10 results on '"Elhachmia Ech-chihbi"'
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2. Impact of Water Stress and Temperature on Metabolites and Essential Oil of Rosmarinus officinalis (Phytochemical Screening, Extraction, and Gas Chromatography)
- Author
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Abdelouahid Laftouhi, Noureddine Eloutassi, Soufiane Drioua, Elhachmia Ech-Chihbi, Zakia Rais, Abdelfattah Abdellaoui, Abdslam Taleb, Mustapha Beniken, and Mustapha Taleb
- Subjects
climate change ,secondary metabolites ,rosmarinus officinalis ,essential oil yield ,primary metabolites ,Environmental technology. Sanitary engineering ,TD1-1066 ,Environmental sciences ,GE1-350 - Abstract
Currently, climate change is disrupting life on Earth by causing imbalances in the biosphere. This work aimed to evaluate the impact of climate change on the content of primary and secondary metabolites and the yield of essential oil of Rosmarinus officinalis. Thus, the results of the conducted experiment show that the content of primary metabolites decreased with increasing temperature and decreasing precipitation along the experiment (proteins from 7.61% to 7.14%, carbohydrates from 6.92% to 5.64%, fats from 1.48% to 1.29% and dietary fiber from 4.96% to 4.22% and mineral composition: Ca from 7.67% to 5.98%, Mg from 8.61% to 7.01%, Fe from 7.53% to 7.21% and Mn from 6.85% to 3.97%), and the content of secondary metabolites increased in the second year when increasing the temperature by 5C° and water stress by 50% (coumarin from 6.59% to 10.99%, saponins from 7.15% to 8.46%, tannin from 3.92% to 5.95%, alkaloids from 6.69% to 15.62% and flavonoid from 8.02% to 15.75%), but in the fourth year when the temperature continued to increase and water stress was 75% the content of secondary metabolites decreased (coumarin from 10.99% to 8.27%, saponins from 8.46% to 7.87%, tannin from 5.95% to 4.85%, alkaloids from 15.62% to 10.68% and flavonoid from 15.75% to 11.36%) and the same results were obtained for the yield of essential oil which increased in the second year and decreased in the fourth year. This GC analysis of the three essential oil samples shows that the majority of compounds in the three essential oils studied are cineole (S1:45.98%, S2:55.36%, S3:43.08%) followed by camphor (S1:17.44%, S2:21.44%, S3:21.56%) and Alpha-pinene (S1:9.30%, S2:8.34%, S3: 9.17%) and other compounds in low percentage.
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- 2023
- Full Text
- View/download PDF
3. Synthesis, Characterization, Antibacterial, Antifungal and Anticorrosion Activities of 1,2,4-Triazolo[1,5-a]quinazolinone
- Author
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Walid Ettahiri, Rajae Salim, Mohamed Adardour, Elhachmia Ech-chihbi, Ismaeel Yunusa, Mohammed M. Alanazi, Sanae Lahmidi, Azeddin El Barnossi, Oussama Merzouki, Abdelilah Iraqi Housseini, Zakia Rais, Abdesselam Baouid, and Mustapha Taleb
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Triazolo[1,5-a]quinazolinone ,biological activity ,molecular docking ,corrosion inhibition ,adsorption ,Organic chemistry ,QD241-441 - Abstract
The synthesis of 5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b]quinazolin-9(4H)-one (THTQ), a potentially biologically active compound, was pursued, and its structure was determined through a sequence of spectral analysis, including 1H-NMR, 13C-NMR, IR, and HRMS. Four bacterial and four fungal strains were evaluated for their susceptibility to the antibacterial and antifungal properties of the THTQ compound using the well diffusion method. The impact of THTQ on the corrosion of mild steel in a 1 M HCl solution was evaluated using various methods such as weight loss, potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM) analysis. The study revealed that the effectiveness of THTQ as an inhibitor increased with the concentration but decreased with temperature. The PDP analysis suggested that THTQ acted as a mixed-type inhibitor, whereas the EIS data showed that it created a protective layer on the steel surface. This protective layer occurs due to the adsorption behavior of THTQ following Langmuir’s adsorption isotherm. The inhibition potential of THTQ is also predicted theoretically using DFT at B3LYP and Monte Carlo simulation.
