281 results on '"lithium ion battery"'
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2. Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries
- Author
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Wang, Chong [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)]
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- 2017
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3. Synthetic control of manganese birnessite: Impact of crystallite size on Li, Na, and Mg based electrochemistry
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Marschilok, Amy [Stony Brook Univ., NY (United States). Dept. of Chemistry; Stony Brook Univ., NY (United States). Dept. of Materials Science and Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States)]
- Published
- 2016
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4. Tragacanth, an exudate gum as suitable aqueous binder for high voltage cathode material
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Daniele Versaci, Oana D. Apostu, Davide Dessantis, Julia Amici, Carlotta Francia, Marco Minella, and Silvia Bodoardo
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high voltage ,Tragacanth gum ,Electrochemistry ,Energy Engineering and Power Technology ,binder ,LNMO ,lithium ion battery ,water-soluble ,tragacanth gum ,lithium-ion battery ,water soluble ,Electrical and Electronic Engineering - Abstract
The improvements in future-generation lithium-ion batteries cannot be exclusively focused on the performance. Other aspects, such as costs, processes, and environmental sustainability, must be considered. Research and development of new active materials allow some fundamental aspects of the batteries to be increased, such as power and energy density. However, one of the main future challenges is the improvement of the batteries’ electrochemical performance by using “non-active” materials (binder, current collector, separators) with a lower cost, lower environmental impact, and easier recycling procedure. Focusing on the binder, the main goal is to replace the current fluorinated compounds with water-soluble materials. Starting from these considerations, in this study we evaluate, for the first time, tragacanth gum (TG) as a suitable aqueous binder for the manufacturing process of a cobalt-free, high-voltage lithium nickel manganese oxide (LNMO) cathode. TG-based LNMO cathodes with a low binder content (3 wt%) exhibited good thermal and mechanical properties, showing remarkably high cycling stability with 60% capacity retention after more than 500 cycles at 1 C and an outstanding rate capability of 72 mAh g−1 at 15 C. In addition to the excellent electrochemical features, tragacanth gum also showed excellent recycling and recovery properties, making this polysaccharide a suitable and sustainable binder for next-generation lithium-ion batteries.
- Published
- 2023
5. Single-step chemical synthesis of CoFe2O4 nanowire arrays/Cu foam integrated electrode as binder-free anode with enhanced lithium storage properties
- Author
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Xinqi Li, Liang He, Ping Li, and Xinran Liu
- Subjects
lithium ion battery ,electrochemistry ,Cu-foam ,integrated electrode ,CoFe2O4 ,Materials of engineering and construction. Mechanics of materials ,TA401-492 ,Chemical technology ,TP1-1185 - Abstract
The properties of lithium ion battery largely depend on the structure of active materials. In the present work, CoFe _2 O _4 nanowire arrays /Cu foam three-dimensional integrated electrode (denoted as CFO/Cu-foam NWAs) was firstly designed and synthesized via a simple hydrothermal method follow annealing as a binder-free anode for lithium ion battery. The CoFe _2 O _4 nanowires with diameter of 50–100 nm are uniformly anchored on the porous conductive substrate. Lithium ion battery based on the CFO/Cu-foam NWAs integrated electrode exhibits a high initial capacity of 882.7 mAh · g ^−1 and excellent cyclic stability of 832.1 mAh · g ^−1 after 100 cycles at 1.0 A · g ^−1 which is much better than traditional coated electrode of CoFe _2 O _4 nanowire (defined as CFO NWAs) and CoFe _2 O _4 nanowire/Cu foil integrated electrode (named CFO/Cu-foil NWAs). The improved electrochemical performance might be attributed to superior conductivity and porous skeleton structure which not only reduce contact resistance and polarization, but also relieve volume alteration during the lithiation/delithiation process. These advantages make the CoFe _2 O _4 /Cu foam integrated electrode a promising anode for Li-ion batteries.
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- 2021
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6. Dual functional effect of the ferroelectricity embedded interlayer in lithium sulfur battery.
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Son, Byung Dae, Cho, Sung Ho, Bae, Ki Yoon, Kim, Byung Hyuk, and Yoon, Woo Young
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ALUMINUM-lithium alloys , *LITHIUM sulfur batteries - Abstract
Abstract A carbon nanotube sheet having homogeneously distributed BaTiO 3 is applied to the Li-S cell system as a pseudo-current collector between the cathode and separator. This interlayer serves as a site distributor, where polysulfide eluted from the cathode continuously reacts, and it is expected to play a role as a more effective current collector by mixing the ferroelectric material. A cell utilizing a ferroelectricity embedded interlayer exhibits a higher capacity (908 mAh g−1) at 0.2C than that of carbon alone (740 mAh g−1) at 200th cycle. This result corresponds to a capacity retention ratio enhancement from 67.5% to 75.6%. Furthermore, it is confirmed that the retention of the coulombic efficiency is effectively maintained in long cycles at 0.5C (94.5%–99.6%). This is not only because the modified interlayer functions as an effective current collector owing to the high affinity of the ferroelectric material to polysulfide, but also because ferroelectricity in the interlayer acts as a polysulfide anchor. The evenly distributed polarization leads to a uniform deposition of sulfur, which results in the prevention of inactive sulfur agglomeration and dissolution of polysulfide. Thus, the utilization of active material can be improved with stabilized reaction. Graphical abstract Image 1 Highlights • Nano-BaTiO 3 embedded MWCNT interlayer is fabricated by vacuum filtration method. • BaTiO 3 interlayer cell performs higher specific capacity and coulombic efficiency. • BaTiO 3 interlayer cell enhances rate capability. • BaTiO 3 interlayer induces homogeneous S distribution with strong affinity. • BaTiO 3 interlayer acts as an efficient pseudo-current collector. [ABSTRACT FROM AUTHOR]
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- 2019
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7. One step synthesis of Fe3O4@C composite as a high performance anode material for Li-ion batteries.
- Author
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Yu, Yang, He, Yuan-Chun, Xu, Na, Geng, Xiaoling, Wang, Lingyan, Sun, Hua-Ting, Zhu, Li-Hua, and Jing, Zhihong
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COMPOSITE materials , *LITHIUM-ion batteries , *MAGNETITE , *ELECTROCHEMISTRY , *ANODES - Abstract
Abstract Fe 3 O 4 @C composite was designed and synthesized by a facile one-step solvothermal route as an anode material for Li-ion batteries (LIBs). The carbon shell can effectively prevent the aggregation and buffer the volume expansion during charge/discharge process. The electrochemical performance displays that the Fe 3 O 4 @C composite exhibits high reversible capacity and good cycling performance. In particular, it displays excellent cycling stability at 2 C rate (640.5/642.2 mA h g−1 after 1000 cycles). The results indicate a simple and useful route to prepare Fe 3 O 4 @C composite as a promising LIBs anode material. Graphical abstract Fe 3 O 4 @C composite with high reversible capacity and good cycling performance has been synthesized by a facile one-step solvothermal route as an anode material for Li-ion batteries (LIBs). fx1 Highlights • Fe 3 O 4 @C composite has been synthesized by a facile one-step solvothermal route. • Fe 3 O 4 @C composite has been studied as an anode material for LIBs. • Fe 3 O 4 @C composite displays high reversible capacity and good cycling performance. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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8. Electrochemistry and redox characterization of rock-salt-type lithium metal oxides Li1+z/3Ni1/2-z/2Ti1/2+z/6O2 for Li-ion batteries.
- Author
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Zheng, Shengquan, Liu, Dongming, Tao, Lei, Fan, Xiaojian, Liu, Ke, Liang, Guanjie, Dou, Aichun, Su, Mingru, Liu, Yunjian, and Chu, Dewei
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ELECTROCHEMISTRY , *LITHIUM-ion batteries , *METALLIC oxides , *X-ray diffraction , *CYCLIC voltammetry - Abstract
Abstract This work explores the compound Li 1+z/3 Ni 1/2-z/2 Ti 1/2+z/6 O 2 (z = 0, 0.1, 0.2, 0.3, 0.4, 0.5) and compares the electrochemical performance difference with z to the proposed percolation network. X-ray diffraction combined with Rietveld refinements show that rock-salt structure is obtained by the simple sol-gel process, and the lattice parameters are increased with the increasing level of Li-excess. Micromorphology observation reveals that particles are irregular and the size is distributed within 100 nm. In addition, a detailed reaction mechanism is examined by X-ray photoelectron spectroscopy and cyclic voltammetry, which exhibits the evolution of Ni, Ti and O in the initial charge-discharge process and confirms that they all make contributions to capacities. Electrochemical performance test shows that the discharge capacities increase with the amount of Li and Li 1.17 Ni 0.25 Ti 0.58 O 2 delivers the discharge capacities up to 223.9 mAh g−1. At the current density of 400 mA g−1, it still provides a large capacity of 120 mAh g−1. Furthermore, Li 1.17 Ni 0.25 Ti 0.58 O 2 has the highest lithium ion diffusion coefficient among all samples. Graphical abstract Image 1 Highlights • The good crystallized Li 1+z/3 Ni 1/2-z/2 Ti 1/2+z/6 O 2 is prepared by a facile method. • The detailed redox process of Ni, Ti and O during the first cycle. • Stable structure and 0-TM network improve performance. • Li 1.17 Ni 0.25 Ti 0.58 O 2 exhibits high capacities and good rate capability. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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9. Research and Development of Thermally Durable Electrolyte for Lithium Ion Battery
- Author
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Takefumi Okumura and Jun Kawaji
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Technology ,Materials science ,Chemical engineering ,Physical and theoretical chemistry ,QD450-801 ,Electrochemistry ,high-energy battery ,quasi-solid-state electrolyte ,Electrolyte ,thermally durable electrolyte ,lithium ion battery ,Lithium-ion battery - Abstract
For ensuring safety of lithium ion batteries (LIBs), we have extensively investigated the quasi-solid electrolyte where lithium ion conducive liquid is quasi-solidified at silica surfaces as thermally durable electrolyte, and applied it to high capacity and high energy density LIB. For the liquid phase, a solvate ionic liquid, which is an equimolar complex of lithium bis(trifluoromethanesulfonyl)amide (LiTFSA) and tetraethylene glycol dimethyl ether (G4), Li(G4)TFSA, was used. For enhancing discharge capability at a higher rate, Li(G4)TFSA was diluted by low viscos solvent such as propylene carbonate (PC). The developed electrolyte possessed a favorable volatilization temperature higher than 373 K. A 100-Wh-class laminated LIB with energy density of 363 Wh L−1 was fabricated by employing the electrolyte to graphite-LiNixCoyMnzO2 chemistry, and it generated neither fire nor smoke in a nail-penetration test. The result suggest that the developed LIB has high safety compared to a LIB comprised of a conventional organic liquid electrolyte. In addition, to enhance the cycle life of the LIB, the formation and growth mechanism of a solid-electrolyte interphase on a graphite-based negative electrode was investigated. Nuclear magnetic resonance and hard x-ray photoelectron spectroscopy revealed that the decompositions of LiTFSA, PC, and G4 contributed to the SEI formation at the initial charge, and that continuous decompositions of G4 and PC were a major reason for the SEI growth during charge-discharge cycles. Based on these analysis, we have substituted a highly concentrated sulfolane based liquid which exhibits a high Li ion conductivity with less amount of the low viscos solvent, for the G4 based liquid. The modification effectively improved the electrochemical durability of the electrolyte, leading to a higher capacity retention after charge-discharge cycle test.
