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Simple Summary: The possibility of pain occurring in animals is often accepted if various criteria are fulfilled. These criteria include prolonged grooming or rubbing at the site of a wound or tissue damage, or other behaviour involving the site of damage. We also expect to see a reduction in such activities if a local anaesthetic is applied. Here, we report on an experiment that applied caustic soda, a known irritant in humans, to one eyestalk of the glass prawn. This caused immediate escape responses and then nipping and picking at the treated eyestalk rather than at the untreated eyestalk. Prior application of a local anaesthetic reduced the amount of directed behaviour. However, the local anaesthetic also appeared to be an irritant as it too caused immediate escape responses and directed behaviour to the eyestalk. The results provide further support to the idea that these animals can experience pain. Acceptance of the possibility of pain in animals usually requires that various criteria are fulfilled. One such criterion is that a noxious stimulus or wound would elicit directed rubbing or grooming at the site of the stimulus. There is also an expectation that local anaesthetics would reduce these responses to damage. These expectations have been fulfilled in decapod crustaceans but there has been criticism of a lack of replication. Here, we report an experiment on the effects of a noxious chemical, sodium hydroxide, applied to one eyestalk of the glass prawn. This caused an immediate escape tail-flick response. It then caused nipping and picking with the chelipeds at the treated eyestalk but much less so at the alternative eyestalk. Prior treatment with benzocaine also caused an immediate tail-flick and directed behaviour, suggesting that this agent is aversive. Subsequently, however, it reduced the directed behaviour caused by caustic soda. We thus demonstrated responses that are consistent with the idea of pain in decapod crustaceans. [ABSTRACT FROM AUTHOR]

Introduction. The industrial sector of Russia is the most important segment of the country’s economy. Until the beginning of the 21st century, large chemical enterprises in Russia were focused on the domestic market. There was a so-called supply strategy formed back in the USSR for the Union Socialist republics. The products of the chemical industry were mainly transported by road around the city and to neighboring regions, the main cargo traffic for longer distances was mastered by rail and river transport. Currently, the largest chemical industry enterprise in the Volgograd region, AO Kaustik, is actively exporting to Europe, South America and Asia. To carry out international transportation of the company’s products, hired tractors with semi-trailers that meet all modern standards of environmental safety are used. The interaction of road transport with rail, river, and sea is actively taking place, effective logistics multimodal systems for the delivery of chemical products are being organized. Road and rail transportation of products is organized with Asian countries, with European countries – by road, rail and sea, with South American countries – by sea. Today, the company’s transport carries out international multimodal transportation to the near and far abroad. The issue of improving the efficiency of road transport is relevant. The paper considers the links of the logistics system of transportation of chemical products of the enterprise between the countries, along the routes: Russia – Netherlands and Russia – Kyrgyzstan. The comparison of road and rail transportation by time and cost on Volgograd – Bishkek route is carried out. The full loading of the vehicle with transport packages according to the calculation takes place in compliance with the loads on the axles of the tractor and semi-trailer. Improving the efficiency of transportation depends on the organization of loading and unloading points, customs control points, movement along routes, and the work of drivers. The statistical regularities of the distribution of the execution time of elements and operations in the loading point of the enterprise are investigated. The ways of organizing the work of motor transport drivers on the international Volgograd – Bishkek – Volgograd route are considered, the calculation of the duration of the elements of the transportation process and their cost is presented.Materials and methods. The paper uses methods of statistical and economic analysis of data on the functioning of the chemical industry in the region. Graph-analytical methods are used to form transport packages and ensure that the car is fully loaded. Methods for determining the shortest distances and drawing up routes on the transport network are used. Methods of organizing the work of drivers are used to ensure single and tour work on the international route. The effectiveness of the proposed measures is evaluated by economic methods.Results. It is revealed that the chemical industry of the region has a stable economic situation that allows it to develop new international markets. The links of the multimodal logistics system for the delivery of the company’s products along Volgograd – Bishkek and Volgograd – Netherlands international routes are investigated. Improving the efficiency of transportation depends on the organization of loading and unloading points. A statistical analysis of the elements and stages of the transportation process of caustic soda was carried out. A scheme for placing transport packages with bags of caustic soda in a semi-trailer of a motor vehicle has been developed. International routes of transportation of products of AO Kaustik using road transport have been developed: Volgograd – Bishkek and Volgograd – Netherlands routes. The mode of operation of motor transport when performing international transportation using tour and single organization of drivers’ work is calculated. We recommend a tour trip as the most effective way to organize the work of drivers. Tour riding is recommended as the most effective way of organizing the work of road transport in the organization of international transportation to near and far abroad. The final price of 1 ton of transported products on the Volgograd – Bishkek route has been determined. The effective functioning of road transport in the international logistics system for the delivery of caustic soda allows you to reduce transport time, transport costs and reduce the cost of a unit of production for the end user.Conclusions. The article develops measures to improve the organization of international transportation of products of JSC «Caustic» using road transport. The final price of 1 ton of products in the Bishkek warehouse, taking into account the initial cost of granular caustic soda and transportation costs in the case of organizing a single driver’s ride, will be 83246 rubles/ton, and for tour driving, respectively, 81355 rubles/ton.

