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International audience; Understanding the cosmogonic record encoded in the parent volatiles stored in cometary nuclei requires investigating whether evolution (thermal or otherwise) has modified the composition of short-period comets during successive perihelion passages. As the most volatile molecules systematically observed in comets, the abundances of CO, CH 4 , and C 2 H 6 in short-period comets may serve to elucidate the interplay between natal conditions and post-formative evolution in setting present-day composition, yet secure measurements of CO and CH 4 in Jupiterfamily comets (JFCs) are especially sparse. The highly favorable 2018 apparition of JFC 21P/Giacobini-Zinner enabled a sensitive search for these "hypervolatiles" in a prototypical carbon-chain depleted comet. We observed 21P/Giacobini-Zinner with the iSHELL spectrograph at the NASA Infrared Telescope Facility on four preperihelion dates, two dates near-perihelion, and one post-perihelion date. We obtained detections of CO, CH 4 , and C 2 H 6 simultaneously with H 2 O on multiple dates. We present rotational temperatures, production rates, and mixing ratios. Combined with previous work, our results may indicate that the hypervolatile coma composition of 21P/ Giacobini-Zinner was variable across apparitions as well as within a particular perihelion passage, yet the spread in these measurements is a relatively small fraction of the variation in each molecule from comet to comet. We discuss the implications of our measured hypervolatile content of 21P/Giacobini-Zinner for the evolution of JFCs, and place our results in the context of findings from the Rosetta mission and ground-based studies of comets.

We present H$_2$O production rates for comet C/2012 S1 (ISON) derived from observations of [OI] and OH emission during its inbound leg, covering a heliocentric distance range of 1.8-0.44 AU. Our production rates are in agreement with previous measurements using a variety of instruments and techniques and with data from the various observatories greatly differing in their projected fields of view. The consistent results across all data suggest the absence of an extended source of H$_2$O production, for example sublimation of icy grains in the coma, or a source with spatial extent confined to the dimensions of the smallest projected field of view (in this case $ 1.2 AU, which then decreased to about half this value from R$_h$=1.2-0.9 AU. This was followed by a rapid increase in active area at about R$_h$=0.6 AU, corresponding to the first of three major outbursts ISON experienced inside of 1 AU. The combination of a detected outburst in the light curve and rapid increase in active area likely indicates a major nucleus fragmentation event. The 5-10 km$^2$ active area observed outside of R$_h$=0.6 AU is consistent with a 50-100% active fraction for the nucleus, larger than typically observed for cometary nuclei. Although the absolute value of the active area is somewhat dependent on the thermal model employed, the changes in active area observed are consistent among models. The conclusion of a 50-100+% active fraction is robust for realistic thermal models of the nucleus. However the possibility of a contribution of a spatially unresolved distribution of icy grains cannot be discounted., Comment: 26 pages, 5 figures, 5 tables, accepted for publication in Icarus

The 2018 perihelion passage of comet 46P/Wirtanen afforded an opportunity to measure the abundances and spatial distributions of coma volatiles in a Jupiter-family comet with exceptional spatial resolution for several weeks surrounding its closest approach to Earth (Δmin ∼0.078 au on UT December 16). We conducted near-infrared spectroscopic observations of 46P/Wirtanen using iSHELL at the NASA Infrared Telescope Facility on UT 2018 December 18 in direct coordination with observations using the newly upgraded NIRSPEC-2 instrument at the W. M. Keck Observatory, and securely detected fluorescent emission from CH3OH, C2H6, and H2O. This coordinated campaign utilizing the two premier near-infrared facilities in the northern hemisphere enabled us to sample distinct projections of the coma into the plane of the sky simultaneously, and provided an unprecedented view into the inner coma of 46P/Wirtanen near closest approach. We report rotational temperatures, production rates, and abundance ratios (i.e., mixing ratios) for all sampled species and compare our iSHELL results to simultaneous (or near-simultaneous) measurements taken with NIRSPEC-2. We demonstrate the extraordinary synergy of coordinated measurements using iSHELL and NIRSPEC-2, and advocate for future cometary studies that jointly leverage the capabilities of these two facilities.

A major upgrade to the NIRSPEC instrument at the Keck II telescope was successfully completed in time for near-infrared spectroscopic observations of comet 46P/Wirtanen during its exceptionally close flyby of Earth in 2018 December. These studies determined the abundances of several volatiles, including C2H2, C2H6, CH3OH, NH3, HCN, H2CO, and H2O. Long-slit spatial distributions of gas rotational temperature and column density are diagnostic for the presence of icy grains in the coma and understanding if different volatiles are associated with common or distinct outgassing sources. These spatial distributions suggest that C2H2, C2H6, and HCN have a common outgassing source, whereas H2O and CH3OH have additional, more extended sources. The synergy of these findings with observations by space missions (Rosetta and EPOXI) motivates continuing studies to address whether or not C2H6, C2H2, and HCN have a common source of release (plausibly associated with CO2) in a larger sample of comets and whether systematic differences exist in the release of these species compared to H2O and CH3OH. Abundances of volatiles are reported relative to H2O, as traditionally done, as well as C2H6. While not unique, the choice of C2H6 demonstrates the value of extending the chemical taxonomy of parent volatiles in comets toward additional compositional “baselines” and, importantly, closer integration between coma abundances and the underlying volatile associations as revealed by spatial distributions. Our findings on composition and sources of outgassing include information relevant to future evaluations of 46P/Wirtanen as a prospective spacecraft target.

