62 results on '"Interface Analysis Centre"'
Search Results
2. In-situ, time resolved monitoring of uranium in BFS:OPC grout. Part 2: Corrosion in water
- Author
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C. A. Stitt, C. Paraskevoulakos, A. Banos, N. J. Harker, K. R. Hallam, H. Pullin, A. Davenport, S. Street, T. B. Scott, Interface Analysis Centre, University of Bristol [Bristol], European Synchrotron Radiation Facility (ESRF), School of Metallurgy and Materials, and University of Birmingham [Birmingham]
- Subjects
Multidisciplinary ,[SDV]Life Sciences [q-bio] ,lcsh:R ,lcsh:Medicine ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,OXYGEN ,Article ,0104 chemical sciences ,MECHANISMS ,IMMOBILIZATION ,CEMENT ,TEMPERATURES ,VAPOR ,lcsh:Q ,0210 nano-technology ,lcsh:Science ,(null) - Abstract
To reflect potential conditions in a geological disposal facility, uranium was encapsulated in grout and submersed in de-ionised water for time periods between 2–47 weeks. Synchrotron X-ray Powder Diffraction and X-ray Tomography were used to identify the dominant corrosion products and measure their dimensions. Uranium dioxide was observed as the dominant corrosion product and time dependent thickness measurements were used to calculate oxidation rates. The effectiveness of physical and chemical grout properties to uranium corrosion and mobilisation is discussed and Inductively Coupled Plasma Mass Spectrometry was used to measure 238U(aq) content in the residual water of several samples.
- Published
- 2018
3. Exploring the distribution of copper-Schiff base complex covalently anchored onto the surface of mesoporous MCM 41 silica
- Author
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Allen, Geoffrey [Interface Analysis Centre, University of Bristol, Bristol BS2 8BS (United Kingdom)]
- Published
- 2005
- Full Text
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4. In-situ, time resolved monitoring of uranium in BFS:OPC grout. Part 1: Corrosion in water vapour
- Author
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A. Banos, Steven R. Street, Huw Pullin, Keith R Hallam, N. J. Harker, C.A. Stitt, Alison J. Davenport, C. Paraskevoulakos, Thomas Bligh Scott, Interface Analysis Centre, University of Bristol [Bristol], European Synchrotron Radiation Facility (ESRF), School of Metallurgy and Materials, and University of Birmingham [Birmingham]
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Materials science ,Science ,Uranium dioxide ,0211 other engineering and technologies ,Oxide ,Analytical chemistry ,chemistry.chemical_element ,Mineralogy ,02 engineering and technology ,engineering.material ,OXIDATION ,Oxygen ,Article ,OXYGEN ,Corrosion ,MECHANISMS ,Reaction rate ,chemistry.chemical_compound ,PHASES ,TEMPERATURES ,CEMENT ,021105 building & construction ,KINETICS ,[PHYS]Physics [physics] ,Multidisciplinary ,Science & Technology ,Grout ,MIXTURES ,Uranium ,021001 nanoscience & nanotechnology ,Multidisciplinary Sciences ,chemistry ,RAY PHOTOELECTRON-SPECTROSCOPY ,engineering ,Medicine ,Science & Technology - Other Topics ,0210 nano-technology ,Water vapor ,DIOXIDE - Abstract
Uranium encapsulated in grout was exposed to water vapour for extended periods of time. Through synchrotron x-ray powder diffraction and tomography measurements, uranium dioxide was determined the dominant corrosion product over a 50-week time period. The oxide growth rate initiated rapidly, with rates comparable to the U + H2O reaction. Over time, the reaction rate decreased and eventually plateaued to a rate similar to the U + H2O + O2 reaction. This behaviour was not attributed to oxygen ingress, but instead the decreasing permeability of the grout, limiting oxidising species access to the metal surface.
- Published
- 2017
5. Nanoscale Metallic Iron for Environmental Remediation: Prospects and Limitations
- Author
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Sabine Caré, Chicgoua Noubactep, Richard A. Crane, Department of Applied Geology [Göttingen], Georg-August-University [Göttingen], Kultur und Nachhaltige Entwicklung CDD e.V, Kultur und Nachhaltige Entwicklung CDD e.V ONG de droit allemand, Rhéophysique, Laboratoire Navier (navier umr 8205), École des Ponts ParisTech (ENPC)-Centre National de la Recherche Scientifique (CNRS)-Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR)-École des Ponts ParisTech (ENPC)-Centre National de la Recherche Scientifique (CNRS)-Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR), Interface Analysis Centre, and University of Bristol [Bristol]
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Environmental remediation ,Material reactivity ,Nanoscale iron ,Roll-front ,Zerovalent iron ,Environmental Engineering ,Groundwater remediation ,0211 other engineering and technologies ,FOS: Physical sciences ,Physics - Classical Physics ,02 engineering and technology ,010501 environmental sciences ,01 natural sciences ,Article ,[SPI.MAT]Engineering Sciences [physics]/Materials ,[PHYS.MECA.MEMA]Physics [physics]/Mechanics [physics]/Mechanics of materials [physics.class-ph] ,Environment ,Atmospheric Protection/Air Quality Control/Air Pollution ,Climate Change ,Environment, general ,Soil Science & Conservation ,Hydrogeology ,Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution ,[SPI.MECA.MEMA]Engineering Sciences [physics]/Mechanics [physics.med-ph]/Mechanics of materials [physics.class-ph] ,Environmental Chemistry ,0105 earth and related environmental sciences ,Water Science and Technology ,021110 strategic, defence & security studies ,Ecological Modeling ,Classical Physics (physics.class-ph) ,[CHIM.MATE]Chemical Sciences/Material chemistry ,Pollution ,6. Clean water ,Ecological Modelling ,13. Climate action ,Environmental remediation . Material reactivity . Nanoscale iron . Roll-front . Zerovalent iron ,Environmental science ,Biochemical engineering - Abstract
International audience; The amendment of the subsurface with nanoscale metallic iron particles (nano-Fe0) has been discussed in the literature as an efficient in situ technology for groundwater remediation. However, the introduction of this technology was controversial and its efficiency has never been univocally established. This unsatisfying situation has motivated this communication whose objective was a comprehensive discussion of the intrinsic reactivity of nano-Fe0 based on the contemporary knowledge on the mechanism of contaminant removal by Fe0 and a mathematical model. It is showed that due to limitations of the mass transfer of nano-Fe0 to contaminants, available concepts cannot explain the success of nano-Fe0 injection for in situ groundwater remediation. It is recommended to test the possibility of introducing nano-Fe0 to initiate the formation of roll-fronts which propagation would induce the reductive transformation of both dissolved and adsorbed contaminants. Within a roll-front, FeII from nano-Fe0 is the reducing agent for contaminants. FeII is recycled by biotic or abiotic FeIII reduction. While the roll-front concept could explain the success of already implemented reaction zones, more research is needed for a science-based recommendation of nano- Fe0 for subsurface treatment by roll-fronts
- Published
- 2011
6. An Investigation on the Persistence of Uranium Hydride during Storage of Simulant Nuclear Waste Packages
- Author
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Stitt, CA, Harker, NJ, Hallam, KR, Paraskevoulakos, C, Banos, A, Rennie, S, Jowsey, J, Scott, TB, Interface Analysis Centre [Bristol ], H. H. Wills Physics Laboratory [Bristol], University of Bristol [Bristol]-University of Bristol [Bristol], European Synchrotron Radiation Facility (ESRF), Sellafield Ltd, Seascale, Cumbria, England, and Janssen, PJ
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General Science & Technology ,[SDV]Life Sciences [q-bio] ,MD Multidisciplinary ,lcsh:R ,lcsh:Medicine ,lcsh:Q ,lcsh:Science - Abstract
International audience; Synchrotron X-rays have been used to study the oxidation of uranium and uranium hydride when encapsulated in grout and stored in de-ionised water for 10 months. Periodic synchrotron X-ray tomography and X-ray powder diffraction have allowed measurement and identification of the arising corrosion products and the rates of corrosion. The oxidation rates of the uranium metal and uranium hydride were slower than empirically derived rates previously reported for each reactant in an anoxic water system, but without encapsulation in grout. This was attributed to the grout acting as a physical barrier limiting the access of oxidising species to the uranium surface. Uranium hydride was observed to persist throughout the 10 month storage period and industrial consequences of this observed persistence are discussed
- Published
- 2015
7. Modeling the permeability loss of metallic Iron water filtration Systems
- Author
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Richard A. Crane, Chicgoua Noubactep, Antoine Ghauch, Sabine Caré, Emile Temgoua, Paolo S. Calabrò, Matériaux et Structures Architecturés (msa), Laboratoire Navier (navier umr 8205), École des Ponts ParisTech (ENPC)-Centre National de la Recherche Scientifique (CNRS)-Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR)-École des Ponts ParisTech (ENPC)-Centre National de la Recherche Scientifique (CNRS)-Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR), Interface Analysis Centre, University of Bristol [Bristol], Mechanics and Materials department MECMAT, Reggio Calabria, Universita Mediterranea of Reggio Calabria [Reggio Calabria], Department of Chemistry, American University of Beirut, Faculty of Engineering, Beirut, Lebanon, Department of Applied Geology [Göttingen], Georg-August-University [Göttingen], Kultur und Nachhaltige Entwicklung CDD e.V, and Kultur und Nachhaltige Entwicklung CDD e.V ONG de droit allemand
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Materials science ,Hydraulic conductivity ,Groundwater remediation ,0207 environmental engineering ,02 engineering and technology ,010501 environmental sciences ,01 natural sciences ,Corrosion ,[SPI.MAT]Engineering Sciences [physics]/Materials ,Environmental Chemistry ,020701 environmental engineering ,0105 earth and related environmental sciences ,Water Science and Technology ,Zerovalent iron ,Aqueous solution ,Deep-bed filtration ,Modelling, Permeability loss ,Environmental engineering ,[CHIM.MATE]Chemical Sciences/Material chemistry ,Pollution ,6. Clean water ,Permeability (earth sciences) ,Chemical engineering ,Permeable reactive barrier ,Porous medium - Abstract
International audience; Over the past 30 years the literature has burgeoned with in situ approaches for groundwater remediation. Of the methods currently available, the use of metallic iron (Fe0) in permeable reactive barrier (PRB) systems is one of the most commonly applied. Despite such interest, an increasing amount of experimental and field observations have reported inconsistent Fe0 barrier operation compared to contemporary theory. In the current work, a critical review of the physical chemistry of aqueous Fe0 corrosion in porous media is presented. Subsequent implications for the design of Fe0 filtration systems are modeled. The results suggest that: (i) for the pH range of natural waters (>4.5), the high volumetric expansion of Fe0 during oxidation and precipitation dictates that Fe0 should be mixed with a non-expansive material; (ii) naturally occurring solute precipitates have a negligible impact on permeability loss compared to Fe0 expansive corrosion; and (iii) the proliferation of H2 metabolizing bacteria may contribute to alleviate permeability loss. As a consequence, it is suggested that more emphasis must be placed on future work with regard to considering the Fe0 PRB system as a physical (size-exclusion) water filter device.
