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Mgaloblishvili, a Vitis vinifera cultivar, exhibits unique resistance traits against Plasmopara viticola, the downy mildew agent. This offers the unique opportunity of exploring the molecular responses in compatible and incompatible plant-pathogen interaction. In this study, whole transcriptomes of Mgaloblishvili, Pinot noir (a V. vinifera susceptible cultivar), and Bianca (a resistant hybrid) leaves, inoculated and non-inoculated with the pathogen, were used to identify P. viticola effector-encoding genes and plant susceptibility/resistance genes. Multiple effector-encoding genes were identified in P. viticola transcriptome, with remarkable expression differences in relation to the inoculated grapevine cultivar. Intriguingly, five apoplastic effectors specifically associated with resistance in V. vinifera. Gene coexpression network analysis identified specific modules and metabolic changes occurring during infection in the three grapevine cultivars. Analysis of these data allowed, for the first time, the detection in V. vinifera of a putative P. viticola susceptibility gene, encoding a LOB domain-containing protein. Finally, the de novo assembly of Mgaloblishvili, Pinot noir, and Bianca transcriptomes and their comparison highlighted novel candidate genes that might be at the basis of the resistant phenotype. These results open the way to functional analysis studies and to new perspectives in molecular breeding of grapevine for resistance to P. viticola.

In recent years, the advent of NGS technology has made genome sequencing much cheaper than in the past; the high parallelization capability and the possibility to sequence more than one organism at once have opened the door to processing whole symbiotic consortia. However, this approach needs the development of specific bioinformatics tools able to analyze these data. In this work, we describe SeqDex, a tool that starts from a preliminary assembly obtained from sequencing a mixture of DNA from different organisms, to identify the contigs coming from one organism of interest. SeqDex is a fully automated machine learning–based tool exploiting partial taxonomic affiliations and compositional analysis to predict the taxonomic affiliations of contigs in an assembly. In literature, there are few methods able to deconvolve host–symbiont datasets, and most of them heavily rely on user curation and are therefore time consuming. The problem has strong similarities with metagenomic studies, where mixed samples are sequenced and the bioinformatics challenge is trying to separate contigs on the basis of their source organism; however, in symbiotic systems, additional information can be exploited to improve the output. To assess the ability of SeqDex to deconvolve host–symbiont datasets, we compared it to state-of-the-art methods for metagenomic binning and for host–symbiont deconvolution on three study cases. The results point out the good performances of the presented tool that, in addition to the ease of use and customization potential, make SeqDex a useful tool for rapid identification of endosymbiont sequences.

Grotta Romanelli, located on the Adriatic coast of southern Apulia (Italy), is considered a key site for the Mediterranean Pleistocene for its archaeological and palaeontological contents. The site, discovered in 1874, was re-evaluated only in 1900, when P. E. Stasi realised that it contained the first evidence of the Palaeolithic in Italy. Starting in 1914, G.A. Blanc led a pioneering excavation campaign, for the first-time using scientific methods applied to systematic paleontological and stratigraphical studies. Blanc proposed a stratigraphic framework for the cave. Different dating methods (C14 and U/Th) were used to temporally constrain the deposits. The extensive studies of the cave and its contents were mostly published in journals with limited distribution and access, until the end of the 1970s, when the site became forgotten. In 2015, with the permission of the authorities, a new excavation campaign began, led by a team from Sapienza University of Rome in collaboration with IGAG CNR and other research institutions. The research team had to deal with the consequences of more than 40 years of inactivity in the field and the combined effect of erosion and legal, as well as illegal, excavations. In this paper, we provide a database of all the information published during the first 70 years of excavations and highlight the outstanding problems and contradictions between the chronological and geomorphological evidence, the features of the faunal assemblages and the limestone artefacts., Rivista Italiana di Paleontologia e Stratigrafia (Research In Paleontology and Stratigraphy), V. 124, N. 2 (2018)

