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A simple and effective single-shot pump-probe technique is reported for studying the ultrafast dynamic processes in various materials. Using only two commercial gratings, a large time window of ~ 95.58 ps is spatially encoded in a single probe pulse, and single-shot time-resolved measurements are implemented. This time window exceeds the maximum reported values for single-shot pump-probe techniques using the echelon or angle beam encoding strategy. The phase difference problem in the echelon encoding strategies is also eliminated and a customized echelon is not needed in this technique. The ultrafast dynamic processes of ZnSe and indolium squaraine at a wavelength of 650 nm were investigated using this technique., Comment: 14 pages, 4 figures

In this study, using only a single pulse, pump-probe measurement with a large time window of more than 100 ps is implemented. A commercial grating is used to encode a time window of ~ 56 ps in a single pulse; therefore, there is no need for machining customization. In addition, in this technique, the grating surface is accurately imaged, eliminating the image blur problem caused by phase differences in previous echelon-based techniques. Moreover, to make full use of the grating surface and obtain a larger time window, a simple reflection echelon is combined that matches the grating in the time window. This combination encoding strategy results in a total time window of ~ 109 ps and maintains accurate imaging of the grating surface. This time window is an order of magnitude greater than the maximum reported values of the echelon encoding strategy and the angle beam encoding strategy. To demonstrate this single-shot pump-probe technique, the two-photon absorption process of ZnSe and the excited-state absorption process of a symmetrical phenoxazinium bromine salt were studied. The possibility of further improving the experimental setup is also discussed., Comment: 20 pages,8 figures