- Published
- 2013
8. The Distribution of Boron within the Microstructure of a Ferritic Steel determined using Secondary Ion Mass Spectroscopy
- Author
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Peter J Heard, R.K. Wild, Peter E J Flewitt, Interface Analysis Ctr, Retired-Bristol University, Interface Analysis Centre, and University of Bristol [Bristol]
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inorganic chemicals ,Materials science ,020502 materials ,fungi ,Metallurgy ,Analytical chemistry ,chemistry.chemical_element ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Microstructure ,Secondary ion mass spectrometry ,0205 materials engineering ,chemistry ,Bulk samples ,Physical Sciences ,High spatial resolution ,0210 nano-technology ,Boron ,Volume concentration - Abstract
International audience; Boron in ferritic steels at low concentrations can potentially have a significant effect on the mechanical properties. High spatial resolution microanalyses have been undertaken on a normalised C-Mn ferritic steel containing less than 1 wt. ppm boron. Secondary ion mass spectroscopy on bulk samples has been used to map the distribution of boron with the overall microstructure. Image analysis has been used to determine the location and concentration of boron within the overall microstructure of the steel. The results are discussed in terms of the microstructure, distribution, detection capability and overall audit of boron.
- Published
- 2006
9. Grief and coping among relatives of patients who died of COVID-19 in intensive care during the height of the COVID-19 pandemic.
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Rodriguez-Villar S, Okegbola EO, Arevalo-Serrano J, Duval Y, Mathew A, Rodriguez-Villar C, Smith KV, Kennedy RC, and Prigerson HG
- Abstract
Background: The grief of relatives of patients who died of COVID-19 in an intensive care unit (ICU) has exacted an enormous toll worldwide., Aims: To determine the prevalence of probable prolonged grief disorder (PGD) at 12 months post-loss and beyond. We also sought to examine circumstances of the death during the COVID-19 pandemic that might pose a heightened risk of PGD, and the associations between probable PGD diagnosis, quality of life and social disconnection., Method: We conducted an observational, cross-sectional multicentre study of the next of kin of those who died of COVID-19 between March 2020 and December 2021. Participants were recruited from ICUs in South-East London. The Prolonged Grief Disorder Scale (PG-13-R), Quality-of-Life Scale (QOLS) and Oxford Grief-Social Disconnection Scale (OG-SD) were used., Results: A total of 73 relatives were recruited and assessed, all of them over a year after their loss. Twenty-five (34.2%; 95% CI 23.1-45.4%) relatives of patients who died in the ICU met the criteria for PGD. Those who met the criteria had significantly worse quality of life (QOLS score mean difference 26; 95% CI 17-34; P < 0.001) and endorsed greater social disconnection (OG-SD score means difference 41; 95% CI 27-54; P < 0.001)., Conclusions: The findings suggest that rates of PGD are elevated among relatives of patients who died of COVID-19 in the ICU. This, coupled with worse quality of life and greater social disconnection experienced by those meeting the criteria, suggests the need to attend to the social deprivations and social dysfunctions of this population group.
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- 2024
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10. Long-Range Imaging of Alpha Emitters Using Radioluminescence in Open Environments: Daytime and Night-Time Applications.
- Author
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Kong L, Scott TB, Day JCC, and Megson-Smith DA
- Abstract
Alpha emitters like plutonium pose severe health risks when ingested, damaging DNA and potentially causing cancer. Traditional detection methods require proximity within millimeters of the contamination source, presenting safety risks and operational inefficiencies. Long-range detection through alpha radioluminescence (RL) offers a promising alternative. However, most of the previous experiments have been carried out under controlled conditions that preclude the overwhelming effect of ambient light. This study demonstrates the successful detection of a 3 MBq alpha emitter in an open environment using a compact alpha camera. This camera incorporates a deep-cooled CCD and a low f-number lens system designed to minimize the blue shift effects of filters. Night-time imaging was achieved with a dual-filter system using a sandwich filter assembly centered at 337 nm and 343 nm for capturing alpha RL and subtracting background light, respectively. At night, the alpha source was detected from 1 m away within one minute, and the lowest detection limit can be calculated as 75 kBq. The system was also evaluated under simulated urban lighting conditions. For daytime imaging, a stack of tilted 276 nm short pass filters minimized sunlight interference, enabling the detection of the alpha source at 70 cm within 10 min under indirect sunlight. This research highlights the viability of long-range optical detection of alpha emitters for environmental monitoring in real-world settings.
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- 2024
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11. Advancements in Remote Alpha Radiation Detection: Alpha-Induced Radio-Luminescence Imaging with Enhanced Ambient Light Suppression.
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Kong L, Scott TB, Day JCC, and Megson-Smith DA
- Abstract
Heavy nuclides like uranium and their decay products are commonly found in nuclear industries and can pose a significant health risk to humans due to their alpha-emitting properties. Traditional alpha detectors require close contact with the contaminated surface, which can be time-consuming, labour-intensive, and put personnel at risk. Remote detection is urgently needed but very challenging. To this end, a candidate detection mechanism is alpha-induced radio-luminescence. This approach uses the emission of photons from radio-ionised excited nitrogen molecules to imply the presence of alpha emitters from a distance. Herein, the use of this phenomenon to remotely image various alpha emitters with unparalleled levels of sensitivity and spatial accuracy is demonstrated. Notably, the system detected a 29 kBq Am-241 source at a distance of 3 m within 10 min. Furthermore, it demonstrated the capability to discern a 29 kBq source positioned 7 cm away from a 3 MBq source at a 2 m distance. Additionally, a 'sandwich' filter structure is described that incorporates an absorptive filter between two interference filters to enhance the ambient light rejection. The testing of the system is described in different lighting environments, including room light and inside a glovebox. This method promises safer and more efficient alpha monitoring, with applications in nuclear forensics, waste management and decommissioning.
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- 2024
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12. Examining the residual radiological footprint of a former colliery: An industrial nuclear archaeology investigation.
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Parker E, Ryan Tucker M, Okeme I, Holland E, Connor DT, Mohamed O, Martin PG, and Scott TB
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- Archaeology, Radioisotopes analysis, Coal Ash analysis, Coal analysis, Radiation Monitoring methods, Uranium analysis, Coal Mining
- Abstract
Nuclear industrial archaeology utilises radiation mapping and characterisation technologies to gain an insight into the radiological footprint of industrial heritage sites. Increased concentrations of naturally occurring radioactive materials at legacy mine sites are the result of elemental enrichment during coal mining and subsequent combustion. Public safety is of concern around these sites, and therefore, an increased understanding of their associated hazard is essential. Using coincident laser scanning and gamma detection technologies, this study sought to assess the radiological legacy of a coal mine located in Bristol, UK. From this, we can increase our understanding of the residual footprints associated with the local coal mining industry. Samples taken from inside the site were characterised using high resolution gamma spectrometry, wherein the radionuclide content and activities of samples were then quantified. An area of elevated low-level radioactivity was observed at and around buildings believed to belong to the colliery, while Th, U, and K are confirmed at the site from photopeak's of daughter radionuclides. Activities of the radionuclides K-40, U-238, and Th-232 were further quantified during subsequent laboratory analysis. Results highlight an enrichment of naturally occurring radionuclides when compared with global averages for unburned coal. Employing these techniques at further legacy sites would enable an increased understanding of the lasting traces of the coal mining industry, with a focus on NORM enrichment in residual fly ash., Competing Interests: Declaration of competing interest The authors declare no conflict of interest, financial or otherwise. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript, or in the decision to publish the results., (Copyright © 2023 The Authors. Published by Elsevier Ltd.. All rights reserved.)
- Published
- 2023
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13. Airborne gamma-ray mapping using fixed-wing vertical take-off and landing (VTOL) uncrewed aerial vehicles.
