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The Upper Cretaceous carbonates along the Zagros thrust-fold belt “Harir-Safin anticlines” experienced extensive hot brine fluids that produced several phases of hydrothermal cements, including saddle dolomites. Detailed fluid inclusion microthermometry data show that saddle dolomites precipitated from hydrothermal (83–160 °C) and saline fluids (up to 25 eq. wt.% NaCl; i.e., seven times higher than the seawater salinity). The fluids interacted with brine/rocks during their circulation before invading the Upper Cretaceous carbonates. Two entrapment episodes (early and late) of FIs from the hydrothermal “HT” cements are recognized. The early episode is linked to fault-related fractures and was contemporaneous with the precipitation of the HT cements. The fluid inclusions leaked and were refilled during a later diagenetic phase. The late episode is consistent with low saline fluids (0.18 and 2.57 eq. wt.% NaCl) which had a meteoric origin. Utilizing the laser ablation U-Pb age dating method, two numerical absolute ages of ~70 Ma and 3.8 Ma are identified from calcrete levels in the Upper Cretaceous carbonates. These two ages obtained in the same level of calcrete indicate that this unit was twice exposed to subaerial conditions. The earlier exposure was associated with alveolar and other diagenetic features, such as dissolution, micritization, cementation, while the second calcrete level is associated with laminae, pisolitic, and microstromatolite features which formed during the regional uplifting of the area in Pliocene times. In conclusion, the hydrothermal-saddle dolomites were precipitated from high temperature saline fluids, while calcrete levels entrapped large monophase with very low salinity fluid inclusions, indicative for a low temperature precipitation from water with a meteoric origin.

The Rio del Rey Basin belongs to the coastal basins of Cameroon with Cretaceous to Cenozoic deposits. The Cretaceous (Cenomanian and Campanian-Maastrichtian) and Cenozoic (Paleocene) sediments were studied using major and trace elements geochemistry associated with mineralogical data. The studied samples are mainly made up of Fe-shale and shale with rare intercalations of Fe-sand in the Cenomanian deposits, Fe-shale and shale in the Campanian-Maastrichtian deposits and sub-litharenite, Fe-sand, shale and Fe-shale in the Paleocene deposits. These samples contain high LREE/HREE ratios (9.27 -24.23), no to slight positive Eu anomalies (Eu/Eu*= 1.02 – 1.44), moderate to high Al2O3/TiO2 (10.42 – 112.93) ratio and their position in the Ce vs. La/Yb, Zr vs. TiO2 and La/Sc vs. Th/Co diagrams indicate that they derivate from mainly felsic associated with subordinate intermediate igneous rocks. The CIA (Chemical Index of Alteration; 61.69 – 92.76), PIA (Plagioclase Index of Alteration; 62.16 – 99.47), K2O/Na2O ratios (0.08 – 22.125) and Zr/Sc vs. Th/Sc diagram suggest the source rocks have experienced low to high recycling and weathering (Paleocene deposits), high chemical weathering (Campanian-Maastrichtian) and moderate to high chemical watering (Cenomanian deposits). The SiO2 vs. Al2O3 + K2O + Na2O plot suggests a predominant semi-arid to arid climate with periodically semi-humid climate during the Paleocene, attested by the evolution of the clay minerals composition with association of illite-chlorite/vermiculite/kaolinite in the Cenomanian sediments and periodic appearance of siderite in the Campanian-Maastrichtian and Paleocene deposits. The Sr/Ba (0.41 – 2) and U/Th (0.16 – 0.28) ratios indicate brackish to shallow marine environment of deposition. The Arc-Rift-Collision of two sets of high and low silica rocks and SiO2 vs. K2O/Na2O diagrams indicate a Collisional or Active Continental Margin tectonic setting similar as the Cretaceous (Lower Mundeck and Logbadjeck Formation) and Paleocene (Nkapa Formation) deposits from the Douala sub-basin, which could reflect the Precambian basement history linked to the Neoproterozoic orogeny.

