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Soft chemistry techniques, such as ion exchange, hold great potential for the development of battery electrode materials that cannot be stabilized via conventional equilibrium synthesis methods. Nevertheless, the intricate mechanisms governing ion exchange remain elusive. Herein, we investigate the evolution of the long-range and local structure, as well as the ion (de)intercalation mechanism during electrochemical Li-to-Na ion exchange initiated from an O3-type lithium-layered oxide cathode. The in situ-formed mixed-cation electrolyte leads to competitive intercalation of Li and Na ions. While Li ion intercalation predominates at the beginning of initial discharge, Na ion cointercalation into a different layer results in ion redistribution and phase separation, with the emergence of a P3-Na phase alongside an O3-Li phase. Further, this study spatially resolves the heterogeneous nature of electrochemical ion exchange reactions within individual particles and provides insights into the correlations between local Ni redox processes and phase separation. Overall, electrochemical ion exchange leads to a mixed-phase cathode and alters its reaction kinetics. Those findings have important implications for the development of new metastable materials for renewable energy devices and ion separation applications.

Internal combustion engine fueled by carbon-free hydrogen (H2-ICE) offers a promising alternative for sustainable transportation. Herein, we report a facile and universal strategy through the physical mixing of Pt catalyst with zeolites to significantly improve the catalytic performance in the selective catalytic reduction of nitrogen oxides (NOx) with H2 (H2-SCR), a process aiming at NOx removal from H2-ICE. Via the physical mixing of Pt/TiO2 with Y zeolite (Pt/TiO2 + Y), a remarkable enhancement of NOx reduction activity and N2 selectivity was simultaneously achieved. The incorporation of Y zeolite effectively captured the in-situ generated water, fostering a water-rich environment surrounding the Pt active sites. This environment weakened the NO adsorption while concurrently promoting the H2 activation, leading to the strikingly elevated H2-SCR activity and N2 selectivity on Pt/TiO2 + Y catalyst. This study provides a unique, easy and sustainable physical mixing approach to achieve proficient heterogeneous catalysis for environmental applications.

Effective synthesis and application of single-atom catalysts on supports lacking enough defects remain a significant challenge in environmental catalysis. Herein, we present a universal defect-enrichment strategy to increase the surface defects of CeO2-based supports through H2 reduction pretreatment. The Pt catalysts supported by defective CeO2-based supports, including CeO2, CeZrOx, and CeO2/Al2O3 (CA), exhibit much higher Pt dispersion and CO oxidation activity upon reduction activation compared to their counterpart catalysts without defect enrichment. Specifically, Pt is present as embedded single atoms on the CA support with enriched surface defects (CA-HD) based on which the highly active catalyst showing embedded Pt clusters (PtC) with the bottom layer of Pt atoms substituting the Ce cations in the CeO2 surface lattice can be obtained through reduction activation. Embedded PtC can better facilitate CO adsorption and promote O2 activation at PtC-CeO2 interfaces, thereby contributing to the superior low-temperature CO oxidation activity of the Pt/CA-HD catalyst after activation.

Four different high-entropy spinel oxide ferrite (HESO) electrode materials containing 5-6 distinct metals were synthesized by a simple, rapid combustion synthesis process and evaluated as conversion anode materials in lithium half-cells. All showed markedly superior electrochemical performance compared to conventional spinel ferrites such as Fe3O4 and MgFe2O4, having capacities that could be maintained above 600 mAh g-1 for 150 cycles, in most cases. X-ray absorption spectroscopy (XAS) results on pristine, discharged, and charged electrodes show that Fe, Co, Ni, and Cu are reduced to the elemental state during the first discharge (lithiation), while Mn is only slightly reduced. Upon recharge (delithiation), Fe is reoxidized to an average oxidation state of about 2.6+, while Co, Ni, and Cu are not reoxidized. The ability of Fe to be oxidized past 2+ accounts for the high capacities observed in these materials, while the presence of metallic elements after the initial lithiation provides an electronically conductive network that aids in charge transfer.

Co- and Ni-free disordered rocksalt cathodes utilize oxygen redox to increase the energy density of lithium-ion batteries, but it is challenging to achieve good cycle life at high voltages >4.5 V (versus Li/Li+). Here we report a family of Li-excess Mn-rich cathodes that integrates rocksalt- and polyanion-type structures. Following design rules for cation filling and ordering, we demonstrate the bulk incorporation of polyanion groups into the rocksalt lattice. This integration bridges the two primary families of lithium-ion battery cathodes—layered/spinel and phosphate oxides—dramatically enhancing the cycling stability of disordered rocksalt cathodes with 4.8 V upper cut-off voltage. The cathode exhibits high gravimetric energy densities above 1,100 Wh kg−1 and >70% retention over 100 cycles. This study opens up a broad compositional space for developing battery cathodes using earth-abundant elements such as Mn and Fe.

In CH3COONa-HCl buffer solution, ClO2- oxidizes excess I- to generate I3-, and I3- forms complex particles with positively charged methylene blue under electrostatic attraction, which enhances the resonance scattering intensity of the system. Based on this principle, a new method for the determination of trace NaClO2 in water by resonance scattering spectroscopy was established.The measurement conditions of this method were optimized to improve the resonance scattering intensity. The optimal dosage of CH3COONa-HCl buffer solution, KI solution, and methylene blue solution, as well as the optimal reaction time and measurement wavelength, were obtained during the measurement. Under the optimal conditions, the resonance scattering intensity increased with the increase of ClO2- mass concentration in the range of 0.018 2-0.364 0 mg/L, which showed a good linear relationship with a detection limit of 0.004 8 mg/L. When this method was used to determine the content of chlorite in groundwater, the relative standard deviation of the measurement results was 1.5%-2.9%, and the recovery rate was 96%-99%.

