1. Gram-Scale One-Pot Synthesis of Highly Luminescent Blue Emitting Cd1−xZnxS/ZnS Nanocrystals.
- Author
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Wan Ki Bae, Min Ki Nam, Kookheon Char, and Seonghoon Lee
- Subjects
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NANOCRYSTALS , *CONCHOLOGISTS , *BODY covering (Anatomy) , *DATA transmission systems - Abstract
We demonstrated a facile synthesis of highly luminescent blue emitting Cd 1− xZn xS/ZnS core/shell structured nanocrystals (NCs) in straightforward and reproducible manner. The alloyed Cd 1− xZn xS cores with homogeneity in both size and composition were prepared by introducing S precursors (S dissolved in the noncoordinating solvent (1-octadecene)) into the mixed solution of Cd−Oleate (Cd(OA) 2) and Zn−Oleate (Zn(OA) 2) at elevated temperature (300 °C). ZnS shells were successively overcoated on the prepared cores by the second injection of S precursors (S powder dissolved in tributylphosphine, TBPS) directly into the reactor with existing alloyed Cd 1− xZn xS NC cores without any purification steps. The prepared NCs exhibit strong band edge emission with high photoluminescent quantum yield (PL QY, up to 80%) and narrow spectral bandwidth (fwhm < 25 nm), which is believed to originate from the successful growth of ZnS shell layers on the Cd 1− xZn xS cores and the interfacial compatibility between Cd 1− xZn xS cores and the ZnS shell layers through the intradiffusion of Zn atoms from the ZnS shells into the Cd 1− xZn xS cores during the shell formation reaction. The emission wavelength (PL λ max.) of Cd 1− xZn xS/ZnS core/shell NCs was finely tuned from violet (415 nm) to blue (461 nm) by adjusting the amount of S precursors in the first injection (S in 1-octadecene) and thus changing actual Cd content ratio in the alloyed Cd 1− xZn xS cores (0.49 ≤ x≤ 0.76). Furthermore, multigram (3 g) scale production of Cd 1− xZn xS/ZnS core/shell NCs with narrow size distribution and spectral bandwidth was also demonstrated. [ABSTRACT FROM AUTHOR]
- Published
- 2008
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