Bullslaughter Bay in southern Pembrokeshire, UK, exposes sections of Upper Mississippian limestone strata. In many places, the rock suffered an isovolumetric alteration during a period of sea-level oscillations. We used multiple approaches to study the weathered rocks, combining sedimentological, petrographic and isotopic compositions (δ18O and δ13C values). Two main microfacies are recognized: (i) packstones/grainstones, characteristic of an open marine shallow subtidal/intertidal environment, with a high degree of agitation, slightly elevated salinity and temporary subaerial exposure; and (ii) mudstones/wackestones in a lagoonal setting and intertidal or supratidal environments, with a pedogenetic influence. In both cases, a complex diagenetic story, which started early in a meteoric environment, induced a strong alteration producing loose sediments in place of the parent rock. Calcretization, at or near the sediment surface in the vadose zone, was one of the most widespread diagenetic modes. It could be associated with beachrocks. Carbon and oxygen stable isotope analyses from more or less weathered limestones support the petrographic data: they show non-marine values with δ13C ranges of from −2.13 ‰ to 1.75 ‰ and δ18O from −6.05 ‰ to −4.66 ‰. These values are systematically lower than those of the middle Carboniferous seawater. Some periods of low sea level and subaerial exposure allowed gypsum to form. Neoformation of euhedral quartz by probable replacement after sulfate, and halite pseudomorphs after gypsum in a hypersaline environment are documented for the first time in southern Pembrokeshire. The studied weathered limestones present a complex diagenetic evolution related to sea-level oscillations in a range of hot and contrasting seasonal climates.

Utilizing sophisticated tools in carbonate rocks is crucial to interpretating the origin and evolution of diagenetic fluids from the Upper Jurassic carbonate rocks along the Zagros thrust-fold Belt. The origin and evolution of the paleofluids utilizing in-situ strontium isotope ratios by high resolution laser ablation ICP-MS, integrated with stable isotopes, petrography and fieldwork are constrained. Due to the lack of information on the origin of the chemistry of the fluids, the cements that filled the Jurassic carbonate rocks were analysed from the fractures and pores. This allowed us to trace the origin of fluids along a diagenetic sequence, which is defined at the beginning from the sediment deposition (pristine facies). Based on petrography and geochemistry (oxygen-, carbon- and strontium-isotope compositions) two major diagenetic stages involving the fluids were identified. The initial stage, characterized by negative δ13CVPDB values (reaching −10.67‰), involved evaporated seawater deposited with the sediments, mixed with the input of freshwater. The second stage involved a mixture of meteoric water and hot fluids that precipitated as late diagenetic cements. The late diagenetic cements have higher depleted O–C isotope compositions compared to seawater. The diagenetic cements display a positive covariance and were associated with extra- δ13CVPDB and δ18OVPDB values (−12.87‰ to −0.82‰ for δ18OVPDB and −11.66‰ to −1.40‰ for δ13CVPDB respectively). The distinction between seawater and the secondary fluids is also evident in the 87Sr/86Sr of the host limestone versus cements. The limestones have 87Sr/86Sr up to 0.72859, indicative of riverine input, while the cements have 87Sr/86Sr of (0.70772), indicative of hot fluid circulation interacting with meteoric water during late diagenesis.