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Woodbridge E, Connor DT, Verbelen Y, Hine D, Richardson T, and Scott TB
- Abstract
Low-cost uncrewed aerial vehicles (UAVs) are replacing manned aircraft for airborne radiation mapping applications such as nuclear accident response scenarios or surveying ore deposits and mine sites because of their cost-effectiveness and ability to conduct surveys at lower altitude compared to manned counterparts. Both multi-rotor UAVs and fixed-wing UAVs are well established technologies for aerial radiation mapping applications, however, both also have drawbacks: multi-rotor UAVs are very limited in flight time and range, and fixed-wing UAVs usually require facilities for take-off and landing. A compromise solution is introduced in this work, using a fixed-wing vertical take-off and landing (VTOL) UAV that combines the flexibility of a multi-rotor UAV with the range and flight time of a fixed-wing UAV. The first implementation of a VTOL with radiation mapping capabilities is presented, based on a commercial WingtraOne UAV augmented with CsI scintillator and CZT semiconductor gamma spectrometers. The radiation mapping capabilities of the prototype are demonstrated in a case study, mapping the distribution of radionuclides around the South Terras legacy uranium mine in the south of England, United Kingdom, and the results are compared with previous studies using multi-rotor and manned aircraft to survey the same area., Competing Interests: The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest., (Copyright © 2023 Woodbridge, Connor, Verbelen, Hine, Richardson and Scott.)
- Published
- 2023
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14. Modelling 'Type B' ejecta formation reveals reactor Unit 1 conditions during the Fukushima Daiichi Nuclear Disaster.
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Carno LAS, Turner JJ, and Martin PG
- Abstract
For the first time, a model was developed to simulate the cooling of the Fukushima Daiichi Nuclear Power Plant reactor Unit 1-derived, 'Type B' radiocaesium bearing microparticles, distributed into the environment during the 2011 nuclear meltdown. By establishing an analogy between 'Type B' CsMP and volcanic pyroclasts, the presented model simulates the rapid cooling of an effervescent silicate melt fragment upon atmospheric release. The model successfully reproduced the bi-modal distribution of internal void diameters observed in 'Type B' CsMP, however, discrepancies resulted primarily due to the neglection of surface tension and internal void coalescence. The model was subsequently utilised to estimate the temperature within reactor Unit 1 in the instant preceding the hydrogen explosion-between 1900 and 1980 K. Such a model demonstrates the accuracy of the volcanic pyroclast-'Type B' CsMP analogue, and confirms radial variations in cooling rate as the cause of the vesicular texture of Unit 1 ejecta. The presented findings provide scope to further explore the comparison between volcanic pyroclasts and 'Type B' CsMP via experimentation, which will provide a deeper understanding of the specific conditions within reactor Unit 1 during the catastrophic meltdown at the Japanese coastal plant., (© 2023. The Author(s).)
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- 2023
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15. Modelling acute antibody-mediated rejection of human kidney transplants using ex-vivo warm machine perfusion.
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Chandak P, Phillips BL, Bennett D, Uwechue R, Kessaris N, Shaw O, Maggs T, Woodford L, Veniard D, Perera R, Parmar K, Hunt BJ, Callaghan C, Dorling A, and Mamode N
- Subjects
- Humans, HLA Antigens, ABO Blood-Group System, Graft Rejection, Antibodies, Kidney pathology, Perfusion, Kidney Transplantation adverse effects
- Abstract
Background: Transplant rejection is a major cause of graft loss and morbidity. Currently, no human models of antibody-mediated rejection (AMR) exist, limiting mechanistic investigation and organ-specific targeted therapy. Here, using 12 human kidneys and ex-vivo normothermic machine perfusion, we demonstrate phenotypes of AMR after addition of antibodies against either human HLA class I or blood group antigens (A, B), thus modelling clinical AMR that can follow HLA incompatible (HLAi) or blood group incompatible (ABOi) transplantation., Methods: Discarded human kidneys with wide ranging demographics and cold ischaemia times (11-54 h) were perfused with red blood cells and fresh frozen plasma (FFP) as a source of complement/coagulation factors. For the HLAi model, 600 μg of W6/32 anti-class 1 HLA antibody was added to the circuit (time '0'). For the ABOi model, high titre FFP of the relevant blood group antibody was added. Renal blood flow index (RBFi, mL/min/100 g), C3 desArg, prothrombin fragments 1 + 2 and histology were determined. Our endpoints included haemodynamic changes, thrombosis, and biopsy proven complement deposition., Findings: Compared to control kidneys perfused without anti-donor antibodies, both models demonstrated haemodynamic collapse after antibody perfusion with only the HLAi model showing glomerular C4d deposition., Interpretation: We show that a clinically relevant human kidney model of AMR is feasible, and anticipate that these models, with refinements, could provide a basis to test different strategies to prevent AMR., Funding: The Rosetrees and Stonygate Trust, The Royal College of Surgeons of England Fellowship Grant, NIHR Biomedical Research Centre/KCL Early Career Grant, Kidney Research U.K., Competing Interests: Declaration of interests The authors declare that they have no conflict of interest., (Copyright © 2022 The Authors. Published by Elsevier B.V. All rights reserved.)
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- 2022
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16. X-ray nanotomography and electron backscatter diffraction demonstrate the crystalline, heterogeneous and impermeable nature of conodont white matter.
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Atakul-Özdemir A, Warren X, Martin PG, Guizar-Sicairos M, Holler M, Marone F, Martínez-Pérez C, and Donoghue PCJ
- Abstract
Conodont elements, microfossil remains of extinct primitive vertebrates, are commonly exploited as mineral archives of ocean chemistry, yielding fundamental insights into the palaeotemperature and chemical composition of past oceans. Geochemical assays have been traditionally focused on the so-called lamellar and white matter crown tissues; however, the porosity and crystallographic nature of the white matter and its inferred permeability are disputed, raising concerns over its suitability as a geochemical archive. Here, we constrain the characteristics of this tissue and address conflicting interpretations using ptychographic X-ray-computed tomography (PXCT), pore network analysis, synchrotron radiation X-ray tomographic microscopy (srXTM) and electron back-scatter diffraction (EBSD). PXCT and pore network analyses based on these data reveal that while white matter is extremely porous, the pores are unconnected, rendering this tissue closed to postmortem fluid percolation. EBSD analyses demonstrate that white matter is crystalline and comprised of a single crystal typically tens of micrometres in dimensions. Combined with evidence that conodont elements grow episodically, these data suggest that white matter, which comprises the denticles of conodont elements, grows syntactically, indicating that individual crystals are time heterogeneous. Together these data provide support for the interpretation of conodont white matter as a closed geochemical system and, therefore, its utility of the conodont fossil record as a historical archive of Palaeozoic and Early Mesozoic ocean chemistry., (© 2021 The Authors.)
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- 2021
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17. Raptor wing morphing with flight speed.
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Cheney JA, Stevenson JPJ, Durston NE, Maeda M, Song J, Megson-Smith DA, Windsor SP, Usherwood JR, and Bomphrey RJ
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- Animals, Biomechanical Phenomena, Flight, Animal, Wings, Animal, Eagles, Raptors
- Abstract
In gliding flight, birds morph their wings and tails to control their flight trajectory and speed. Using high-resolution videogrammetry, we reconstructed accurate and detailed three-dimensional geometries of gliding flights for three raptors (barn owl, Tyto alba ; tawny owl, Strix aluco , and goshawk, Accipiter gentilis ). Wing shapes were highly repeatable and shoulder actuation was a key component of reconfiguring the overall planform and controlling angle of attack. The three birds shared common spanwise patterns of wing twist, an inverse relationship between twist and peak camber, and held their wings depressed below their shoulder in an anhedral configuration. With increased speed, all three birds tended to reduce camber throughout the wing, and their wings bent in a saddle-shape pattern. A number of morphing features suggest that the coordinated movements of the wing and tail support efficient flight, and that the tail may act to modulate wing camber through indirect aeroelastic control.
- Published
- 2021
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18. Miniaturised Low-Cost Gamma Scanning Platform for Contamination Identification, Localisation and Characterisation: A New Instrument in the Decommissioning Toolkit.
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Verbelen Y, Martin PG, Ahmad K, Kaluvan S, and Scott TB
- Abstract
Formerly clandestine, abandoned and legacy nuclear facilities, whether associated with civil or military applications, represent a significant decommissioning challenge owing to the lack of knowledge surrounding the existence, location and types of radioactive material(s) that may be present. Consequently, mobile and highly deployable systems that are able to identify, spatially locate and compositionally assay contamination ahead of remedial actions are of vital importance. Deployment imposes constraints to dimensions resulting from small diameter access ports or pipes. Herein, we describe a prototype low-cost, miniaturised and rapidly deployable 'cell characterisation' gamma-ray scanning system to allow for the examination of enclosed (internal) or outdoor (external) spaces for radioactive 'hot-spots'. The readout from the miniaturised and lead-collimated gamma-ray spectrometer, that is progressively rastered through a stepped snake motion, is combined with distance measurements derived from a single-point laser range-finder to obtain an array of measurements in order to yield a 3-dimensional point-cloud, based on a polar coordinate system-scaled for radiation intensity. Existing as a smaller and more cost-effective platform than presently available, we are able to produce a millimetre-accurate 3D volumetric rendering of a space-whether internal or external, onto which fully spectroscopic radiation intensity data can be overlain to pinpoint the exact positions at which (even low abundance) gamma-emitting materials exist.
