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Copper slag particles were prepared by rotary cup atomizer. Carbon-containing copper slag pellets were prepared by copper slag particles, carbon reductant, binder and slag former. The effects of six factors on reduction ratio of carbon-containing copper slag pellets were in accordance with the sequence of reaction temperature > the ratio of slag former > atmosphere > the types of reduction reductant > particle size of copper slag > the addition ratio of reductant, under experiment conditions. The optimum condition for direct reduction of carbon-containing copper slag pellets was that the reaction temperature was 1150℃, the ratio of slag former was 1∶0.4, atmosphere was CO2(50%)+N2(50%), the reductant was coal, particle size of copper slag was +0.425 mm and the addition ratio of reductant was 1.2∶1. On this condition, the reduction ratio of copper slag is 98.2%.

Perovskite SCR catalysts have become a hot research topic in the field of de-NOx catalyst development. This article selects LaMnO3 with high performance as the research object, modifies the catalyst by doping some iron elements instead of manganese elements, and applies density functional theory to study its reaction mechanism, providing theoretical reference for further research on perovskite. Research has found that several main reactants such as NH3, NO, and O2 can form stable adsorption at the active site, with NO more inclined to adsorb at the nitrogen atom end at the active site. The oxidation of O2 molecules after adsorption is greater than that of the active site. The adsorption capacity of the Mn active site of the catalyst before modification on the above molecules is weaker than that of the Fe active site introduced after modification. Under both anaerobic and aerobic conditions in the SCR reaction process, NH3 molecules are first adsorbed at the active site, and then influenced by lattice oxygen under anaerobic conditions. Under aerobic conditions, they are gradually dehydrogenated and produce NH2 and NH radicals. These two radicals react with NO molecules to form intermediate products in the form of NH2NO and NHNO molecules. Due to the instability of the intermediate products, they ultimately decompose into N2 and H2O molecules. The introduction of Fe active sites can increase the generation of NH2 and NH radicals during the reaction process and simplify the reaction process between NH2 radicals and NO molecules, which will be conducive to the completion of the reaction.

NaOH, dolomite and NiCl2 were used as catalysts to examine their effects on co–pyrolysis with waste bicycle tires (WT) and waste engine oil (WEO). The pyrolysis behaviors with catalysts were investigated by thermogravimetric analysis. The activation energy of the catalytic main reaction stage was derived by the Kissinger–Akahira–Sunose (KAS) method under four different heating rates conditions. The calculations show that all three catalysts can reduce the activation energy of the reaction. Co–pyrolysis of WT and WEO with different catalysts was performed in a self–made lab bench at 600 °C to explore the impact on the distribution of three–phase products. The properties of gas and oil products were characterized by FTIR and Py–GC/MS (Agilent 7890B, Santa Clara, CA, USA). With the mixing of catalysts, activation energy (Eα) decreased by 15–30% in the main reaction process. NaOH and dolomite increased the yield of gas by 7% and 10%. NaOH can significantly improve the yield of CH4. The proportion of limonene in pyrolysis oil increased to 19.65% with 10% NaOH. This article provides a new method for efficiently producing limonene by mixing WT and WEO with NaOH.

The tail gas with relatively high calorific value, generated from the depleted reduction of copper slag, can be used as fuel for gas turbines. In this study, the flame speed calculation module in PREMIX of CHEMKIN was used to simulate the combustion characteristics of the tail gas after sulfide removal, the effects of equivalence ratio, gas preheating temperature, and the CO2 concentration on the flame propagation speed and the flame combustion temperature were mainly investigated. Results show that the flame propagation speed and the flame combustion temperature increase continuously with the increase in preheating temperature, while it decreases continuously with the increase in CO2 concentration. Additionally, the peak flame combustion temperature appears at an equivalent ratio of 1.1, while the peak flame propagation speed appears at an equivalent ratio of 2.0, which indicates that the flame combustion temperature is not the main factor affecting flame propagation speed for tail gas.

The combustion mechanism of biogas mixture is unclear, which leads to the lack of basis for the control of operating parameters. Combustion characteristics and reaction path of typical low calorific value biogas with variation of preheating temperature and air equivalence ratio (Φ) are discussed in this paper. Preheating can not only improve the flame propagation speed and flame temperature, but also increase the proportion of NO in the product at the end of combustion flame. To some extent, improving combustion efficiency and NOx control are contradictory operating parameters. The amount of NO increases with the increase in flame distance. The maximum value of NO appears when Φ is 1.1. NO formation rate is improved by preheating the biogas. The paths of N2 → N2O →NO, N2 → NNH →NO, and N2 →NO are all enhanced. When the equivalence ratio changes from 1.0 to 0.8, NO formation rates decrease.