We present analysis of IR and optical spectroscopy of Jupiter-family comet (JFC) 46P/Wirtanen obtained in 2019 January, when the comet had sufficient geocentric velocity to enable studies of the hypervolatiles CO and CH4, as well as [O i] emission. These species could not be studied near closest approach in mid-December because there was insufficient Doppler shift to separate the cometary emission from their corresponding telluric absorption lines. We employed the [O i] observations as a proxy for the CO2/H2O ratio, as CO2 cannot be observed directly from the ground, and space-based assets sensitive to CO2 were not able to observe 46P during this apparition. We focused our analysis on H2O, CO, CH4, C2H6, CH3OH, and CO2 (via [O i] emission). We detected strong emissions from H2O, C2H6, and CH3OH. Over the 3 nights, we found evidence for changing mixing ratios, mostly due to a variable H2O production rate. In 46P, C2H6 and CH3OH are enriched compared to cometary averages, with mixing ratios relative to H2O of ∼1% and ∼3%, respectively. Measurements of CH4 and CO have been especially rare in JFCs. We report significant 3σ upper limits on CH4/H2O < 0.97% and CO/H2O < 0.54%. They place CH4 being near-average or depleted, and CO being strongly depleted in 46P compared with Oort cloud comets. 46P has comparable CO/H2O to the few other measurements in JFCs, but enriched in C2H6 and CH3OH. Our inferred CO2/H2O mixing ratio is ∼15%, though accounting for systematic uncertainties from the lack of knowledge of [O i] photochemistry means a value between 10% and 20% is likely. The compositional profile of 46P is similar to another small, hyperactive comet: 103P/Hartley 2. The mechanism of CO2-driven water-rich ice grain production proposed for 103P/Hartley 2 may be operating on 46P as well.

Spectra of the comae of four comets were obtained with an integral field unit spectrograph on the Harlan J. Smith Telescope at McDonald Observatory. The passband of the spectrograph permitted the observation of C2, C3, CH, CN, and NH2 transitions for these comets. The classical Haser model was used to derive production rates for each observed species. The production rates obtained for the comets were also used to obtain mixing ratios relative to CN. The relative abundances with respect to CN obtained for these comets vary greatly, but are largely consistent with ranges established from prior comet chemistry surveys. The notable exception is 168P/Hergenrother, which the results suggest is extremely depleted in volatiles, even with respect to many other comets designated as volatile depleted in prior surveys. The results for comet Hergenrother add to a small, but growing, body of data suggesting that there may be a subgroup of carbon-chain-depleted Jupiter-family comets that are also depleted in ammonia.

We present high spectral resolution optical observations of comet 21P/Giacobini–Zinner from six nights in 2018. The observations were obtained with the Tull Coudé Spectrograph on the 2.7 m Harlan J. Smith Telescope of the McDonald Observatory. This comet’s spectrum shows strong depletions in C2, C3, CH, and NH2 relative to CN. We explore what it means for a comet to be depleted and show that all of the species are present in the spectrum at similar relative line intensities within a a molecular band compared with a typical comet. The depletions represent a much lower abundance of the species studied.

We present analysis of observations of CO2 and OI emission in three comets to measure the CO2 abundance and evaluate the possibility of employing observations of OI emission in comets as a proxy for CO2. We obtained NIR imaging sensitive to CO2 of comets C/2012 K1 (PanSTARRS), C/2012 K5 (LINEAR), and 290P/Jager with the IRAC instrument on Spitzer. We acquired observations of OI emission in these comets with the ARCES echelle spectrometer mounted on the 3.5-meter telescope at Apache Point Observatory and observations of OH with the Swift observatory (PanSTARRS) and with Keck HIRES (Jager). The CO2/H2O ratios derived from the Spitzer images are 12.6 +/- 1.3% (PanSTARRS), 28.9 +/- 3.6% (LINEAR), and 31.3 +/- 4.2% (Jager). These abundances are derived under the assumption that contamination from CO emission is negligible. The CO2 abundance for PanSTARRS is close to the average abundance measured in comets at similar heliocentric distance to date, while the abundances measured for LINEAR and Jager are significantly larger than the average abundance. From the coma morphology observed in PanSTARRS and the assumed gas expansion velocity, we derive a rotation period for the nucleus of about 9.2 hours. Comparison of H2O production rates derived from ARCES and Swift data, as well as other observations, suggest the possibility of sublimation from icy grains in the inner coma. We evaluate the possibility that the OI emission can be employed as a proxy for CO2 by comparing CO2/H2O ratios inferred from the OI lines to those measured directly by Spitzer. We find that for PanSTARRS we can reproduce the observed CO2 abundance to an accuracy of ~20%. For LINEAR and Jager, we were only able to obtain upper limits on the CO2 abundance inferred from the OI lines. These upper limits are consistent with the CO2 abundances measured by Spitzer., Comment: 30 pages, 6 tables, 7 figures, accepted for publication in Icarus