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- 2021
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19. A Non-Destructive, Tuneable Method to Isolate Live Cells for High-Speed AFM Analysis.
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Evans CT, Baldock SJ, Hardy JG, Payton O, Picco L, and Allen MJ
- Abstract
Suitable immobilisation of microorganisms and single cells is key for high-resolution topographical imaging and study of mechanical properties with atomic force microscopy (AFM) under physiologically relevant conditions. Sample preparation techniques must be able to withstand the forces exerted by the Z range-limited cantilever tip, and not negatively affect the sample surface for data acquisition. Here, we describe an inherently flexible methodology, utilising the high-resolution three-dimensional based printing technique of multiphoton polymerisation to rapidly generate bespoke arrays for cellular AFM analysis. As an example, we present data collected from live Emiliania huxleyi cells, unicellular microalgae, imaged by contact mode High-Speed Atomic Force Microscopy (HS-AFM), including one cell that was imaged continuously for over 90 min.
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- 2021
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20. Structural and compositional characteristics of Fukushima release particulate material from Units 1 and 3 elucidates release mechanisms, accident chronology and future decommissioning strategy.
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Martin PG, Jones CP, Bartlett S, Ignatyev K, Megson-Smith D, Satou Y, Cipiccia S, Batey DJ, Rau C, Sueki K, Ishii T, Igarashi J, Ninomiya K, Shinohara A, Rust A, and Scott TB
- Abstract
The structural form and elemental distribution of material originating from different Fukushima Daiichi Nuclear Power Plant reactors (Units 1 and 3) is hereby examined to elucidate their contrasting release dynamics and the current in-reactor conditions to influence future decommissioning challenges. Complimentary computed X-ray absorption tomography and X-ray fluorescence data show that the two suites of Si-based material sourced from the different reactor Units have contrasting internal structure and compositional distribution. The known event and condition chronology correlate with the observed internal and external structures of the particulates examined, which suggest that Unit 1 ejecta material sustained a greater degree of melting than that likely derived from reactor Unit 3. In particular, we attribute the near-spherical shape of Unit 1 ejecta and their internal voids to there being sufficient time for surface tension to round these objects before the hot (and so relatively low viscosity) silicate melt cooled to form glass. In contrast, a more complex internal form associated with the sub-mm particulates invoked to originate from Unit 3 suggest a lower peak temperature, over a longer duration. Using volcanic analogues, we consider the structural form of this material and how it relates to its environmental particulate stability and the bulk removal of residual materials from the damaged reactors. We conclude that the brittle and angular Unit 3 particulate are more susceptible to further fragmentation and particulate generation hazard than the round, higher-strength, more homogenous Unit 1 material.
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- 2020
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21. Radiation Mapping and Laser Profiling Using a Robotic Manipulator.
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White SR, Megson-Smith DA, Zhang K, Connor DT, Martin PG, Hutson C, Herrmann G, Dilworth J, and Scott TB
- Abstract
The use of a robotic arm manipulator as a platform for coincident radiation mapping and laser profiling of radioactive sources on a flat surface is investigated in this work. A combined scanning head, integrating a micro-gamma spectrometer and Time of Flight (ToF) sensor were moved in a raster scan pattern across the surface, autonomously undertaken by the robot arm over a 600 × 260 mm survey area. A series of radioactive sources of different emission intensities were scanned in different configurations to test the accuracy and sensitivity of the system. We demonstrate that in each test configuration the system was able to generate a centimeter accurate 3D model complete with an overlaid radiation map detailing the emitted radiation intensity and the corrected surface dose rate., Competing Interests: JD was employed by the company KUKA Systems UK Ltd. The remaining authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest., (Copyright © 2020 White, Megson-Smith, Zhang, Connor, Martin, Hutson, Herrmann, Dilworth and Scott.)
- Published
- 2020
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22. Development of a facile fluorophosphonate-functionalised titanium surface for potential orthopaedic applications.
- Author
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Shiel AI, Ayre WN, Blom AW, Hallam KR, Heard PJ, Payton O, Picco L, and Mansell JP
- Abstract
Background: Aseptic loosening of total joint replacements (TJRs) continues to be the main cause of implant failures. The socioeconomic impact of surgical revisions is hugely significant; in the United Kingdom alone, it is estimated that £137 m is spent annually on revision arthroplasties. Enhancing the longevity of titanium implants will help reduce the incidence and overall cost of failed devices., Methods: In realising the development of a superior titanium technology, we exploited the natural affinity of titanium for phosphonic acids and developed a facile means of coating the metal with (3S)1-fluoro-3-hydroxy-4-(oleoyloxy)butyl-1-phosphonate (FHBP), a phosphatase-resistant analogue of lysophosphatidic acid (LPA). Importantly LPA and selected LPA analogues like FHBP synergistically cooperate with calcitriol to promote human osteoblast formation and maturation., Results: Herein, we provide evidence that simply immersing titanium in aqueous solutions of FHBP afforded a surface that was superior to unmodified metal at enhancing osteoblast maturation. Importantly, FHBP-functionalised titanium remained stable to 2 years of ambient storage, resisted ∼35 kGy of gamma irradiation and survived implantation into a bone substitute (Sawbone™) and irrigation., Conclusion: The facile step we have taken to modify titanium and the robustness of the final surface finish are appealing properties that are likely to attract the attention of implant manufacturers in the future., The Translational Potential of This Article: We have generated a functionalised titanium (Ti) surface by simply immersing Ti in aqueous solutions of a bioactive lipid. As a facile procedure it will have greater appeal to implant manufacturers compared to onerous and costly developmental processes., Competing Interests: The authors have no conflicts of interest to disclose in relation to this article., (© 2020 The Author(s).)
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- 2020
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23. The kinetics and mechanism of the uranium hydride - water vapour system under ambient conditions.
- Author
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Banos A and Scott TB
- Abstract
This work investigated the reaction of uranium hydride powder with saturated water vapour at 25 °C. Two corrosion experiments were conducted one with deionised water (H
2 O) and one with deuterated water (D2 O). The kinetics of the reaction were measured through gas generation method while concurrent residual gas analysis (RGA) allowed better understanding of the oxidation mechanism governing the system. From the analysis, it was found that the kinetics of the reaction are robust initially, followed by quasi-linear decelerating regime indicative of a 'shrinking core' type oxidation behaviour. The extent of the reaction (conversion to UO2 ) was lower in comparison to other works. The reaction remained incomplete bolstering the case of UH3 persistence in legacy wastes. Through interpretation of the gas analysis data, a mechanism for the uranium hydride water reaction was suggested.- Published
- 2020
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24. Project Gatekeeper: An Entrance Control System Embedded Radiation Detection Capability for Security Applications.
- Author
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Martin PG, Verbelen Y, Sciama Bandel E, Andrews M, and Scott TB
- Abstract
Threat assessments continue to conclude that terrorist groups and individuals as well as those wanting to cause harm to society have the ambition and increasing means to acquire unconventional weapons such as improvised nuclear explosive devices and radiological disposal devices. Such assessments are given credence by public statements of intent by such groups/persons, by reports of attempts to acquire radioactive material and by law enforcement actions which have interdicted, apprehended or prevented attempts to acquire such material. As a mechanism through which to identify radioactive materials being transported on an individual's person, this work sought to develop a detection system that is of lower-cost, reduced form-factor and more covert than existing infrastructure, while maintaining adequate sensitivity and being retrofittable into an industry standard and widely utilised Gunnebo Speed Gate system. The system developed comprised an array of six off-set Geiger-Muller detectors positioned around the gate, alongside a single scintillator detector for spectroscopy, triggered by the systems inbuilt existing IR proximity sensor. This configuration served to not only reduce the cost for such a system but also allowed for source localisation and identification to be performed. Utilising the current setup, it was possible to detect a 1 µSv/h source carried into the Speed Gate in all test scenarios, alongside locating and spectrally analysing the material in a significant number.
- Published
- 2020
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25. Nanometre to micrometre length-scale techniques for characterising environmentally-assisted cracking: An appraisal.
- Author
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Clark RN, Burrows R, Patel R, Moore S, Hallam KR, and Flewitt PEJ
- Abstract
The appraisal is strongly focussed on challenges associated with the nuclear sector, however these are representative of what is generally encountered by a range of engineering applications. Ensuring structural integrity of key nuclear plant components is essential for both safe and economic operation. Structural integrity assessments require knowledge of the mechanical and physical properties of materials, together with an understanding of mechanisms that can limit the overall operating life. With improved mechanistic understanding comes the ability to develop predictive models of the service life of components. Such models often require parameters which can be provided only by characterisation of processes occurring in situ over a range of scales, with the sub-micrometre-scale being particularly important, but also challenging. This appraisal reviews the techniques currently available to characterise microstructural features at the nanometre to micrometre length-scale that can be used to elucidate mechanisms that lead to the early stages of environmentally-assisted crack formation and subsequent growth. Following an appraisal of the techniques and their application, there is a short discussion and consideration for future opportunities., (© 2020 The Author(s).)
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- 2020
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26. Corrigendum: Radiological Mapping of Post-Disaster Nuclear Environments Using Fixed-Wing Unmanned Aerial Systems: A Study From Chornobyl.