- Published
- 2021
10. Effect of AlF3-Coated Li4Ti5O12 on the Performance and Function of the LiNi0.5Mn1.5O4||Li4Ti5O12 Full Battery—An in-operando Neutron Powder Diffraction Study
- Author
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Gemeng Liang, Anoop Somanathan Pillai, Vanessa K. Peterson, Kuan-Yu Ko, Chia-Ming Chang, Cheng-Zhang Lu, Chia-Erh Liu, Shih-Chieh Liao, Jin-Ming Chen, Zaiping Guo, and Wei Kong Pang
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lithium ion battery ,in-operando ,neutron powder diffraction ,real-time analysis ,electrochemistry ,protective coating ,General Works - Abstract
The LiNi0.5Mn1.5O4 ||Li4Ti5O12 (LMNO||LTO) battery possesses a relatively-high energy density and cycle performance, with further enhancement possible by application of an AlF3 coating on the LTO electrode particles. We measure the performance enhancement to the LMNO||LTO battery achieved by a AlF3 coating on the LTO particles through electrochemical testing and use in-operando neutron powder diffraction to study the changes to the evolution of the bulk crystal structure during battery cycling. We find that the AlF3 coating along with parasitic Al doping slightly increases capacity and greatly increases rate capability of the LTO electrode, as well as significantly reducing capacity loss on cycling, facilitating a gradual increase in capacity during the first 50 cycles. Neutron powder diffraction reveals a structural response of the LTO and LNMO electrodes consistent with a greater availability of lithium in the battery containing AlF3-coated LTO. Further, the coating increases the rate of structural response of the LNMO electrode during charge, suggesting faster delithiation, and enhanced Li diffusion. This work demonstrates the importance of studying such battery performance effects within full configuration batteries.
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- 2018
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11. Comparative study of Sn-doped Li[Ni0.6Mn0.2Co0.2-xSnx]O2 cathode active materials (x= 0-0.5) for lithium ion batteries regarding electrochemical performance and structural stability.
- Author
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Eilers-Rethwisch, M., Hildebrand, S., Evertz, M., Ibing, L., Dagger, T., Winter, M., and Schappacher, F.M.
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CATHODES , *COPRECIPITATION (Chemistry) , *ELECTROCHEMISTRY , *LITHIUM , *TIN , *THERMAL analysis - Abstract
Layered Ni-rich Li[Ni 0.6 Mn 0.2 Co 0.2- x Sn x ]O 2 cathode active materials with x = 0–0.05 are synthesized via a co-precipitation synthesis route and the effect of doping content on the structural behavior and electrochemical performance are investigated. All synthesized materials show a well-defined layered structure of the hexagonal α -NaFeO 2 phase (space group R 3 ¯ m ) analyzed by X-ray diffraction (XRD). Electrochemical Li-metal/cathode cell studies exhibit that a Sn-content of 1%–2% is beneficial regarding specific discharge capacity and cycle life (≥20%). Detailed electrochemical investigations of Li-metal and lithium ion cells with cathodes consisting of LiNi 0.6 Mn 0.2 Co 0.2 O 2 and LiNi 0.6 Mn 0.2 Co 0.18 Sn 0.02 O 2 are conducted. Post mortem analyses by means of ICP-OES and TXRF show beneficial effects of the Sn-doping with regard to a lower transition metal dissolution and a higher available Li content in the cathode active material. The thermal analyses (TGA, DSC, ARC) show a stabilizing effect of Sn-doping, which results from a lower mass loss and less heat evolution of the charged cathode active materials at elevated temperatures. [ABSTRACT FROM AUTHOR]
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- 2018
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12. Enhanced electrochemical and safe performances of LiNi1/3Co1/3Mn1/3O2 by nano-CeO2 coating via a novel hydrolysis precipitate reaction route.
- Author
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Cheng, Cuixia, Chen, Fang, Yi, Huiyang, and Lai, Guosong
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ELECTROCHEMISTRY , *CERIUM oxides , *HYDROLYSIS , *PRECIPITATION (Chemistry) , *X-ray diffraction - Abstract
The homogeneous nano-CeO 2 coated on the LiNi 1/3 Co 1/3 Mn 1/3 O 2 powder like substrate was prepared via a novel hydrolytic precipitation reaction followed by the thoroughly baking at 450 °C. The chemical composite of nano-CeO 2 coating layer was spectroscopically examined by X-ray diffraction, field-emission scanning electron microscopy and X-ray photoelectron spectrometer. The electrochemical characterization of the resulting materials proclaim that nano-CeO 2 coating can drastically improve lithium storage performances. The optimum coating amount of CeO 2 is as high as 2 wt%, which rendered a discharge capacity of 148.9 mAh g −1 with 91.6% capacity retention ensuing as many as 100 cycles. In particular, the exothermic peak is vastly increased from 256.4 to 338.2 °C. The value is superior to its counterparts, LiNi 1/3 Co 1/3 Mn 1/3 O 2 . It paves a new avenue for developing high safety lithium batteries. [ABSTRACT FROM AUTHOR]
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- 2018
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13. An easy and scalable approach to synthesize three-dimensional sandwich-like Si/Polyaniline/Graphene nanoarchitecture anode for lithium ion batteries.
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Huang, Rui-An, Guo, Yuzhong, Chen, Zhining, Zhang, Xingshuai, Wang, Jianhua, and Yang, Bin
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LITHIUM-ion batteries , *GRAPHENE , *ANODES , *POLYANILINES , *ELECTRIC conductivity , *ELECTROCHEMISTRY - Abstract
A new three-dimensional (3D) sandwich-like Si/Polyaniline/Graphene nanoarchitecture anode for lithium ion batteries (LIBs) is successfully fabricated through an easy approach. In this nanoarchitecture, the in-situ polymerized electronic conductive polyaniline (PAni) hydrogel, acting as “glue”, agglutinates tightly to both the silicon nanoparticles (SiNPs) and graphene sheets, forming efficient conductive networks with high elastic modulus and high tensile strength. This mechanically robust nanoarchitecture can endure the great volume change of silicon and retain structural stability during Li-ion insertion/extraction. The electrodes consisting of this 3D sandwich-like Si/Polyaniline/Graphene nanoarchitecture reveal excellent electrochemical performance. The progress made in this work provides an easy and scalable route for preparing Si-based anode materials with high performance for advanced LIBs. [ABSTRACT FROM AUTHOR]
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- 2018
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14. Theoretical calculation and experimental verification of Zn3V3O8 as an insertion type anode for LIBs.
- Author
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Tang, Jun, Ni, Shibing, Zhou, Bo, Chao, Dongliang, Li, Tao, and Yang, Xuelin
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LITHIUM-ion batteries , *ZINC compounds , *ANODES , *ELECTROCHEMISTRY , *CRYSTAL structure - Abstract
The charge/discharge mechanism and electrochemical performance of Zn 3 V 3 O 8 as anode for Li-ion batteries are systematically studied. Theoretical calculation predicts that Zn 3 V 3 O 8 can act as a host for Li storage, and a possible diffusion way of Li-ions within the crystal structure is calculated via first principle methods. Experimentally, Zn 3 V 3 O 8 nanosheets with porous architecture are fabricated via a facile hydrothermal pretreatment and subsequent sintering. The Zn 3 V 3 O 8 shows superior electrochemical performance with graphite electric additive, exhibiting discharge/charge capacity of 541/537 mAh g −1 after 200 cycles at a specific current of 120 mA g −1 . The Li-storage mechanism is also studied via ex-situ XRD, and the maintenance of main diffraction peaks during lithiation/delithiation process suggests a possible intercalation/extraction mechanism of the Zn 3 V 3 O 8 . [ABSTRACT FROM AUTHOR]
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- 2018
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15. Simultaneous surface modification method for 0.4LiMnO-0.6LiNiCoMnO cathode material for lithium ion batteries: Acid treatment and LiCoPO coating.