We present high spectral resolution optical spectra obtained with the ARCES instrument at Apache Point Observatory showing detection of the [OI]6300 A line in interstellar comet 2I/Borisov. We employ the observed flux in this line to derive an H$_2$O production rate of (6.3$\pm$1.5)$\times$10$^{26}$ mol s$^{-1}$. Comparing to previously reported observations of CN, this implies a CN/H$_2$O ratio of $\sim$0.3-0.6%. The lower end of this range is consistent with the average value in comets, while the upper end is higher than the average value for Solar System comets, but still within the range of observed values. C$_2$/H$_2$O is depleted, with a value likely less than 0.1%. The dust-to-gas ratio is consistent with the normal value for Solar System comets. Using a simple sublimation model we estimate an H$_2$O active area of 1.7 km$^2$, which for current estimates for the size of Borisov suggests active fractions between 1-150%, consistent with values measured in Solar System comets. More detailed characterization of 2I/Borisov, including compositional information and properties of the nucleus, is needed to fully interpret the observed H$_2$O production rate., 8 pages, 2 figures, 1 table, Accepted in ApJ Letters

We modeled observations of the C$_2$ $\mathrm{d} ^3\Pi_g - \mathrm{a} ^3\Pi_u$ (Swan) $\Delta \nu = 0$ sequence observed in spectra of comet 122P/de Vico obtained with the 2.7m Harlan J. Smith Telescope and Tull Coude spectrograph of McDonald observatory on 10/03/1995 and 10/04/1995. The data used spanned 4986-5169\AA at R=$\lambda/\Delta\lambda$=60,000. We used the PGOPHER molecular spectra model to generate and fit synthetic spectra with the d$^3\Pi_g$ having one and two rotational temperatures. We found the excited state had a two component rotational temperature, similar to that found for comet Halley. The modeled spectrum was sufficiently high quality that local perturbations were important to include. The large perturbation, b$^3\Sigma_g^-(\nu=10)$, was added to our fits and some new estimates on its molecular constants were found., Comment: This document is the unedited Author's version of a Submitted Work that was subsequently accepted for publication in Journal of Physical Chemistry, Part A:Isolated Molecules, Clusters, Radicals, and Ions; Environmental Chemistry, Geochemistry, and Astrochemistry; New Tools and Methods, copyright American Chemical Society after peer review

We present high spectral-resolution observations of comets 122P/de Vico and 153P/Ikeya-Zhang obtained with the Tull Coud\'{e} spectrograph on the 2.7m Harlan J. Smith telescope of McDonald Observatory. We used these data to study the distribution of the lines of the $\mathrm{d} ^3\Pi_g - \mathrm{a} ^3\Pi_u$ C$_2$ (Swan) bands. We show that the data are best represented with two rotational temperatures, with the lowest energy lines being at a relatively cool temperature and the higher energy lines being at a higher temperature. We discuss the implications of this two temperature distribution and suggest future work., Comment: 15 pages, 8 figures

We present results from spectroscopic follow-up observations of stars identified in the Kepler field and carried out by teams of the Kepler Follow-Up Observation Program. Two samples of stars were observed over six years (2009-2015): 614 standard stars (divided into "platinum" and "gold" categories) selected based on their asteroseismic detections and 2667 host stars of Kepler Objects of Interest (KOIs), most of them planet candidates. Four data analysis pipelines were used to derive stellar parameters for the observed stars. We compare the $T_{\mathrm{eff}}$, $\log$(g), and [Fe/H] values derived for the same stars by different pipelines; from the average of the standard deviations of the differences in these parameter values, we derive error floors of $\sim$ 100 K, 0.2 dex, and 0.1 dex for $T_{\mathrm{eff}}$, $\log$(g), and [Fe/H], respectively. Noticeable disagreements are seen mostly at the largest and smallest parameter values (e.g., in the giant star regime). Most of the $\log$(g) values derived from spectra for the platinum stars agree on average within 0.025 dex (but with a spread of 0.1-0.2 dex) with the asteroseismic $\log$(g) values. Compared to the Kepler Input Catalog (KIC), the spectroscopically derived stellar parameters agree within the uncertainties of the KIC, but are more precise and are thus an important contribution towards deriving more reliable planetary radii., Accepted by ApJ; 43 pages

We report on imaging and spectroscopic observations of comet C/2016~R2 (Pan-STARRS) obtained with the 0.8\,m and 2.7\,m telescopes of McDonald Observatory in November and December 2017 respectively. The comet was at a heliocentric distance greater than 3\,{\sc au} during both sets of observations. The images showed a well-developed tail with properties that suggested it was an ion tail. The spectra confirmed that we were observing well-developed bands of CO$^+$ and N$_2^+$. The N$_2^+$ detection was unequivocally cometary and was one of the strongest bands of N$_2^+$ detected in a comet spectrum. We derived the ratio of these two ions and from that we were able to derive that N$_2$/CO = 0.15. This is the highest such ratio reported for a comet. Note erratum - N2/CO=0.06 not 0.15., Comment: Published in ApJL 9 February 2018. This version includes an erratum on the last page after references (accepted by ApJL) on the value of N2/CO