Coal fines formed in the process of coal mining are of no commercial value and accumulate in dumps, harming the environment. At the same time, they can be used as a source of low-smoke fuel used by the population for domestic needs. To create such a product, it is necessary to solve many technical problems related to selecting binders for coal, providing mechanical strength, and initiating the combustion process of coal briquettes. This study presents the results of obtaining briquette fuel from fine particles of brown coal. Low-temperature pyrolysis determined the qualitative and quantitative composition of volatile components and proposed a mechanism for forming a porous structure of coal after thermal exposure. A composition of a mixture of caustic soda and grain processing waste was used as a binder for the production of briquettes. The mechanism of the formation of adhesive properties of the binder material is explained, and the optimal concentration of sodium hydroxide in it is determined. The positive role of caustic soda as a catalyst for the burning of briquettes is shown, and the activation energy of the burning process is calculated.

The numerical optimization of the spray dryer operations for the evaporation of caustic soda solution was investigated in this work. The optimization for the drying operation was explored with the Response Surface Methodology (RSM) by utilization of the Design Expert software Version 11.1.2.0 64-bit. The numerical optimization of the spray dryer operations at three inlet air temperatures of 391, 382 and 373 K revealed various operating characteristics, performances and result outputs. The operation at 391 K provided the highest w/w% of the NaOH drying operation and factors or variables needed to achieve the operation. Justifiable optimum parameters obtained are 71.82%, 0.2631 kg/s, 9077.53 kJ/kg, 0.2978 kg/s and 99.5364% for the inlet w/w% of the NaOH solution, outlet mass flow rate of the dried product, specific drying energy per kg of NaOH required, inlet mass flow rate of NaOH solution and final w/w% of the NaOH dried product at inlet air temperature of 391 K respectively. [ABSTRACT FROM AUTHOR]

Acceptance of the possibility of pain in animals usually requires that various criteria are fulfilled. One such criterion is that a noxious stimulus or wound would elicit directed rubbing or grooming at the site of the stimulus. There is also an expectation that local anaesthetics would reduce these responses to damage. These expectations have been fulfilled in decapod crustaceans but there has been criticism of a lack of replication. Here, we report an experiment on the effects of a noxious chemical, sodium hydroxide, applied to one eyestalk of the glass prawn. This caused an immediate escape tail-flick response. It then caused nipping and picking with the chelipeds at the treated eyestalk but much less so at the alternative eyestalk. Prior treatment with benzocaine also caused an immediate tail-flick and directed behaviour, suggesting that this agent is aversive. Subsequently, however, it reduced the directed behaviour caused by caustic soda. We thus demonstrated responses that are consistent with the idea of pain in decapod crustaceans.

Inactivation of avian influenza viruses (AIVs) using chemical disinfectants is an indispensable biosecurity measure during outbreaks. The efficiency of disinfection process depends on disinfectant type and presence or absence of organic matter. It is also not clear whether AIV pathotype could influence its tolerability to a given disinfectant. Here, we assessed the efficiency of formalin and caustic soda against high (H5N1) and low (H9N2) pathogenic AIVs in the presence and absence of wet faeces. Our results showed that the effectiveness of both disinfectants depends on the target virus with the low pathogenic H9N2 virus being generally more susceptible to disinfection than the high pathogenic H5N1 virus. Wet faeces slightly influenced disinfection action in a virus- and contact time- dependent manner. This study highlights the importance of eliminating faecal matter before initiating a disinfection process and indicates the influence of disinfectant type and AIVs pathotype when selecting the appropriate disinfectant. [ABSTRACT FROM AUTHOR]