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- 2023
- Full Text
- View/download PDF
4. Anticorrosive Effects of Essential Oils Obtained from White Wormwood and Arâr Plants
- Author
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Ghada Beniaich, Mustapha Beniken, Rajae Salim, Nadia Arrousse, Elhachmia Ech-chihbi, Zakia Rais, Asmae Sadiq, Hiba-Allah Nafidi, Yousef A. Bin Jardan, Mohammed Bourhia, and Mustapha Taleb
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aromatic plants ,Artemisia herba-alba ,Juniperus phoenicea ,essential oil ,anticorrosive activity ,potentiodynamic polarization ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
This article is part of the contribution to the development of two medicinal plants widely used by the Moroccan population: white wormwood (Artemisia herba-alba) andArâr (Juniperus phoenicea), species belonging to the Asteraceae and Cupressaceae families, respectively. The present work was conducted to investigate the chemical composition and anticorrosive properties of essential oils (EOs) extracted from these plants. The chemical analysis of the essential oils (EOs) was carried out by GC-MS/MS. Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and quantum chemical calculations by density-functional theory at B3lYP were used to study the anticorrosive effect of the researched oils on mild steel in 1 M hydrochloric acid solution. Moreover, SEM-EDX analysis was used to identify the surface morphology of mild steel surface. GC-MSMS results showed the presence of 32 potentially active compounds in the EOs of Artemisia herba-alba. The average yield of the EOs was about 1.39 ± 0.17 mL/100 g dry matter. Beta thujone (30.07%) and alpha thujone (13.32%) are the main components, while for the EOs of Juniperus phoenicea, the study showed the presence of 30 constituents, with alpha-pinene (43.61%) and manoyl oxide (11.5%) as the main components. The average yield of HE was 1.10 ± 0.03 mL/100 g dry matter. The findings demonstrated an important anticorrosive action of EOs from Artemisia herba-alba and Juniperus phoenicea. Notably, the experimental results showed good efficiency of the studied essential oils and correlated well with the density-functional theory (DFT) calculations. The results of potentiodynamic polarization measurements showed that hydrazone acted as a mixed-type inhibitor. The EIS results showed an increase in charge transfer resistance accompanied by a noticeable decrease in Cdl values, revealing that both studied oils were effective as reliable inhibitors for the protection of mild steel in 1 M HCl solution. Also, the efficiency decreased with decreasing inhibitor concentrations. Surface studies ensure the effectiveness of both investigated oils and the reduction of the surface roughness of mild steel. Furthermore, DFT results of the major constituents of Artemisia herba-alba and Juniperus phoenicea EOs revealed insights into the chemical reactivity of the tested oils while supporting the experimental conclusions and showed outstanding adsorption ability of both investigated EOs on the steel surface.