We present analysis of high spectral resolution NIR spectra of CO and H$_2$O in comet C/2009 P1 (Garradd) taken during its 2011-2012 apparition with the CSHELL instrument on NASA's Infrared Telescope Facility (IRTF). We also present analysis of observations of atomic oxygen in comet Garradd obtained with the ARCES echelle spectrometer mounted on the ARC 3.5-meter telescope at Apache Point Observatory and the Tull Coude spectrograph on the Harlan J. Smith 2.7-meter telescope at McDonald Observatory. The observations of atomic oxygen serve as a proxy for H$_2$O and CO$_2$. We confirm the high CO abundance in comet Garradd and the asymmetry in the CO/H$_2$O ratio with respect to perihelion reported by previous studies. From the oxygen observations, we infer that the CO$_2$/H$_2$O ratio decreased as the comet moved towards the Sun, which is expected based on current sublimation models. We also infer that the CO$_2$/H$_2$O ratio was higher pre-perihelion than post-perihelion. We observe evidence for the icy grain source of H$_2$O reported by several studies pre-perihelion, and argue that this source is significantly less abundant post-perihelion. Since H$_2$O, CO$_2$, and CO are the primary ices in comets, they drive the activity. We use our measurements of these important volatiles in an attempt to explain the evolution of Garradd's activity over the apparition., 35 pages, 10 figures, 9 tables, accepted for publication in Icarus

We present a summary of the campaign of remote observations that supported the European Space Agency's Rosetta mission. Telescopes across the globe (and in space) followed comet 67P/Churyumov-Gerasimenko from before Rosetta's arrival until nearly the end of mission in September 2016. These provided essential data for mission planning, large-scale context information for the coma and tails beyond the spacecraft, and a way to directly compare 67P with other comets. The observations revealed 67P to be a relatively `well behaved' comet, typical of Jupiter family comets and with activity patterns that repeat from orbit-to-orbit. Comparison between this large collection of telescopic observations and the in situ results from Rosetta will allow us to better understand comet coma chemistry and structure. This work is just beginning as the mission ends -- in this paper we present a summary of the ground-based observations and early results, and point to many questions that will be addressed in future studies., Comment: Author prepared version; final published version available at journal. 22 pages

We present analysis of high spectral resolution optical spectra of Comet 103P/Hartley taken during its Fall 2010 apparition. These spectra include transitions belonging to CN, C2, CH, NH2, and OI. We measure production rates and mixing ratios from these spectra. We find evidence for large changes in production rates (factors of a few) over the course of a nucleus rotation, in agreement with other measurements. We also measure variability with rotational phase in the CN/H2O and C2/CN ratios, which has not been previously reported for any comet. There may also be variability in the NH2/H2O ratio with rotational phase, but this trend is not as clear as for CN/H2O. We interpret the changing mixing ratios as due to H2O and C2 being released primarily from the icy grain halo, while the CN parent molecule comes directly from the nucleus. There is evidence that the CH/CN ratio is higher pre-perihelion than post-perihelion. We conclude that the observed CN and NH2 abundances are consistent with HCN and NH3 being the dominant parent molecules for these species. The C2 and CH abundances are higher than those of candidate parent molecules (C2H2 and CH4 respectively), so there must be another source for these molecules in 103P’s coma. Carbonaceous dust grains could serve as this source.

Based on two decades of radial velocity (RV) observations using Keck/HIRES and McDonald/Tull, and more recent observations using the Automated Planet Finder, we found that the nearby star HR 5183 (HD 120066) hosts a 3$M_J$ minimum mass planet with an orbital period of $74^{+43}_{-22}$ years. The orbit is highly eccentric (e$\simeq$0.84), shuttling the planet from within the orbit of Jupiter to beyond the orbit of Neptune. Our careful survey design enabled high cadence observations before, during, and after the planet's periastron passage, yielding precise orbital parameter constraints. We searched for stellar or planetary companions that could have excited the planet's eccentricity, but found no candidates, potentially implying that the perturber was ejected from the system. We did identify a bound stellar companion more than 15,000 au from the primary, but reasoned that it is currently too widely separated to have an appreciable effect on HR 5183 b. Because HR 5183 b's wide orbit takes it more than 30 au (1") from its star, we also explored the potential of complimentary studies with direct imaging or stellar astrometry. We found that a Gaia detection is very likely, and that imaging at 10 $\mu$m is a promising avenue. This discovery highlights the value of long-baseline RV surveys for discovering and characterizing long-period, eccentric Jovian planets. This population may offer important insights into the dynamical evolution of planetary systems containing multiple massive planets., Comment: 23 pages, 12 figures. Accepted to AJ

