6 results on '"Pérez-Carvajal, Javier"'
Search Results
2. A Self-Folding Polymer Film Based on Swelling Metal–Organic Frameworks
- Author
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Troyano, Javier, Carné-Sánchez, Arnau, Pérez-Carvajal, Javier, León-Reina, Laura, Imaz, Inhar, Cabeza-Diaz, Aurelio, and Maspoch, Daniel
- Subjects
Metal–organic frameworks ,Conductores orgánicos ,Self-folding ,Composites ,Films ,Swelling behaviour - Abstract
Herein, we exploit the well-known swelling behaviour of metal–organic frameworks (MOFs) to create a selffolding polymer film. Namely, we show that incorporating crystals of the flexible MOF MIL-88A into a polyvinylidene difluoride (PVDF) matrix affords a polymer composite film that undergoes reversible shape transformations upon exposure to polar solvents and vapours. Since the self-folding properties of this film correlate directly with the swelling properties of the MIL-88A crystals, it selectively bends to certain solvents and its degree of folding can be controlled by controlling the relative humidity. Moreover, it shows a shapememory effect at relative humidity values from 60% to 90%. As proof of concept, we demonstrate that these composite films can lift cargo and can be used to assemble 3D structures from 2D patterns. Our strategy is a straightforward method for designing autonomous soft materials with folding properties that can be tuned by judicious choice of the constituent flexible MOF. Proyecto del MINECO MAT2013-41836-R y de la Junta de Andalucía P12-FQM-1656
- Published
- 2018
3. Self-assembly of polyhedral metal–organic framework particles into three-dimensional ordered superstructures
- Author
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Avci, Civan, Imaz, Inhar, Carné-Sánchez, Arnau, Pariente, Jose Angel, Tasios, Nikos, Pérez-Carvajal, Javier, Alonso, Maria Isabel, Blanco, Alvaro, Dijkstra, M., López, Cefe, Maspoch, Daniel, Sub Soft Condensed Matter, Soft Condensed Matter and Biophysics, Sub Soft Condensed Matter, and Soft Condensed Matter and Biophysics
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Metal–organic frameworks ,Chemistry ,General Chemical Engineering ,Nanotechnology ,02 engineering and technology ,General Chemistry ,Self-assembly ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Photonic metamaterial ,Coordination chemistry ,Dodecahedron ,Octahedron ,Lattice (order) ,Optical materials ,Taverne ,Metal-organic framework ,0210 nano-technology ,Plasmon ,Photonic crystal - Abstract
Altres ajuts: Comunidad de Madrid project S2013/MIT-2740 (PHAMA_2.0). CERCA Programme/Generalitat de Catalunya Self-assembly of particles into long-range, three-dimensional, ordered superstructures is crucial for the design of a variety of materials, including plasmonic sensing materials, energy or gas storage systems, catalysts and photonic crystals. Here, we have combined experimental and simulation data to show that truncated rhombic dodecahedral particles of the metal-organic framework (MOF) ZIF-8 can self-assemble into millimetre-sized superstructures with an underlying three-dimensional rhombohedral lattice that behave as photonic crystals. Those superstructures feature a photonic bandgap that can be tuned by controlling the size of the ZIF-8 particles and is also responsive to the adsorption of guest substances in the micropores of the ZIF-8 particles. In addition, superstructures with different lattices can also be assembled by tuning the truncation of ZIF-8 particles, or by using octahedral UiO-66 MOF particles instead. These well-ordered, sub-micrometre-sized superstructures might ultimately facilitate the design of three-dimensional photonic materials for applications in sensing.