- Author
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Connor DT, Wood K, Martin PG, Goren S, Megson-Smith D, Verbelen Y, Chyzhevskyi I, Kirieiev S, Smith NT, Richardson T, and Scott TB
- Abstract
[This corrects the article DOI: 10.3389/frobt.2019.00149.]., (Copyright © 2020 Connor, Wood, Martin, Goren, Megson-Smith, Verbelen, Chyzhevskyi, Kirieiev, Smith, Richardson and Scott.)
- Published
- 2020
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27. Compositional and structural analysis of Fukushima-derived particulates using high-resolution x-ray imaging and synchrotron characterisation techniques.
- Author
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Martin PG, Jones CP, Cipiccia S, Batey DJ, Hallam KR, Satou Y, Griffiths I, Rau C, Richards DA, Sueki K, Ishii T, and Scott TB
- Subjects
- Dust analysis, Fukushima Nuclear Accident, Japan, Nuclear Power Plants, Radiation Monitoring methods, Radiography methods, Soil Pollutants, Radioactive, Synchrotrons, Water Pollutants, Radioactive analysis, X-Rays, Cesium Radioisotopes chemistry, Radioactive Fallout analysis
- Abstract
Both the three-dimensional internal structure and elemental distribution of near-field radioactive fallout particulate material released during the March 2011 accident at the Fukushima Daiichi Nuclear Power Plant is analysed using combined high-resolution laboratory and synchrotron radiation x-ray techniques. Results from this study allow for the proposition of the likely formation mechanism of the particles, as well as the potential risks associated with their existence in the environment, and the likely implications for future planned reactor decommissioning. A suite of particles is analyzed from a locality 2 km from the north-western perimeter of the site - north of the primary contaminant plume in an area formerly attributed to being contaminated by fallout from reactor Unit 1. The particles are shown to exhibit significant structural similarities; being amorphous with a textured exterior, and containing inclusions of contrasting compositions, as well as an extensive internal void volume - bimodal in its size distribution. A heterogeneous distribution of the various elemental constituents is observed inside a representative particle, which also exhibited a Fukushima-derived radiocesium (134Cs, 135Cs and 137Cs) signature with negligible natural Cs. We consider the structure and composition of the particle to suggest it formed from materials associated with the reactor Unit 1 building explosion, with debris fragments embedded into the particles surface. Such a high void ratio, comparable to geological pumice, suggests such material formed during a rapid depressurisation and is potentially susceptible to fragmentation through attrition.
- Published
- 2020
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28. Radiological Mapping of Post-Disaster Nuclear Environments Using Fixed-Wing Unmanned Aerial Systems: A Study From Chornobyl.
- Author
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Connor DT, Wood K, Martin PG, Goren S, Megson-Smith D, Verbelen Y, Chyzhevskyi I, Kirieiev S, Smith NT, Richardson T, and Scott TB
- Abstract
In the immediate aftermath following a large-scale release of radioactive material into the environment, it is necessary to determine the spatial distribution of radioactivity quickly. At present, this is conducted by utilizing manned aircraft equipped with large-volume radiation detection systems. Whilst these are capable of mapping large areas quickly, they suffer from a low spatial resolution due to the operating altitude of the aircraft. They are also expensive to deploy and their manned nature means that the operators are still at risk of exposure to potentially harmful ionizing radiation. Previous studies have identified the feasibility of utilizing unmanned aerial systems (UASs) in monitoring radiation in post-disaster environments. However, the majority of these systems suffer from a limited range or are too heavy to be easily integrated into regulatory restrictions that exist on the deployment of UASs worldwide. This study presents a new radiation mapping UAS based on a lightweight (8 kg) fixed-wing unmanned aircraft and tests its suitability to mapping post-disaster radiation in the Chornobyl Exclusion Zone (CEZ). The system is capable of continuous flight for more than 1 h and can resolve small scale changes in dose-rate in high resolution (sub-20 m). It is envisaged that with some minor development, these systems could be utilized to map large areas of hazardous land without exposing a single operator to a harmful dose of ionizing radiation., (Copyright © 2020 Connor, Wood, Martin, Goren, Megson-Smith, Verbelen, Chyzhevskyi, Kirieiev, Smith, Richardson and Scott.)
- Published
- 2020
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29. In-situ growth of NiWO 4 saw-blade-like nanostructures and their application in photo-electrochemical (PEC) immunosensor system designed for the detection of neuron-specific enolase.
- Author
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Soomro RA, Kalwar NH, Avci A, Pehlivan E, Hallam KR, and Willander M
- Subjects
- Electrochemical Techniques methods, Electrodes, Humans, Immunoassay methods, Light, Nanostructures ultrastructure, Nanotechnology methods, Phosphopyruvate Hydratase analysis, Tin Compounds chemistry, Biosensing Techniques methods, Nanostructures chemistry, Nickel chemistry, Oxides chemistry, Phosphopyruvate Hydratase blood, Tungsten chemistry
- Abstract
This study describes the construction of highly-sensitive photo-electrochemical (PEC) immunosensor for the detection of neuron-specific enolase (NSE). The biosensing platform is comprised of photo-active NiWO
4 nanostructures, in-situ-grown over a conductive substrate (indium tin oxide) using a low-temperature template-based co-precipitation approach. The discussed approach enables the formation of discrete, yet morphologically-analogous, nanostructures with complete coverage (pinhole-free) of the electrode surface. The in-situ-grown nanostructure possess dense population with sharp saw-blade like morphological features that can support substantial immobilisation of anti-NSE agent. The constructed platform demonstrated excellent photo-catalytic activity towards uric acid (UA) which served as the base for the Electrochemical -mechanism (EC) based PEC inhibition sensing. The detection of NSE, relied on its obstruction in analytical signal observed for the photo-oxidation of UA after binding to the electrode surface via protein-antibody interaction. The constructed PEC immunosensor exhibits signal sensitivity up to 0.12 ng mL-1 of NSE with excellent signal reproducibility and electrode replicability. Moreover, the constructed platform was successfully used for NSE determination in human serum samples., (Copyright © 2019 Elsevier B.V. All rights reserved.)- Published
- 2019
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30. Evaluation of Scintillator Detection Materials for Application within Airborne Environmental Radiation Monitoring.
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Lowdon M, Martin PG, Hubbard MWJ, Taggart MP, Connor DT, Verbelen Y, Sellin PJ, and Scott TB
- Abstract
In response to the Fukushima Daiichi Nuclear Power Plant accident, there has occurred the unabated growth in the number of airborne platforms developed to perform radiation mapping-each utilising various designs of a low-altitude uncrewed aerial vehicle. Alongside the associated advancements in the airborne system transporting the radiation detection payload, from the earliest radiological analyses performed using gas-filled Geiger-Muller tube detectors, modern radiation detection and mapping platforms are now based near-exclusively on solid-state scintillator detectors. With numerous varieties of such light-emitting crystalline materials now in existence, this combined desk and computational modelling study sought to evaluate the best-available detector material compatible with the requirements for low-altitude autonomous radiation detection, localisation and subsequent high spatial-resolution mapping of both naturally occurring and anthropogenically-derived radionuclides. The ideal geometry of such detector materials is also evaluated. While NaI and CsI (both elementally doped) are (and will likely remain) the mainstays of radiation detection, LaBr
3 scintillation detectors were determined to possess not only a greater sensitivity to incident gamma-ray radiation, but also a far superior spectral (energy) resolution over existing and other potentially deployable detector materials. Combined with their current competitive cost, an array of three such composition cylindrical detectors were determined to provide the best means of detecting and discriminating the various incident gamma-rays.- Published
- 2019
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31. Provenance of uranium particulate contained within Fukushima Daiichi Nuclear Power Plant Unit 1 ejecta material.
- Author
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Martin PG, Louvel M, Cipiccia S, Jones CP, Batey DJ, Hallam KR, Yang IAX, Satou Y, Rau C, Mosselmans JFW, Richards DA, and Scott TB
- Abstract
Here we report the results of multiple analytical techniques on sub-mm particulate material derived from Unit 1 of the Fukushima Daiichi Nuclear Power Plant to provide a better understanding of the events that occurred and the environmental legacy. Through combined x-ray fluorescence and absorption contrast micro-focused x-ray tomography, entrapped U particulate are observed to exist around the exterior circumference of the highly porous Si-based particle. Further synchrotron radiation analysis of a number of these entrapped particles shows them to exist as UO
2 -identical to reactor fuel, with confirmation of their nuclear origin shown via mass spectrometry analysis. While unlikely to represent an environmental or health hazard, such assertions would likely change should break-up of the Si-containing bulk particle occur. However, more important to the long-term decommissioning of the reactors at the FDNPP (and environmental clean-upon), is the knowledge that core integrity of reactor Unit 1 was compromised with nuclear material existing outside of the reactors primary containment.- Published
- 2019
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32. Iron-based nanoparticles prepared from yerba mate extract. Synthesis, characterization and use on chromium removal.
