Search

Competition between selenium (IV) and silicic acid for the hematite (α-Fe2O3) surface has been studied during this work. Single batch experiments have been performed to study separately the sorption of selenium (IV) and silicic acid as a function of the pH. With the help of the 2-pK surface complexation model, experimental data have been fitted using the FITEQL 4.0 program. Two monodentate inner-sphere surface complexes have been used to fit selenite ions retention, and :inf loc="post">3. In order to fit sorption of silicic acid, the two following surface complexes, namely f loc="post">3SiO4, and , have been used. Using the surface complexation constants coming from these two binary systems, prediction curves of the effect of silicic acid on the retention of selenium (IV) onto hematite have been obtained. Finally, performed experiments showed a competition between selenium (IV) and silicic acid for the surface sites of hematite. Experimental data matched DDLM predictions, confirming the ability of the surface complexation model to predict quantitatively and qualitatively the ternary system selenium (IV)/H4SiO4/hematite. [Copyright &y& Elsevier]

Abstract: The sorption of europium(III) species from EuCl3 solution at pH=5.4 onto dickite particles is investigated using spectroscopic methods. Thanks to the neutrality of phyllosilicate sheets of dickite, cation exchange is prevented. X-ray photoelectron spectroscopy reveals that chloride atoms probably remain in the ligand sphere of the europium(III) cation. The edge site-specific reactivity is evidenced by epifluorescence microscopy and Raman spectroscopy. Comparison between dickite/europium(III) samples rinsed or not with distilled water shows that the surface processes not only involve inner-sphere complex formation, but also either outer-sphere complex or surface precipitation. Raman spectra also indicate that europium(III) surface complexes are preferentially localised at the edge of tetrahedral silica sheets. [Copyright &y& Elsevier]

The aim of this study is to understand the sorption of tributyltin (TBT) onto natural quartz sand by classical batch experiments and spectroscopic surface analyses. At pH<6, the major species of TBT is the cation TBT+. Due to the presence of both the cationic part and the butyl chains, TBT should present amphiphilic properties. For concentrations lower than 40 μM, TBT sorption occurs as a homovalent 1:1 cation exchange between either H+ or Na+ and TBT+. The increasing affinity of TBT with respect to the different materials follows the series kaolinite≪natural sand. From XPS analyses, where the chemical environment of Sn did not change, indicating possible complete reversibility of the TBT sorption, it seems that inner-sphere surface complexes could be formed due to the increase in the 3d-level binding energy. At TBT concentrations higher than 100 μM, we showed by flotation experiments and XPS analysis that the surface becomes hydrophobic. After one monolayer was formed, the TBT sorption could thus be due to hydrophobic interaction between the butyl chains of the sorbed TBT and those of the TBT still available from the bulk solution. This mechanism is consistent with surface condensation and the shape of the sorption isotherm. [Copyright &y& Elsevier]

In the framework on a study of the acido-basic and sorption properties of iron oxides, a thorough characterization of two types of goethite powders was performed in several laboratories joined in a common project. Chemical analysis by ICPAES; high-resolution SEM, TEM, and AFM observations; XRD with line width analysis; and argon and nitrogen sorption isotherms were used for that purpose. The main crystallographic faces of goethite particles could be identified as {001}, {101}, and {121}, and their abundance correlated with the distribution of low-pressure argon adsorption local isotherms. These results will be very useful for further studies on the relationship between surface reactivity in aqueous solution and orientation of solid surfaces. [Copyright &y& Elsevier]