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1. Nitric acid-catalyzed aerobic oxidation of benzylic sp3 C[sbnd]H bonds of isochromans, xanthenes and 9-fluorenone under additive-free conditions.

Author

Tian, Xinzhe, Ren, Fangping, Zhao, Bo, Ren, Yun-Lai, Zhao, Shuang, and Wang, Jianji

Subjects
*NITRIC acid, *CARBON-hydrogen bonds, *OXIDATION, *XANTHENE, *BENZYLIC group, *FLUORENONE
Abstract

HNO 3 was demonstrated to be an effective catalyst for aerobic oxidation of benzylic sp 3 C H bonds under additive-free conditions. A series of isochromans, xanthenes and fluorenes underwent this transformation to give the targeted products in low to high yields under the catalysis of HNO 3 , which provided an effective method for the synthesis of the synthetically and biologically valued isochromanones, xanthones and 9-fluorenones. [ABSTRACT FROM AUTHOR]

Published
2018
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