A study on mineral characterization and nano titanium dioxide synthesis from ilmenite ore of Bangka Island, Indonesia, has been carried out using a caustic fusion method and hydrochloric acid leaching. Comprehensive mineral characterization was conducted using X-ray fluorescence spectroscopy (XRF) and X-ray diffraction (XRD) to depict each fractionated particle's elemental composition and mineralogy, i.e., +80, ?80+100, ?100+150, ?150+200, -200+325, and -325 mesh. Other analyses performed are VSM to measure the magnetic properties and SEM to determine the distribution of elements at each particle size. Based on the characteristics of the ilmenite ore, magnetic separation was applied for the initial stage and analyzed gravimetrically. Later processing was the synthesis of nano titanium dioxide, conducted sequentially, including roasting and leaching. Roasting was run at 900°C with and without caustic soda, and then hydrochloric acid was applied. In reference to the elemental analysis, titanium (Ti) concentration is higher in smaller particle sizes and vice versa for iron (Fe) concentration, so the synthesis of nano titanium dioxide was carried out using a -100+150 mesh particle size. The optimum condition for nano titanium dioxide synthesis was 2:1 of NaOH and ilmenite weight ratio, 20% HCl concentration, and 4 hours of leaching time. The nano titanium dioxide (TiO2) obtained was then characterized using XRF, XRD, particle size analyzer (PSA), and transmission electron microscopy (TEM). Roasting with caustic soda showed better nano titanium dioxide purity with 96.04% of TiO2 with particle size in the range of 50–80 nanometers.

The significance of textile coloration is inevitable as coloration is a critical process and it can be affected by several parameters i. e. time, temperature, pH, and liquor ratio (M:L). This research reveals the behavior of different dye bath pH (2 to 12) on the basis of spectrophotometric characteristics and colorfastness using the most useable brand of reactive dye in Bangladesh i. e. Remazol Yellow RR. Earlier researches were performed on the basis of other coloration controlling factors i. e. temperature, time and liquor ratio (M:L) where pH acts as the dependent variable. However in this study, pH was taken as an independent variable where lower pH (2, 4 and 6), medium pH (8 and 10) and higher pH (12) were taken into consideration for verifying the dyeing performance. Meanwhile, the mentioned pH was achieved by adding acetic acid, soda ash and caustic soda respectively. In this study, the impact of pH is analyzed on the basis of color strength, chromaticity, hue angle, CIELAB color space, spectrophotometric image, reflectance percentage and color fastness tests i. e color fastness to rubbing, color fastness to wash, color fastness to perspiration, color fastness to light. Gradually elevated pH boosts up the color strength and chromaticity, at the same time downgrades of hue angle results orangish tone in the dyed fabric. Even more, the lightness of dyed fabric decreases and redness rises with the increment of dyebath pH which results in orangish red darker tone of dyed fabric. Consequently, fabric dyed at acidic dye bath pH exhibits higher resistance in case of color change and color staining from the dyed fabric and multifiber fabric respectively and vice versa.

The baobab is a tree of multipurpose and biological properties; being its roots, tubers, twigs, fruits, seeds, leaves and edible flowers and used as common ingredients in traditional dishes in Africa. The objective of this study was to evaluate the chemical scarification with sulfuric acid and caustic soda to overcome the integumentary dormancy in baobab seeds. The design was completely randomized in a 2 x 4 + 1 factorial scheme (chemical scarification: sulfuric acid (H2SO4) and caustic soda (NaOH) x immersion times: 2; 4; 6 and 8 hours + untreated seeds (control)). The efficacy of the treatments was evaluated by the emergence, speed index and mean time of emergence, stem diameter, length and dry mass of shoot and root system of normal seedlings. The results showed that the chemical scarification with caustic soda and sulfuric acid for the periods of 2; 4; 6 and 8 hours caused the tegument rupture of the seeds, which contributed to increase the emergence of baobab seedlings, however, the emergence of seedlings of the seeds scarified with caustic soda for 2 hours did not differ from the values of the seedlings from the untreated seeds. Caustic soda and sulfuric acid were efficient in overcoming the integumentary dormancy of baobab seeds, however, caustic soda is more indicated because it is easy to acquire and low cost.

Reducing industrial slags and developing building materials on its basis is one of the priority areas for the development of the construction industry. The problem of obtaining cellular concrete from mineral wool production waste (lightweight geopolymers) is considered within the framework of the researches, the results of which are presented in the article. The research purpose was to establish the impact of composition of the raw material mixture and technological production features on the physical, mechanical and thermophysical properties of light geopolymers based on mineral wool production waste. Light geopolymers were obtained by preparing a mixture of ground slugs (specific surface is 400±20 m2/kg), alkaline activator (NaOH), water, a gas-forming additive (aluminum powder), fine aggregate and a water-holding additive. The resulting mixture was placed in the form without vibration. Molded products were steamed in order to accelerate hardening. The mobility of mortar mixtures was studied during the work, the average density, compressive strength, and thermal conductivity was studied for hardened samples. The compositions of lightweight geopolymers with an average density from 610 to 1,130 kg/m3, compressive strength from 1.7 to 5.4 MPa, and a thermal conductivity from 0.144 to 0.345 W/m∙°C were obtained. The application of the results will contribute to the expansion of the raw material base for obtaining light geopolymers, thereby reducing the amount of waste generated during the mineral wool production. The developed materials can be used for the construction of walling, and also as the insulation of the roof and floor of industrial and civil facilities.

