1. Synthesis of Yb3 +/Ho3 + co-doped Bi2WO6 upconversion photocatalyst with highly improved visible light photocatalytic activity.
- Author
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Li, Hong, Hao, Hongshun, Jin, Shanshan, Guo, Weihua, Hu, Xiaofei, Hou, Hongman, Zhang, Gongliang, Yan, Shuang, Gao, Wenyuan, and Liu, Guishan
- Subjects
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CHEMICAL synthesis , *PHOTOCATALYSTS , *CALCINATION (Heat treatment) , *IRRADIATION , *DOPING agents (Chemistry) - Abstract
As a novel visible-light-driven photocatalyst, Yb 3 + /Ho 3 + co-doped Bi 2 WO 6 (Yb 3 + /Ho 3 + -Bi 2 WO 6 ) was synthesized via a simple hydrothermal method and subsequent a calcination process. The as-synthesized Yb 3 + /Ho 3 + -Bi 2 WO 6 samples were characterized by various analytical methods. The BIW-5 (Yb 3 + /Ho 3 + molar ratios is 5) sample showed the highest photocatalytic activity. The RhB was degraded (99.8%) under visible light irradiation in 20 min. The improved photocatalytic activity could be attributed to the efficient energy transfer between Yb 3 + /Ho 3 + and Bi 2 WO 6 via infrared to visible upconversion and the reduced combination rate of photogenerated electron-hole pairs through doping Yb 3 + /Ho 3 + ions. Therefore, this study may provide a better method to obtain stable upconversion photocatalyst with greatly improved activity. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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