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In this paper, atmospheric water-soluble cation and anion contents of PM10 are analysed in Makkah, Saudi Arabia. PM10 samples were collected at five sites for a whole year. PM10 concentrations (µg/m3) ranged from 82.11 to 739.61 at Aziziyah, 65.37 to 421.71 at Sanaiyah, 25.20 to 466.60 at Misfalah, 52.56 to 507.23 at Abdeyah, and 40.91 to 471.99 at Askan. Both daily and annual averaged PM10 concentrations exceeded WHO and Saudi Arabia national air quality limits. Daily averaged PM10 concentration exceeded the national air quality limits of 340 µg/m3, 32% of the time at Aziziyah, 8% of the time at Sanaiyah, and 6% of the time at the other three sites. On average, the cations and anions made a 37.81% contribution to the PM10 concentrations. SO42−, NO3−, Ca2+, Na+, and Cl− contributed 50.25%, 16.43%, 12.11%, 11.12%, and 8.70% to the total ion concentrations, respectively. The minor ions (F−, Br−, Mg2+, NO2−, and PO43−) contributed just over 1% to the ion mass. Four principal components explained 89% variations in PM10 concentrations. Four major emission sources were identified: (a) Road traffic, including emission from the exhaust, wear-and-tear, and the resuspension of dust particles (F−, SO42−, NO3−, Ca2+, Na+, Mg+, Br−, Cl−, NO2−, PO43−); (b) Mineral dust (Cl−, F−, Na+, Ca2+, Mg2+, PO43−); (c) Industries and construction–demolition work (F−, SO42−, Ca2+, Mg2+); and (d) Seaspray and marine aerosols (Cl−, Br−, Mg2+, Na+). Future work would include an analysis of the metal contents of PM10 and their spatiotemporal variability in Makkah. [ABSTRACT FROM AUTHOR]

Studying groundwater quality is crucial for ensuring its safety because it is widely used for drinking and for domestic, agricultural, and industrial purposes. Owing to the lack of surface water in the Tabuk area of Saudi Arabia, here groundwater wells are one of the primary sources of water for drinking, agriculture, and industry. Groundwater quality is determined by the aquifer characteristics of the regional geology, and it is extensively influenced by both natural and anthropogenic activities. To understand the geochemical evolution and assess the suitability of groundwater for irrigation, major ion geochemistry was utilized to characterize the chemical composition of groundwater in the Tabuk area, which is considered a semiarid plateau region. Depending on its mineral composition, irrigation water's quality reflects how it affects plants and soil. In total, 80 groundwater samples have been collected and analyzed in laboratory for major cations and anions. Temperature, alkalinity (ALK), pH, total dissolved solids (TDS), electric conductivity (EC), total hardness (TH), oxidation reduction potential (ORP), and cation and anion concentrations were measured. Water chemistry classification was carried out by using a Piper diagram and a Gibbs diagram. In the current study, statistical methods, combined with geochemical modeling and conventional plots, have been used to investigate groundwater and related geochemical processes in the Tabuk area of Saudi Arabia. Applications and calculations of hydrogeochemical parameters, specifically SAR, RSC, PI, CR, MH, Na%, KR, and HI, showed that 92.5% of the collected groundwater well samples are suitable for drinking and irrigation purposes after treatment processes. [ABSTRACT FROM AUTHOR]