International audience; The Neoproterozoic Schisto-Calcaire Group (630 to ca. 580 Ma) was deposited on an extensive carbonate shelf in the margin of the Congo Craton in the Niari-Nyanga and Comba subbasins (Gabon and Republic of the Congo). It consists of three carbonate-dominated subgroups (SCI to SCIII, up to 1300 m-thick) recording relative sea-level changes. The SCIc Formation, at the upper part of the SCI Subgroup, is a carbonate succession of meter-scale shallowing-upward cycles, composed of a standard sequence of 7 facies grouped in 5 facies associations recording the evolution of a marine ramp from distal carbonate muds and giant stromatolitic bioherms (F1–F2) and extensive ooid shoals (F3), to proximal settings submitted to evaporation near a sabkha (F7). Fifth-order ‘meter-scale’ (or elementary parasequences) packages are grouped into fourth-order sequences (parasequence sets), which are not correlative in the whole basin. Two categories of fifth-order elementary parasequences are recognized, on the basis of physical bounding surfaces: (i) subtidal cycles bounded by marine flooding surfaces across which subfacies deepen; and (ii) peritidal cycles bounded by subaerial exposure surfaces. These cycles are the result of the interplay of relative sea-level changes due to eustatic variations related to periodic extensional tectonic events affecting the whole basin. The Niari-Nyanga and Comba subbasins experienced basin tectonics in the general context of the rifting of Rodinia creating changes of relative sea-level in the different parts of the shelf. The SCIc cycles are enclosed into a third-order sequence with two major transgressive-regressive phases, related to the deposition of the SCI Subgroup. The most typical sedimentologic feature of the SCIc Formation is the deposition of giant stromatolitic bioherms (stacked up to 20 m) topped by ooid shoals (up to 75 m thick) deposited during high systems tract prograding and forced regressive systems tract phases that ended with a lowstand systems tract phase with evaporitic and karstic conditions at the top of the SCIc Formation. The elementary parasequences and parasequence sets are probably the result of the migration of lateral environments related to the variation of the energy in relation to tectonic setting. As a result, a regional sea-level increase is for the first time highlighted in transgressive systems tract phase (composed of microbial induced sedimentary structures Facies) in the lower part of the SCIc Formation. The third-order succession can be followed more than 100 km in the Republic of the Congo and several hundred meters from South of Gabon to the Lower Congo in the Democratic Republic of the Congo. Tentative detailed sequence stratigraphy correlations between both Congo's highlight the role of tectonics affecting both areas.

We report the discovery of 715 to ca. 810 million–year–old fungal fossils through molecular characterization of vestigial chitin., Precambrian fossils of fungi are sparse, and the knowledge of their early evolution and the role they played in the colonization of land surface are limited. Here, we report the discovery of fungi fossils in a 810 to 715 million year old dolomitic shale from the Mbuji-Mayi Supergroup, Democratic Republic of Congo. Syngenetically preserved in a transitional, subaerially exposed paleoenvironment, these carbonaceous filaments of ~5 μm in width exhibit low-frequency septation (pseudosepta) and high-angle branching that can form dense interconnected mycelium-like structures. Using an array of microscopic (SEM, TEM, and confocal laser scanning fluorescence microscopy) and spectroscopic techniques (Raman, FTIR, and XANES), we demonstrated the presence of vestigial chitin in these fossil filaments and document the eukaryotic nature of their precursor. Based on those combined evidences, these fossil filaments and mycelium-like structures are identified as remnants of fungal networks and represent the oldest, molecularly identified remains of Fungi.

A field, petrographic and geochemical study of two Triassic&ndash, Jurassic carbonate successions from the Maritime Alps, SE France, indicates that dolomitization is related to episodic fracturing and the flow of hydrothermal fluids. The mechanism governing hydrothermal fluids has been documented with the best possible spatio-temporal resolutions specifying the migration and trapping of hydrothermal fluids as a function of depth. This is rarely reported in the literature, as it requires a very wide range of disciplines from facies analysis (petrography) to very diverse and advanced chemical methods (elemental analysis, isotope geochemistry, microthermometry). In most cases, our different recognized diagenetic phases were mechanically separated on a centimetric scale and analyzed separately. The wide range of the &delta, 18OVPDB and 87Sr/86Sr values of diagenetic carbonates reflect three main diagenetic realms, including: (1) the formation of replacive dolomites (Type I) in the eogenetic realm, (2) formation of coarse to very coarse crystalline saddle dolomites (Types II and Type III) in the shallow to deep burial mesogenetic realm, respectively, and (3) telogenetic formation of a late calcite cement (C1) in the telogenetic realm due to the uplift incursion of meteoric waters. The Triassic dolomites show a lower 87Sr/86Sr ratio (mean = 0.709125) compared to the Jurassic dolomites (mean = 0.710065). The Jurassic calcite (C1J) shows lower Sr isotopic ratios than the Triassic C1T calcite. These are probably linked to the pulses of the seafloor&rsquo, s hydrothermal activity and to an increase in the continental riverine input during Late Cretaceous and Early Cenozoic times. This study adds a new insight into the burial diagenetic conditions during multiple hydrothermal flow events.