- Author
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Lee, Min-Joon, Lho, Eunsol, Oh, Pilgun, Son, Yoonkook, and Cho, Jaephil
- Abstract
Li-rich layered cathode materials have been considered the most promising candidates for large-scale Li-ion batteries due to their low cost and high reversible capacity. However, these materials have many drawbacks that hinder commercialization, such as low initial efficiency and cyclability at elevated temperatures. To overcome these barriers, we propose an efficient and effective surface modification method, in which chemical activation (acid treatment) and LiCoPO coating were carried out simultaneously. During the synthesis, the lithium ions were extracted from the lattice, leading to improved Columbic efficiency, and these ions were used for the formation of LiCoPO. The Ni and Co doped spinel phase was formed at the surface of the host material, which gives rise to the facile pathway for lithium ions. The LiCoPO and highly doped spinel on the surface acted as double protection layers that effectively prevented side reactions on the surface at 60 °C. Moreover, the transition metal migration of the modified cathode was weakened, due to the presence of the spinel structure at the surface. Consequently, the newly developed Li-rich cathode material exhibited a high 1st efficiency of 94%, improved capacity retention of 82% during 100 cycles at 60 °C, and superior rate capability of 62% at 12C (1C = 200 mA/g) rate at 24 °C. In addition, the thermal stability of the modified cathode was significantly improved as compared to that of a bare counterpart at 4.6 V, showing a 60% decrease in the total heat generation. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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16. Mechanistic insights into high lithium storage performance of mesoporous chromium nitride anchored on nitrogen-doped carbon nanotubes.
- Author
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Idrees, Memona, Abbas, Syed Mustansar, Ata-Ur-Rehman, null, Ahmad, Nisar, Mushtaq, Muhammad Waheed, Naqvi, Rizwan Ali, Nam, Kyung-Wan, Muhammad, Bakhtiar, and Iqbal, Zafar
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CARBON nanotubes , *CHROMIUM compounds synthesis , *AMMONIA analysis , *ELECTROCHEMISTRY , *ELECTROCHEMICAL electrodes , *LITHIUM , *X-ray diffraction - Abstract
Chromium nitride (CrN) synthesized by heating at 550 °C under a continuous stream of ammonia has been investigated as anode material for lithium electrochemistry. Due to its low lithium insertion potential, Cr is an attractive material for lithium–ion battery application, but the usual volume variation effect obstructs its practical use. In this study, different concentrations of carbon nanotubes doped with nitrogen (NCNTs) are combined with CrN to attain high electrochemical performance. The synthesized CrN/0.08%–NCNTs nanocomposite demonstrates network structure with 30–40 nm CrN nanoparticles anchored to specific sites on 40–60 nm diameter NCNTs. Upon electrochemical testing, CrN/0.08%–NCNTs nanocomposite displays a discharge capacity of 1172 mAh g −1 after 200 cycles with high coulombic efficiency (∼100%) and rate capability. The electrode can deliver a reversible capacity of 1042.9 mAh g −1 at 20 C. The n-type concentration, along with the conductive CNTs framework, mesoporous channels, appropriate surface area and buffering capability of CNTs, are together responsible for the excellent electrochemical performance. The electrochemical reaction mechanism of CrN with lithium is explored by investigating the structural changes using ex situ X-ray photoelectron spectroscopy, X-ray diffraction, selected area electron diffraction, and high-resolution transmission electron microscopy. The reversible conversion reaction of CrN into Cr metal and Li 3 N is revealed. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
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17. Enhanced electrochemical performances of LiNi0.5Mn1.5O4 spinel in half-cell and full-cell via yttrium doping.
- Author
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Wu, Wei, Guo, Jianling, Qin, Xing, Bi, Chunbo, Wang, Jiangfeng, Wang, Li, and Liang, Guangchuan
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ELECTROCHEMISTRY , *LITHIUM compounds , *YTTRIUM compounds , *SPINEL group , *X-ray diffraction - Abstract
Pristine and yttrium-doped LiNi 0.5- x Y x Mn 1.5 O 4 spinel powders ( x = 0, 0.005, 0.01, 0.02, 0.04) were synthesized by a facile solid-state method. The effect of yttrium doping content on the electrochemical properties of LiNi 0.5- x Y x Mn 1.5 O 4 was investigated by using half-cells paired with lithium metal and full-cells paired with graphite. XRD and FT-IR analysis shows that the cation disordering degree (Mn 3+ content) first increase ( x ≤ 0.02) and then decrease with Y doping content and the Y doping can effectively inhibit the formation of Li x Ni 1- x O impurity phase. Electrochemical results show that in half-cells, the LiNi 0.5-x Y x Mn 1.5 O 4 cathode material with appropriate Y doping ( x = 0.01) exhibits optimal rate capability and cycling stability, due to higher phase purity, enlarged lattice parameter, higher disordering degree, higher structural stability by introducing Y O bond, lower charge transfer resistance and higher lithium ion diffusion coefficient, although the 0.2C discharge capacity is slightly lower than pristine LiNi 0.5 Mn 1.5 O 4 . Atomic Absorption Spectroscopy result shows that appropriate Y doping can effectively decrease the transition metal dissolution to certain extent, despite of higher Mn 3+ content. All above factors lead to the improved cycling performance of Y-doped electrode in half-cells paired with metallic Li at elevated temperature (55 °C) and in full-cells paired with graphite at room temperature. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
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18. Meticulous guard: The role of Al/F doping in improving the electrochemical performance of high-voltage spinel cathode
- Author
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Ying Luo, Wang Yong, Liqin Yan, Liheng Zhang, Jingying Xie, Yang Yang, and Zhimin Xue
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Materials science ,LiNi0.5Mn1.5O4 ,02 engineering and technology ,Temperature cycling ,Electrolyte ,engineering.material ,010402 general chemistry ,Electrochemistry ,01 natural sciences ,law.invention ,law ,Specific surface area ,lcsh:TA401-492 ,Suppress side reactions ,Spinel ,Doping ,Metals and Alloys ,021001 nanoscience & nanotechnology ,High temperature ,Cathode ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Lithium ion battery ,Chemical engineering ,Electrode ,engineering ,lcsh:Materials of engineering and construction. Mechanics of materials ,0210 nano-technology ,Morphology control - Abstract
Spinel LiNi0.5Mn1.5O4, which is considered as one of the most attractive candidates for high energy density battery due to its high voltage platform over 4.7 V, suffers from the side reactions with electrolyte, strong oxidability of Ni4+ and therefore the complicated and frangible Solid Electrolyte Interfaces (SEI) layer that hinders the practical application of LiNi0.5Mn1.5O4. In this work, traditional co-precipitation method is applied and improved by anion and cation doping method to construct superior interface on the surface of LiNi0.5Mn1.5O4 to suppress side reactions especially at high temperature. Detailed properties including structure, morphology and electrochemical performance of pristine sample, single-doped and co-doped samples are probed. Physical characterizations reveal that the co-doped sample with regular octahedron has a moderate grain size and specific surface area between Al and F single doping, and holds the advantages of rate performance and capacity retention causing by Al doping and better stability under high temperature constructing by F. It exhibits the best capacity retention of 92% after 200 cycles under 55 °C, which is higher than that of the pristine sample (87%). Analysis of the electrode after cycling shows that doping reduces the thickness of the electrode interface film and the content of inorganic substances such as LiF to improve the interface characteristics and the high temperature cycling performance. This work has certain significance for the commercial application of LiNi0.5Mn1.5O4.
- Published
- 2021
19. Designing carbon-supported Fe2O3 anodes for lithium ion batteries
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Billur Deniz Karahan and Mehmet Feryat Gülcan
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Materials science ,General Chemical Engineering ,Iron oxide ,Hematite ,chemistry.chemical_element ,Lithium Ion Battery ,Carbon Black ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,Carbide ,chemistry.chemical_compound ,Materials Chemistry ,Electrochemistry ,Composite Anodes ,Carbon black ,Size Optimization By Taguchi Methodology ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,chemistry ,Chemical engineering ,Hydrothermal Synthesis ,Particle ,Lithium ,Particle size ,0210 nano-technology ,Carbon ,Faraday efficiency - Abstract
In this study, within the defined orthogonal array of Taguchi design, the hydrothermal process parameters have been optimized for fabricating the smallest particle sized iron oxide (Fe2O3) particles. The finest particle size (210 nm) has been achieved when 0.02 M FeCl3 solution at pH 10 is hydrothermally treated for 90 min with an autoclave filling ratio of 100% (D3). Afterwards, to improve the physical properties of iron oxide particles, carbon black powder is added into the precursor solution as the seeding agent before the hydrothermal treatment. Structural and morphological analyses show that upon the existence of carbon in the precursor solution, C-supported Fe2O3 (D5) is fabricated. In the latter, carbon is present in graphitic form and no carbide formation is detected. Electrochemical test results verify that unlike to Fe2O3 (D3), C-supported Fe2O3 (D5) electrode performs lower charge transfer resistance and polarization leading to higher first coulombic efficiency, capacity retention, and improved rate performance, eventually. Thanks to the favorable characteristics of the latter, after 150 cycles, D5 performs 550, 390, and 333 mAh g(-1) discharge capacities under loads of 50 mA g(-1), 500 mA g(-1), and 1.5 A g(-1), respectively. Finally, to understand the contribution of capacitive and diffusion-controlled reactions to the total stored charge, an adopted sweep rate method has been used. The calculated voltammograms reveal that fabricating C-supported Fe2O3 particles led to improved rate performance because faradaic reactions that occur at the surface of the material prevail.
