Search

This study presents the design, preparation, and characterization of thirty new medium-entropy alloys (MEAs) in three systems: Al-Ti-Nb-Zr, Al-Ti-Nb-V, and Al-Ti-Nb-Hf. The hardness of the alloys ranged from 320 to 800 HV0.3. Among the alloys studied, Al15Ti40Nb30Zr15 exhibited the highest-reversible hydrogen storage capacity (1.03 wt.%), with an H/M value of 0.68, comparable to LaNi5, but with a reduced density (5.11 g·cm−3) and without rare earth elements. This study further reveals a strong correlation between hardness and hydrogen absorption/desorption; higher hardness is responsible for reduced hydrogen uptake. This finding highlights the interplay between a material's properties and hydrogen storage behavior in MEAs, and has implications for the development of efficient hydrogen storage materials. [ABSTRACT FROM AUTHOR]

Hydrogen is a key element in the changing energy sector and presents an accessible alternative to conventional fossil fuel sources. In this work, a system of ten high-entropy alloys was prepared based on the Hume-Rothery rules. One of the biggest advantages of these alloys is their storage capacity, which reaches the highest value among all known alloys intended for hydrogen storage. Alloys based on Al-Ti-Nb-Zr elements with different atomic fractions show interesting accumulation capabilities with fast absorption kinetics and low specific gravity. Each alloy in this study underwent high-pressure gravimetric absorption and desorption tests. The main goals of this work were to prepare alloys with the lowest-possible specific gravity and the highest-possible storage capacity. One alloy from our system shows storage capacity values similar to commercial alloys, without any rare-earth elements. [ABSTRACT FROM AUTHOR]

In the realm of advanced anode materials for lithium-ion batteries, this study explores the electrochemical performance of a high-entropy oxide (HEO) with a unique spinel structure. The equiatomic composition of CrMnFeCoCu was synthesized and subjected to a comprehensive materials characterization process, including X-ray diffraction and microscopy techniques. The multicomponent alloy exhibited a multiphase structure, comprising two face-centered cubic (FCC) phases and an oxide phase. Upon oxidation, the material transformed into a spinel oxide with a minor presence of CuO. The resulting high-entropy oxide demonstrated excellent electrochemical behavior when utilized as an anode material. Cyclic voltammetry revealed distinctive reduction peaks attributed to cation reduction and solid electrolyte interphase (SEI) layer formation, while subsequent cycles showcased high reversibility. Electrochemical impedance spectroscopy indicated a decrease in charge transfer resistance during cycling, emphasizing the remarkable electrochemical performance. Galvanostatic charge/discharge tests displayed characteristic voltage profiles, with an initial irreversible capacity attributed to SEI layer formation. The HEO exhibited promising rate capability, surpassing commercial graphite at higher current densities. The battery achieved 80% (275 mAh g−1) of its initial stable capacity at a current density of 500 mA g−1 by the 312th cycle. Post-mortem analysis revealed structural amorphization during cycling, contributing to the observed electrochemical behavior. This research highlights the potential of HEOs as advanced anode materials for lithium-ion batteries, combining unique structural features with favorable electrochemical properties. [ABSTRACT FROM AUTHOR]