- Published
- 2018
4. Estrategias bottom-up para la síntesis de nanoarquitecturas porosas sobre soportes silícicos
- Author
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Pérez Carvajal, Javier, Ruiz-Hitzky, Eduardo, Aranda Gallego, Pilar, UAM. Departamento de Geología y Geoquímica, and CSIC. Instituto de Ciencia de Materiales de Madrid (ICMM)
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Silicio - Tesis doctorales ,Geología ,Química ,Materiales nanoestructurados - Tesis doctorales ,Materiales porosos - Tesis doctorales - Abstract
Tesis doctoral inédita leída en la Universidad Autónoma de Madrid, Facultad de Ciencias, Departamento de Geología y Geoquímica. Fecha de lectura: 12-02-2015
- Published
- 2015
5. A CO2optical sensor based on self-assembled metal–organic framework nanoparticles
- Author
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Olalla Calvo-Lozano, Javier Pérez-Carvajal, Blanca Chocarro-Ruiz, Laura M. Lechuga, Civan Avci, Daniel Maspoch, Maria Isabel Alonso, Fundación Domingo Martínez, Ministerio de Economía y Competitividad (España), European Research Council, European Commission, Generalitat de Catalunya, Chocarro Ruiz, Blanca, Pérez-Carvajal, Javier, Alonso, M. I., Maspoch, Daniel, Lechuga, Laura M., Chocarro Ruiz, Blanca [0000-0003-3835-9046], Pérez-Carvajal, Javier [0000-0002-6916-1158], Alonso, M. I. [0000-0001-7669-5871], Maspoch, Daniel [0000-0003-1325-9161], and Lechuga, Laura M. [0000-0001-5187-5358]
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Fabrication ,Materials science ,Zeolitic imidazolate framework-8 ,Nanoparticle ,Humid conditions ,Nanotechnology ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,Self assembled ,Food packaging ,chemistry.chemical_compound ,Imidazolate ,General Materials Science ,Human safety ,Linear response ,Renewable Energy, Sustainability and the Environment ,Transparent films ,Limits of detection ,Optical CO2 sensors ,General Chemistry ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Metal organic framework ,Carbon dioxide sensor ,chemistry ,Metal-organic framework ,0210 nano-technology - Abstract
The development of devices for sensing and monitoring CO2 levels is crucial for many fields such as food packaging and for human safety indoors. Herein the fabrication of an optical CO2 sensor by integration of a metal–organic framework (MOF) onto bimodal optical waveguides is reported. This sensor is constructed via self-assembly of a transparent film of zeolitic imidazolate framework-8 (ZIF-8) nanoparticles (size: 32 ± 5 nm) on the waveguides. The nanoZIF-8-based sensor exhibits a broad linear response, with limits of detection of 3130 ppm at room temperature and 774 ppm at 278 K. Furthermore, it is robust, selective, fast and reusable, and can be stored under humid conditions with no loss in performance., This work was supported by a grant from the Fundación Domingo Martínez (Ayuda a la Investigación 2016. Área de Aplicaciones Materiales), the Spanish MINECO (projects PN MAT2015-65354-C2-1-R and MAT2016-79053-P), the Catalan AGAUR (project 2014 SGR 80 and 2014 SGR 624), and the ERC, under the EU FP7 (ERC-Co 615954). It was also funded by the CERCA Program/Generalitat de Catalunya. This work also made use of the Spanish ICTS Network MICRONANOFABS, which is partially supported by MEINCOM. ICN2 and ICMAB acknowledge the support of the Spanish MINECO through the Severo Ochoa Centers of Excellence Program, under Grants SEV-2013-0295 and SEV-2015-0496.
- Published
- 2018
6. Silica-Ti 3 C 2 T x MXene Nanoarchitectures with Simultaneous Adsorption and Photothermal Properties.
- Author
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Ruiz-Hitzky E, Ounis M, Younes MK, and Pérez-Carvajal J
- Abstract
Layered Ti
3 C2 Tx MXene has been successfully intercalated and exfoliated with the simultaneous generation of a 3D silica network by treating its cationic surfactant intercalation compound (MXene-CTAB) with an alkoxysilane (TMOS), resulting in a MXene-silica nanoarchitecture, which has high porosity and specific surface area, together with the intrinsic properties of MXene (e.g., photothermal response). The ability of these innovative MXene silica materials to induce thermal activation reactions of previously adsorbed compounds is demonstrated here using NIR laser irradiation. For this purpose, the pinacol rearrangement reaction has been selected as a first model example, testing the effectiveness of NIR laser-assisted photothermal irradiation in these processes. This work shows that Ti3 C2 Tx -based nanoarchitectures open new avenues for applications that rely on the combined properties inherent to their integrated nanocomponents, which could be extended to the broader MXene family.- Published
- 2024
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