- Published
- 2021
20. Analysis of Electrochemical Reaction in Positive and Negative Electrodes during Capacity Recovery of Lithium Ion Battery Employing Recovery Electrodes
- Author
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Jun Kawaji, Ito Shota, Eiji Seki, Takefumi Okumura, Masatoshi Sugimasa, and Kohei Honkura
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Technology ,Materials science ,Physical and theoretical chemistry ,QD450-801 ,Inorganic chemistry ,recovery electrode ,capacity recovery ,Electrochemistry ,Lithium-ion battery ,mental disorders ,Electrode ,discharge curve analysis ,lithium ion battery ,psychological phenomena and processes - Abstract
Electrochemical reactions in positive and negative electrodes during recovery from capacity fades in lithium ion battery cells were evaluated for the purpose of revealing the recovery mechanisms. We fabricated laminated type cells with recovery electrodes, which sandwich the assemblies of negative electrodes, separators, and positive electrodes. The positive electrodes were replenished with Li+ by applying current between the recovery and the positive electrodes. A discharge curve analysis revealed that Li+ replenishment enabled the cells to recover from the capacity fade originating from capacity slippage between the positive and the negative electrodes. However, an issue is low recovery efficiency, which is defined as the ratio of recovery capacity of capacity slippage to the electric charge between the recovery and the positive electrodes. The cause of low recovery efficiency was elucidated by evaluating the positive and the negative electrodes after replenishment. It was found that the following mechanisms are involved in the replenishment of the positive electrodes: (a) Li+ are intercalated into the positive electrodes as they are released from the recovery electrodes, which significantly contributes to recovery from capacity slippage; however, (b) some amount of Li+ is released from the planes of the negative electrodes facing the positive electrodes as they are intercalated into the planes of the negative electrodes facing the recovery electrodes, which does not significantly contribute to recovery. Consequently, the recovery efficiencies were less than 50 %. We conclude that, to increase recovery efficiency, process (b) should be suppressed.
- Published
- 2021
21. Machine learning for optimal electrode wettability in lithium ion batteries
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Amina El Malki, Mark Asch, Oier Arcelus, Abbos Shodiev, Jia Yu, Alejandro A. Franco, Laboratoire réactivité et chimie des solides - UMR CNRS 7314 (LRCS), Université de Picardie Jules Verne (UPJV)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Réseau sur le stockage électrochimique de l'énergie (RS2E), Aix Marseille Université (AMU)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)-Nantes Université (Nantes Univ)-Université de Montpellier (UM)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM), Université de Montpellier (UM), Laboratoire Amiénois de Mathématique Fondamentale et Appliquée - UMR CNRS 7352 (LAMFA), Université de Picardie Jules Verne (UPJV)-Centre National de la Recherche Scientifique (CNRS), Advanced Lithium Energy Storage Systems - ALISTORE-ERI (ALISTORE-ERI), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut Universitaire de France (IUF), and Ministère de l'Education nationale, de l’Enseignement supérieur et de la Recherche (M.E.N.E.S.R.)
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Electrolyte wettability ,Machine learning ,Lattice Boltzmann method ,Materials Chemistry ,Electrochemistry ,Energy Engineering and Power Technology ,[CHIM.MATE]Chemical Sciences/Material chemistry ,Lithium ion battery - Abstract
International audience; Electrode wetting is a critical step in the Lithium-Ion Battery manufacturing process. The injection of electrolyte in the electrodes’ porosity requires the application of pressure-vacuum pumping strategies without warranty that the full porosity will be fully occupied with electrolyte at the end of this process step. The electrode wettability strongly depends on the contact angle between the electrolyte and the electrode, the electrode microstructure characterized by its porosity, pore network and tortuosity factor, the electrolyte viscosity and density. Computational fluid dynamics approaches such as the Lattice Boltzmann Method can provide relevant information of the filling process, yet these approaches come with significant computational cost. The use of machine learning techniques can provide surrogate models for the optimization of this multi-parameter process that depends on both chemical and physical properties. Within this context, we propose a general workflow for realizing this objective and provide detailed simulation-based experiments. These physics-informed surrogate models open the path to tractable, rapid solutions of parameter identification and design optimization problems. They also provide a general workflow for applications on other optimal battery material design problems.
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- 2023
22. Liquid lithium metal processing into ultrathin metal anodes for solid state batteries
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Robin Lissy, rer. nat. Felix Hippauf, rer. nat. Benjamin Schumm, Dr.-Ing. habil. Christoph Leyens, Holger Althues, rer. nat. habil. Stefan Kaskel, Kay Schönherr, and Publica
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Battery (electricity) ,Materials science ,Lithium deposition ,Lithium metal anode ,chemistry.chemical_element ,02 engineering and technology ,Substrate (electronics) ,engineering.material ,010402 general chemistry ,Electrochemistry ,01 natural sciences ,7. Clean energy ,Chemical engineering ,Coating ,business.industry ,all solid state battery ,General Medicine ,All-solid-state battery ,Current collector ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Anode ,Lithium ion battery ,chemistry ,engineering ,Optoelectronics ,Lithium ,TP155-156 ,Wetting ,0210 nano-technology ,business - Abstract
Lithium metal anodes are among the most promising candidates for further increasing the energy density of lithium ion batteries and all-solid-state batteries. A reduction of the anode thickness by using ultrathin lithium metal films is a crucial requirement to achieve a significant overall reduction of thickness on cell level. However, besides anode stabilization, realizing scalable technologies for an efficient production of thin lithium metal anodes is one of the most challenging obstacles for the success of various next-generation battery chemistries. In this publication we introduce a disruptive lithium melt deposition process for thin lithium metal coating on thin copper current collector foils. The wetting of molten lithium on the substrate can only be achieved through a lithiophilic interlayer. As a result fast and homogeneous lithium spreading on the substrate is enabled allowing roll-to-roll coating with liquid-deposition technologies as demonstrated in this contribution with a speed of several meters per minute and reaching 100 mm width. With this new process the anode thickness can be tuned in a wide range (1 - 30 µm). Evaluation in a prototype solid battery system shows high electrochemical lithium utilization and no detrimental effects compared to commercially available lithium reference foils.
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- 2022
23. Understanding the Influence of Temperature on Phase Evolution during Lithium-Graphite (De-)Intercalation Processes: An Operando X-ray Diffraction Study
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K. Andreas Friedrich, Alexander Kube, Norbert Wagner, and Christina Schmitt
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Materials science ,Intercalation (chemistry) ,Temperature ,chemistry.chemical_element ,Lithium Ion Battery ,Phase evolution ,Catalysis ,chemistry ,X-ray crystallography ,Electrochemistry ,Physical chemistry ,Lithium ,Graphite - Published
- 2022
24. Pulse combustion reactor as a fast and scalable synthetic method for preparation of Li-ion cathode materials.
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Križan, Gregor, Križan, Janez, Dominko, Robert, and Gaberšček, Miran
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LITHIUM-ion batteries , *HYDROTHERMAL synthesis , *ELECTROCHEMISTRY , *CARBONATES , *COMBUSTION reactors - Abstract
In this work a novel pulse combustion reactor method for preparation of Li-ion cathode materials is introduced. Its advantages and potential challenges are demonstrated on two widely studied cathode materials, LiFePO 4 /C and Li-rich NMC. By exploiting the nature of efficiency of pulse combustion we have successfully established a slightly reductive or oxidative environment necessary for synthesis. As a whole, the proposed method is fast, environmentally friendly and easy to scale. An important advantage of the proposed method is that it preferentially yields small-sized powders (in the nanometric range) at a fast production rate of 2 s. A potential disadvantage is the relatively high degree of disorder of synthesized active material which however can be removed using a post-annealing step. This additional step allows a further tuning of materials morphology as shown and commented in some detail. [ABSTRACT FROM AUTHOR]
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- 2017
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25. Co3O4/Co nanoparticles enclosed graphitic carbon as anode material for high performance Li-ion batteries.
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Yan, Zhiliang, Hu, Qiyang, Yan, Guochun, Li, Hangkong, Shih, Kaimin, Yang, Zhewei, Li, Xinhai, Wang, Zhixing, and Wang, Jiexi
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COMPOSITE materials , *COBALT oxides , *NANOPARTICLES , *ANODES , *ELECTROCHEMISTRY , *CARBONIZATION , *GRAPHITIZATION , *THERMAL oxidation (Materials science) - Abstract
The composite of Co 3 O 4 , Co and graphitized carbon is synthesized by carbonization and cobalt-catalyzed-graphitization of carboxymethyl chitosan, followed by low-temperature thermal oxidation. At the high temperature, the Co(+2) is reduced to metallic Co and the produced Co acts as a catalyst for the graphitization of the pyrolytic carbon. The low-temperature oxidation is conducted to selectively oxidize Co to Co 3 O 4 while the carbon remains unreacted. The structure analysis indicates that three crystal phases (graphite, metallic Co, Co 3 O 4 ) accompanied with amorphous carbon are co-existed in the composite. Morphological results demonstrate that a lot of graphite grains around the Co element are distributed in the carbon. The electrochemical testing results indicate that the composite shows good electrochemical performance. It delivers a reversible capacity of 843 mAh g −1 at low current density, and remains 88.9% after 60 cycles at 200 mA g −1 . Even performed at 1 A g −1 , it also exhibits 493 mAh g −1 . The performance improvement is mainly due to the high capacity of Co 3 O 4 , high conductivity of graphitic carbon and metallic cobalt, the porous structure offering enough ion transport pathways and relieving the strain during cycling. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
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26. Electrochemical performances of MgH2 and MgH2-C films for lithium ion battery anode.
