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Your search keyword '"ELLER, P. GARY"' showing total 2 results
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1. Metal corrosion studies with the fluorosulphonic acid–antimony pentafluoride superacid system

Author

Eller, P. Gary, Kissane, Richard J., Abney, Kent D., Avens, Larry R., Kinkead, Scott A., and Hanrahan, Robert J.

Subjects
*CORROSION & anti-corrosives, *SUPERACIDS, *ACTINIDE elements, *OXIDES
Abstract

Because of their rapid dissolution of many actinide metals and refractory oxides, superacids such as HSO3F/SbF5 have potential applications in actinide processing. However, material compatibility must first be addressed because of the highly corrosive nature of superacids. This paper describes the qualitative rates of attack of fluorosulphonic acid–antimony pentafluoride superacid on a variety of metal substrates relevant to nuclear processing. [Copyright &y& Elsevier]

Published
2004
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2. Chromyl fluoride in acidic and basic hydrogen fluoride solutions

Author

Besida, John, O'Donnell, Thomas A., and Eller, P. Gary

Abstract

Chromyl fluoride provides a nonconducting solution in anhydrous hydrogen fluoride with Raman spectroscopic features indistinguishable from those of the solute in the gas phase, indicating no fluoride or proton transfer in solution. With increasing acidity in the SbF5–HF solvent system, CrO2F2forms cationic species, the nature of which is discussed. The acidity-dependence of cationic speciation in HF–TaF5and in HF–AsF5is consistent with that in HF–SbF5. Keywords: chromyl fluoride, antimony fluoride, Lewis acid, Raman spectroscopy, hydrogen fluoride.

Published
1989
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