- Author
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García FE, Senn AM, Meichtry JM, Scott TB, Pullin H, Leyva AG, Halac EB, Ramos CP, Sacanell J, Mizrahi M, Requejo FG, and Litter MI
- Subjects
- Chromium, Iron, Plant Extracts, Ilex paraguariensis, Nanoparticles, Water Pollutants, Chemical
- Abstract
Iron-based nanoparticles were synthesized by a rapid method at room temperature using yerba mate (YM) extracts with FeCl
3 in different proportions. Materials prepared from green tea (GT) extracts were also synthesized for comparison. These materials were thoroughly characterized by chemical analyses, XRD, magnetization, SEM-EDS, TEM-SAED, FTIR, UV-Vis, Raman, Mössbauer and XANES spectroscopies, and BET area analysis. It was concluded that the products are nonmagnetic iron complexes of the components of the extracts. The applicability of the materials for Cr(VI) (300 μM) removal from aqueous solutions at pH 3 using two Cr(VI):Fe molar ratios (MR), 1:3 and 1:0.5, has been tested. At Cr(VI):Fe MR = 1:3, the best YM materials gave complete Cr(VI) removal after two minutes of contact, similar to that obtained with commercial nanoscale zerovalent iron (N25), with dissolved Fe(II), and with a likewise prepared GT material. At a lower Cr(VI):Fe MR (1:0.5), although Cr(VI) removal was not complete after 20 min of reaction, the YM nanoparticles were more efficient than N25, GT nanoparticles and Fe(II) in solution. The results suggest that an optimal Cr(VI):Fe MR ratio could be reached when using the new YM nanoparticles, able to achieve a complete Cr(VI) reduction, and leaving very low Cr and Fe concentrations in the treated solutions. The rapid preparation of the nanoparticles would allow their use in removal of pollutants in soils and groundwater by direct injection of the mixture of precursors., (Copyright © 2019 Elsevier Ltd. All rights reserved.)- Published
- 2019
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33. Production of phosphorene nanoribbons.
- Author
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Watts MC, Picco L, Russell-Pavier FS, Cullen PL, Miller TS, Bartuś SP, Payton OD, Skipper NT, Tileli V, and Howard CA
- Abstract
Phosphorene is a mono-elemental, two-dimensional (2D) substance with outstanding, highly directional properties and a bandgap that depends on the number of layers of the material
1-8 . Nanoribbons, meanwhile, combine the flexibility and unidirectional properties of one-dimensional nanomaterials, the high surface area of 2D nanomaterials and the electron-confinement and edge effects of both. The structures of nanoribbons can thus lead to exceptional control over electronic band structure, the emergence of novel phenomena and unique architectures for applications5,6,9-24 . Phosphorene's intrinsically anisotropic structure has motivated numerous theoretical calculations of phosphorene nanoribbons (PNRs), predicting extraordinary properties5,6,12-24 . So far, however, discrete PNRs have not been produced. Here we present a method for creating quantities of high-quality, individual PNRs by ionic scissoring of macroscopic black phosphorus crystals. This top-down process results in stable liquid dispersions of PNRs with typical widths of 4-50 nm, predominantly single-layer thickness, measured lengths of up to 75 μm and aspect ratios of up to 1,000. The nanoribbons are atomically flat single crystals, aligned exclusively in the zigzag crystallographic orientation. The ribbons have remarkably uniform widths along their entire lengths, and are extremely flexible. These properties-together with the ease of downstream manipulation via liquid-phase methods-should enable the search for predicted exotic states6,12-14,17-19,21 , and an array of applications in which PNRs have been predicted to offer transformative advantages. These applications range from thermoelectric devices to high-capacity fast-charging batteries and integrated high-speed electronic circuits6,14-16,20,23,24 .- Published
- 2019
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34. Radiological comparison of a FDNPP waste storage site during and after construction.
- Author
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Connor DT, Martin PG, Pullin H, Hallam KR, Payton OD, Yamashiki Y, Smith NT, and Scott TB
- Subjects
- Cesium Radioisotopes analysis, Fukushima Nuclear Accident, Japan, Radiation Monitoring, Hazardous Waste Sites, Radioactive Waste
- Abstract
The clean-up effort that is occurring across the region affected by the 2011 Fukushima Daiichi Nuclear Power Plant accident is unprecedented in its magnitude as well as the financial cost that will eventually result. A major component of this remediation is the stripping of large volumes of material from the land surface, depositing this into large waste storage bags before placing these 1 cubic meter bags into specially constructed stores across Fukushima Prefecture. In this work, using an unmanned aerial vehicle to perform radiological surveys of a site, the time-resolved distribution of contamination during the construction of one of these waste storage sites was assessed. The results indicated that radioactive material was progressively leaching from the store into the surrounding environment. A subsequent survey of the site conducted eight months later revealed that in response to this survey and remedial actions, the contamination issue once existing on this site had been successfully resolved. Such results highlight the potential of low-altitude unmanned aerial systems to easily and rapidly assess site-wide changes over time - providing highly-visual results; therefore, permitting for prompt remedial actions to be undertaken as required. Use of UAV radiation mapping and airborne photogrammetry to produce a time-resolved assessment of remediation efforts within a Fukushima temporary storage facility., (Copyright © 2018 The Authors. Published by Elsevier Ltd.. All rights reserved.)
- Published
- 2018
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35. Spatial pattern of plutonium and radiocaesium contamination released during the Fukushima Daiichi nuclear power plant disaster.
- Author
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Dunne JA, Martin PG, Yamashiki Y, Ang IXY, Scott TB, and Richards DA
- Subjects
- Environmental Monitoring methods, Mass Spectrometry methods, Spatial Analysis, Cesium Radioisotopes analysis, Fukushima Nuclear Accident, Plutonium analysis, Radiation Monitoring methods, Radioactive Fallout analysis
- Abstract
Plutonium and radiocaesium are hazardous contaminants released by the Fukushima Daiichi nuclear power plant (FDNPP) disaster and their distribution in the environment requires careful characterisation using isotopic information. Comprehensive spatial survey of
134 Cs and137 Cs has been conducted on a regular basis since the accident, but the dataset for135 Cs/137 Cs atom ratios and trace isotopic analysis of Pu remains limited because of analytical challenges. We have developed a combined chemical procedure to separate Pu and Cs for isotopic analysis of environmental samples from contaminated catchments. Ultra-trace analyses reveal a FDNPP Pu signature in environmental samples, some from further afield than previously reported. For two samples, we attribute the dominant source of Pu to Reactor Unit 3. We review the mechanisms responsible for an emergent spatial pattern in134,135 Cs/137 Cs in areas northwest (high134 Cs/137 Cs, low135 Cs/137 Cs) and southwest (low134 Cs/137 Cs, high135 Cs/137 Cs) of FDNPP. Several samples exhibit consistent134,135 Cs/137 Cs values that are significantly different from those deposited on plant specimens collected in previous works. A complex spatial pattern of Pu and Cs isotopic signature is apparent. To confidently attribute the sources of mixed fallout material, future studies must focus on analysis of individual FDNPP-derived particles.- Published
- 2018
- Full Text
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36. Tunable Magnetocaloric Effect in Ni-Mn-Ga Microwires.
- Author
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Qian M, Zhang X, Wei L, Martin P, Sun J, Geng L, Scott TB, and Peng HX
- Abstract
Magnetic refrigeration is of great interest due to its high energy efficiency, environmental friendliness and low cost. However, undesired hysteresis losses, concentrated working temperature interval (WTI) and poor mechanical stability are vital drawbacks that hinder its practical application. Off-stoichiometric Ni-Mn-Ga Heusler alloys are capable of giant magnetocaloric effect (MCE) and tunable transformation temperatures. Here, by creating Ni-Mn-Ga microwires with diameter of 35-80 μm using a melt-extraction technique, negligible hysteresis and relatively good mechanical stability are found due to the high specific surface area (SSA) that reduces incompatibility between neighboring grains. The high SSA also favors the element evaporation at high temperatures so that the transformation temperatures can be feasibly adjusted. Tunable magnetocaloric effect owing to different magneto-structural coupling states is realized by (i) composition design and subsequent tuning, which adjusts the temperature difference between the martensite transformation (MT) and the magnetic transition, and (ii) creation of gradient composition distribution state, which manipulates the MT range. Magnetic entropy change ΔS
m ~-18.5 J kg-1 K-1 with relatively concentrated WTI and WTI up to ~60 K with net refrigeration capacity ~240 J kg-1 at 50 kOe are demonstrated in the present Ni-Mn-Ga microwires. This criterion is also applicable for other small-sized materials.- Published
- 2018
- Full Text
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37. Algal Viruses: The (Atomic) Shape of Things to Come.
- Author
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Evans CT, Payton O, Picco L, and Allen MJ
- Subjects
- Imaging, Three-Dimensional, Phycodnaviridae physiology, Plant Diseases virology, Microscopy, Atomic Force, Microscopy, Electron, Phycodnaviridae ultrastructure
- Abstract
Visualization of algal viruses has been paramount to their study and understanding. The direct observation of the morphological dynamics of infection is a highly desired capability and the focus of instrument development across a variety of microscopy technologies. However, the high temporal (ms) and spatial resolution (nm) required, combined with the need to operate in physiologically relevant conditions presents a significant challenge. Here we present a short history of virus structure study and its relation to algal viruses and highlight current work, concentrating on electron microscopy and atomic force microscopy, towards the direct observation of individual algae⁻virus interactions. Finally, we make predictions towards future algal virus study direction with particular focus on the exciting opportunities offered by modern high-speed atomic force microscopy methods and instrumentation.
- Published
- 2018
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38. In-situ, time resolved monitoring of uranium in BFS:OPC grout. Part 2: Corrosion in water.