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Peng, Xiang, Wang, Hui, Hu, Renzong, Ouyang, Liuzhang, Liu, Jiangwen, and Zhu, Min
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ELECTROCHEMISTRY , *MAGNESIUM compounds , *METALLIC films , *LITHIUM-ion batteries , *ANODES , *HYDROGEN storage - Abstract
As a high-capacity hydrogen storage material, MgH 2 also shows specific advantages for LIB anode. In this work, MgH 2 and MgH 2 -C films were prepared by magnetron sputtering and hydrogenation treatment, and their microstructural and electrochemical properties were investigated. Through the conversion reaction of MgH 2 with lithium (MgH 2 + 2Li + → Mg + 2LiH), the reversible lithium storage was achieved in the MgH 2 and MgH 2 -C films. The MgH 2 film delivers the initial discharge capacity of 313.9 μAh cm −2 (∼2956 mAh g −1 ), the discharge and charge capacities related to the conversion process are respectively 150.0 μAh cm −2 (∼1412 mAh g −1 ) and 55.0 μAh cm −2 (∼518 mAh g -1 ), with the inefficiency of 63.3%. The GITT measurement determined the equilibrium potential of this conversion reaction to be 0.55 V vs. Li/Li + , and the voltage hysteresis between discharge and charge is only 10 mV vs. Li/Li + . In comparison with the MgH 2 film, the MgH 2 -C film has smaller crystallite size, lower polarization effect and structural stability, but exhibiting lower capacity and equally poor cyclic performance. The poor cycle life of MgH 2 -C film electrode is due to the large irreversibility of conversion reaction of MgH 2 , instead of structural damage of film electrode during cycling. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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27. Optimally designed interface of lithium rich layered oxides for lithium ion battery.
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He, Zhenjiang, Ping, Jing, Yi, Zhaojun, Peng, Cheng, Shen, Chensi, and Liu, Jianshe
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LITHIUM-ion batteries , *CRYSTAL morphology , *CRYSTAL structure , *ELECTROCHEMISTRY , *METALLIC oxides , *CALCINATION (Heat treatment) - Abstract
Particle morphology structure design combined with surface modification has been applied to improve the electrochemical properties of lithium rich layered oxides. Hollow spherical lithium rich layered Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2 oxides with different shell thickness are synthesized by co-precipitation followed by calcination. The morphology and interior structure have been investigated by SEM and cross section, and their electrochemical properties have been evaluated to identify an appropriate shell thickness. Furthermore, a Zr compound coating layer has been applied to modify the interface between corrosive electrolyte and hollow spherical particles with an appropriate shell thickness. The Electrochemical impedance spectroscopy shows hollow spherical structure and Zr compound coating layer both can modificate the electronic and ionic transmission capacities and inhibit their deterioration during charge-discharge process at the same time. The HRTEM tests indicate that hollow spherical structure and Zr compound coating layer can dramatically suppress Mn dissolution in electrolyte and make the crystal structure more stable during the electrode process. Therefore, a surface modification combine with the hollow spherical structure (with an appropriate shell thickness) can effectively enhance these electrochemical properties of lithium ion layered oxides. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
28. Self-supported PVdF/P(VC-VAc) blended polymer electrolytes for LiNi0.5Mn1.5O4/Li batteries.
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Minkai Zhao, Xiaoxi Zuo, Xiangdong Ma, Xin Xiao, Jiansheng Liu, and Junmin Nan
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- *
POLYELECTROLYTES , *LITHIUM compounds , *ELECTROCHEMISTRY , *FOURIER transform infrared spectroscopy , *POROUS materials - Abstract
New self-supported poly(vinylidene fluoride)/poly (vinyl chloride-co-vinyl acetate) (PVdF/P(VC-VAc)) blended polymer membranes are prepared via a phase inversion method, and then their electrochemical performances, immersed in the liquid electrolyte as the polymer electrolyte for lithium-ion batteries (LIBs), are evaluated. The Fourier transform infrared spectroscopy analysis, the differential scanning calorimeter test and the X-ray diffraction measurement demonstrate that homogeneous PVdF/P(VC-VAc) polymer composites can form at all blend compositions and the crystallinity degree of the blended polymers decreases as the P(VC-VAc) content increases. Specifically, when the proportion of PVdF/P(VC-VAc) is 70:30 (wt%), membranes with a rich surface and internal porous structure can be acquired. The ionic conductivity of the polymer electrolyte achieves a maximum value of 3.57 mS cm-1 at room temperature, and favourable electrochemical performances of LIBs can be obtained. LiNi0.5Mn1.5O4/Li cells with the as-prepared polymer electrolyte exhibit a higher initial discharge capacity of 131.0 mAh g-1 and superior cycle stability with a capacity retention of 96.1% at 0.2 C after 200 cycles compared to cells based on pure PVdF and P(VC-VAc) membranes. This can be attributed to the superior compatibility of the electrolyte with the electrodes. The results also indicate this electrolyte has promising applications in high-voltage LIBs. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
29. Synthesis and electrochemical properties of FeCO3 with different morphology for lithium-ion battery application.
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Liu, Xiaolin, Yang, Shuijin, Chen, Xiao, Zheng, Hao, Guo, Zaiping, and Feng, Chuanqi
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LITHIUM-ion batteries , *ELECTROCHEMISTRY , *IRON compound synthesis , *SURFACE morphology , *AMMONIUM bicarbonate , *X-ray photoelectron spectroscopy - Abstract
FeCO 3 with the morphology of microspheres and rice-like were successfully fabricated by a facile mixed solvothermal method by using urea and ammonium bicarbonate as precipitants, respectively. The as-synthesized samples were characterized by X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy. The electrochemical properties of the samples were investigated by battery testing system. The influences of different precipitants on its structure, morphology and the electrochemical properties were also discussed. The results showed that the diameter of FeCO 3 microspheres (FCO-1) was 8–10 μm by using urea as precipitant, while the size of FeCO 3 rice-like (FCO-2) by using ammonium bicarbonate as precipitant was 0.5–1.0 μm. When used as an anode material for lithium ion batteries, FCO-1 and FCO-2 delivered the initial specific discharge capacities of 1563.54 and 1518.09 mAh g −1 at the current density of 100 mA g −1 in the voltage range of 0.01–3 V and remained its reversible value of 854.65 and 1019.47 mAh g −1 over 100 cycles, respectively. The FCO-2 still possessed a considerable capacity of 890.23 mAh g −1 at a high current density of 500 mA g −1 . Therefore, FCO-2 synthesized through using ammonium bicarbonate as precipitant could be a potential anode candidate for lithium ion batteries. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
30. Optimized fabrication of NiCr2O4 and its electrochemical performance in half-cell and full-cell lithium ion batteries.
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Tang, Jun, Ni, Shibing, Chen, Qichang, Yang, Xuelin, and Zhang, Lulu
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LITHIUM-ion batteries , *NICKEL chromite , *MICROFABRICATION , *ELECTROCHEMISTRY , *EFFECT of temperature on metals - Abstract
Temperature dependent fabrication of NiCr 2 O 4 is studied and the application of the as-prepared NiCr 2 O 4 in both half-cell with Li metal anode and full-cell with LiFePO 4 cathode are assessed. When mixing with natural graphite (NG), the NiCr 2 O 4 obtained at 550 °C can deliver initial charge and discharge capacities of 795 and 1275.5 mAh g −1 at a specific current of 150 mA g −1 , maintaining of 939 and 955 mAh g −1 after 140 cycles. In contrast, after 140 cycles at the same specific current, the NiCr 2 O 4 obtained at 450 °C and 650 °C can maintain charge/discharge capacities of 800/814 and 523/528 mAh g −1 , respectively. When matching with a LiFePO 4 cathode, The NiCr 2 O 4 /NG (obtained at 550 °C) electrode delivers initial discharge capacity of 285 mAh g −1 , which maintains of 106 mAh g −1 after 50 cycles at a specific current of 100 mA g −1 . [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
31. Electrochemical properties of micron-sized Co3O4 hollow powders consisting of size controlled hollow nanospheres.
- Author
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Park, Jin-Sung, Cho, Jung Sang, Kim, Jong Hwa, Choi, Yun Ju, and Kang, Yun Chan
- Subjects
- *
ELECTROCHEMISTRY , *COBALT oxides , *POWDER metallurgy , *PYROLYSIS , *NANOCRYSTALS - Abstract
Micron-sized Co 3 O 4 hollow powders consisting of size controlled hollow nanospheres are prepared by applying Ostwald ripening and Kirkendall effect to the spray pyrolysis process. The Co-C composite powders uniformly dispersed with different sizes of metallic Co nanocrystals are formed by reduction of the cobalt oxide-carbon composite powders prepared using spray pyrolysis. Subsequent oxidation of the Co-C composite powders with filled structures forms the micron-sized Co 3 O 4 hollow powders consisting of size controlled hollow nanospheres. The mean sizes of the Co 3 O 4 hollow nanospheres oxidized from Co-C composite powders formed at reduction temperatures of 400, 600, and 800 °C are 37, 55, and 73 nm, respectively. The discharge capacities of the Co 3 O 4 powders formed from the Co-C composite powders reduced at temperatures of 400, 600, and 800 °C for the 300 th cycle are 644, 702, and 660 mA h g −1 , respectively, and their capacity retentions calculated from the second cycle are 81, 86, and 84%, respectively. The porous-structured Co 3 O 4 powders formed from the Co-C composite powders reduced at 800 °C show slightly better rate performance than those of the other two samples. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
32. Different roles of ionic liquids in lithium batteries.
- Author
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Eftekhari, Ali, Liu, Yang, and Chen, Pu
- Subjects
- *
IONIC liquids , *LITHIUM-ion batteries , *ELECTROCHEMISTRY , *PLASTICIZERS , *POLYELECTROLYTES - Abstract
Ionic liquids are often named solvents of the future because of flexibility in design. This statement has given credence that ionic liquids should simply replace the problematic electrolytes of lithium batteries. As a result, the promising potentials of ionic liquids in electrochemical systems are somehow obscured by inappropriate expectations. We summarize recent advancements in this field, especially, ionic liquids as standalone electrolytes, additives, plasticizers in gel polymer electrolytes, and binders; and attempt to shed light on the future pathway of this area of research. Ionic liquids are not dilute media to serve as pure solvents in electrochemical systems where mobility of ions is the priority; instead, they can contribute to the ionic conductivity of various components in a battery system. Owing to the enormous possibilities of ionic liquids, it is not merely a matter of choice. Ionic liquids can be used to design novel types of electrolytes for a new generation of lithium batteries. A promising possibility, which is still at a very early stage, is supercooled ionic liquid crystals for fast ion diffusion through the guided channels of a liquid-like medium. This, of course, will be a breakthrough in the realm of electrochemistry, far beyond lithium battery field, when materialized. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
33. Effect of particle size on the conductive and electrochemical properties of LiZnTiO.
- Author
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Nikiforova, P., Stenina, I., Kulova, T., Skundin, A., and Yaroslavtsev, A.