This study concerns the absolute LA ICP-MS U-Pb dating of hydrothermal cementation, particularly in tectonically controlled fractures filling saddle dolomites and blocky calcites in the carbonate succession of Bekhme Formation (Campanian–Maastrichtian). Dating of multiphase hydrothermal cementation combined with δ18O and δ13C analyses, petrography and field observations shows two major episodes of hydrothermal fluid circulation. The first was measured at ~73.8 Ma and is associated with the Zagros folding-faulting tectonic event (Late Cretaceous) and with the depositional age of the Bekhme Formation (75.1 Ma), and the second was at 30.3 Ma and is associated with the second folding-faulting tectonic event during the Tertiary. The δ18O and δ13C values grouped into two populations corroborate the two episodes of hydrothermal fluid flow. Late Cretaceous folding and faulting tectonics and reactivation during the Tertiary in the study area provided conduits for the hydrothermal fluids along deeply seated faults. This work shows for the first time through U-Pb dating that the hydrothermal diagenetic processes in Upper Cretaceous Bekhme Formation are directly linked with the timings of the major regional tectonics in the Zagros Fold-Thrust Belt (ZFTB) through the flow of hot fluid fluxes in a fractured sedimentary basin.

New detailed lithological, sedimentological, chemostratigraphic data were obtained from exploration drilling samples on the C5 carbonate-dominated formation of the Neoproterozoic Lukala Subgroup (former Schisto-Calcaire Subgroup) from the West Congo Belt (WCB) in the Democratic Republic of Congo. This formation records the last post-Marinoan sea-level events that occurred in the whole basin, followed by the development of the Araçuaï-West Congo Orogen between 630 and 560 Ma. The C5 Formation consists of back-reef lagoonal and peritidal/sabkha cycles of ∼2.0 m in thickness, that record a short-time marine regression, rapidly flooded by a marine transgression with deposition of organic-rich argillaceous carbonates or shales under dysoxia and anoxia conditions. These dysoxic/anoxic waters were rapidly followed by a regional-scale marine transgression, favouring mixing with well-oxygenated waters, and the development of benthic Tonian to Cambro-Ordovician Obruchevella parva-type ‘seagrasses’ in the nearshore zones of the lagoons. New δ13C and 87Sr/86Sr isotopic data in the C5 Formation of the Lukala Subgroup are used in the frame of a correlation with the Sete Lagoas Formation in Brazil. Relatively comparable negative to positive δ13C excursions point to marine flooding of the whole basin and allow extension of the debatable Late Ediacaran age of the uppermost Sete Lagoas and C5 formations. Sr isotope “blind dating” failed due to low Sr concentration related to a dolomitization event close 540 Ma. Several tentative datings of the C5 Formation converge to a Late Ediacaran age ranging between 575 and 540 Ma. As the overlying Mpioka folded Subgroup, the C5 series suffered the Pan African deformation, dated at 566 ± 42 Ma. Unlike the previously generally accepted interpretation, our data suggests that the Mpioka Subgroup was deposited in the Early Cambrian.

