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1. Iron(II)-catalyzed sulfimidation and [2,3]-sigmatropic rearrangement of propargyl sulfides with tert-butoxycarbonyl azide. Access to N-allenylsulfenimides

Author

Bacci, James P., Greenman, Kevin L., and Van Vranken, David L.

Subjects
Chemistry, Organic -- Research, Organic compounds -- Composition, Iron compounds -- Composition, Rearrangements (Chemistry) -- Analysis, Catalysts -- Composition, Sulfides -- Composition, Azo compounds -- Composition, Carbon compounds -- Composition, Biological sciences, Chemistry
Abstract

Research has been conducted on tert-butoxycarbonyl azide and allyl sulfides. The authors report that the iron(II)-catalyzed Bach reaction of these compounds has been extended in order to include propargyl sulfides and to produce N-allenylsulfenimides.

Published
2003

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