Peptidoglycan is the predominant stress-bearing structure in the cell envelope of most bacteria, and also a potent stimulator of the eukaryotic immune system. Obligate intracellular bacteria replicate exclusively within the interior of living cells, an osmotically protected niche. Under these conditions peptidoglycan is not necessarily needed to maintain the integrity of the bacterial cell. Moreover, the presence of peptidoglycan puts bacteria at risk of detection and destruction by host peptidoglycan recognition factors and downstream effectors. This has resulted in a selective pressure and opportunity to reduce the levels of peptidoglycan. In this review we have analysed the occurrence of genes involved in peptidoglycan metabolism across the major obligate intracellular bacterial species. From this comparative analysis, we have identified a group of predicted "peptidoglycan-intermediate" organisms that includes the Chlamydiae, Orientia tsutsugamushi, Wolbachia and Anaplasma marginale. This grouping is likely to reflect biological differences in their infection cycle compared with peptidoglycan-negative obligate intracellular bacteria such as Ehrlichia and Anaplasma phagocytophilum, as well as obligate intracellular bacteria with classical peptidoglycan such as Coxiella, Buchnera and members of the Rickettsia genus. The signature gene set of the peptidoglycan-intermediate group reveals insights into minimal enzymatic requirements for building a peptidoglycan-like sacculus and/or division septum. This article is protected by copyright. All rights reserved.

This paper reports an infrared spectroscopic study of a set of sodalite-group minerals. The specimens have been identified using a combination of X-ray diffraction and microchemical analysis. As expected, the Si/Al ratio is ~1; the extra framework cation content is characterized by a well-defined Na > (Ca+K) substitution. The lattice parameters of the studied samples range from sodalite (sample LM11) with a = 8.889(2) Å , to haüyne (sample HR3S) with a = 9.1265(2) Å . The specimens, having the SO42- group as a dominant anion, show a clear correlation between the a cell edge and the K content. Singlecrystal FTIR spectroscopy shows that haüyne and nosean typically contain enclathrated CO2 molecules, inadditionto H2O and minor carbonate, while sodalite is virtually CO2-free. Detailed microspectrometric mappings show a non-homogeneous distribution of volatile constituents across the crystals, which may be related to the presence of fractures in the crystals. Because of such zoning, a relatively wide variation is observed when calibrating extinction coefficients on the basis of a bulk analytical method such as CHN elemental analysis.

The sodalite-group include: sodalite s.s. Na8[Al6Si6O24]Cl2, noseane Na8[Al6Si6O24]SO4•H2O, haüyne, Na6Ca2[Al6Si6O24](SO4)2, and lazurite Na6Ca2[[Al6Si6O24]S2. These minerals occur almost exclusively in alkali-rich, silica-deficient igneous rocks, and occasionally in metasomatized limestones. The structure of the sodalite-group minerals is cubic P 3n and is characterized by an ordered framework of AlO4 and SiO4 tetrahedra, with an Al:Si ratio = 1:1. These tetrahedra are linked such as to form six-membered rings stacked following an ABCABC... sequence, and are arranged such as to form continuous channels parallel to [111] that offer diffusion paths for intra-framework ions (Barrer and Vaughan, 1971). The overall linkage between the rings gives rise to cubo-octahedral “sodalite” cages, also known as $IMM_COM_0005 cages (Pauling, 1930); these may host a large variety of cations (e.g. Na+, Ca2+, K+), anions (e.g. OH-, Cl-, SO42-, S2-) and neutral molecules (H2O), but also noble gases (e.g. Xe, Ar). The cage has a diameter of  4 Å hence sodalite-group minerals can be considered as microporous materials (Rouquerol et al. 1994). We relate here the recent developments of our micro-FTIR studies on a series of sodalite-group minerals from different localities and geological occurrences. Spectra were collected on doubly-polished slabs using a NicPlan microscope with a nitrogen-cooled MCT detector attached to a Nicolet Magna 760 spectrometer with a KBr beamsplitter and a Globar as IR source. Microspectrometric mappings were acquired with a Hyperion 3000 Bruker microscope equipped with a computer-controlled motorized stage. HT spectra in situ were collected using a Linkam FTIR600 heating stage (single-crystals); annealing experiment were done using an HT device. Single-crystal FTIR spectra show that the different species in the group, and different samples of the same species, have different degrees of hydration; H is present in various forms, including OH, H2O, H3O+ and H3O2- groups. Carbon occurs as CO2, CO32- and possibly as HCO3-. Carbonate and hydrogencarbonate arrangements are detected in several haüyne and sodalites s.s. specimens, while CO2 is observed, in decreasing amount, in noesane, lazurites and haüynes; CO2 has been so far observed only in one sample of sodalites s.s. HT-FTIR measurements show, in all samples, a continuous and linear release of H2O up to the structure collapse at ~ 900° C. On heating, the CO2 absorption increasingly broadens, as already observed for beryl and codierite (Aines and Rossman 1984), and recovers its initial shape for decreasing T. However, release of CO2 from the sample occurs only for T > 900°C. Microspectrometry mappings shows typically a non-homogeneous distributions of hydrogen and carbon across the samples. Using the molar absorption coefficients available in the literature for glasses with similar compositions, H contents in the range 400 to 800 ppm and CO2 contents in the range 200 to 800 ppm are calculated. References Aines R.D., Rossman G.R. (1984) Am. Mineral., 69, 319-327. Barrer, R.M., Vaughan D.E.W. (1971) J. Phys. Chem. Solids 32, 731-743. Pauling, L. (1930) Z. Kristallogr., 74, 213-225. Rouquerolt T., Avnir D., Fairbridge C.W., Everett D.H., Haynes J.H., Pernicone N., Ramsay J.D.F., Sing K.S.W., Unger K.K. (1994) Pure and Appl. Chem., 66, 1739-1758.

