1. Novel photocatalysts Pt/Cd1−xZnxS/ZnO/Zn(OH)2: Activation during hydrogen evolution from aqueous solutions of ethanol under visible light.
- Author
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Kozlova, Ekaterina A., Cherepanova, Svetlana V., Markovskaya, Dina V., Saraev, Andrey A., Gerasimov, Evgeny Yu., and Parmon, Valentin N.
- Subjects
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PHOTOCATALYSTS , *HYDROGEN evolution reactions , *AQUEOUS solutions , *ETHANOL , *VISIBLE spectra , *X-ray diffraction - Abstract
The transformations of single-phase Pt/Cd 1− x Zn x S and multiphase Pt/Cd 1− x Zn x S/ZnO/Zn(OH) 2 and Pt/Cd 1− x Zn x S/Zn(OH) 2 during photocatalytic hydrogen evolution from aqueous solutions of ethanol under visible light ( λ = 450 nm) were investigated. Cyclic tests including long-term experiments were conducted for all photocatalysts. The photocatalysts were investigated before and after the photocatalytic reaction by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and UV–vis spectroscopy techniques. Activation during photocatalytic hydrogen evolution was observed for all multiphase photocatalysts, whereas single phase Pt/Cd 1− x Zn x S was shown to exhibit a strong deactivation. The activation is likely caused by the formation of the ϵ-Zn(OH) 2 phase in a basic medium. The highest exhibited rate of hydrogen evolution on the composite photocatalyst was 3400 μmol g −1 h −1 , and stability during ten 5-hour photocatalytic runs was observed. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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