Caustic soda ingestion causes strictures in the respiratory, gastrointestinal systems and even death. In the oral and perioral areas it causes contractures leading to microstomia that is difficult to manage to restore structure and function of the oral cavity. The present case is of a 42-year-old female who presented with microstomia, no endoscopic esophageal injury and ankyloglossia following ingestion of caustic soda in an attempted suicide following a dispute with her spouse. Satisfactory mouth opening and tongue movement were achieved by bilateral release of buccal contractures, commissuroplasty and release of the tongue that was tethered to the floor of the mouth. [ABSTRACT FROM AUTHOR]

In drilling fluid program, selecting the drilling fluid that will reduce the lost time is the first objective, and will be economical regardless of its cost. The amount and type of solids in drilling fluid is the primary control of the rheological and filtration properties. Palygorskite clay (attapulgite) is an active solid that has the ability to reactive with its environment and form a gel structure within a fluid and due to its stability in the presence of brines and electrolytes this type of clay is preferred for use. The aim of this study is to improve properties of Iraqi palygorskite (PAL) by adding different chemical additives such as caustic soda NaOH and soda ash Na2CO3 with a different concentration in both fresh and salt water-based drilling fluid to satisfy the API specification and to compete with imported palygorskite. The palygorskite claystone of Late Cretaceous age is present in the Western Desert of Iraq within the Digma Formation. In this study, two areas in Western Desert palygorskite were obtained, Bahr Al-Najaf and Trefawi. The results of rheological properties showed that the performance of Bahr Al-Najaf PAL was more affected by caustic soda than Trefawi PAL. In contrast, Trefawi PAL performance was more affected with low concentrations of soda ash than Bahr Al-Najaf PAL in both fresh and salt water-based drilling fluid. Also, these additives lead to improve the value of pH in both fresh and salt drilling fluid that increases the ability of clay to be more dispersed in drilling fluid. Besides that, enhancement of drilling fluid prepared with Iraqi palygorskite stability to 85 and 80 in fresh and saltwater, respectively, was observed with soda ash additions.

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Pakistan has sufficient production capacity of caustic soda to cater the needs of the local industry. Presently, Pakistan has four major plants with production capacity around 435,000 mega ton per year of caustic soda of various grades. Textile industry of Pakistan is the major consumer of produced high grade caustic soda; as the presence of any impurities especially dissolved salts and metals is unfavorable for wet processing of cotton. This study investigates the performance of three different local brands of caustic soda intended for use in textile wet processing of cotton fabric specifically for mercerization process. The brands were selected based on their purity grades. The selected caustic soda samples were chemically analyzed for the presence of impurities. Twenty seven cotton fabric samples (nine samples of each brand) were prepared by mercerization in slack state. The cotton fabric samples were tested for changes in surface morphology, tensile strength (warp and weft), tear strength, air permeability and K/S (Colour Strength). The results were analyzed using one-way ANOVA (Analysis of Variance) to ascertain the statistical equivalence within and between the tested brands. The results showed no significant differences across the tested brands at a 95% confidence level except for air permeability and K/S in blue shade.

The fabric mercerizing process is carried out using concentrated caustic soda solutions with the objectives of increasing the fabric brightness and the dye affinity. To recirculate the soda solution is necessary once it has been concentrated, in order to reduce operating costs. However, the recirculated soda solution poor quality undermines the quality of mercerized obtained fabric, so this research was conducted to evaluate a modification of caustic soda solution purification scheme from the determination of its inadequacies. The soda solution from the mercerized was characterized and its concentration was 237.33 g / L, which indicates impurities presence that maintain the correct density, but falsify the concentration. With Nessler test is detected that there is presence of cellulose and hydrocellulose in soda solution samples. To improve the efficiency of caustic soda solution recovery process, the alternative that has the peroxide filter before the reconcentration system was selected, with an equipment acquisition cost of 2007342.61 CUC. With MATLAB simulator, the steam consumption was obtained, which achieves an economy of 2 kg of evaporated steam/kg of steam fed in correspondence with the double effect proposed for solution concentration. [ABSTRACT FROM AUTHOR]