Structural investigations, integrated with X-ray diffraction, fluid inclusion microthermometry and oxygen-stable isotope analyses are used to reconstruct the deformation history and the palaeo-fluid circulation during formation of the low-grade, turbidite-dominated Early Palaeozoic Robertson Bay accretionary complex of north Victoria Land (Antarctica). Evidence for progressive deformation is elucidated by analysing the textural fabric of chronologically distinct, thrust-related quartz vein generations, incrementally developed during progressive shortening and thickening of the Robertson Bay accretionary complex. Our data attest that orogenic deformation was mainly controlled by dissolution–precipitation creep, modulated by stress- and strain-rate-dependent fluid pressure cycling, associated with local and regional permeability variations induced by the distribution and evolution of the fracture network during regional thrusting. Fracture-related fluid pathways constituted efficient conduits for episodic fluid flow. The dominant migrating fluid was pre-to-syn-folding and associated with the migration of warm (160–200 C) nitrogen- and carbonic (CO2 and CH4)-bearing fluids. Both fluid advection and diffusive mass transfer are recognized as operative mechanisms for fluid–rock interaction and vein formation during continuous shortening. In particular, fluid–rock interaction was the consequence of dissolution–precipitation creep assisted by tectonically driven cooling fluids moving through the rock section as a result of seismic pumping. The most likely source of the migrating fluids would be the frontal part of the growing accretionary complex, where fluids from the deep levels in the hinterland are driven trough channelization operated by the thrust-related fracture (fault) systems.

This paper describes the fluids circulating in the extensive thrust-related quartz-bearing vein systems developed within the low-grade turbidite-dominated Early Paleozoic Robertson Bay Terrane of north Victoria Land, Antarctica. It provides a well-preserved example of fossil accretionary complex, developed during the Paleozoic subdution-related accretionary process at the paleo-Pacifica margin of Gondwana. Fluid inclusions are analysed in quartz crystals hosted within distinct generations of veins, which are interpreted to record the incremental deformation history during shortening and accretionary complex formation. Our data provides clues to the tectono-thermal history associated with orogenic complex formation, also providing inferences on the fluid storage and recycling through time.