Atomically dispersed catalysts such as single-atom catalysts have been shown to be effective in selectively oxidizing methane, promising a direct synthetic route to value-added oxygenates such as acetic acid or methanol. However, an important challenge of this approach has been that the loading of active sites by single-atom catalysts is low, leading to a low overall yield of the products. Here, we report an approach that can address this issue. It utilizes a metal-organic framework built with porphyrin as the linker, which provides high concentrations of binding sites to support atomically dispersed rhodium. It is shown that up to 5 wt% rhodium loading can be achieved with excellent dispersity. When used for acetic acid synthesis by methane oxidation, a new benchmark performance of 23.62 mmol·gcat-1·h-1 was measured. Furthermore, the catalyst exhibits a unique sensitivity to light, producing acetic acid (under illumination, up to 66.4% selectivity) or methanol (in the dark, up to 65.0% selectivity) under otherwise identical reaction conditions.

Agrivoltaic systems emerge as a promising solution to the ongoing conflict between allocating agricultural land for food production and establishing solar parks. This field experiment, conducted during the spring and summer seasons of 2023, aims to showcase barley production in a vertical agrivoltaic system compared to open-field reference conditions at Kärrbo Prästgård, near Västerås, Sweden. The dataset presented in this article encompasses both barley kernel and straw yields, kernel crude protein levels, starch content in kernels and thousand kernel weight. All collected data underwent analysis of variance (ANOVA) with Tukey pairwise comparison when possible, using dedicated software RStudio 4.3.2. This dataset article illustrates the effects of the vertical agrivoltaic design system on barley productivity. Interested researchers can benefit from this data to better comprehend barley yield under this specific agrivoltaic design and conduct further analyses and comparisons with yields from different locations or design configurations. The experimental data holds the potential to foster collaborations and advance research in agrivoltaic systems, providing a valuable resource for anyone interested in the subject. It was observed that the mean barley yield in all the different areas of the vertical agrivoltaic system were higher than the one in the control area. Additionally, weather and solar irradiance data collected during the growing season are provided in the repository for further usage.

Constructing single atom catalysts with fine-tuned coordination environments can be a promising strategy to achieve satisfactory catalytic performance. Herein, via a simple calcination temperature-control strategy, CeO2 supported Pt single atom catalysts with precisely controlled coordination environments are successfully fabricated. The joint experimental and theoretical analysis reveals that the Pt single atoms on Pt1/CeO2 prepared at 550 °C (Pt/CeO2-550) are mainly located at the edge sites of CeO2 with a Pt-O coordination number of ca. 5, while those prepared at 800 °C (Pt/CeO2-800) are predominantly located at distorted Ce substitution sites on CeO2 terrace with a Pt-O coordination number of ca. 4. Pt/CeO2-550 and Pt/CeO2-800 with different Pt1-CeO2 coordination environments exhibit a reversal of activity trend in CO oxidation and NH3 oxidation due to their different privileges in reactants activation and H2O desorption, suggesting that the catalytic performance of Pt single atom catalysts in different target reactions can be maximized by optimizing their local coordination structures.

This study investigates the performance of agrivoltaic systems employing bifacial photovoltaic modules. A comparison between yield in Sweden and Italy was carried out. Three agrivoltaic system designs were evaluated: vertical fixed, single-axis tracker, and dual-axis tracker. The results showed that the specific production varied between 1090 to 1440 kWh/kWp/yr in Sweden and 1584 to 2112 kWh/kWp/yr in Italy, where the lowest production was obtained with the vertical fixed agrivoltaic system while the highest production was obtained with the dual-axis tracking agrivoltaic system. The vertical fixed design had a higher electricity production during low solar elevation angles, while the single-axis and dual-axis tracking designs had significantly higher power production during mid-day. The electricity production gain using a dual-axis tracker design was mostly during mid-day, but the increase compared to the single-axis tracker was only 1-2%. The study concludes that low-height, fixed agrivoltaic systems without tracking are well-suited for high-latitude countries like Sweden, while elevated systems with tracker solutions are more suitable for locations like Italy. The findings suggest that the performance of agrivoltaic systems with bifacial photovoltaic modules is highly dependent on geographical location and the specific characteristics of the crops grown beneath them.

In agrivoltaic systems combining solar photovoltaic and agricultural activities, ground albedo is mainly characterized by the crop and its seasonal variations. This study examines the effects of using fixed, satellite-derived, and hourly measured albedo on the performance of a vertical bifacial system and a 1-axis tracking system using a bifacial photovoltaic model (AgriOptiCE). The model is developed with Matlab® and partially based on the open-source package pvlib. AgriOptiCE is firstly validated by comparing estimated front and rear irradiances with on-site measurements for specific periods from a 1-axis tracker site in Golden, USA and a vertical agrivoltaic system in Västerås, Sweden. Furthermore, photovoltaic system power output estimations using AgriOptiCE are also validated for the vertical agrivoltaic system and the conventional ground-mounted fixed-tilt system at the same location. The validations demonstrate the high accuracy of the proposed model in estimating front and rear irradiances and power output, obtaining R2 > 0.85 for all the studied cases. The study results indicate that measured albedo provides the highest accuracy, while satellite-derived albedo has poorer results due to the broader spatial, temporal, and spectral resolution. Fixed albedo is not recommended for yearly assessment of bifacial PV systems because it cannot account for snow events and daily variations, resulting in lower overall accuracy.