Comet C/2016 R2 (PanSTARRS) has a peculiar volatile composition, with CO being the dominant volatile as opposed to H$_2$O and one of the largest N$_2$/CO ratios ever observed in a comet. Using observations obtained with the \textit{Spitzer Space Telescope}, NASA's Infrared Telescope Facility, the 3.5-meter ARC telescope at Apache Point Observatory, the Discovery Channel Telescope at Lowell Observatory, and the Arizona Radio Observatory 10-m Submillimeter Telescope we quantified the abundances of 12 different species in the coma of R2 PanSTARRS. We confirm the high abundances of CO and N$_2$ and heavy depletions of H$_2$O, HCN, CH$_3$OH, and H$_2$CO compared to CO reported by previous studies. We provide the first measurements (or most sensitive measurements/constraints) on H$_2$O, CO$_2$, CH$_4$, C$_2$H$_6$, OCS, C$_2$H$_2$, and NH$_3$, all of which are depleted relative to CO by at least one to two orders of magnitude compared to values commonly observed in comets. The observed species also show strong enhancements relative to H$_2$O, and even when compared to other species like CH$_4$ or CH$_3$OH most species show deviations from typical comets by at least a factor of two to three. The only mixing ratios found to be close to typical are CH$_3$OH/CO$_2$ and CH$_3$OH/CH$_4$. While R2 PanSTARRS was located at a heliocentric distance of 2.8 AU at the time of our observations in January/February 2018, we argue that this alone cannot account for the peculiar observed composition of this comet and therefore must reflect its intrinsic composition. We discuss possible implications for this clear outlier in compositional studies of comets obtained to date, and encourage future dynamical and chemical modeling in order to better understand what the composition of R2 PanSTARRS tells us about the early Solar System., 36 pages, 12 figures, 7 tables, accepted for publication in AJ

Volatile production rates, relative abundances, rotational temperatures, and spatial distributions in the coma were measured in C/2012 S1 (ISON) using long-slit high-dispersion ( λ /Δ λ ∼ 2.5 × 10 4 ) infrared spectroscopy as part of a worldwide observing campaign. Spectra were obtained on UT 2013 October 26 and 28 with NIRSPEC at the W.M. Keck Observatory, and UT 2013 November 19 and 20 with CSHELL at the NASA IRTF. H 2 O was detected on all dates, with production rates increasing markedly from (8.7 ± 1.5) × 10 27 molecules s −1 on October 26 ( R h = 1.12 AU) to (3.7 ± 0.4) × 10 29 molecules s −1 on November 20 ( R h = 0.43 AU). Short-term variability of H 2 O production is also seen as observations on November 19 show an increase in H 2 O production rate of nearly a factor of two over a period of about 6 h. C 2 H 6 , CH 3 OH and CH 4 abundances in ISON are slightly depleted relative to H 2 O when compared to mean values for comets measured at infrared wavelengths. On the November dates, C 2 H 2 , HCN and OCS abundances relative to H 2 O appear to be within the range of mean values, whereas H 2 CO and NH 3 were significantly enhanced. There is evidence that the abundances with respect to H 2 O increased for some species but not others between October 28 ( R h = 1.07 AU) and November 19 ( R h = 0.46 AU). The high mixing ratios of H 2 CO/CH 3 OH and C 2 H 2 /C 2 H 6 on November 19, and changes in the mixing ratios of some species with respect to H 2 O between October 28 to November 19, indicates compositional changes that may be the result of a transition from sampling radiation-processed outer layers in this dynamically new comet to sampling more pristine natal material as the outer processed layer was increasingly eroded and the thermal wave propagated into the nucleus as the comet approached perihelion for the first time. On November 19 and 20, the spatial distribution for dust appears asymmetric and enhanced in the antisolar direction, whereas spatial distributions for volatiles (excepting CN) appear symmetric with their peaks slightly offset in the sunward direction compared to the dust. Spatial distributions for H 2 O, HCN, C 2 H 6 , C 2 H 2 , and H 2 CO on November 19 show no definitive evidence for significant contributions from extended sources; however, broader spatial distributions for NH 3 and OCS may be consistent with extended sources for these species. Abundances of HCN and C 2 H 2 on November 19 and 20 are insufficient to account for reported abundances of CN and C 2 in ISON near this time. Differences in HCN and CN spatial distributions are also consistent with HCN as only a minor source of CN in ISON on November 19 as the spatial distribution of CN in the coma suggests a dominant distributed source that is correlated with dust and not volatile release. The spatial distributions for NH 3 and NH 2 are similar, suggesting that NH 3 is the primary source of NH 2 with no evidence of a significant dust source of NH 2 ; however, the higher production rates derived for NH 3 compared to NH 2 on November 19 and 20 remain unexplained. This suggests a more complete analysis that treats NH 2 as a distributed source and accounts for its emission mechanism is needed for future work.

Our aim is to determine the isotopic ratios {$^{12}$C/$^{13}$C}{} and {$^{14}$N/$^{15}$N}{} in a variety of comets and link these measurements to the formation and evolution of the solar system. The {$^{12}$C/$^{13}$C}{} and {$^{14}$N/$^{15}$N}{} isotopic ratios are measured {for} the CN radical by means of high-resolution optical spectra of the R branch of the B-X (0,0) violet band. {23 comets from different dynamical classes} have been observed, sometimes at various heliocentric {and nucleocentric} distances, in order to estimate possible variations of the isotopic ratios in parent molecules. The {$^{12}$C/$^{13}$C}{} and {$^{14}$N/$^{15}$N}{} isotopic ratios in CN are remarkably constant (average values of, respectively, $91.0\pm3.6$ and $147.8\pm5.7$) within our measurement errors, for all comets whatever their origin or heliocentric distance. While the carbon isotopic ratio does agree with the terrestrial value (89), the nitrogen ratio is a factor of two lower than the terrestrial value (272), indicating a fractionation in the early solar system, or in the protosolar nebula, common to all the comets of our sample. This points towards a common origin of the comets independently of their birthplaces, and a relationship between HCN and CN., 54 pages