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- 2023
- Full Text
- View/download PDF
5. Anticorrosive Effects of Essential Oils Obtained from White Wormwood and Arâr Plants
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Taleb, Ghada Beniaich, Mustapha Beniken, Rajae Salim, Nadia Arrousse, Elhachmia Ech-chihbi, Zakia Rais, Asmae Sadiq, Hiba-Allah Nafidi, Yousef A. Bin Jardan, Mohammed Bourhia, and Mustapha
- Subjects
aromatic plants ,Artemisia herba-alba ,Juniperus phoenicea ,essential oil ,anticorrosive activity ,potentiodynamic polarization ,impedance spectroscopy - Abstract
This article is part of the contribution to the development of two medicinal plants widely used by the Moroccan population: white wormwood (Artemisia herba-alba) andArâr (Juniperus phoenicea), species belonging to the Asteraceae and Cupressaceae families, respectively. The present work was conducted to investigate the chemical composition and anticorrosive properties of essential oils (EOs) extracted from these plants. The chemical analysis of the essential oils (EOs) was carried out by GC-MS/MS. Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and quantum chemical calculations by density-functional theory at B3lYP were used to study the anticorrosive effect of the researched oils on mild steel in 1 M hydrochloric acid solution. Moreover, SEM-EDX analysis was used to identify the surface morphology of mild steel surface. GC-MSMS results showed the presence of 32 potentially active compounds in the EOs of Artemisia herba-alba. The average yield of the EOs was about 1.39 ± 0.17 mL/100 g dry matter. Beta thujone (30.07%) and alpha thujone (13.32%) are the main components, while for the EOs of Juniperus phoenicea, the study showed the presence of 30 constituents, with alpha-pinene (43.61%) and manoyl oxide (11.5%) as the main components. The average yield of HE was 1.10 ± 0.03 mL/100 g dry matter. The findings demonstrated an important anticorrosive action of EOs from Artemisia herba-alba and Juniperus phoenicea. Notably, the experimental results showed good efficiency of the studied essential oils and correlated well with the density-functional theory (DFT) calculations. The results of potentiodynamic polarization measurements showed that hydrazone acted as a mixed-type inhibitor. The EIS results showed an increase in charge transfer resistance accompanied by a noticeable decrease in Cdl values, revealing that both studied oils were effective as reliable inhibitors for the protection of mild steel in 1 M HCl solution. Also, the efficiency decreased with decreasing inhibitor concentrations. Surface studies ensure the effectiveness of both investigated oils and the reduction of the surface roughness of mild steel. Furthermore, DFT results of the major constituents of Artemisia herba-alba and Juniperus phoenicea EOs revealed insights into the chemical reactivity of the tested oils while supporting the experimental conclusions and showed outstanding adsorption ability of both investigated EOs on the steel surface.
- Published
- 2023
- Full Text
- View/download PDF
6. Taxus baccata (L.) leaves extract as eco-friendly corrosion inhibitor for mild steel in 1 M HCl: GC/MS, electrochemical, SEM/EDX analysis and DFT studies
- Author
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Ouassima Riffi, Elhachmia Ech-chihbi, Rajae Salim, Mustapha Taleb, Jamila Fliou, and Ali Amechrouq
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This study aims at the valorization of Taxus baccata (L.) in corrosion inhibition. The effect of the extract on corrosion inhibition of mild steel in 1.0 M HCl solution by weight loss measurements, potentiodynamic polarization (PP) and electrochemical impedance spectroscopy (EIS) showed that Taxus baccata (L.) leaves extract is a good corrosion inhibitor with an inhibition efficiency of 98%, 96% and 95% at the concentration of 1.0 g/L respectively. Polarisation curves indicated that the extract acted as a mixed type inhibitor. The adsorption on the mild steel surface obeyed the Langmuir isotherm. The activation energy values ∆G0ads (-29.61 KJ.mol-1) confirmed the physical adsorption process of this inhibitor. The study of adsorption kinetics showed a maximum inhibitory efficiency of 90.5 % after one hour of immersion time. Scanning electron microscopy revealed the formation of a protective layer on the steel surface. Analysis of the extract by gas chromatography revealed the dominance of Diisooctyl phthalate (17.22%), Bicyclo [4.4.0] dec-2-ene-4-ol,2-methyl-9-(prop-1-en-3-ol-2-yl) (16.43%), Methanesulfonic acid,4-oxoadamantan-2-yl ester (8.75%), Diethyl phthalate (8. 31 %), The structural and electronic properties of the main components of this extract were calculated using DFT to better understand the adsorption behaviour and inhibition mechanism of this plant.