The Ediacaran Schisto-Calcaire Group is a ∼1300 m-thick succession belonging to the West Congo Supergroup in Central Africa. In the Comba Basin, it consists of three carbonate-dominated units defined as formations (SCI to SCIII) that are unconformably overlain by clastic deposits (Mpioka Group) interpreted as a molassic formation associated with the Panafrican Orogen. The underlying Upper Tillite and Cap Carbonate (SCIa) units, considered as markers of the Snowball Earth event were studied in three sections. We investigated the carbonates of the Schisto-Calcaire Group by defining new microfacies (MF1-MF7) and we performed C and O isotopic analyses in order to constraint the depositional and diagenetic events directly after the Marinoan interval. Stratigraphic variations of the stable isotopes are important in the series with lighter δ18O values (>1.5‰) than those of the Neoproterozoic ocean in the SCIc unit. According to regional stratigraphy a temperature effect can be dismissed and a freshwater surface layer is the origin of such negative δ18O values in this unit. The negative δ13C anomaly (−3.5‰ on average) of the Cap Carbonate is similarly to the δ18O values (−6.4‰ on average) in the range of the marine domain during postglacial sea level rise. The sample suite as a whole (SCII and SCIII formations) displays heavier δ18O and δ13C than those of the lower part (SCI unit) of the Schisto-Calcaire Group. The comparison with the Lower Congo (Democratic Republic of Congo) and Nyanga (Gabon) basins shows that the meteoric flushing in SCIc unit of the Schisto-Calcaire Group was regional and not local, and could be derived from a climatic evolution. Although an overall overprint is present, our isotopic relationships argue against overall diagenetic resetting of primary compositions and suggest that with careful examination combined with detailed petrographic analysis general depositional and diagenetic controls can be discerned in oxygen and carbon isotopic data in the Schisto-Calcaire Group.

Ostracods from the Sourd d'Ave section have been collected in the Moulin Boreux and Fort Hulobiet Members (Fromelennes Fm., Givet Group) and in the Pont d'Avignon Member (Nismes Fm., Frasnes Group). Ostracods collected in the Fromelennes Fm. by Milhau (1983a) and in the Nismes Fm. by Casier (1987a) have been also reviewed. Forty-four ostracod species are identified in the Fromelennes Fm. and 25 in the Nismes Fm. They belong exclusively to the Eifelian Mega-Assemblage, and several assemblages indicative of restricted and shallow marine, sometimes agitated, environments are recognized in the Fromelennes Fm. The great rarity of ostracods in the upper part of this formation provides evidence for less favourable lagoonal conditions probably related to increasing aridity at the end of the Givetian. In the Frasnes Group, assemblages are exclusively open marine and indicative of increasing water depth. The majority of ostracod species recognized in the Givet Group are missing in the base of the Frasnes Group as a consequence of the Frasnes Event. A systematic list of ostracods identified in the Fromelennes Fm. at Sourd d'Ave is published as an annex. Systematic sampling has been carried out in order to establish the sedimentological evolution of the environments and to detail the Givetian-Frasnian (G/F) transition. This allowed recognition of 13 microfacies types that replicate the standard sequence of Preat & Mamet (1989) from open marine shallow subtidal to restricted supratidal near emersion. The Boreux Member and the Fort Hulobiet Member display restricted facies (Amphipora, spongiostromid and algal bafflestones and bindstones, loferites with desiccation lumps) with poorly fossiliferous beds interbedded with higher energy peloidal and sometimes oolitic grainstone facies. Laminite horizons, sometimes with small-sized lateral linked hemispheroid stromatolites are uncommon, and are associated with dolomicrites showing pseudomorphs of evaporite minerals. These evaporitic facies become common in the upper part of the Fort Hulobiet Member suggesting the palaeoclimate became more arid at the G/F transition. Metre-scale cyclicity is pervasive throughout the Givetian part of the section. The boundary between the Givet Group and the Frasnes Group is very distinctive in the field, and is characterized by a transition from restricted evaporative lagoonal facies to open marine interbedded marly shales and nodular limestones. The upper part of the Fort Hulobiet Member consists of interbedded biostromes (semi-restricted stromatoporoid boundstones) followed by Amphipora floatstones, then fossil-poor units and restricted supratidal laminites with well-developed fenestral fabrics. The Frasnian Pont d'Avignon Member contains a rich faunal assemblage (bryozoans brachiopods, molluscs, nautiloids, tentaculitids) suggesting an abrupt drowning from the marginal Givetian carbonate platform into a Frasnian distal ramp or deep basinal environment below or near storm wave base.