We report on low-spectral resolution observations of comet 9P/Tempel 1 from 1983, 1989, 1994 and 2005 using the 2.7m Harlan J. Smith telescope of McDonald Observatory. This comet was the target of NASA's Deep Impact mission and our observations allowed us to characterize the comet prior to the impact. We found that the comet showed a decrease in gas production from 1983 to 2005, with the the decrease being different factors for different species. OH decreased by a factor 2.7, NH by 1.7, CN by 1.6, C$_{3}$ by 1.8, CH by 1.4 and C$_{2}$ by 1.3. Despite the decrease in overall gas production and these slightly different decrease factors, we find that the gas production rates of OH, NH, C$_{3}$, CH and C$_{2}$ ratioed to that of CN were constant over all of the apparitions. We saw no change in the production rate ratios after the impact. We found that the peak gas production occurred about two months prior to perihelion. Comet Tempel 1 is a "normal" comet., Accepted for publication in Icarus. 21 total manuscript pages including 8 tables and 4 figures

We report on the detection of atomic oxygen lines in the spectra of 8 comets. These forbidden lines are a result of the photodissociation of the parent oxygen-bearing species directly into an excited state. We used high resolution spectra obtained at the McDonald Observatory 2.7m telescope to resolve the cometary oxygen lines from the telluric oxygen lines and from other cometary emissions. We find that the relative intensities of the two red lines (6300.304 and 6363.776A) are consistent with theory. The green line (5577.339A) has an intensity which is about 10% of the sum of the intensities of the two red lines. We show that collisional quenching may be important in the inner coma. If we assume the relative excitation rates of potential parents which have appeared in the literature, then H2O would be the parent of the cometary green oxygen line. However, those rates have been questioned. We measured the width of the three oxygen lines and find that the green line is wider than either of the two red lines. The finding of a wider line could imply a different parent for the green and red lines. However, the constancy of the green to red line flux ratio suggests the parent is the same for these lines but that the exciting photons have different energies., Comment: 20 pages; 9 figures; 5 tables; Accepted for publication in Icarus

We present high precision radial velocity observations of HD17156 during a transit of its eccentric Jovian planet. In these data, we detect the Rossiter-McLaughlin effect, which is an apparent perturbation in the velocity of the star due to the progressive occultation of part of the rotating stellar photosphere by the transiting planet. This system had previously been reported by Narita et al. (2008) to exhibit a lambda = 62 +/- 25 degree misalignment of the projected planetary orbital axis and the stellar rotation axis. We model our data, along with the Narita et al. data, and obtain lambda = 9.4 +/- 9.3 degrees for the combined data set. We thus conclude that the planetary orbital axis is actually very well aligned with the stellar rotation axis., 4 pages, 1 figure, Ap.J. Letters in press

From millimeter and optical observations of the Jupiter-family comet 17P/Holmes performed soon after its huge outburst of October 24, 2007, we derive 14 N/15N = 139 +/- 26 in HCN, and 14N/15N = 165 +/- 40 in CN, establishing that HCN has the same non-terrestrial isotopic composition as CN. The same conclusion is obtained for the long-period comet C/1995 O1 (Hale-Bopp) after a reanalysis of previously published measurements. These results are compatible with HCN being the prime parent of CN in cometary atmospheres. The 15N excess relative to the Earth atmospheric value indicates that N-bearing volatiles in the solar nebula underwent important N isotopic fractionation at some stage of Solar System formation. HCN molecules never isotopically equilibrated with the main nitrogen reservoir in the solar nebula before being incorporated in Oort-cloud and Kuiper-belt comets. The 12C/13C ratios in HCN and CN are measured to be consistent with the terrestrial value., Comment: Accepted for publication in the Astrophysical Journal (Letters) 4 pages

This paper is the result of the International Cometary Workshop, held in Toulouse, France in April 2014, where the participants came together to assess our knowledge of comets prior to the ESA Rosetta Mission. In this paper, we look at the composition of the gas and dust from the comae of comets. With the gas, we cover the various taxonomic studies that have broken comets into groups and compare what is seen at all wavelengths. We also discuss what has been learned from mass spectrometers during flybys. A few caveats for our interpretation are discussed. With dust, much of our information comes from flybys. They include {\it in situ} analyses as well as samples returned to Earth for laboratory measurements. Remote sensing IR observations and polarimetry are also discussed. For both gas and dust, we discuss what instruments the Rosetta spacecraft and Philae lander will bring to bear to improve our understanding of comet 67P/Churyumov-Gerasimenko as "ground-truth" for our previous comprehensive studies. Finally, we summarize some of the initial Rosetta Mission findings., Comment: To appear in Space Science Reviews

We report on observations of comet 9P/Tempel 1 carried out before, during, and after the NASA DEEP IMPACT event (UT July 4), with the optical spectrometers UVES and HIRES mounted on the telescopes Kueyen of the ESO VLT (Chile) and Keck 1 on Mauna Kea (Hawaii), respectively. A total observing time of about 60 hours, distributed over 15 nights around the impact date, allowed us (i) to find a periodic variation of 1.709 +/- 0.009 day in the CN and NH flux, explained by the presence of two major active regions; (ii) to derive a lifetime > ~ 5 x 10^4 s for the parent of the CN radical from a simple modeling of the CN light curve after the impact; (iii) to follow the gas and dust spatial profiles evolution during the 4 hours following the impact and derive the projected velocities (400 m/s and 150 m/s respectively); (iv) to show that the material released by the impact has the same carbon and nitrogen isotopic composition as the surface material (12C/13C = 95 +/- 15 and 14N/15N = 145 +/- 20).

