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1. Copper-Catalyzed Redox Coupling of Nitroarenes with Sodium Sulfinates.

Author

Liu, Saiwen, Chen, Ru, Zhang, Jin, and McPhee, Derek J.

Subjects
*NITROAROMATIC compounds, *NANOPARTICLES, *HETEROCYCLIC compounds, *CATALYSIS, *CRYSTAL structure
Abstract

A simple copper-catalyzed redox coupling of sodium sulfinates and nitroarenes is described. In this process, abundant and stable nitroarenes serve as both the nitrogen sources and oxidants, and sodium sulfinates act as both reactants and reductants. A variety of aromatic sulfonamides were obtained in moderate to good yields with broad substrate scope. No external additive is employed for this kind of transformation. [ABSTRACT FROM AUTHOR]

Published
2019
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