1. Rare-earth element doped barium titanate-based ceramics exhibiting ultra-wide temperature span electrocaloric effect.
- Author
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Ma, Xiyu, Huang, Yunyao, Jing, Ruiyi, Alikin, Denis, Wei, Xiaoyong, Yan, Yan, and Jin, Li
- Subjects
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PYROELECTRICITY , *BARIUM titanate , *DOPING agents (Chemistry) , *LEAD-free ceramics , *SAMARIUM , *CERAMICS , *BARIUM - Abstract
Electrocaloric effect (ECE) refrigeration stands out as a promising alternative to conventional compression refrigeration owing to its potential for miniaturization, high energy conversion efficiency, cost-effectiveness, and environmental friendliness. However, the practical applications of ECE refrigeration in lead-free ceramics face limitations due to the challenge of achieving a substantial adiabatic temperature change (Δ T) and a wide operating temperature span (T span). In this study, we tackle this challenge by introducing rare-earth Sm3+ ions into Ba(Ti 0 · 90 Sn 0.10)O 3 (BTSn) ceramics to enhance their ECE stability. We comprehensively investigate the structural, dielectric, and ECE properties of (Ba 1−3 x /2 Sm x) (Ti 0 · 9 Sn 0.1)O 3 (BSmTSn, x = 0−0.03) ceramics. Our findings reveal that the incorporation of Sm3+ ions leads to a reduction in the temperature at which the permittivity reaches its maximum, accompanied by an increased dispersion compared to undoped BTSn ceramics. Particularly noteworthy is the achievement of a Δ T of 0.9 K with a T span of 55.5 °C in the x = 0.005 composition. Furthermore, increasing x to 0.01 enables the realization of a wide T span of 70 °C, starting from 30 °C. These significant enhancements in the T span across all BSmTSn ceramics, facilitated by the introduction of Sm3+ ions, present a promising strategy for optimizing the ECE performance of BaTiO 3 -based ceramics. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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