Sinorhizobium meliloti is a soil bacterium that invades the root nodules it induces on Medicago sativa, whereupon it undergoes an alteration of its cell cycle and differentiates into nitrogen-fixing, elongated and polyploid bacteroid with higher membrane permeability. In Caulobacter crescentus, a related alphaproteobacterium, the principal cell cycle regulator, CtrA, is inhibited by the phosphorylated response regulator DivK. The phosphorylation of DivK depends on the histidine kinase DivJ, while PleC is the principal phosphatase for DivK. Despite the importance of the DivJ in C. crescentus, the mechanistic role of this kinase has never been elucidated in other Alphaproteobacteria. We show here that the histidine kinases DivJ together with CbrA and PleC participate in a complex phosphorylation system of the essential response regulator DivK in S. meliloti. In particular, DivJ and CbrA are involved in DivK phosphorylation and in turn CtrA inactivation, thereby controlling correct cell cycle progression and the integrity of the cell envelope. In contrast, the essential PleC presumably acts as a phosphatase of DivK. Interestingly, we found that a DivJ mutant is able to elicit nodules and enter plant cells, but fails to establish an effective symbiosis suggesting that proper envelope and/or low CtrA levels are required for symbiosis., National Institutes of Health (U.S.) (Grant GM31010)

Background Cansiliella servadeii (Coleoptera) is an endemic troglobite living in deep carbonate caves in North-Eastern Italy. The beetle constantly moves and browses in its preferred habitat (consisting in flowing water and moonmilk, a soft speleothem colonized by microorganisms) self-preens to convey material from elytra, legs, and antennae towards the mouth. We investigated its inner and outer microbiota using microscopy and DNA-based approaches. Results Abundant microbial cell masses were observed on the external appendages. Cansiliella’s midgut is fully colonized by live microbes and culture-independent analyses yielded nearly 30 different 16S phylotypes that have no overlap with the community composition of the moonmilk. Many of the lineages, dominated by Gram positive groups, share very low similarity to database sequences. However for most cases, notwithstanding their very limited relatedness with existing records, phylotypes could be assigned to bacterial clades that had been retrieved from insect or other animals’ digestive traits. Conclusions Results suggest a history of remote separation from a common ancestor that harboured a set of gut-specific bacteria whose functions are supposedly critical for host physiology. The phylogenetic and coevolutionary implications of the parallel occurrences of these prokaryotic guilds appear to apply throughout a broad spectrum of animal diversity. Their persistence and conservation underlies a possibly critical role of precise bacterial assemblages in animal-bacteria interactions.

Fissure ridge travertines grown from geothermal springs of Denizli Basin, southwestern Turkey, are investigated through stratigraphic, structural, geochemical, and geochronological methods, with the aim of understanding the growth of these elongate mound-shaped structures. Two main types of travertine deposits are recognized: (1) bedded travertines, which grew as flowstone on sloping surfaces and form the bulk of fissure ridges, and (2) banded travertines, which grew as veins within the bedded travertine chiefly along its central feeding conduit. Stratigraphic and structural observations shed light on the bedded-banded travertine relationships, where the banded features grew through successive accretion phases, crosscutting the bedded travertine or forming sill-like structures. The bedded and banded travertines alternated their growth, as demonstrated by complicated crosscutting relationships and by the upward suture, in places, of banded travertine by bedded travertine that was, in turn, crosscut by younger banded travertine. The bedded travertine is often tilted away from the central axis of the fissure ridge, thus leaving more room for the central banded travertine to form. U-series ages confirm the bedded-banded travertine temporal relationships and show that the growth of the studied fissure ridges lasted up to several tens of thousands of years during Quaternary time. The banded travertine was deposited mainly during cold events, possibly in coincidence with seismic events that might have triggered the outflow of deep geothermal fluids. C and 0 stable isotope and rare earth element data indicate a shallow feeding circuit for the studied structures with a fluid component deriving from a deeper geothermal circuit. A crack-and-seal mechanism of fissure ridge growth is proposed, modulated by the interplay of local and regional influencing factors and mechanisms such as geothermal fluid discharge, paleoclimate, tectonics, and the progressive tilting of bedded travertine limbs over a soft substratum creating the necessary space for the central veins to grow.