- Author
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Stitt CA, Paraskevoulakos C, Banos A, Harker NJ, Hallam KR, Pullin H, Davenport A, Street S, and Scott TB
- Abstract
To reflect potential conditions in a geological disposal facility, uranium was encapsulated in grout and submersed in de-ionised water for time periods between 2-47 weeks. Synchrotron X-ray Powder Diffraction and X-ray Tomography were used to identify the dominant corrosion products and measure their dimensions. Uranium dioxide was observed as the dominant corrosion product and time dependent thickness measurements were used to calculate oxidation rates. The effectiveness of physical and chemical grout properties to uranium corrosion and mobilisation is discussed and Inductively Coupled Plasma Mass Spectrometry was used to measure
238 U(aq) content in the residual water of several samples.- Published
- 2018
- Full Text
- View/download PDF
39. A high-strength silicide phase in a stainless steel alloy designed for wear-resistant applications.
- Author
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Bowden D, Krysiak Y, Palatinus L, Tsivoulas D, Plana-Ruiz S, Sarakinou E, Kolb U, Stewart D, and Preuss M
- Abstract
Hardfacing alloys provide strong, wear-resistant and corrosion-resistant coatings for extreme environments such as those within nuclear reactors. Here, we report an ultra-high-strength Fe-Cr-Ni silicide phase, named π-ferrosilicide, within a hardfacing Fe-based alloy. Electron diffraction tomography has allowed the determination of the atomic structure of this phase. Nanohardness testing indicates that the π-ferrosilicide phase is up to 2.5 times harder than the surrounding austenite and ferrite phases. The compressive strength of the π-ferrosilicide phase is exceptionally high and does not yield despite loading in excess of 1.6 GPa. Such a high-strength silicide phase could not only provide a new type of strong, wear-resistant and corrosion-resistant Fe-based coating, replacing more costly and hazardous Co-based alloys for nuclear applications, but also lead to the development of a new class of high-performance silicide-strengthened stainless steels, no longer reliant on carbon for strengthening.
- Published
- 2018
- Full Text
- View/download PDF
40. The Impact of Alkaliphilic Biofilm Formation on the Release and Retention of Carbon Isotopes from Nuclear Reactor Graphite.
- Author
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Rout SP, Payne L, Walker S, Scott T, Heard P, Eccles H, Bond G, Shah P, Bills P, Jackson BR, Boxall SA, Laws AP, Charles C, Williams SJ, and Humphreys PN
- Abstract
14 C is an important consideration within safety assessments for proposed geological disposal facilities for radioactive wastes, since it is capable of re-entering the biosphere through the generation of14 C bearing gases. The irradiation of graphite moderators in the UK gas-cooled nuclear power stations has led to the generation of a significant volume of14 C-containing intermediate level wastes. Some of this14 C is present as a carbonaceous deposit on channel wall surfaces. Within this study, the potential of biofilm growth upon irradiated and13 C doped graphite at alkaline pH was investigated. Complex biofilms were established on both active and simulant samples. High throughput sequencing showed the biofilms to be dominated by Alcaligenes sp at pH 9.5 and Dietzia sp at pH 11.0. Surface characterisation revealed that the biofilms were limited to growth upon the graphite surface with no penetration of the deeper porosity. Biofilm formation resulted in the generation of a low porosity surface layer without the removal or modification of the surface deposits or the release of the associated14 C/13 C. Our results indicated that biofilm formation upon irradiated graphite is likely to occur at the pH values studied, without any additional release of the associated14 C.- Published
- 2018
- Full Text
- View/download PDF
41. Source identification of uranium-containing materials at mine legacy sites in Portugal.
- Author
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Keatley AC, Martin PG, Hallam KR, Payton OD, Awbery R, Carvalho FP, Oliveira JM, Silva L, Malta M, and Scott TB
- Subjects
- Mining, Portugal, Radiation Monitoring methods, Soil Pollutants, Radioactive analysis, Uranium analysis
- Abstract
Whilst prior nuclear forensic studies have focused on identifying signatures to distinguish between different uranium deposit types, this paper focuses on providing a scientific basis for source identification of materials from different uranium mine sites within a single region, which can then be potentially used within nuclear forensics. A number of different tools, including gamma spectrometry, alpha spectrometry, mineralogy and major and minor elemental analysis, have been utilised to determine the provenance of uranium mineral samples collected at eight mine sites, located within three different uranium provinces, in Portugal. A radiation survey was initially conducted by foot and/or unmanned aerial vehicle at each site to assist sample collection. The results from each mine site were then compared to determine if individual mine sites could be distinguished based on characteristic elemental and isotopic signatures. Gamma and alpha spectrometry were used to differentiate between samples from different sites and also give an indication of past milling and mining activities. Ore samples from the different mine sites were found to be very similar in terms of gangue and uranium mineralogy. However, rarer minerals or specific impurity elements, such as calcium and copper, did permit some separation of the sites examined. In addition, classification rates using linear discriminant analysis were comparable to those in the literature., (Crown Copyright © 2018. Published by Elsevier Ltd. All rights reserved.)
- Published
- 2018
- Full Text
- View/download PDF
42. Application of airborne photogrammetry for the visualisation and assessment of contamination migration arising from a Fukushima waste storage facility.
- Author
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Connor DT, Martin PG, Smith NT, Payne L, Hutson C, Payton OD, Yamashiki Y, and Scott TB
- Subjects
- Radioactive Waste, Remote Sensing Technology, Fukushima Nuclear Accident, Photogrammetry, Radiation Monitoring methods
- Abstract
Airborne systems such as lightweight and highly portable unmanned aerial vehicles (UAVs) are becoming increasingly widespread in both academia and industry - with an ever-increasing range of applications, including (but not limited to), air quality sampling, wildlife monitoring and land-use mapping. In this work, high-resolution airborne photogrammetry obtained using a multi-rotor system operating at low survey altitudes, is combined with ground-based radiation mapping data acquired at an interim storage facility for wastes removed as part of the large-scale Fukushima clean-up program. The investigation aimed to assess the extent to which the remediation program at a specific site has contained the stored contaminants, as well as present a new methodology for rapidly surveying radiological sites globally. From the three-dimensional rendering of the site of interest, it was possible to not only generate a powerful graphic confirming the elevated radiological intensity existing at the location of the waste bags, but also to also illustrate the downslope movement of contamination due to species leakage from the large 1m
3 storage bags. The entire survey took less than 1 h to perform, and was subsequently post-processed using graphical information software to obtain the renderings. The conclusions within this study not only highlight the usefulness of incorporating three-dimensional renderings within radiation mapping protocols, but also conclude that current methods of monitoring these storage facilities in the long term could be improved through the integration of UAVs within the standard protocol., (Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.)- Published
- 2018
- Full Text
- View/download PDF
43. DNA nanomapping using CRISPR-Cas9 as a programmable nanoparticle.
- Author
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Mikheikin A, Olsen A, Leslie K, Russell-Pavier F, Yacoot A, Picco L, Payton O, Toor A, Chesney A, Gimzewski JK, Mishra B, and Reed J
- Subjects
- High-Throughput Nucleotide Sequencing, Humans, Image Processing, Computer-Assisted methods, Immunoglobulin Heavy Chains genetics, Lymphoma, Follicular genetics, Microscopy, Atomic Force methods, Nanotechnology methods, Proto-Oncogene Proteins c-bcl-2 genetics, Translocation, Genetic, CRISPR-Cas Systems, Chromosome Mapping methods, DNA genetics, Genomics methods, Nanoparticles
- Abstract
Progress in whole-genome sequencing using short-read (e.g., <150 bp), next-generation sequencing technologies has reinvigorated interest in high-resolution physical mapping to fill technical gaps that are not well addressed by sequencing. Here, we report two technical advances in DNA nanotechnology and single-molecule genomics: (1) we describe a labeling technique (CRISPR-Cas9 nanoparticles) for high-speed AFM-based physical mapping of DNA and (2) the first successful demonstration of using DVD optics to image DNA molecules with high-speed AFM. As a proof of principle, we used this new "nanomapping" method to detect and map precisely BCL2-IGH translocations present in lymph node biopsies of follicular lymphoma patents. This HS-AFM "nanomapping" technique can be complementary to both sequencing and other physical mapping approaches.
- Published
- 2017
- Full Text
- View/download PDF
44. In-situ, time resolved monitoring of uranium in BFS:OPC grout. Part 1: Corrosion in water vapour.
- Author
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Stitt CA, Paraskevoulakos C, Banos A, Harker NJ, Hallam KR, Davenport A, Street S, and Scott TB
- Abstract
Uranium encapsulated in grout was exposed to water vapour for extended periods of time. Through synchrotron x-ray powder diffraction and tomography measurements, uranium dioxide was determined the dominant corrosion product over a 50-week time period. The oxide growth rate initiated rapidly, with rates comparable to the U + H
2 O reaction. Over time, the reaction rate decreased and eventually plateaued to a rate similar to the U + H2 O + O2 reaction. This behaviour was not attributed to oxygen ingress, but instead the decreasing permeability of the grout, limiting oxidising species access to the metal surface.- Published
- 2017
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- View/download PDF
45. High-resolution radiation mapping to investigate FDNPP derived contaminant migration.
- Author
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Martin PG, Payton OD, Yamashiki Y, Richards DA, and Scott TB
- Subjects
- Japan, Pacific Ocean, Radioactive Fallout, Spectrometry, Gamma, Cesium Radioisotopes analysis, Fukushima Nuclear Accident, Radiation Monitoring, Soil Pollutants, Radioactive analysis
- Abstract
As of March 2016, five years will have passed since the earthquake and ensuing tsunami that crippled the Fukushima Daiichi Nuclear Power Plant on Japan's eastern coast, resulting in the explosive release of significant quantities of radioactive material. Over this period, significant time and resource has been expended on both the study of the contamination as well as its remediation from the affected environments. Presented in this work is a high-spatial resolution foot-based radiation mapping study using gamma-spectrometry at a site in the contaminated Iitate Village; conducted at different times, seventeen months apart. The specific site selected for this work was one in which consistent uniform agriculture was observed across its entire extent. From these surveys, obtained from along the main northwest trending line of the fallout plume, it was possible to determine the rate of reduction in the levels of contamination around the site attributable to the natural decay of the radiocesium, remediation efforts or material transport. Results from the work suggest that neither the natural decay of radiocesium nor its downward migration through the soil horizons were responsible for the decline in measured activity levels across the site, with the mobilisation of contaminant species likely adhered to soil particulate and the subsequent fluvial transport responsible for the measurable reduction in activity. This transport of contaminant via fluvial methods has already well studied implications for the input of contaminant material entering the neighbouring Pacific Ocean, as well as the deposition of material along rivers within previously decontaminated areas., (Copyright © 2016 The Author(s). Published by Elsevier Ltd.. All rights reserved.)