- Subjects
- *
ELECTROCHEMISTRY , *PARTICLE size distribution , *LITHIUM compounds , *TITANATES , *ELECTRIC conductivity , *LITHIUM-ion batteries - Abstract
We have studied the effect of final annealing temperature on the formation of lithium zinc titanate, its electrical conductivity, and its electrochemical performance. LiZnTiO has been shown to form in a wide range of annealing temperatures, from 673 to 1073 K. Its particle size increases systematically with increasing annealing temperature, whereas its conductivity decreases. The highest electrochemical capacity at low currents is offered by the materials annealed at 773 and 873 K, and the highest cycling stability is offered by the material prepared at 873 K. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
34. Highly reversible insertion of lithium into MoO2 as an anode material for lithium ion battery.
- Author
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Kim, Ayoung, Park, Eunjun, Lee, Hyosug, and Kim, Hansu
- Subjects
- *
LITHIUM-ion batteries , *MOLYBDENUM , *X-ray diffraction , *ELECTROCHEMISTRY , *GRAVIMETRIC analysis , *ELECTRODES - Abstract
MoO 2 has gained renewed attention as a safe oxide anode host material for lithium ion insertion because of its high gravimetric/volumetric capacity and highly stable cycling behavior. However, these recent results are completely contrary to previous reports. To confirm that MoO 2 is an appropriate anode material as well as further understand lithium ion reactions when inserted into MoO 2 , we combine electrochemical characterization of MoO 2 electrodes and ex situ X-ray diffraction analysis with first principle calculations. Theoretical capacity of the MoO 2 electrode (∼209 mAh g −1 ) and stable capacity retention up to 100 cycles are simultaneously attained using a proper particle size and type of binder. Ex situ XRD analysis with first principle calculations of the phase transformation of MoO 2 electrodes shows that MoO 2 undergoes reversible structural changes upon lithiation and subsequent delithiation, clearly demonstrating that nanostructured MoO 2 can be used as an anode material for highly reliable lithium ion batteries. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
35. The Remaining Useful Life Prediction by Using Electrochemical Model in the Particle Filter Framework for Lithium-Ion Batteries
- Author
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Qianqian Liu, Chao Lv, Jingyuan Zhang, and Ke Li
- Subjects
Battery (electricity) ,new particle filter framework ,General Computer Science ,Computer science ,020209 energy ,General Engineering ,Stability (learning theory) ,Process (computing) ,chemistry.chemical_element ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Electrochemistry ,simplified electrochemical model ,Lithium-ion battery ,Lithium ion battery ,Reliability engineering ,chemistry ,0202 electrical engineering, electronic engineering, information engineering ,remaining useful life prediction ,General Materials Science ,Lithium ,lcsh:Electrical engineering. Electronics. Nuclear engineering ,0210 nano-technology ,Particle filter ,lcsh:TK1-9971 - Abstract
The remaining useful life (RUL) prediction is critical for the safe and reliable operation of lithium-ion battery (LIB) systems, which characterizes the aging status of the battery and provides early warning for battery replacement. Most existing RUL prediction methods rely on empirical aging models, and the role of the battery mechanism is not considered in the subsequent algorithm settings. The accuracy and stability of data-driven algorithms are severely limited by battery aging data. A new electrochemical-model-based particle filter (PF) framework for LIB RUL prediction is proposed in this paper. Parameters of a simplified electrochemical model (SEM) are used as state variables of the PF algorithm and these parameters can be identified by applying specially designed current excitations to the battery. The SEM-based capacity simulation process is taken as the observation equation in the PF algorithm framework. Therefore, the mechanism of the battery is fully considered when making the RUL prediction. The proposed method is validated through cyclic aging experiment of a cylindrical LFP/graphite LIB of 45Ah. The accuracy of the method is compared with a data-driven-based PF framework for RUL prediction and shows better accuracy and stability, which provides a choice for achieving high-quality RUL prediction.
- Published
- 2020
36. Electrochemical Characterization, Structural Evolution, and Thermal Stability of LiVOPO_4 over Multiple Lithium Intercalations
- Author
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Shigeto Okada, Hiroki Kitamura, Atsushi Sano, and Akinobu Nojima
- Subjects
evergreen ,Materials science ,Cathode material ,chemistry.chemical_element ,LiVOPO_4 ,Management, Monitoring, Policy and Law ,Electrochemistry ,Structural evolution ,Lithium ion battery ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Characterization (materials science) ,chemistry ,Chemical engineering ,Ceramics and Composites ,Lithium ,Thermal stability - Abstract
α1-LiVOPO_4, β-LiVOPO_4, and α-LiVOPO_4 are known as multiple lithium intercalation cathode materials. They were characterized by means of half-cell performance, operando X-ray diffraction (XRD), X-ray absorption spectroscopy (XAS), and differential scanning calorimetry (DSC). The operando XRD revealed differences in crystal structure evolution during charging/ discharging among the three crystal phases. Although the charge/discharge profiles and the crystal structure evolution behaviors were the same among the three crystal phases in the range of 3.5 - 4.5 V, the profiles and behaviors differed completely in the range of 1.0 - 3.5 V. The thermal stability of each phase of LiVOPO_4 is similar to that of LiFePO_4 in the fully charged state from the results of the DSC profiles.
- Published
- 2019
37. A novel all-fiber-based LiFePO4/Li4Ti5O12 battery with self-standing nanofiber membrane electrodes
- Author
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Maoxiang Jing, Fei Chen, Hua Yang, Wei-yong Yuan, Shanshan Yao, Xiangqian Shen, Chong Han, Li-li Chen, and Xin-yu Hu
- Subjects
Battery (electricity) ,Materials science ,General Physics and Astronomy ,02 engineering and technology ,010402 general chemistry ,Electrochemistry ,lcsh:Chemical technology ,01 natural sciences ,lcsh:Technology ,Lithium-ion battery ,Full Research Paper ,self-standing electrodes ,Nanotechnology ,General Materials Science ,lcsh:TP1-1185 ,Fiber ,Electrical and Electronic Engineering ,nanofiber ,lcsh:Science ,electrospinning ,flexible electrodes ,business.industry ,lcsh:T ,021001 nanoscience & nanotechnology ,Electrospinning ,lcsh:QC1-999 ,0104 chemical sciences ,Nanoscience ,Nanofiber ,Electrode ,3d network ,Optoelectronics ,lcsh:Q ,0210 nano-technology ,business ,lithium ion battery ,Faraday efficiency ,lcsh:Physics - Abstract
Electrodes with high conductivity and flexibility are crucial to the development of flexible lithium-ion batteries. In this study, three-dimensional (3D) LiFePO4 and Li4Ti5O12 fiber membrane materials were prepared through electrospinning and directly used as self-standing electrodes for lithium-ion batteries. The structure and morphology of the fibers, and the electrochemical performance of the electrodes and the full battery were characterized. The results show that the LiFePO4 and Li4Ti5O12 fiber membrane electrodes exhibit good rate and cycle performance. In particular, the all-fiber-based gel-state battery composed of LiFePO4 and Li4Ti5O12 fiber membrane electrodes can be charged/discharged for 800 cycles at 1C with a retention capacity of more than 100 mAh·g−1 and a coulombic efficiency close to 100%. The good electrochemical performance is attributed to the high electronic and ionic conductivity provided by the 3D network structure of the self-standing electrodes. This design and preparation method for all-fiber-based lithium-ion batteries provides a novel strategy for the development of high-performance flexible batteries.
- Published
- 2019
38. Self-Healing of a Covalently Cross-Linked Polymer Electrolyte Membrane by Diels-Alder Cycloaddition and Electrolyte Embedding for Lithium Ion Batteries
- Author
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Baohua Zhang, Lijuan Chen, Xisen Cai, Niu Li, Bao Yu, Zhonghui Sun, Zhenbang Liu, and Dongxue Han
- Subjects
Battery (electricity) ,thermally self-healing ,Diels-Alder reaction ,covalently crosslinked ,polymer electrolyte ,lithium ion battery ,Materials science ,Polymers and Plastics ,chemistry.chemical_element ,Organic chemistry ,General Chemistry ,Electrolyte ,Electrochemistry ,Lithium-ion battery ,Article ,Membrane ,QD241-441 ,chemistry ,Chemical engineering ,Ionic conductivity ,Lithium ,Separator (electricity) - Abstract
Thermally reversible self-healing polymer (SHP) electrolyte membranes are obtained by Diels-Alder cycloaddition and electrolyte embedding. The SHP electrolytes membranes are found to display high ionic conductivity, suitable flexibility, remarkable mechanical properties and self-healing ability. The decomposition potential of the SHP electrolyte membrane is about 4.8 V (vs. Li/Li+) and it possesses excellent electrochemical stability, better than that of the commercial PE film which is only stable up to 4.5 V (vs. Li/Li+). TGA results show that the SHP electrolyte membrane is thermally stable up to 280 °C in a nitrogen atmosphere. When the SHP electrolyte membrane is used as a separator in a lithium-ion battery with an LCO-based cathode, the SHP membrane achieved excellent rate capability and stable cycling for over 100 cycles, and the specific discharge capacity could be almost fully recovered after self-healing. Furthermore, the electrolyte membrane exhibits excellent electrochemical performance, suggesting its potential for application in lithium-ion batteries as separator material.