The existence of inert gases such as N2 and CO2 in biogas will reduce the proportion of combustible components in syngas and affect the combustion and NOX formation characteristics. In this study, ANSYS CHEMKIN-PRO software combined with GRI-MECH 3.0 mechanism was used to numerically simulate the effects of different CO2 concentrations (CO2 volume ratio in biogas is 0–41.6%) on flame combustion temperature, flame propagation speed and nitrogen oxide formation of complex biogas with low calorific value. The results showed that when the combustion reaches the chemical equilibrium, the flame combustion temperature and flame propagation speed decrease with the increase of CO2 concentration, and the flame propagation speed decreases even more slowly. Meanwhile, the molar fraction of NO at chemical equilibrium decreases with the increase of CO2 concentration and the decrease is decreasing, which indicates that the effect of CO2 concentration in biogas on NO is simpler. While the molar fraction of NO2 does not change regularly with the change of CO2 concentration, the effect of CO2 concentration in biogas on NO2 is complicated. The highest molar fraction of NO2 was found at chemical equilibrium when the CO2 concentration was 33.6%, when the target was a typical low calorific value biogas.

In order to study the effect of biomass on the pyrolysis characteristics of urea-formaldehyde resin, the thermogravimetric experiments were carried out respectively using urea-formaldehyde resin (UF), rice straw (RS), and their mixed pellets with different proportions. The pyrolysis kinetics analysis was conducted. The results showed that the pyrolysis process of UF resin and mixed pellets could be divided into three stages: the drying and dehydration of the material, the rapid decomposition of volatile matter, and residue decomposition. The reaction order of UF resin and mixed pellets was discussed using the Coats–Redfern method, the activation energy of UF resin was 54.27 kJ/mol, and this value decreased with the addition of rice straw. As the mass ratio of UF resin to rice straw was 3:1, the activation energy achieved the lowest value, which means that the addition of rice straw was beneficial to the pyrolysis process of UF. In the process of pellet preparation, the falling strength and compressive strength of UF resin pellets can be improved by adding an appropriate proportion of rice straw. In this test, the yield of pyrolytic carbon reached the highest value of 23.93%, as the mass ratio of UF resin to rice straw was 3:2. When the mass ratio was 4:1, the highest liquid product yield of 43.21% was achieved.

TG-FTIR and PY-GC/MS were used to analyze the pyrolysis behaviors of pine wood, urea-formaldehyde resin (UF resin) and their blended pellets. The pyrolysis process was divided into three stages: water evaporation, devolatilization and pyrolysis residue decomposition. During the pyrolysis process of the blended pellets, with the increase of the addition ratio of UF resin, the peak value of the weight loss decreased in the decomposition stage of the pyrolysis residue, while the temperature shifted to the low-temperature region. This was mainly due to the structural stability of pyrolytic carbon produced by UF resin, which hindered the thermal decomposition of lignin-produced residues in pine. FTIR showed that CO2 was the main product of pyrolysis. For UF resin, nitrogen compounds accounted for a large proportion. With the addition of UF resin, the nitrogen in the blended pellets increased significantly. Since the synergistic effect promoted the further decomposition of the organic oxygen-containing structure, the NO release was still increased. PY-GC/MS showed that co-pyrolysis produced more nitrogen-containing compounds and promoted the decomposition of macromolecular phenol derivatives, lipids and ketones, resulting in more small-molecule acids and alcohols.

In this paper, the effects of three typical operation modes, namely short-circuit fault, load change, and chemical energy storage on the frequency of a regional power grid after photovoltaic asynchronous interconnection were studied with different penetration ratios, taking the power grid in Northern Henan Province as the research object. It was found that with an increase in the photovoltaic penetration ratio, the maximum value of the system frequency and the fluctuation amplitude gradually increased, and the power grid system in Northern Henan became less and less stable. With an increase in the penetration ratio, the peak value of the system frequency at the corresponding node gradually increased, and the valley value gradually decreased. With an increase in load, the peak value of the frequency curve gradually increased, and the valley value gradually decreased. When photoelectricity was connected to the grid through chemical energy storage, the system stability during a short-circuit fault and load change operation was significantly improved. Compared with that before energy storage, the frequency amplitude of the system after energy storage was reduced to approximately one tenth of the original. Compared with the case before energy storage, when the load changed, the frequency amplitude of the system decreased to approximately a quarter of the original.