High-resolution (R ~ 60,000) spectra of the CN B 2Σ+-X 2Σ+ (0, 0) band (near 3880 A) in the Halley-type comet 122P/1995 S1 de Vico (with a period of 74 yr) and the "intermediate-period" comet 153P/2002 C1 Ikeya-Zhang (P ~ 370 yr) were obtained with the 2dcoude spectrograph at the 2.7 m Harlan J. Smith telescope of the McDonald Observatory. The comets were within 1 AU from the Sun (0.66 and 0.92 AU, respectively) at the time of the observations. While the measured 12C/13C isotope ratios of both comets (90 ± 10 and 90 ± 25, respectively) are in very good agreement with the solar system value, the 14N/15N ratios (140 ± 20 and 170 ± 50, respectively) are approximately half the value in Earth's atmosphere. The similarity is striking between these ratios and those obtained recently for two other long-period Oort Cloud comets, C/1995 O1 (Hale-Bopp) and C/2000 WM1 (LINEAR). While these optical determinations of 14N/15N are consistent with each other, they disagree with those obtained in comet Hale-Bopp from submillimeter measurements of HCN, generally believed to be the main parent of CN. This puzzling difference points toward the existence of (an)other unknown parent(s) of CN, with an even higher 15N excess. Organic compounds like those found in interplanetary dust particles are good candidates.

The Comet Nucleus Tour (CONTOUR) is a low-cost NASA Discovery mission designed to conduct three close flybys of comet nuclei. Selected configuration tradeoffs conducted to balance science requirements with low mission cost are reviewed. The tradeoffs discussed focus on the optical instruments and related spacecraft considerations. Two instruments are under development. The CONTOUR Forward Imager (CFI) is designed to perform optical navigation, moderate resolution nucleus/jet imaging, and imaging of faint molecular emission bands in the coma. The CONTOUR Remote Imager and Spectrometer (CRISP) is designed to obtain high-resolution multispectral images of the nucleus, conduct spectral mapping of the nucleus surface, and provide a backup optical navigation capability. Tradeoffs discussed are: (1) the impact on the optical instruments of not using reaction wheels on the spacecraft, (2) the improved performance and simplification gained by implementing a dedicated star tracker instead of including this function in CFI, (3) the improved flexibility and robustness of switching to a low frame rate tracker for CRISP, (4) the improved performance and simplification of replacing a visible imaging spectrometer by enhanced multispectral imaging in CRISP, and (5) the impact on spacecraft resources of these and other tradeoffs.

We report low- and high-resolution spectra of comet C/2002 C1 (Ikeya-Zhang) from McDonald Observatory. The comet had a well-developed ion tail including CO+, CO2+, CH+, and H2O+. We used our high-resolution spectra to search for N2+. None was detected and we placed upper limits on N2+/CO+ of 5.4 times 10^{-4}. N2+ was detected in the low-resolution spectra but we show that this emission was probably telluric in origin (if cometary, we derive N2+/CO+ = 5.5 times 10^{-3}, still very low). We discuss the implications for the conditions in the early solar nebula of the non-detection of N2+. These depend on whether the H2O ice was deposited in the amorphous or crystalline form. If H2O was deposited in its crystalline form, the detection of CO+ but not N2+ has implications for H2O/H2 in the early solar nebula.

We performed high-dispersion near-infrared spectroscopic observations of comet C/2010 G2 (Hill) at 2.5 AU from the Sun using NIRSPEC (R ≈ 25,000) at the Keck II Telescope on UT 2012 January 9 and 10, about a week after an outburst had occurred. Over the two nights of our observations, prominent emission lines of CH{sub 4} and C{sub 2}H{sub 6}, along with weaker emission lines of H{sub 2}O, HCN, CH{sub 3}OH, and CO were detected. The gas production rate of CO was comparable to that of H{sub 2}O during the outburst. The mixing ratios of CO, HCN, CH{sub 4}, C{sub 2}H{sub 6}, and CH{sub 3}OH with respect to H{sub 2}O were higher than those for normal comets by a factor of five or more. The enrichment of CO and CH{sub 4} in comet Hill suggests that the sublimation of these hypervolatiles sustained the outburst of the comet. Some fraction of water in the inner coma might exist as icy grains that were likely ejected from nucleus by the sublimation of hypervolatiles. Mixing ratios of volatiles in comet Hill are indicative of the interstellar heritage without significant alteration in the solar nebula.

Theoretical resonance fluorescence calculations are presented of the triatomic C3 radical and are compared with observations of the C3 emission in comets Hale-Bopp and de Vico. A theoretical model of the C3 vibration-rotational structure in the electronic system is introduced. The model takes into account the detailed structure of the bending mode which is responsible for the emission of the 4050 Agroup. A total of 1959 levels are considered, with 515 levels in the ground state. The main effort is to model high-resolution spectra of the 4050 A emission in comets C/1995 O1 Hale-Bopp and 122P/1995 S1 de Vico. The agreement between observed and theoretical spectra is good for a value of the dipole moment derivative of Debye A-1 . The modeled C3 emission exhibits a pronounced Swings effect.

