by near and mid-IR interferometry. In this paper, we try to reconcile the IR interferometric and ISO-SWS spectroscopic results on Alpha Orionis with a thorough modelling of the photosphere, molecular layer(s) and dust shell. From the ISO and near-IR interferometric observations, we find that Alpha Orionis has only a very low density water layer close above the photosphere. However, mid-IR interferometric observations and a narrow-slit N-band spectrum suggest much larger extra-photospheric opacity close to the photosphere at those wavelengths, even when taking into account the detached dust shell. We argue that this cannot be due to the water layer, and that another source of mid-IR opacity must be present. We show that this opacity source is probably neither molecular nor chromospheric. Rather, we present amorphous alumina (Al2O3) as the best candidate and discuss this hypothesis in the framework of dust-condensation scenarios., 15 pages, 18 figures, accepted for publication in A&A

We present a preliminary analysis of a set of optical (3800-8800 Å) high resolution (R = 80,000) spectra for 69 diffuse interstellar band targets. We carried out a sensitive search for interstellar features in the wavelength range 8470-8740 Å that will be covered by the upcoming GAIA mission. We also investigate how the λ8620Å DIB strength varies as a function of other interstellar parameters (other DIBs, E(B-V) and atomic and molecular column densities).

We present the first results of an exploratory VLT/X-Shooter survey of near-infrared diffuse interstellar bands (DIBs) in diffuse to translucent interstellar clouds. These observations confirm the presence of recently discoved NIR DIBs and provide more accurate rest wavelengths and line widths. Example spectra are shown for the reddened, AV ~ 10 mag, line-of-sight towards the distant binary system 4U 1907+09.

We report the detection of strong absorption and weak emission features in the 4-27 μm Spitzer Infrared Spectrograph (IRS) spectrum of the distant ultraluminous infrared galaxy IRAS F00183-7111 (z = 0.327). The absorption features of CO2 and CO gas, water ice, hydrocarbons, and silicates are indicative of a strongly obscured (A9.6 ≥ 5.4; AV ≥ 90) and complex line of sight through both the hot diffuse interstellar medium and shielded cold molecular clouds toward the nuclear power source. From the profile of the 4.67 μm CO fundamental vibration mode, we deduce that the absorbing gas is dense (n ~ 106 cm-3) and warm (720 K) and has a CO column density of ~1019.5 cm-2, equivalent to NH ~ 1023.5 cm-2. The high temperature and density, as well as the small inferred size (

Analysis of high spectral resolution observations of the $\lambda$6614 diffuse interstellar band (DIB) line profile show systematic variations in the positions of the peaks in the substructure of the profile. These variations -- shown here for the first time -- can be understood most naturally in the framework of rotational contours of large molecules, where the variations are caused by changes in the rotational excitation temperature. We show that the rotational excitation temperature for the DIB carrier is likely significantly lower than the gas kinetic temperature -- indicating that for this particular DIB carrier angular momentum buildup is not very efficient., Comment: Accepted by ApJ Letters; 16 pages, 2 figures

We provide direct observational evidence for a link between photospheric activity and perturbations in the dense inner-most stellar wind regions of the B supergiant starOri. The results, which are relevant to our understanding of the origin of wind structure, are based on a multi-spectral line analysis of optical time-series data secured in 1998 using the HEROS spectrograph on the ESO Dutch 0.9-m telescope in La Silla. A period of ∼1.9 days is consistently identified in Balmer, He  absorption, and weak metal lines such as Si  and C . The primary characteristic is a large-amplitude swaying of the central absorption trough of the line, with differential velocities in lines formed at varying depths in the atmosphere. The variance resulting from the "S-wave" velocity behaviour of the lines is constrained within ± the projected rotation velocity (∼80 km s −1 ) in the weakest absorption lines, but extends blue-ward to over −200 km s −1 in Hα. A second (superimposed) 1.9 day signal is present at more extended blue-ward velocities (to ∼−300 km s −1 ) in lines containing stronger circumstellar components. Inspection of archival optical data from 1996 provides evidence that this modulation signal has persisted for at least 2.5 years. Non-radial pulsational modelling is carried out in an attempt to reproduce the key observational characteristics of the line profile variability. Only limited success is obtained with prograde (m = −1) modes. The principal S-wave pattern cannot be matched by these models and remains enigmatic.

We analyse ISO-SWS01 (R ∼ 1500) 12-27.5 μm (band 3) spectra of the 10 standard calibration stars with the highest flux using synthetic spectra generated from (MARCS) atmosphere models. The comparison between the observed and synthetic spectra reveals the quality of (1) the atmospheric model construction and subsequent synthetic spectra computation and of (2) the (OLP 10.1) calibration and data reduction of the spectrometer at these wavelengths. The models represent the general features of the observations, but the synthetic spectrum computation is hampered by the lack of comprehensive molecular and atomic line lists. We also suspect some problems with the temperature distribution in the outer layers of the model and inaccuracies in the extrapolation of the collision-induced absorption coefficients of H 2 pairs. We detect baseline ripples and fringes in the observed spectra, that survive the calibration and detailed reduction process. Photometric calibration uncertainties are estimated by means of the scaling factors between the synthetic and observed spectra.

The composition of ice grains provides an important tool for the study of the molecular environment of star forming regions. Using ISAAC at the VLT to obtain spectra around 4.65 microns we have detected for the first time `XCN' and CO ice in an extragalactic environment: the nuclear region of the nearby dusty starburst/AGN galaxy NGC4945. The profile of the solid CO band reveals the importance of thermal processing of the ice while the prominence of the XCN band attests to the importance of energetic processing of the ice by FUV radiation and/or energetic particles. In analogy to the processing of ices by embedded protostars in our Galaxy, we attribute the processing of the ices in the center of NGC4945 to ongoing massive star formation. Our M-band spectrum also shows strong HI Pfund-beta and H2 0-0 S(9) line emission and gas phase CO absorption lines. The HI, H2, PAH, gas phase CO and the ices seem to be embedded in a rotating molecular disk which is undergoing vigorous star formation. Recently, strong OCN- absorption has been detected in the spectrum of the Galactic center star GC:IRS19. The most likely environment for the OCN- absorption is the strongly UV-exposed GC molecular ring. The presence of processed ice in the center of NGC4945 and our Galactic center leads us to believe that processed ice may be a common characteristic of dense molecular material in star forming galactic nuclei., 9 pages, 8 figures. Accepted for publication in A&A. Also available at this http://www.astro.rug.nl/~spoon/publications.html