Pakistan has sufficient production capacity of caustic soda to cater the needs of the local industry. Presently, Pakistan has four major plants with production capacity around 435,000 mega ton per year of caustic soda of various grades. Textile industry of Pakistan is the major consumer of produced high grade caustic soda; as the presence of any impurities especially dissolved salts and metals is unfavorable for wet processing of cotton. This study investigates the performance of three different local brands of caustic soda intended for use in textile wet processing of cotton fabric specifically for mercerization process. The brands were selected based on their purity grades. The selected caustic soda samples were chemically analyzed for the presence of impurities. Twenty seven cotton fabric samples (nine samples of each brand) were prepared by mercerization in slack state. The cotton fabric samples were tested for changes in surface morphology, tensile strength (warp and weft), tear strength, air permeability and K/S (Colour Strength). The results were analyzed using one-way ANOVA (Analysis of Variance) to ascertain the statistical equivalence within and between the tested brands. The results showed no significant differences across the tested brands at a 95% confidence level except for air permeability and K/S in blue shade. [ABSTRACT FROM AUTHOR]

Adhesives play a fundamental role in many modern technologies, and adhesive failure can have catastrophic consequences. It is, therefore, valuable to understand the factors important for the production of a good durable adhesive bond. The additives are also used to enrich the properties. The objective of this paper is to increase the drying speed of the starch adhesive by adding suitable additives and thereby increasing the production speed of corrugated board manufacturing. The other functional additives that could be incorporated in minor amounts for better drying speed are studied and selected. Their properties such as drying speed, strength, viscosity and pH are tested. The results from the tests are compared and the best additive for fast drying is selected.

Acquired vaginal stenosis is a rare obstructing anomaly, which can be caused by use of chemicals in the vagina. A 21-year-old gravida 1 para 1, presented with secondary amenorrhea and inability to have sexual intercourse, after normal spontaneous vaginal delivery complicated by post partum bleeding. The delivery was conducted by untrained traditional birth attendant at home. The wash cloth soaked with caustic soda was packed in the patient’s vagina and was left in situ for 10 days, which ultimately led to the severe scarring and stenosis of the vagina. Patient underwent surgical management and the extensive vaginal adhesions were excised and a patent vagina was reconstructed. Patient then reported successful vaginal intercourse without dyspareunia. Post partum vaginal stenosis due to chemical vaginitis is rare. These cases can be prevented by adequate training of untrained health care workers.

Palmyra palm fruit fibers have the properties to be used as an alternative raw material of cellulosic pulps for papermaking.Acid and alkali pulping were investigated by using nitric acid and caustic soda on a laboratory scale, with the purpose of producing printing or writing grade pulp. The chemical composition of fiber strands from palmyra palm fruits were examined, such as holocellulose, cellulose, pentosan, lignin and extractives. The yields of acid and soda pulps were below 40%. The main physical and mechanical properties of hand sheets produced from acid and soda processes were evaluated on 80 g/m2 test sheets as functions of the following parameters: tensile index, tear index, and brightness. The mechanical properties of soda pulps were developed by twin-roll press while it was not necessary to fibrillate acidic pulps through the beating step. The soda pulp sheets presented a lower brightness than that of acidic pulp sheets. The mechanicaland physical properties of the acidic and alkaline pulps verified that they were of an acceptable quality for papermaking.

Increasingly stringent environmental regulations and increasing input costs negatively affects the sustainability and competitiveness of the pulp and paper industry. As a result, it has become necessary that broader strategies aimed at helping the industry to improve the environment performance whilst also reducing the operation costs are initiated. Recovering water and chemical from the bleach plant effluent streams could be one of such initiatives. In this paper, a preliminary techno-economic assessment of recovering water and caustic soda from alkaline bleach plant effluent using ultrafiltration and reverse osmosis membrane systems is presented. The scope of this work included; assessing the practicality and the economic performance of this membrane process. In terms of the practicality, the data acquired revealed that the proposed concept can only be applied to the alkaline effluents from the alkaline extraction stage, where caustic soda, oxygen, and peroxide are used as the pulp bleaching chemicals. Economic performance of this membrane system, however, is dependent on the effluent flow rates and the amount of water recovered. To be economically viable, the flow rates must higher than 480 m 3 /day and water recovery rate need to be higher than 70%. At this optimum effluent flow and water recovery rates, the process cost is approximately R 19/m 3 . Depending on the flow rates, the investment cost is in the range of R 5–25 million and the payback time is between 3 and 4 years. However, motivations of caustic recovery should be based on environmental rather than economic benefits. Mills can use the detailed information/data acquired in this study to determine whether it would be beneficial for them to implement this type of integrated waste management strategy in their processes. [ABSTRACT FROM AUTHOR]