- Published
- 2021
39. Solid Electrolyte Interphase Layer Formation on the Si-Based Electrodes with and without Binder Studied by XPS and ToF-SIMS Analysis
- Author
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Zhan-Yu Wu, Li Deng, Jun-Tao Li, Sandrine Zanna, Antoine Seyeux, Ling Huang, Shi-Gang Sun, Philippe Marcus, and Jolanta Światowska
- Subjects
Electrochemistry ,Energy Engineering and Power Technology ,Electrical and Electronic Engineering ,Lithium ion battery ,Si anode ,SEI layer ,binder ,XPS ,ToF-SIMS - Abstract
The formation and evolution of the solid electrolyte interphase (SEI) layer as a function of electrolyte and electrolyte additives has been extensively studied on simple and model pure Si thin film or Si nanowire electrodes inversely to complex composite Si-based electrodes with binders and/or conductive carbon. It has been recently demonstrated that a binder-free Si@C-network electrode had superior electrochemical properties to the Si electrode with a xanthan gum binder (Si-XG-AB), which can be principally related to a reductive decomposition of electrolytes and formation of an SEI layer. Thus, here, the Si@C-network and Si-XG-AB electrodes have been used to elucidate the mechanism of SEI formation and evolution on Si-based electrodes with and without binder induced by lithiation and delithiation applying surface analytical techniques. The X-ray photoelectron spectroscopy and time-of-flight ion mass spectrometry results demonstrate that the SEI layer formed on the surface of the Si-XG-AB electrode during the discharge partially decomposes during the subsequent charging process, which results in a less stable SEI layer. Contrarily, on the surface of the Si@C-network electrode, the SEI shows less significant decomposition during the cycle, demonstrating its stability. For the Si@C-network electrode, initially, the inorganic and organic species are formed on the surface of the carbon shell and the silicon surface, respectively. These two parts of species in the SEI layer gradually grow and then fuse when the electrode is fully discharged. The behavior of the SEI layer on both electrodes corroborates with the electrochemical results.
- Published
- 2022
40. Composite Cathodes Based on Lithium-Iron Phosphate and N-Doped Carbon Materials
- Author
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Irina Stenina, Danis Safikanov, Polina Minakova, Svetlana Novikova, Tatiana Kulova, and Andrey Yaroslavtsev
- Subjects
LiFePO4 ,carbon coating ,nitrogen-doped carbon ,CNT ,PANI ,cathode ,lithium ion battery ,Electrochemistry ,Energy Engineering and Power Technology ,Electrical and Electronic Engineering - Abstract
The effect of different nitrogen-doped carbon additives (carbon coating from polyaniline, N-doped carbon nanotubes, and N-doped carbon nanoparticles) on electrochemical performance of nanocomposites based on the olivine-type LiFePO4 was investigated. Prepared materials were characterized by XRD, SEM, TGA-MS, CHNS-analysis, IR-, Raman, and impedance spectroscopies. Polyaniline deposition on the LiFePO4 precursor with following annealing lead to the formation of a LiFePO4/C nanocomposite with a carbon coating doped with nitrogen. Due to nitrogen atoms presence in carbon coating, the LiFePO4/N-doped carbon nanocomposites showed enhanced conductivity and C-rate capability. The discharge capacities of the synthesized materials in LIBs were close to the theoretical value at 0.1 C and retained high values with increasing current density. At high C-rates, the best results were obtained for a more dispersed LiFePO4/C composite with carbon coating prepared from polyaniline previously in situ deposited on LiFePO4 precursor particles. Its discharge capacity reached 96, 84, 73, and 47 mAh g−1 at 5, 10, 20, and 60 C-rates, respectively.
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- 2022
41. Surface Modification of Nanocrystalline LiMn2O4 Using Graphene Oxide Flakes
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Monika Michalska, Arjun Thapa, Dominika A. Buchberger, Jacek B. Jasinski, and Amrita Jain
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Technology ,Materials science ,Oxide ,02 engineering and technology ,010402 general chemistry ,Electrochemistry ,01 natural sciences ,Article ,Lithium-ion battery ,law.invention ,lithium manganese oxide ,chemistry.chemical_compound ,law ,General Materials Science ,Microscopy ,QC120-168.85 ,cathode material ,Nanocomposite ,Graphene ,QH201-278.5 ,Engineering (General). Civil engineering (General) ,021001 nanoscience & nanotechnology ,Nanocrystalline material ,TK1-9971 ,0104 chemical sciences ,LiMn2O4 ,Descriptive and experimental mechanics ,Chemical engineering ,chemistry ,Surface modification ,graphene oxide ,Electrical engineering. Electronics. Nuclear engineering ,Crystallite ,TA1-2040 ,0210 nano-technology ,lithium ion battery - Abstract
In this work, a facile, wet chemical synthesis was utilized to achieve a series of lithium manganese oxide (LiMn2O4, (LMO) with 1-5%wt. graphene oxide (GO) composites. The average crystallite sizes estimated by the Rietveld method of LMO/GO nanocomposites were in the range of 18-27 nm. The electrochemical performance was studied using CR2013 coin-type cell batteries prepared from pristine LMO material and LMO modified with 5%wt. GO. Synthesized materials were tested as positive electrodes for Li-ion batteries in the voltage range between 3.0 and 4.3 V at room temperature. The specific discharge capacity after 100 cycles for LMO and LMO/5%wt. GO were 84 and 83 mAh g(-1), respectively. The LMO material modified with 5%wt. of graphene oxide flakes retained more than 91% of its initial specific capacity, as compared with the 86% of pristine LMO material. Web of Science 14 15 art. no. 4134
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- 2021
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42. Versatile AC Current Control Technique for a Battery Using Power Converters
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S. M. Rakiul Islam and Sung-Yeul Park
- Subjects
TK1001-1841 ,Materials science ,Energy Engineering and Power Technology ,02 engineering and technology ,charger ,Lithium-ion battery ,Production of electric energy or power. Powerplants. Central stations ,0203 mechanical engineering ,Control theory ,bi-directional control ,0202 electrical engineering, electronic engineering, information engineering ,Electrochemistry ,Output impedance ,Electrical and Electronic Engineering ,Electronic circuit ,AC current injection ,business.industry ,020208 electrical & electronic engineering ,Electrical engineering ,Battery (vacuum tube) ,020302 automobile design & engineering ,TP250-261 ,Industrial electrochemistry ,business ,lithium ion battery ,Pulse-width modulation ,DC bias ,Voltage - Abstract
Although a battery is a DC device, AC current is often necessary for testing, preheating, impedance spectroscopy, and advanced charging. This paper presents a versatile control technique to inject AC current to a battery. Synchronous buck and H-bridge topologies are operated in bidirectional mode and controlled by uni-polar and bi-polar pulse width modulation techniques for the AC current injection. The input and output passive circuits are specially designed considering AC current and the properties of the battery. A controller is proposed considering a small internal impedance, small AC ripple voltage, and variable DC offset voltage of a battery. The controller is capable of maintaining stable operation of AC current injection in two power quadrant within a small DC voltage boundary of a battery. The controller is comprised of a feedback compensator, a feedforward term, and an estimator. The feedback gain is designed considering the internal impedance. The feedforward gain is designed based on estimated open circuit battery voltage and input voltage. The open circuit voltage estimator is designed based on filters and battery model. For validation, AC current is injected to a Valence U-12XP battery. The battery is rated for 40 Ah nominal capacity and 13.8 V nominal voltage The controller successfully injected AC current to a battery with +10 A, 0 A and −10 A DC currents. The magnitude and frequency of the AC current was up to 5 A and 2 kHz respectively.
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- 2021
- Full Text
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43. Thermal Modelling Utilizing Multiple Experimentally Measurable Parameters
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Anosh Mevawalla, Yasmin Shabeer, Manh Kien Tran, Satyam Panchal, Michael Fowler, and Roydon Fraser
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lithium ion battery ,heat transfer ,surface methods ,equivalent circuit model ,physiochemical model ,thermal model ,Electrochemistry ,Energy Engineering and Power Technology ,Electrical and Electronic Engineering - Abstract
This paper presents three equivalent thermal circuit models with multiple input parameters, namely, the state of health (SOH), state of charge (SOC), current and temperature. Typical physiochemical models include parameters such as porosity and tortuosity, which are not easily experimentally available; this model allows for model parameters such as the internal impedance to be easily estimated using more practical inputs. The paper models the internal impedance resistance of a LiFePO4 battery at five different ambient temperatures (5, 15, 25, 35, 45 °C), at three different discharge rates (1C, 2C, 3C) and at three different SOHs (90%, 83%, 65%). The internal impedance surface fit experimental measurements with a Pearson coefficient of 0.945. Three thermal models were then created that implemented the internal resistance model. The first two thermal models were 0D models that did not include the influence of the thermal conductivity of the battery. The first model assumed simple heating through internal resistance and convection energy loss, while the second also included the Bernardi Reversible heat term. The final third model was a 2D model that included all previous heat source terms as well as tab heating. The 2D model was solved using a simple Euler method and finite center difference. The R2 values for the 0D thermal models were 0.9964 and 0.9962 for the simple internal resistance and reversible heating models, respectively. The R2 value for the 2D thermal model was 0.996.
