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The pool boiling characteristics on the enhanced surfaces with sintered copper powder coatings with and without nano-treatment were experimentally investigated. Three kinds of enchanted surfaces formed by sintered porous layers with copper powder particles and their further nano-treated surfaces were adopted as the test surfaces. The thermal oxidation process was used to form nanostructures with super hydrophilic characteristic on the surface of sintered copper particles. Refrigerant R245fa was selected as the test fluid due to the potential the application in electronic cooling field. The saturation temperature of boiling experiments was maintained about 20 °C. The result showed that the boiling heat transfer performance was effectively improved by coating sintered copper powder porous layer on the plain copper surface, and the maximum heat transfer coefficient and CHF value enhancement could reach 151% and 160% of the plain one, respectively. The enhanced surfaces no matter with or without nano-treatment could trigger the nucleation process at the wall superheats lower than 12 °C rather than the value as high as 30 °C for plain copper surface. After nano-treatment, the heat transfer enhancement for sintered porous surfaces was further improved at medium and low heat flux, where the bubble nucleation or detachment remained robust. The CHF peaked as 140% of untreated surface, while the heat transfer coefficient increased to 108% at most. [ABSTRACT FROM AUTHOR]