In this study, a two-stage diffusion dialysis (DD) and electrodialysis (ED) system for the removal and recovery of sodium hydroxide from industrial wastewater were investigated. The study was carried out at laboratory scale using food industry wastewater. Sodium hydroxide is commonly used as principal strong base by various chemical industries. The processed wastewater therefore enhances the pH levels of receiving water bodies that affects the physiological functions of aquatic organisms, plants, and makes the water inappropriate for human consumption. 1.0-μm PTFE (Advantec, USA), forward osmosis (FO) (Hydration Technology Innovation) membranes, platinum coated over titanium anode, and graphite cathode were used in this study. In the first stage of the DD process, NaOH from the feed solution (FS) i.e. wastewater to draw solution (DS) i.e. deionized water (DI) was carried out through PTFE membrane in a diffusion cell. The initial concentration of NaOH in the FS was from 1 to 3 M and in the first step, 60 to 62% of NaOH was diffused from the FS to DS. In the second step of the DD process, further 48 to 50% NaOH was transferred from the FS to DS and overall 80 to 83% NaOH was removed from the FS. In the second stage, the DS collected from diffusion cell was transferred to the ED cell as the FS for further treatment and recovery of caustic soda. During the ED process, 15.0 V was applied for 5.0 h batch time. Sodium cations were transported from the FS to DS under the influence of electric potential through FO membrane and up to 44% of NaOH was recovered. [ABSTRACT FROM AUTHOR]

The study aimed to produce activated carbon by gradual heating to about 550°C for 4hr. The mixture consist of 1:2 ( residual petroleum: sodium hydroxide) The residual petroleum used was the atmospheric residual from Hammam AL-AIil in the northen of Iraq. The prepared activated carbon gives good results for the adsorption of iodine No. and methylene blue in comparson to synthetic carbon . Another characters for activated carbon were studied like ash content and density.

Background: Disastrous effects and lifelong complications, ranging from respiratory and gastrointestinal burns to death can result from caustic soda ingestion. Accidental and non-accidental ingestions occur in different age groups. However, it is very troubling to find ingestion of caustic soda a very common occurrence among children below 5 years since they do not have the developmental level required to independently weigh up risks and are also under parental and societal protections. This study was therefore planned to investigate the ingestions of caustic soda by these children for purposes of proposing measures to curb the problem. Methods: Descriptive survey was employed for this study. A 14-item, semi-structure questionnaire was purposively issued to 57 parents/guardians whose wards had ingested caustic soda. Data was analysed with SPSS V.20. Results: Twenty-seven (47.4 %) children got access to the soda at storage, 1 (1.86 %) was administered accidentally by a sibling while 29 (50.9 %) ingested during soap preparation. In respect of the former, the majority got access because it was stored in soft drink and water bottles in their parents/guardians rooms or kitchen. For the later, the children got access to the left-over soda because the soap-makers failed to adhere to good storage and disposal practices. Conclusion: Storage of caustic soda in soft drink and water bottles in accessible places, and training of children to drink directly from bottles influence caustic soda ingestion in children under five. Non-compliance to good practices of storage and disposal of caustic soda during soap preparation increases exposure and access of children to caustic soda ingestion. [ABSTRACT FROM AUTHOR]

Perlite is a volcanic aluminosilicate abundant in several countries that are major producers of portland cement. The amorphous nature and silica-to-alumina ratio of ground perlite indicate that it can be activated with alkaline solutions. This study presents the strength development of mixtures containing only ground perlite as their powder binder, activated with sodium hydroxide and/or sodium silicate solutions, at room temperature or using oven curing. The structure of the formed geopolymers is investigated using X-ray diffraction, Fourier transform infrared spectroscopy, and nuclear magnetic resonance spectroscopy. The thermal stability and acid resistance of the mixtures are evaluated. Sodium silicate-activated mixtures slowly reach moderate strengths at room temperature but sodium hydroxide-activated ones do not develop strength regardless of activator concentration. Both activators produce geopolymers with high strengths with 100°C dry oven curing. Sodium silicate-activated specimens are more resistant to high temperatures but less resistant to a sulfuric acid solution than are sodium hydroxide solution-activated specimens. Being natural and having a more consistent chemical composition compared with most artificial pozzolans make perlite an attractive geopolymer raw material. [ABSTRACT FROM AUTHOR]