Very high resolution (R~200,000) and high signal-to-noise echelle spectra were obtained of comet Hyakutake (C/1996 B2) using the 2D coude spectrograph on the 2.7 m telescope at W. J. McDonald Observatory during 1996 in late March and early April. Doppler resolved profiles are presented for individual lines of the major optical neutral species: CN, C2, NH2, O1D) at 6300 A, and H Balmer-α at 6563 A. They are consistent with the expected expansion of a water-dominated cometary coma. Because of the small aperture and the small geocentric distance of the comet, the profiles of CN, C2, and NH2 are totally shaped by the outflowing hydrodynamic coma. The NH2 is the narrowest of the group because of the very short lifetime of the NH2 parent (NH3. The profile of C2 is somewhat broadened, compared with NH2, because of the relatively larger contribution of C2 radicals farther from the nucleus where the bulk outflow speed is larger. Any exothermic ejection speed they receive upon their production would be quenched. Although the profile of CN is broader than C2, this is due to the fact that most of the CN lines are blends of two closely spaced but nearly equal strength components. Because O1D) atoms in the region samples are produced mainly by the photodissociation of water which results in a prompt emission photon, the line retains contributions of both the basic coma expansion velocity and the 1.6 km s-1 exothermal ejection speed of the O1D) atoms. The H Balmer-α line is complicated by a chance coincidence of a line of H2O+ and/or NH2 and by optical depth effects in solar Lyβ which are primarily responsible for the Balmer-α excitation. However, the width of the line wings is consistent with other comet observations, including Hyakutake itself, and the production by dissociation of H2O and OH and partial thermalization. We have successfully reproduced these data using a hybrid kinetic/hydrodynamic and Monte Carlo approach which include the important physical/chemical processes which can shape the spectral lines. Because the model includes no adjustable fitting parameters, the model-data agreement indicates that the underlying assumptions and calculated coma outflow speeds are quite reasonable.

The limiting magnitude of the Hubble Space Telescope (HST) data set used by Cochran and coworkers in 1995 to detect small objects in the Kuiper belt is reevaluated, and the methods used are described in detail. It is shown, by implanting artificial objects in the original HST images and rereducing the images using our original algorithm, that the limiting magnitude of our images (as defined by the 50% detectability limit) is V=28.4. This value is statistically the same as the value found in the original analysis. We find that ~50% of the moving Kuiper belt objects with V=27.9 are detected when trailing losses are included. In the same data in which these faint objects are detected, we find that the number of false detections brighter than V=28.8 is less than one per WFPC2 image. We show that, primarily due to a zero-point calibration error, but partly due to inadequacies in modeling the HST's data noise characteristics and Cochran and coworkers' reduction techniques, Brown and coworkers in 1997 underestimated the signal-to-noise ratio of objects in the HST data set by over a factor of 2, and their conclusions are therefore invalid.

A comparison has been made between the unidentified spectral lines of comet 122P/de Vico and observed dispersed fluorescence spectra in the UV and visible region from jet cooled CS2. Twenty-eight lines of the spectral atlas of this comet have been identified as originating from emission of CS2 when this molecule is excited by solar radiation in the near-ultraviolet region of the spectra. This work proves the presence of CS2 in comets and points to a new method for identifying parent molecules in comets.

Targets within the solar system generally fall into one of two types: a) major planets (except Pluto) and our Moon; b) minor planets, comets, Pluto and planetary satellites. The first group is noteworthy for being reasonably bright. Most are also spatially extended. The inner planets never achieve large solar elongation. The second group comprises bodies which are generally faint. Comets are spatially extended. The minor planets and comets may be in orbits which are highly inclined or viewed at small solar elongations. Comets may even be in retrograde orbits. Planetary satellites may be bright or faint but suffer from being in the glare of the parent planet.

We propose a scenario that explains the apparent nitrogen deficiency in comets in a way consistent with the fact that the surfaces of Pluto and Triton are dominated by nitrogen-rich ice. We use a statistical thermodynamic model to investigate the composition of the successive multiple guest clathrates that may have formed during the cooling of the primordial nebula from the most abundant volatiles present in the gas phase. These clathrates agglomerated with the other ices (pure condensates or stoichiometric hydrates) and formed the building blocks of comets. We report that molecular nitrogen is a poor clathrate former, when we consider a plausible gas phase composition of the primordial nebula. This implies that its trapping into cometesimals requires a low disk temperature ($\sim$20 K) in order to allow the formation of its pure condensate. We find that it is possible to explain the lack of molecular nitrogen in comets as a consequence of their postformation internal heating engendered by the decay of short-lived radiogenic nuclides. This scenario is found consistent with the presence of nitrogen-rich ice covers on Pluto and Triton. Our model predicts that comets should present xenon-to-water and krypton-to-water ratios close to solar xenon-to-oxygen and krypton-to-oxygen ratios, respectively. In contrast, the argon-to-water ratio is predicted to be depleted by a factor of $\sim$300 in comets compared to solar argon-to-oxygen, as a consequence of poor trapping efficiency and radiogenic heating., Comment: Accepted for publication in The Astrophysical Journal