This study integrates field, geochronological and geochemical data to constrain fluid circulation in the damage and core zone of the seismogenic Monte Morrone Fault System (MMFS), central Apennines (Italy). Faulting along the MMFS evolved from a diffuse deformation at the damage zone towards progressive localisation of a narrower fault core and, finally, to (re)activation of discrete slip surfaces at shallower crustal conditions. Multiple generations of carbonate mineralisations, including veins and slickfibers, occur along the main fault surfaces. Carbonate mineralisations are locally fractured and incorporated in the surrounding cataclasites, documenting repetitive structurally-controlled fluid infiltration during transient episodes of permeability creation and destruction. Stable carbon and oxygen isotopes of the carbonate mineralisations document a dominant meteoric water source probably mixed with deeper circulating waters having longer residence time. Clumped-isotope yield formation temperatures of vein and slickenfibers in the range between 23 and 40 °C. UTh dating of carbonate mineralisations yield Middle Pleistocene ages (from 268 to 189 ka BP), with a 10–15-ka cyclicity that we link to the coseismic rejuvenation of the structural permeability in the fault zone. We propose that fault-related mineralisations recorded the interactions among tectonic deformation and climate during the Quaternary. Our study is the first documentation of fault-controlled recurrence intervals in fluid infiltration in a seismically active fault of central Apennines. Keywords: Normal faulting; Mineralising fluid; Seismic cycle; U-Th carbonate dating; Monte Morrone Fault; Central Apennines

Modulation of nutrient digestion and absorption is one of the post-ingestion mechanisms that guarantees the best exploitation of food resources, even when they are nutritionally poor or unbalanced, and plays a pivotal role in generalist feeders, which experience an extreme variability in diet composition. Among insects, the larvae of black soldier fly (BSF), Hermetia illucens, can grow on a wide range of feeding substrates with different nutrient content, suggesting that they can set in motion post-ingestion processes to match their nutritional requirements. In the present study we address this issue by investigating how the BSF larval midgut adapts to diets with different nutrient content. Two rearing substrates were compared: a nutritionally balanced diet for dipteran larvae and a nutritionally poor diet that mimics fruit and vegetable waste. Our data show that larval growth performance is only moderately affected by the nutritionally poor diet, while differences in the activity of digestive enzymes, midgut cell morphology, and accumulation of long-term storage molecules can be observed, indicating that diet-dependent adaptation processes in the midgut ensure the exploitation of poor substrates. Midgut transcriptome analysis of larvae reared on the two substrates showed that genes with important functions in digestion and absorption are differentially expressed, confirming the adaptability of this organ.

In extensional continental settings, crustal-scale normal faults can accommodate deformation and subsidence at their hanging wall via activation and deactivation of subsidiary tectonic structures. Geological data obtained from subsidiary structures are required to infer the position of the tectonic deformation during the spatial-temporal evolution of the growth-fault system, with significant implications for structures belonging to seismogenic settings. Here, we describe a subsidiary tectonic structure (the Amatrice Fault System) accommodating Quaternary extensional deformation in the Amatrice Basin (central Apennines, Italy), which is an intermountain morpho-structural depression involved by the 2016–2017 seismic sequence. Structurally, the Amatrice Fault System defines a ∼10 km-long tectonic feature running through the Amatrice Basin, and consists of NNW-SSE-striking and E-W-striking fault segments that interact and link over time. Cross-cutting fault relationships are used to reconstruct a kinematic scenario of fault growth and propagation under an ENE-WSW-directed crustal stretching, consistent with the paleostress regime governing the Quaternary activity of the central Apennines. The analysis of stable carbon and oxygen isotopes on syn-kinematic carbonate mineralizations (calcite veins and calcite fibers on fault surfaces) indicates a meteoric water circulation during the development of the growing fault structure, characterized by variable contributions of organic carbon (soil CO2), and suggesting surface rupture and hydrodynamic interconnection with the vadose zone during faulting. Geochronological U-Th dating on the same mineralizations indicates Middle-Late Pleistocene ages for the main phase of tectonic activity of the Amatrice Fault System, with the younger age being 108 ± 10 ka. To date, we cannot exclude minor activations of the Amatrice Fault System during the Holocene. Our results shed light on the Pleistocene tectonics in the Amatrice Basin, in which the Amatrice Fault System records fault growth, hydrodynamic regime and structural permeability network developed under possible coseismic conditions. The evolution of minor tectonic structures, such as the Amatrice Fault System, can provide insights on the localization of tectonic deformation at the hanging wall of a master fault, with implication on the releasing seismogenic potential in active tectonic domains similar to the central Apennines.

