Search

An ultra violet (UV)-cured glassy material with less than 30 wt% organic residues was fabricated by the fast sol-gel method. The material presents high thermal stability, good optical quality and high adhesive strength. It is suitable for optical bonding and for manufacture of optical elements and micro-structured optical devices. Either soft-lithography or photo-lithography may be used for manufacture of the devices with either, thermal-curing (few hours) or UV-curing (few seconds). In this work we present the technology to fabricate optical elements at scales spanning the sub-micron to centimeter range. This technology enables mass-production of optical elements at low cost.

We investigate here the properties of fast sol-gel for optical bonding. The precursors of the fast sol-gel material are organically modified alkoxides generating a transparent hybrid (organic-inorganic) substance with silica glass-like properties whose index of refraction can be modified by the addition of various metal-oxides. The fast sol-gel method consists of rapid fabrication of a viscous resin and its subsequent dilution for long shelf life use. This material, when used as an adhesive offers the option of either a thermal or UV curing procedure. We demonstrate a bonding strength of ∼ 10 MPa when a 15 µm layer is applied between two glass elements. The bonding remained stable after an extensive −40°C – 120°C temperature cycling with minimal residual solvent evaporation at 150°C. The fast sol-gel material was tested for optical bonding between silica bulks, between silica bulk and silicon wafers and as an adhesive in silica fibre couplers.

Three-dimensional direct laser writing based on a two-photon polymerization process of hybrid organic-inorganic material was used to print micrometer-scale refractive phase elements that were designed to manipulate incoming Gaussian beams into line and square intensity-flattened profiles. Here we present new results of shaping light beams, enabled by tailoring a two-photon absorption process for printing hybrid material structures based on a fast solgel process. The optical design and calculations of the optical elements are described, along with characterization of their performance in manipulating incoming light beams. The novelty described in this work, to the best of our knowledge, is the implementation of 3D solgel materials as better and improved micro-optics. This new ability provides upgraded 3D high resolution and smooth, printed optical phase structures using tailored hybrids with improved optical and mechanical properties compared to standard common photoresists. This opens new and exciting opportunities for compact and robust beam shaping by reaching glassy material properties and overcoming limitations of organic polymers.

We report on the successful fine-tuning of silica aerogel hydrophobicity, through a gas-phase surface modification process. Aerogel hydrophobicity is a widely discussed matter, as it contributes to the aerogel's preservation and determines its functionality. Still, a general procedure for tuning the hydrophobicity, without affecting other aerogel properties was missing. In the developed procedure, silica aerogel was modified with trimethylchlorosilane vapor for varying durations, resulting in gradual hydrophobicity, determined by solid-state NMR and contact angle measurements. The generality of this post-synthesis treatment allows its application on a variety of aerogel materials, while having minimum effect on their porosity and transparency. We demonstrate the applicability of the gradual hydrophobization by tuning drug release rates from the silica aerogel. Two chlorhexidine salts - widely employed as antiseptic agents - were used as model drugs, one representing a soluble drug, and the other an insoluble drug; they were entrapped in silica aerogel, following hydrophobization to varying degrees. The drug release patterns showed that depending on the degree, hydrophobization can increase or decrease release kinetics, compared to the unmodified aerogel. This arises from the effect of the hydrophobic degree on pore structure, diffusional rates and wetting of the aerogel carrier. We suggest the use of the gradual hydrophobization process for other drug-aerogel systems, as well as for other aerogel applications, such as transparent insulation panels, contaminate sorbents or catalysis supports., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

A method for the realization of low-loss integrated optical components is proposed and demonstrated. This approach is simple, fast, inexpensive, scalable for mass production, and compatible with both 2D and 3D geometries. The process is based on a novel dual-step soft nano imprint lithography process for producing devices with smooth surfaces, combined with fast sol-gel technology providing highly transparent materials. As a concrete example, this approach is demonstrated on a micro ring resonator made by direct laser writing (DLW) to achieve a quality factor improvement from one hundred thousand to more than 3 million. To the best of our knowledge this also sets a Q-factor record for UV-curable integrated micro-ring resonators. The process supports the integration of many types of materials such as light-emitting, electro-optic, piezo-electric, and can be readily applied to a wide variety of devices such as waveguides, lenses, diffractive elements and more.

Conversion of a Gaussian beam into a top-hat beam or to an annular beam is demonstrated using 3D direct laser printing. Micron-scale refractive phase elements were designed and printed directly on standard commercially available lenses. These structures modify the phase of the incoming beam into either three intensity-flattened profiles, having line, square, or circular shapes, or to an annular beam profile. This method to functionalize lenses opens new and exciting opportunities for compact and robust beam shaping, as well as for reduction of the aberrations of the lens itself.

We demonstrate the realization of 3D whispering-gallery-mode (WGM) microlasers by direct laser writing (DLW) and their replication by nanoimprint lithography using a soft mold technique ("soft NIL"). The combination of DLW as a method for rapid prototyping and soft NIL offers a fast track towards large scale fabrication of 3D passive and active optical components applicable to a wide variety of materials. A performance analysis shows that surface-scattering-limited Q-factors of replicated resonators as high as 1×10 5 at 635 nm can be achieved with this process combination. Lasing in the replicated WGM resonators is demonstrated by the incorporation of laser dyes in the target material. Low lasing thresholds in the order of 15  kW/cm 2 are obtained under ns-pulsed excitation.

We report a comparison between two commercially available methods for printing phase shaping optical microstructures. Phase elements that convert a zero-order Hermite-Gaussian (HG 00 ) mode into higher-order modes (HG 10 , HG 01 , HG 20 , and HG 02 ) were fabricated by 3D-direct laser writing (3D-DLW) and nanoimprint lithography (NIL). The structures in each method were characterized and the corresponding beam qualities were analyzed. The direct comparison of equivalent optical devices enables us to reveal the limitations and advantages of the two fabrication methods in order to optimize the fabrication of useful optical microstructure devices. 3D-DLW enables sharper edges and a straightforward lithography process, while NIL enables fabrication of thinner elements, and allows using a larger variety of optical materials including sol-gel glasses, which possess better surface optical quality.