1. Ferromagnetism on an atom-thick & extended 2D metal-organic coordination network.
- Author
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Lobo-Checa J, Hernández-López L, Otrokov MM, Piquero-Zulaica I, Candia AE, Gargiani P, Serrate D, Delgado F, Valvidares M, Cerdá J, Arnau A, and Bartolomé F
- Abstract
Ferromagnetism is the collective alignment of atomic spins that retain a net magnetic moment below the Curie temperature, even in the absence of external magnetic fields. Reducing this fundamental property into strictly two-dimensions was proposed in metal-organic coordination networks, but thus far has eluded experimental realization. In this work, we demonstrate that extended, cooperative ferromagnetism is feasible in an atomically thin two-dimensional metal-organic coordination network, despite only ≈ 5% of the monolayer being composed of Fe atoms. The resulting ferromagnetic state exhibits an out-of-plane easy-axis square-like hysteresis loop with large coercive fields over 2 Tesla, significant magnetic anisotropy, and persists up to T
C ≈ 35 K. These properties are driven by exchange interactions mainly mediated by the molecular linkers. Our findings resolve a two decade search for ferromagnetism in two-dimensional metal-organic coordination networks., (© 2024. The Author(s).)- Published
- 2024
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