In this paper, we present the results of the accelerator mass spectrometry radiocarbon (AMS14C) dating campaign performed on samples selected from different levels in Grotta Romanelli (Castro, Italy). Grotta Romanelli is one of the key sites for the chronology of Middle Pleistocene–Holocene in Mediterranean region. After the first excavation campaigns carried out in the first decades of the 1900s, the cave has been systematically re-excavated only since 2015. During the last excavation campaigns different faunal remains were selected and submitted for 14C dating in order to confirm the chronology of the cave with a higher resolution. Isotopic ratio mass spectrometry (IRMS) measurements were also carried out on faunal remains.

The Catalao II carbonatitic complex is part of the Alto Paranaiba Igneous Province (APIP), central Brazil, close to the Catalao I complex. Drill-hole sampling and detailed mineralogical and geochemical study point out the existence of ultramafic lamprophyres (phlogopite-picrites), calciocarbonatites, ferrocarbonatites, magnetitites, apatitites, phlogopitites and fenites, most of them of cumulitic origin. U–Pb data have constrained the age of Catalao I carbonatitic complex between 78 ± 1 and 81 ± 4 Ma. The initial strontium, neodymium and hafnium isotopic data of Catalao II (87Sr/86Sri = 0.70503–0.70599; eNdi = −6.8 to −4.7; 176Hf/177Hf = 0.28248–0.28249; eHfi = −10.33 to −10.8) are similar to the isotopic composition of the Catalao I complex and fall within the field of APIP kimberlites, kamafugites and phlogopite-picrites, indicating the provenance from an old lithospheric mantle source. Carbon isotopic data for Catalao II carbonatites (δ13C = −6.35 to −5.68 ‰) confirm the mantle origin of the carbon for these rocks. The origin of Catalao II cumulitic rocks is thought to be caused by differential settling of the heavy phases (magnetite, apatite, pyrochlore and sulphides) in a magma chamber repeatedly filled by carbonatitic/ferrocarbonatitic liquids (s.l.). The Sr–Nd isotopic composition of the Catalao II rocks matches those of APIP rocks and is markedly different from the isotopic features of alkaline-carbonatitic complexes in the southernmost Brazil. The differences are also observed in the lithologies and the magmatic affinity of the igneous rocks found in the two areas, thus demonstrating the existence of regional-scale heterogeneity in the mantle sources underneath the Brazilian platform.

Fractures, karstic cavities, and calcite precipitates are analysed on Mesozoic, carbonate strata from the Cornicolani Mountains, central Italy, to quantify the relationships between fractures and related karstic cavities and to infer the fracture-controlled fluid pathways. The study area is characterized by active sinkholes and other karstic caves, which are among the deepest ones in the world. Results show a clear control of fractures on the process of dissolutional weathering and, therefore, on the fluid circulation. A model is proposed, in which two different modes of dissolutional weathering coexist: (i) a mode of diffuse weathering consisting in the dissolutional enlargement of closely spaced joints and bedding surfaces. This process affects the strata situated at depths of up to 5 m; (ii) a mode of more concentrated weathering active along highly permeable fault damage zones at depths of at least 70 m. These processes are mostly connected with the shallow circulation of calcite-dissolving meteoric waters, and are controlled by the disparity of permeability between the fault damage zones and the surrounding jointed strata. Some calcite precipitates along the studied fault damage zones may be connected with a dissolutional process operated by waters that interacted with the adjacent quiescent volcanic district. Such calcite-dissolving waters and the presence of high-permeable fault damage zones, along which the waters may ascent, are probably the cause for the development of some of the deep sinkholes along faults in the study area.