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- 2022
7. The Impact of Environmental Stress on the Secondary Metabolites and the Chemical Compositions of the Essential Oils from Some Medicinal Plants Used as Food Supplements
- Author
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Abdelouahid Laftouhi, Noureddine Eloutassi, Elhachmia Ech-Chihbi, Zakia Rais, Abdelfattah Abdellaoui, Abdslam Taleb, Mustapha Beniken, Hiba-Allah Nafidi, Ahmad Mohammad Salamatullah, Mohammed Bourhia, and Mustapha Taleb
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Renewable Energy, Sustainability and the Environment ,ethnobotanical survey ,phytochemical screening ,aromatic and medicinal plant ,Taounate ,Morocco ,Geography, Planning and Development ,Building and Construction ,Management, Monitoring, Policy and Law - Abstract
This study aims to study the impact of environmental stresses on the chemical compositions of essential oils and the content of secondary metabolites of the plants most used by the rural population: Thymus vulgaris, Mentha pulégium and Rosmarinus officinalis. The results of the study indicate that the percentage of secondary metabolites increased in the second year when temperature and water pressure increased by 50%. Specifically, coumarin increased from 3.94% to 9.23%, saponins increased from 6.17% to 7.78%, tannins increased from 2.90% to 6.12%, alkaloids increased from 6.72% to 15.95%, and flavonoids increased from 7.42% to 12.90%. However, in the fourth year, the temperature continued to increase, and water availability decreased by 75%, leading to a decrease in the rate of secondary metabolites. Coumarin decreased from 9.22% to 6.15%, saponin decreased from 7.80% to 6.79%, tannin decreased from 6.11% to 4.16%, alkaloids decreased from 15.95% to 10.45%, and flavonoids decreased from 12.90% to 9.70%. Similar results were observed for the essential oil yield, which increased in year two from 3.57% to 3.84% and decreased in year four to 1.04%. The same pattern was observed for Mentha pulégium and Rosmarinus officinalis. The gas chromatography analysis of the three essential oil samples showed that the majority of the compounds of the three plants were modified under the conditions of climate change. For Mentha pulégium, pulegone was found to represent the highest proportion in sample two (73.3%), followed by sample one (71.1%), and finally, sample three (61.8%). For Rosmarinus officinalis, the majority of compounds were cineole and camphor, with cineole representing 36% in sample two, 45.89% in sample one, and 43.08% in sample three, and camphor representing 21.44% in sample two, 21.56% in sample three, and 17.44% in sample one. For Thymus vulgaris, the majority of the compounds were Thymol and Carvacrol, which underwent approximately the same modifications as the majority of compounds in the other two plants. The results indicate that environmental stresses can lead to significant changes in these compounds, which can affect the medicinal and aromatic properties of these plants. The findings of this study highlight the need for more research to understand the impacts of climate change on plant species and the potential implications for human health and well-being.
- Published
- 2023
8. Insight into the corrosion inhibition mechanism and adsorption behavior of aldehyde derivatives for mild steel in 1.0 M HCl and 0.5 M H2SO4
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Jamila Lazrak, Elhachmia Ech-chihbi, Rajae Salim, Taoufiq Saffaj, Zakia Rais, and Mustapha Taleb
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Colloid and Surface Chemistry - Published
- 2023
9. Experimental and DFT Investigation on the Corrosion Inhibition of Mild Steel by 1, 2, 3- triazole Regioisomers in 1M hydrochloric Acid Solution
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Elhachmia ECH-CHIHBI, CED Ibn Tofail, Khadijah Emran, and Belkheir Hammouti
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chemistry.chemical_compound ,1,2,3-Triazole ,chemistry ,Electrochemistry ,Structural isomer ,Hydrochloric acid ,Nuclear chemistry ,Corrosion - Published
- 2019
10. Mentha viridis oil as a green effective corrosion inhibitor for mild steel in 1 M HCl medium
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Rajae Salim and Elhachmia ECH-CHIHBI
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Materials Chemistry ,Metals and Alloys - Published
- 2020
Catalog
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