Reprocessing soiled cleaning-in-place (CIP) solutions has large economic and environmental costs, and it would be cheaper and greener to recycle them. In food industries, recycling of CIP solutions requires a suitable green process engineered to take into account the extreme physicochemical conditions of cleaning while not altering the process efficiency. To this end, an innovative treatment process combining adsorption-coagulation with flocculation was tested on multiple recycling of acid and basic cleaning solutions. In-depth analysis of time-course evolutions was carried out in the physicochemical properties (concentration, surface tension, viscosity, COD, total nitrogen) of these solutions over the course of successive regenerations. Cleaning and disinfection efficiencies were assessed based on both microbiological analyses and organic matter detachment and solubilization from fouled stainless steel surfaces. Microbiological analyses using a resistant bacterial strain ( Bacillus subtilis spores) highlighted that solutions regenerated up to 20 times maintained the same bactericidal efficiency as de novo NaOH solutions. The cleanability of stainless steel surfaces showed that regenerated solutions allow better surface wettability, which goes to explain the improved detachment and solubilization found on different types of organic and inorganic fouling. [ABSTRACT FROM AUTHOR]

A rational temperature-time regime for obtaining an alkaline concentrate based on quartz and caustic soda is determined. The physical and chemical properties of the concentrate and its effect on the glassmaking properties are studied. The possibility of using the alkaline concentrate with full substitution for glass sand and soda in the composition of the glass batch is substantiated. [ABSTRACT FROM AUTHOR]

Abstract: Life cycle assessment was conducted to estimate the environmental impact of caustic soda production. Electricity and raw salt production accounted for >90% of the overall environmental burden. These findings can be attributed to electrical consumption for bipolar electrolysis and brine extraction, diesel consumption for generating electricity during well production, and direct heavy metal emissions during drilling fluid loss and waste disposal. The key factors in reducing the overall environmental impact include optimizing raw salt production, electricity, and steam consumption efficiency, choosing drilling fluids with less toxic heavy metals (e.g., arsenic, barium, molybdenum, selenium, vanadium, beryllium, and nickel), minimizing brine leakage during brine transport, reducing the volume of drilling fluid lost, and decreasing the transport distance from brine buyers to suppliers. [Copyright &y& Elsevier]

The significance of textile coloration is inevitable as coloration is a critical process and it can be affected by several parameters i. e. time, temperature, pH, and liquor ratio (M:L). This research reveals the behavior of different dye bath pH (2 to 12) on the basis of spectrophotometric characteristics and colorfastness using the most useable brand of reactive dye in Bangladesh i. e. Remazol Yellow RR. Earlier researches were performed on the basis of other coloration controlling factors i. e. temperature, time and liquor ratio (M:L) where pH acts as the dependent variable. However in this study, pH was taken as an independent variable where lower pH (2, 4 and 6), medium pH (8 and 10) and higher pH (12) were taken into consideration for verifying the dyeing performance. Meanwhile, the mentioned pH was achieved by adding acetic acid, soda ash and caustic soda respectively. In this study, the impact of pH is analyzed on the basis of color strength, chromaticity, hue angle, CIELAB color space, spectrophotometric image, reflectance percentage and color fastness tests i. e color fastness to rubbing, color fastness to wash, color fastness to perspiration, color fastness to light. Gradually elevated pH boosts up the color strength and chromaticity, at the same time downgrades of hue angle results orangish tone in the dyed fabric. Even more, the lightness of dyed fabric decreases and redness rises with the increment of dyebath pH which results in orangish red darker tone of dyed fabric. Consequently, fabric dyed at acidic dye bath pH exhibits higher resistance in case of color change and color staining from the dyed fabric and multifiber fabric respectively and vice versa., Competing Interests: The authors declare no conflict of interest., (© 2022 The Authors.)

Aqueous fluosilicic acid solutions were once considered to be only adverse by-products of phosphoric acid production, which required treatment to prevent ecosystem destruction when discharged into the sea. However, a range of chemicals can be generated by the transformation of this industrial waste product. Through experiments undertaken in the laboratory, we have shown the possibility of caustic soda production. Volumetric analysis showed caustic soda to be present as a 6% – 7% solution with yields of about 70% – 80% by weight. Two processes were investigated for the caustification of sodium fluoride, using different precipitates: sodium chloride and ethanol and are described by modelling caustification curves. The activation energies of precipitation determined by semi-empirical correlations showed that precipitation by ethanol (EA = 933.536 J/mol) was more successful than precipitation by sodium chloride(EA = 7452.405 J/mol). Analyses performed on the precipitates highlighted compositions that are essential and useful constituents in the cement industry.