Fluid-rock interaction was investigated in the inner aureole of the Late Miocene Monte Capanne pluton on Elba Island (Tuscany, central Italy) by integrating structural, petrological, fluid inclusion, and stable isotope analyses. In the north-western sector of the aureole (Procchio-Spartaia area), calc-silicates alternate with nearly pure carbonate layers at the metre scale. Close to the pluton, the prograde metamorphic sequence includes calc-silicates that transition within a few metres to overlying nearly pure calcite marbles. The calc-silicates are extensively metasomatised to form massive wollastonite-grossular-bearing exoskarn. The mineralogical assemblage found in the marbles and the unshifted carbon and oxygen isotopic ratios in calcite attest that the fluid phase was internally buffered. On the other hand, the calc-silicates constituted channels for infiltration of disequilibrium fluids of magmatic origin. Fluid infiltration was enhanced by hydrofracturing and structurally-controlled by existing planar anisotropies in calc-silicates (layering and lithological boundaries). At the metamorphic peak (600 degrees C and 1.5-2 kbar), the marble-calc-silicate interface acted as a barrier to fluids exsolved from the crystallising intrusions, separating two different flow patterns in the inner aureole: a high fluid-flux region on its higher grade side (Wol-zone) and a low fluid-flux region on the lower-grade side (Cpx zone). Results of this study: (1) documented that fluid pathways in the aureole rocks at the top of the pluton were largely horizontal, controlled by the lithological layering and the pluton-host rock contact; and (2) elucidated the primary control exerted by the structural and rheological properties of the host rocks on the geometry of fluid flow during pluton emplacement.

Fissure ridge travertines grown from geothermal springs of Denizli Basin, southwestern Turkey, are investigated through stratigraphic, structural, geochemical, and geochronological methods, with the aim of understanding the growth of these elongate mound-shaped structures. Two main types of travertine deposits are recognized: (1) bedded travertines, which grew as flowstone on sloping surfaces and form the bulk of fissure ridges, and (2) banded travertines, which grew as veins within the bedded travertine chiefly along its central feeding conduit. Stratigraphic and structural observations shed light on the bedded-banded travertine relationships, where the banded features grew through successive accretion phases, crosscutting the bedded travertine or forming sill-like structures. The bedded and banded travertines alternated their growth, as demonstrated by complicated crosscutting relationships and by the upward suture, in places, of banded travertine by bedded travertine that was, in turn, crosscut by younger banded travertine. The bedded travertine is often tilted away from the central axis of the fissure ridge, thus leaving more room for the central banded travertine to form. U-series ages confirm the bedded-banded travertine temporal relationships and show that the growth of the studied fissure ridges lasted up to several tens of thousands of years during Quaternary time. The banded travertine was deposited mainly during cold events, possibly in coincidence with seismic events that might have triggered the outflow of deep geothermal fluids. C and 0 stable isotope and rare earth element data indicate a shallow feeding circuit for the studied structures with a fluid component deriving from a deeper geothermal circuit. A crack-and-seal mechanism of fissure ridge growth is proposed, modulated by the interplay of local and regional influencing factors and mechanisms such as geothermal fluid discharge, paleoclimate, tectonics, and the progressive tilting of bedded travertine limbs over a soft substratum creating the necessary space for the central veins to grow.

This paper reports an infrared spectroscopic study of a set of sodalite-group minerals. The specimens have been identified using a combination of X-ray diffraction and microchemical analysis. As expected, the Si/Al ratio is ∼1; the extra framework cation content is characterized by a well-defined Na ⇌ (Ca+K) substitution. The lattice parameters of the studied samples range from sodalite (sample LM11) with a = 8.889(2) A, to hauyne (sample HR3S) with a = 9.1265(2) A. The specimens, having the \batchmode \documentclass[fleqn,10pt,legalpaper]{article} \usepackage{amssymb} \usepackage{amsfonts} \usepackage{amsmath} \pagestyle{empty} \begin{document} \(\mathrm{SO}_{4}^{2-}\) \end{document} group as a dominant anion, show a clear correlation between the a cell edge and the K content. Single-crystal FTIR spectroscopy shows that hauyne and nosean typically contain enclathrated CO2 molecules, in addition to H2O and minor carbonate, while sodalite is virtually CO2-free. Detailed microspectrometric mappings show a non-homogeneous distribution of volatile constituents across the crystals, which may be related to the presence of fractures in the crystals. Because of such zoning, a relatively wide variation is observed when calibrating extinction coefficients on the basis of a bulk analytical method such as CHN elemental analysis.