- Published
- 2016
- Full Text
- View/download PDF
46. Examination of Surface Deposits on Oldbury Reactor Core Graphite to Determine the Concentration and Distribution of 14C.
- Author
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Payne L, Heard PJ, and Scott TB
- Subjects
- Nuclear Reactors, Power Plants, Carbon Radioisotopes analysis, Graphite chemistry
- Abstract
Pile Grade A graphite was used as a moderator and reflector material in the first generation of UK Magnox nuclear power reactors. As all of these reactors are now shut down there is a need to examine the concentration and distribution of long lived radioisotopes, such as 14C, to aid in understanding their behaviour in a geological disposal facility. A selection of irradiated graphite samples from Oldbury reactor one were examined where it was observed that Raman spectroscopy can distinguish between underlying graphite and a surface deposit found on exposed channel wall surfaces. The concentration of 14C in this deposit was examined by sequentially oxidising the graphite samples in air at low temperatures (450°C and 600°C) to remove the deposit and then the underlying graphite. The gases produced were captured in a series of bubbler solutions that were analysed using liquid scintillation counting. It was observed that the surface deposit was relatively enriched with 14C, with samples originating lower in the reactor exhibiting a higher concentration of 14C. Oxidation at 600°C showed that the remaining graphite material consisted of two fractions of 14C, a surface associated fraction and a graphite lattice associated fraction. The results presented correlate well with previous studies on irradiated graphite that suggest there are up to three fractions of 14C; a readily releasable fraction (corresponding to that removed by oxidation at 450°C in this study), a slowly releasable fraction (removed early at 600°C in this study), and an unreleasable fraction (removed later at 600°C in this study)., Competing Interests: We have the following interests: This work was funded by the Engineering and Physical Sciences Research Council (EPSRC) and Radioactive Waste Management (RWM) under the contract GeoWaste (EP/I036354/1). There are no patents, products in development or marketed products to declare. This does not alter our adherence to all the PLOS ONE policies on sharing data and materials, as detailed online in the guide for authors.
- Published
- 2016
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47. Miniature standoff Raman probe for neurosurgical applications.
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Stevens OA, Hutchings J, Gray W, Vincent RL, and Day JC
- Subjects
- Animals, Biopsy, Humans, Optical Fibers, Swine, Brain Neoplasms diagnostic imaging, Equipment Design, Neurosurgery instrumentation, Spectrum Analysis, Raman
- Abstract
Removal of intrinsic brain tumors is a delicate process, where a high degree of specificity is required to remove all of the tumor tissue without damaging healthy brain. The accuracy of this process can be greatly enhanced by intraoperative guidance. Optical biopsies using Raman spectroscopy are a minimally invasive and lower-cost alternative to current guidance methods. A miniature Raman probe for performing optical biopsies of human brain tissue is presented. The probe allows sampling inside a conventional stereotactic brain biopsy system: a needle of length 200 mm and inner diameter of 1.8 mm. By employing a miniature stand-off Raman design, the probe removes the need for any additional components to be inserted into the brain. Additionally, the probe achieves a very low internal silica background while maintaining good collection of Raman signal. To illustrate this, the probe is compared with a Raman probe that uses a pair of optical fibers for collection. The miniature stand-off Raman probe is shown to collect a comparable number of Raman scattered photons, but the Raman signal to background ratio is improved by a factor of five at Raman shifts below ∼500 cm(−1). The probe’s suitability for use on tissue is demonstrated by discriminating between different types of healthy porcine brain tissue.
- Published
- 2016
- Full Text
- View/download PDF
48. Atomic-scale Studies of Uranium Oxidation and Corrosion by Water Vapour.
- Author
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Martin TL, Coe C, Bagot PA, Morrall P, Smith GD, Scott T, and Moody MP
- Abstract
Understanding the corrosion of uranium is important for its safe, long-term storage. Uranium metal corrodes rapidly in air, but the exact mechanism remains subject to debate. Atom Probe Tomography was used to investigate the surface microstructure of metallic depleted uranium specimens following polishing and exposure to moist air. A complex, corrugated metal-oxide interface was observed, with approximately 60 at.% oxygen content within the oxide. Interestingly, a very thin (~5 nm) interfacial layer of uranium hydride was observed at the oxide-metal interface. Exposure to deuterated water vapour produced an equivalent deuteride signal at the metal-oxide interface, confirming the hydride as originating via the water vapour oxidation mechanism. Hydroxide ions were detected uniformly throughout the oxide, yet showed reduced prominence at the metal interface. These results support a proposed mechanism for the oxidation of uranium in water vapour environments where the transport of hydroxyl species and the formation of hydride are key to understanding the observed behaviour.
- Published
- 2016
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- View/download PDF
49. Tactic response of bacteria to zero-valent iron nanoparticles.
- Author
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Ortega-Calvo JJ, Jimenez-Sanchez C, Pratarolo P, Pullin H, Scott TB, and Thompson IP
- Subjects
- Soil chemistry, Soil Microbiology, Iron toxicity, Metal Nanoparticles toxicity, Pseudomonas putida drug effects, Pseudomonas putida physiology
- Abstract
The microbial assessment of pollutant toxicity rarely includes behavioral responses. In this study, we investigated the tactic response of Pseudomonas putida G7, a representative of soil bacterium, towards engineered zero-valent iron nanoparticles (nZVIs), as a new end-point assessment of toxicity. The study integrated the characterization of size distribution and charge of nZVIs and tactic reaction response by means of inverted capillary assay and computer-assisted motion analysis of motility behavior. Iron nanoparticles (diameter ≤ 100 nm) were prepared in the absence of oxygen to prevent aggregation, and then exposed in aerobic conditions. We first demonstrate that iron nanoparticles can elicit a negative tactic response in bacteria at low but environmentally-relevant, sub-lethal concentrations (1-10 μg/L). Cells were repelled by nZVIs in the concentration gradients created inside the capillaries, and a significant increase in turning events, characteristic of negative taxis, was detected under exposure to nZVIs. These tactic responses were not detectable after sustained exposure of the nanoparticles to oxygen. This new behavioral assessment may be prospected for the design of sensitive bioassays for nanomaterial toxicity., (Copyright © 2016 Elsevier Ltd. All rights reserved.)
- Published
- 2016
- Full Text
- View/download PDF
50. The eyes of Tullimonstrum reveal a vertebrate affinity.
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Clements T, Dolocan A, Martin P, Purnell MA, Vinther J, and Gabbott SE
- Subjects
- Animals, Illinois, Melanosomes ultrastructure, Microscopy, Electron, Scanning, Retinal Pigment Epithelium chemistry, Retinal Pigment Epithelium ultrastructure, Vertebrates anatomy & histology, Eye chemistry, Eye cytology, Eye ultrastructure, Fossils, Phylogeny, Vertebrates classification
- Abstract
Tullimonstrum gregarium is an iconic soft-bodied fossil from the Carboniferous Mazon Creek Lagerstätte (Illinois, USA). Despite a large number of specimens and distinct anatomy, various analyses over the past five decades have failed to determine the phylogenetic affinities of the 'Tully monster', and although it has been allied to such disparate phyla as the Mollusca, Annelida or Chordata, it remains enigmatic. The nature and phylogenetic affinities of Tullimonstrum have defied confident systematic placement because none of its preserved anatomy provides unequivocal evidence of homology, without which comparative analysis fails. Here we show that the eyes of Tullimonstrum possess ultrastructural details indicating homology with vertebrate eyes. Anatomical analysis using scanning electron microscopy reveals that the eyes of Tullimonstrum preserve a retina defined by a thick sheet comprising distinct layers of spheroidal and cylindrical melanosomes. Time-of-flight secondary ion mass spectrometry and multivariate statistics provide further evidence that these microbodies are melanosomes. A range of animals have melanin in their eyes, but the possession of melanosomes of two distinct morphologies arranged in layers, forming retinal pigment epithelium, is a synapomorphy of vertebrates. Our analysis indicates that in addition to evidence of colour patterning, ecology and thermoregulation, fossil melanosomes can also carry a phylogenetic signal. Identification in Tullimonstrum of spheroidal and cylindrical melanosomes forming the remains of retinal pigment epithelium indicates that it is a vertebrate; considering its body parts in this new light suggests it was an anatomically unusual member of total group Vertebrata.
- Published
- 2016
- Full Text
- View/download PDF
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