- Published
- 2022
44. Flexible 3D porous boron nitride interconnected network as a high-performance Li-and Na-ion battery electrodes
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Nabil Khossossi, Deobrat Singh, Wei Luo, and Rajeev Ahuja
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Inorganic Chemistry ,Oorganisk kemi ,General Chemical Engineering ,Zigzag BN nanoribbons ,Materials Chemistry ,Electrochemistry ,Materialkemi ,Sodium ion battery density-functional calculations ,Elechtrochemical energy storage ,3D porous boron nitride ,lz1-BN ,Lithium ion battery - Abstract
To achieve the high-rate efficiency in a electrochemical energy storage technologies, it is vital for the battery anode to be electronically as well as ionically conductive. Such a requirement has boosted the survey of three-dimensional (3D) porous networks made up of light-weight non-metallic elements, like carbon, boron, and nitride. A wide range of 3D porous materials composed of carbon and/or boron for Li/Na-ion batteries have been recently reported, whereas analogous efforts for lightest 3D porous boron nitride are yet to be addressed. In this work, we explore the 3D porous boron nitride network namely sp3-linked zigzag BN nanoribbons (BNNRs) with a width of 1 (lz1-BN) by assembling the 2D zigzag BNNRs and its first ever application as battery anodes for Li and Na ion batteries. Upon a consistent DFT and AIMD computations, It is revealed that the 3D porous lz1-BN ma-terial is chemically and thermally stable and yields a high specific capacity of about 539.94 mAh/g with respect to the commercialized graphite (372 mAh/g for LIBs) and recently reported Janus-graphite anode (≈332 mAh/g for SIBs), fast (Li+,Na+)-ionic diffusion, low potential voltage, and slight volume-expansion. Such puzzling electrochemical characteristics, along with the light-weight and high abundance of B and N elements, strongly support the possibility of 3D porous BN as a desirable candidate for Li and Na-ion battery anodes.
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- 2022
45. A comparative study on electrochemical cycling stability of lithium rich layered cathode materials Li1.2Ni0.13M0.13Mn0.54O2 where M = Fe or Co.
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Laisa, C.P., Nanda Kumar, A.K., Selva Chandrasekaran, S., Murugan, P., Lakshminarasimhan, N., Govindaraj, R., and Ramesha, K.
- Subjects
- *
LITHIUM-ion batteries , *CATHODES , *ELECTROCHEMISTRY , *CHEMICAL stability , *OXIDATION-reduction reaction , *X-ray photoelectron spectroscopy - Abstract
In this work we compare electrochemical cycling stability of Fe containing Li rich phase Li 1.2 Ni 0.13 Fe 0.13 Mn 0.54 O 2 (Fe–Li rich) with the well-known Co containing Li rich composition Li 1.2 Ni 0.13 Co 0.13 Mn 0.54 O 2 (Co–Li rich). During the first charge, the activation plateau corresponding to removal of Li 2 O from the structure is smaller (removal of 0.6 Li) in the case of Fe–Li rich compared to Co–Li rich composition (0.8 Li removal). Consequently, the Fe compound shows better capacity retention; for example, after 100 cycles Fe–Li rich compound exhibits 20% capacity degradation where as it is about 40% in the case of Co–Li rich phase. The electrochemical and microscopy studies support the fact that compared to Co–Li rich compound, the Fe–Li rich composition display smaller voltage decay and reduced spinel conversion. XPS studies on charged/discharged Fe–Li rich samples show participation of Fe +3 /Fe +4 redox during electrochemical cycling which is further supported by our first principles calculations. Also the temperature dependent magnetic studies on charge-discharged samples of Fe–Li rich compound point out that magnetic behavior is sensitive to cation oxidation states and Ni/Li disorder. [ABSTRACT FROM AUTHOR]
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- 2016
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46. One-Pot Hydrothermal Synthesis of LiMnO Cathode Material with Excellent High-Rate and Cycling Properties.
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Jiang, Qianqian, Wang, Xingyao, and Zhang, Han
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HYDROTHERMAL synthesis ,CATHODES ,POLYMERS ,ACETONE ,ELECTROCHEMISTRY - Abstract
The spinel LiMnO was prepared by a one-step hydrothermal method using acetone as the reductant under different hydrothermal temperatures. X-ray diffraction and scanning electron microscopy analysis indicated that optimal LiMnO particles (LMO-120) were synthesized at the temperature of 120°C and the particles were well distributed and about 410 nm in size. Electrochemical performance showed that the as-prepared LiMnO particles exhibited a higher initial discharge capacity than commercial LiMnO (131.5 mAh g versus 115.6 mAh g at 0.2 C). An excellent discharge capacity retention rate of 94.07% was observed after 60 charge-discharge cycles. On the other hand, when cycled at the high rate of 1 C, the optimal LiMnO in this work showed a high discharge capacity of 107.5 mAh g in contrast to only 92.3 mAh g of the commercial LiMnO. These results indicate that LMO-120 showed excellent electrochemical performance, especially the prolonged cycling life and high-rate performance, which suggested that this spinel LiMnO has promise for practical application as a high-rate cathode material for lithium ion batteries. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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47. Lithium iron silicate sol–gel synthesis and electrochemical investigation.
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Oghbaei, Morteza, Baniasadi, Fazel, and Asgari, Sirous
- Subjects
- *
IRON silicates , *LITHIUM compounds , *SOL-gel processes , *ELECTROCHEMISTRY , *CHEMICAL synthesis , *CALCINATION (Heat treatment) , *TEMPERATURE effect - Abstract
Li 2 FeSiO 4 was synthesized through Sol–Gel method and the effect of calcination temperature, time and chelating agent concentration were investigated. Appropriate calcination temperature above 550 °C was determined by TG/DTA analysis. Afterward, the dried gel powder was calcined at each temperature of 650 °C, 700 °C and 750 °C for 1, 2 and 3 h. XRD studies illustrated the most appropriate calcination temperature of 700 °C for 1 h. To compare the effect of chelating agent concentration, citric acid with molar ratio of 1/3, 2/3 and 1 were used which 1/3 was determined as the best concentration. FE-SEM observation showed that mean grain is size lower than 100 nm. By using this material, a three electrodes test cell was assembled and its electrochemical properties were investigated. The results showed high charge capacity which could be achieved at current density of 0.05C. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
48. Influence of Mg2+ doping on the structure and electrochemical performances of layered LiNi0.6Co0.2-xMn0.2MgxO2 cathode materials.
- Author
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Huang, Zhenjun, Wang, Zhixing, Guo, Huajun, and Li, Xinhai
- Subjects
- *
MAGNESIUM ions , *DOPING agents (Chemistry) , *ELECTROCHEMISTRY , *LITHIUM compounds , *CATHODES , *DIFFUSION coefficients , *LATTICE constants - Abstract
Introducing the Mg ion into host lattice is applied to improving the electrochemical performance of LiNi 0.6 Co 0.2 Mn 0.2 O 2 . The effect of Mg substitution for Co on the structure, morphology, electrochemical properties and Li + diffusion coefficients are investigated in details. Rietveld refinement results reveal that Mg is incorporated into the bulk lattice, which results in reduced cation mixing and expand c -lattice parameter. All Mg-doped sample exhibit better cycle and rate performances, although the Mg substitution for Co led to decreasing a part of capacity. The Li diffusion coefficients obtained by galvanostatic intermittent titration technique (GITT) are increased with increases of Mg content. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
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49. A new gridding cyanoferrate anode material for lithium and sodium ion batteries: Ti0.75Fe0.25[Fe(CN)6]0.96·1.9H2O with excellent electrochemical properties.
- Author
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Sun, Xin, Ji, Xiao-Yang, Zhou, Yu-Ting, Shao, Yu, Zang, Yong, Wen, Zhao-Yin, and Chen, Chun-Hua
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- *
FERRITES , *ANODES , *LITHIUM-ion batteries , *TITANIUM compounds , *COMPLEX compounds , *ELECTROCHEMISTRY , *PRECIPITATION (Chemistry) , *SOLUTION (Chemistry) - Abstract
A novel air-stable titanium hexacyanoferrate (Ti 0.75 Fe 0.25 [Fe(CN) 6 ] 0.96 ·1.9H 2 O) with a cubic structure is synthesized simply by a solution precipitation method, which is first demonstrated to be a scalable, low-cost anode material for lithium-ion batteries exhibiting high capacity, long cycle life and good rate capability. Nevertheless, it has a low capacity of about 100 mAh g −1 as an anode material for sodium-ion batteries. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
50. Facile synthesis of Mo0.91W0.09S2 ultrathin nanosheets/amorphous carbon composites for lithium-ion battery anode.
- Author
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Xu, Jing, Dong, Linjian, Tang, Hua, and Li, Changsheng
- Subjects
- *
MOLYBDENUM compounds synthesis , *NANOSTRUCTURED materials , *AMORPHOUS carbon , *LITHIUM-ion batteries , *ANODES , *ELECTROCHEMISTRY , *X-ray diffraction , *SURFACES (Technology) - Abstract
We report a facile process to synthesize Mo 0.91 W 0.09 S 2 /amorphous carbon composites with mean thickness of only 5 nm ultrathin nanosheets and their improved electrochemical performance as anode materials for lithium ion batteries (LIBs). Structural and morphological characterizations of the nanocomposite have been investigated by XRD, SEM and TEM. It was found the amorphous carbon to be well dispersed on the ultrathin nanosheets surface. Due to the increased interlayer distance and the synergistic effects between Mo 0.91 W 0.09 S 2 nanosheets and amorphous carbon, the as-prepared Mo 0.91 W 0.09 S 2 /C electrode deliveres exhibit a high Li capacity, an excellent rate capability, and a stable cycling performance, which suggests the Mo 0.91 W 0.09 S 2 /C composites as promising electrode material for LIBs. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
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