Copper slag is a solid pollutant with high recyclability. Reduction and separation are regarded as effective disposal methods. However, during the melting process, the separation and migration behavior of elements in the copper slag is complicated. Thus, the formation of pollutants cannot be controlled merely by optimizing the operation parameters. The elemental distribution and migration behavior are discussed in this work. In reduction experiments, the copper slag smelting liquid was divided into three layers: a reduction slag layer, a reactive boundary layer, and an iron ingot layer. Reduction slag and ingot iron were on the top and bottom of the liquid, respectively. Residual carbon oozed at the interface. C can react with reducible “O” atoms, which exist in 2FeO·SiO2, Fe3O4, and CuO. Meanwhile, CO was generated and overflowed from the liquid layer. After reduction by C or CO, metallic iron and copper were produced and migrated to the iron ingot layer. In the liquid, S gradually diffused into the upper layer. Some of the ZnO and CuS spilled from the liquid into the flume. After reduction, CaO·SiO2 was generated and moved to the upper layer.

Copper slag, an important by-product of the copper smelting process, is mainly composed of 2FeO SiO2, Fe3O4, and SiO2. Due to the sufficient metal oxides, copper slag is regard as a potential oxygen carrier (OC), which can be applied in chemical looping technology. This research proposed to use the granulated copper slag particles as precursor to produce oxygen carrier. Through this method, waste heat of the high-temperature slag can be fully recovered, eliminating the complicated copper slag pretreatment process. In this paper, the reactivity of granulated copper slag after redox calcination was studied by X-ray diffractometer (XRD) and Scanning Electron Microscope (SEM), the highest reactivity occurred at 1,000°C. In addition, the oxygen release and absorption performance of OC were tested in thermal-gravimetric (TG). According to theoretical calculations, the mass loss caused by oxygen release accounts for 70.57% of the total loss and the mass reached by 4.2% at 1,000°C in oxygen absorption experiment. The copper slag modified through calcining in redox condition was proved to be a promising oxygen carrier in chemical looping process. Furthermore, the performance research on OC also provided theoretical references for the operating paraments of OC circulating between air reactor and fuel reactor in practical chemical looping processes.

Waste heat recovery is a key problem to be solved for metallurgical slag. Furthermore, the heat source is a current bottleneck for sewage sludge gasification technology. At present, there is no complete process system for the thermochemical conversion of sludge driven by metallurgical slag waste heat. To recover the waste heat of slag, a granulation and waste heat recovery system using the sewage sludge gasification reaction is proposed in this paper. The sludge gasification kinetics were analyzed using thermogravimetry (TG). The active catalytic components in both Cu and Ni slag were determined using X-ray diffractometry (XRD) and X-ray photoelectron spectroscopy (XPS). The results show that the metallurgical slag could improve the decomposition rate of the sludge gasification reaction. The main catalytic components were Fe3O4 and CaO for Cu slag and Ni slag, respectively. The conversion ratio was increased by 7.8% and 11.8%, while the activation energy decreased from 21.09 kJ/mol to 17.36 kJ/mol and 17.30 kJ/mol, respectively, when Cu slag and Ni slag were added. After oxidative modification, the catalytic function was enhanced for Cu slag, whereas it was weakened for Ni slag.

LaMnO3 with perovskite structure is a SCR de-NOx catalyst with good performance at low temperatures. In this paper, the SCR reaction process on the 010 surface of LaMnO3 catalyst was studied by DFT method, to guide the development of catalysts and their effective application. The results obtained through research indicate that both E-R and L-H mechanisms exist on the catalyst surface. The NH3 molecule can be absorbed on L acid and then oxidized by lattice oxygen to form NH2. Then, NH2 can react with the NO molecule to form NH2NO and decompose to N2 and H2O. The NH3 can also be absorbed with hydroxyl to form NH4+, it can also react with NO to form NH2NO and then decompose. The NH4+ also can react with NO3− which is formed by NO oxidized when O2 is present, to participate in the rapid SCR process.