The Upper Diamictite Formation of the West Congo Supergroup is a diamictite-dominated succession variously interpreted as a continental tillite, glaciomarinite, and glacially-influenced or non-glacial debrite. This paper presents a detailed macroand microscale analysis of soft-sediment deformation structures in order (1) to resolve the long-standing debate on the genetic origin of the Upper Diamictite Formation, and (2) to constrain the paleoenvironmental conditions during the Marinoan global event. The predominance of ductile and brittle deformations and grain-to-grain compression, considered as evidence of high strain rates and local high stress conditions, indicate that the diamictites were deposited as mass flows. The presence of probable pelagic clays, lonestones, and the absence of direct ice-contact deposits point to a subaqueous gravity flow origin. These diamictites were deposited along the margin or at the foot of the basin slope. They were probably triggered by oversteepening and/or tectonic shocks in the Araçuaí-West Congo Orogen between 630 and 660 Ma. The Upper Diamictite Formation provides no support for the postulated global Marinoan glaciation at this time and underscores the importance of a local tectonic control on the sedimentation., SCOPUS: ar.j, info:eu-repo/semantics/published

Until recently Cummingsella was only known by two rare and puzzling species, erected on very limited material. The genus was therefore considered as representing a very uncommon and puzzling form that played no role in carbonate sedimentation. Recent studies of Viséan carbonates in the American Midcontinent have disclosed a prolific Cummingsella flora that indicates the proximity of an algal bank. Cummingsella can therefore be considered locally abundant, cosmopolitan (Europe, Australia, North America), ranging in age from the Tournaisian to the Namurian (Serpukhovian).

In the Maritime Alps (north-west Italy - south-east France), the Middle Triassic-lowermost Cretaceous platform carbonates of the Provençal Domain locally show an intense dolomitization. Dolomitized bodies, irregularly shaped and variable in size from some metres to hundreds of metres, are associated with tabular bodies of dolomite-cemented breccias, cutting the bedding at a high angle, and networks of dolomite veins. Field and petrographic observations indicate that dolomitization was a polyphase process, in which episodes of hydrofracturing and host-rock dissolution, related to episodic expulsion of overpressured fluids through faults and fracture systems, were associated with phases of host-rock dolomitization and void cementation. Fluid inclusion analysis indicates that dolomitizing fluids were relatively hot (170 to 260°C). The case study represents an outstanding example of a fossil hydrothermal system, which significantly contributes to the knowledge of such dolomitization systems in continental margin settings. The unusually favourable stratigraphic framework allows precise constraint of the timing of dolomitization (earliest Cretaceous) and, consequently, direct evaluation of the burial setting of dolomitization which, for the upper part of the dolomitized succession, was very shallow or even close to the surface. The described large-scale hydrothermal system was probably related to deep-rooted faults, and provides indirect evidence of a significant earliest Cretaceous fault activity in this part of the Alpine Tethys European palaeomargin.

The Uppermost Jurassic-Lower Cretaceous limestone succession in the Maiella region of Italy has been investigated in a profile covering more than 400 m stratigraphical thickness at Fara San Martino. The succession mainly consists of peritidal limestones, intertidal and supratidal sequences being dominant, together with subtidal lagoonal facies. As a consequence, the microfossil assemblages are generally poorly developed, Microfossils occur within the subtidal lagoonal facies of this suite of restricted sediments. This feature led us to recognise five informal biostratigraphic intervals, which are facies related - instead of biozones, each of the intervals being characterized by specific micropaleontological associations. The occurrence and/or disappearance of some marker microfossils were used as references for separating these intervals. Based on these markers, the Uppermost Jurassic-Lower Cretaceous carbonate deposits from Maiella region may be correlated with similar deposits from the Apennines and from other regions in the perimediterranean area.