Aqueous fluosilicic acid solutions were once considered to be only adverse by-products of phosphoric acid production, which required treatment to prevent ecosystem destruction when discharged into the sea. However, a range of chemicals can be generated by the transformation of this industrial waste product. Through experiments undertaken in the laboratory, we have shown the possibility of caustic soda production. Volumetric analysis showed caustic soda to be present as a 6% – 7% solution with yields of about 70% – 80% by weight. Two processes were investigated for the caustification of sodium fluoride, using different precipitates: sodium chloride and ethanol and are described by modelling caustification curves. The activation energies of precipitation determined by semi-empirical correlations showed that precipitation by ethanol (EA = 933.536 J/mol) was more successful than precipitation by sodium chloride(EA = 7452.405 J/mol). Analyses performed on the precipitates highlighted compositions that are essential and useful constituents in the cement industry.

Abstract: Adhesives play a fundamental role in many modern technologies, and adhesive failure can have catastrophic consequences. It is, therefore, valuable to understand the factors important for the production of a good durable adhesive bond. The additives are also used to enrich the properties. The objective of this paper is to increase the drying speed of the starch adhesive by adding suitable additives and thereby increasing the production speed of corrugated board manufacturing. The other functional additives that could be incorporated in minor amounts for better drying speed are studied and selected. Their properties such as drying speed, strength, viscosity and pH are tested. The results from the tests are compared and the best additive for fast drying is selected. [Copyright &y& Elsevier]

Abstract: Annually, a great amount of Cold Filter Cake (CFC) residue is produced in lead and zinc plants in Iran. CFC, the Ni–Cd purification step residue, with elemental analysis of 45–55% Zn, 11–16% Cd, 2.5–4% Ni and 0.2–1.5% Cu can be used as a secondary source of zinc, nickel and cadmium. Unfortunately, despite its hazardous content, the waste is treated in such a way that most of the hazardous constituents get easily exposed to the environment. In the present study, treatment of CFC for separation of zinc and recovery of cadmium has been conducted employing alkaline leaching and electowinning processes respectively. Affecting factors, such as alkaline concentration, leaching temperature, holding time, and liquid:solid ratio (volume/weight, L/S), and stirring rate were studied on zinc leaching from CFC with NaOH solution. Results showed that under two-stage alkaline leaching, when CFC was leached for 1h at 75°C in the presence of 8mol/l sodium hydroxide and liquid:solid ratio of 10:1, the leaching rate of Zn was 98% while Ni and Cd remained intact in residue. Thus, zinc was separated from Ni and Cd selectively. In the next step, sulfuric acid leaching of alkaline leach residue, with 1mol/l H2SO4 at 70°C and liquid/solid ratio of 10:1, provided a stock sulfate solution containing 49.92g/l Cd, 2.77g/l Zn, 12.76g/l Ni, and 1.18g/l Cu. The Cd electrowinning experiments and the effects of current density (A/m2) and electrolysis time (h) were studied on stock sulfate solution in the presence of Ni and Zn. The electrowinning was carried out at various current density (100, 180, 250 and 400A/m2) and electrolysis time (5, 8, and 18h). Concentrations of Cd2+, Ni2+ and Zn2+ were determined every hour. Cadmium recovery of 9.8% at 100A/m2 increased sharply to 87% at 400A/m2 in 5h. Maximum total recovery of cadmium from solution was 99.9% achieved at 25°C and 400A/m2 in 18h. Final product was cadmium sponge of high purity 98% and copper was considered the main impurity in cadmium sponge deposit (1.7%). A complete flow sheet of process for the selective separation of zinc and cadmium recovery is presented. [Copyright &y& Elsevier]

Abstract: A technology has been developed for extracting tungsten from scheelite concentrate with caustic soda by an autoclaving process. In this process, the effects of different variables on the digestion of scheelite, and on the evaporation of the crude sodium tungstate leach solution, has been investigated. The results showed that 98.8% W was leached in 2h at 160°C under the conditions of 2.2 stoichiometric ratio of NaOH and liquid /solid ratio 0.8:1 stirred at 400rpm. After evaporation, about 90% sodium tungstate was crystallized, leaving impurities of PO4 2-, AsO4 2− and SiO3 2− in the mother solution. The filtered mother solution contained about 93% of the unconsumed caustic soda which can be recycled for a new round of leaching. This technology has been successfully put into industrial practice and can treat almost any tungsten ore, including scheelite middling and wolframite–scheelite mixed concentrates. [Copyright &y& Elsevier]