This paper discusses ostracods and their environmental setting close to the Givetian/Frasnian boundary in the Puech de la Suque Global Stratotype Section and Point. The ostracod fauna belongs exclusively to the Eifelian mega-assemblage and is largely dominated by Podocopina instars. Consequently, the majority of the 33 species recognised and illustrated is described in open nomenclature. The abundance of instars also indicates that most of beds are related to storm deposition. The composition of the fauna suggests a regression in the late Givetian followed by a transgression at the beginning of the Frasnian. Only one ostracod assemblage collected in the upper part of the section indicates a deeper setting below the storm wave base. Eight taxa disappeared in two steps near the Givetian / Frasnian boundary, probably in relation to the Frasnes Event. The sedimentological analysis confirms that the section is constituted principally of storm deposits and reveals in addition the presence of numerous reddish hardgrounds highlighting an important condensation of the sequence.

Atlas illustrant 54 genres d'Algues marines associees a quelques microproblematiques. Ceux-ci sont observes dans les coupes de terrain et les puits de forage du Groupe de Lisburne dans toute l'etendue des Cordilleres arctiques de l'Alaska (Brooks Range).

[1] Carbonate substrates (dolomites and limestones) are susceptible to fungal attack that results in significant microbial diagenesis of these substrates. In a 15-day experimental study, fungi growing in Petri dishes from airborne spores attacked petrographic thin sections and chips prepared from the dolomites of Terwagne Formation (Visean, Bocahut quarry at Avesnes-sur-Helpe, northern France) and limestones of the Morrone di Pacentro Formation (Lower Cretaceous, Italy). The analyses of the fungal material (samples of mycelia), thin sections and chips under optical microscopy, scanning electron microscope (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD), Raman spectroscopy and stable isotopes (C and O) revealed an extensive fungally induced diagenesis. The results indicate strong diagenesis and biomineral neomorphism: neo-dolomite, glushinskite, weddellite, whewellite and possibly struvite, as well as intense substrate “de-micritization” and “micritization” with oxalates, grain bridging and cementation, open space filling, formation of intergranular and intragranular porosity, and permeability enhancement. Advanced stages of diagenesis were characterized by dissolution and replacement of original minerals by new substrates produced by fungal biomineralization. The formation of new substrates on the original attacked surfaces produced microscale stratification. Stable isotope analysis of fungal biomineralized material and of attacked and unattacked chip surfaces revealed marked differences in their isotopic signatures. The C and O isotopes of biomineralized material within the fungal mass were fractionated differently as compared to the signature measured in the original and unattacked surfaces. In sedimentary cycles, such microbially modified isotopic signature of carbonate substrates may be used to define microbial events, and consequently whether certain types of diagenesis were produced by microbial interaction. The finding of neo-dolomite formed during fungi-dolomite substrate interaction suggests the possibility of sedimentary dolomite recycling in a fungal microenvironment. The results of this experimental study confirm the significant role of fungi in reshaping carbonate substrates and forming new biominerals in the natural environment.

The Hirnantian is an important time in Earth history as it includes one of the major episodes of continental glaciation and marine mass extinction (e.g. Brenchley et alii, 1994). Positive C-isotope excursions and an eustatic lowering of sea level extend from a level near the base of the Normalograptus extraordinarius-N. ojsuensis Zone (lower Hirnantian) to a level within the upper Hirnantian N. persculptus Zone. C-isotope values decline to pre-glacial levels throughout the extent of uppermost Hirnantian strata. At least two discrete and distinct positive shifts of δ13Corg have been observed globally; they may coincide with two pulses of peak glaciation (Melchin et alii, 2003; see also Sutcliffe et alii, 2000).

Not as hot as we thought Earth's early oceans appear not to have been as hot as some have suggested. The oxygen isotope composition of marine carbonates has changed markedly over the past 3.5 billion years. However, it has been difficult to determine whether that is because of a cooling of the seawater (from temperatures as high as 70°C) or an actual change in the isotope composition of the water. Galili et al. calibrated the temperature-dependent oxygen isotope fractionation between iron oxides and aqueous solutions and constructed an oxygen isotope record in marine iron oxides covering the past 2 billion years. Their findings suggest that a change in the isotope composition of the water, rather than its cooling, underlies the observed geological trend. Science , this issue p. 469