1. Photoelectrochemical and photo-Fenton properties of ZnFe2O4@g-C3N4 nanocomposites.
- Author
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Li, Zhiming, Wei, Zhiqiang, Ding, Meijie, Zhao, Jiwei, Yu, Qingsong, and Zhou, Meipan
- Subjects
ELECTRON paramagnetic resonance ,SILVER ,NANOCOMPOSITE materials ,HYDROXYL group ,VISIBLE spectra ,CATALYTIC activity ,PHOTOELECTROCHEMICAL cells ,HETEROJUNCTIONS - Abstract
In the social context of increasing water pollution, we conducted an in-depth study to prepare ZnFe
2 O4 @g-C3 N4 heterojunction nanocomposites by hydrothermal method. The microscopic morphology and structure were analyzed using XRD, SEM, TEM, UV–Vis, and other characterization methods. The photo-Fenton activity of the highly concentrated antibiotic tetracycline was tested under visible light irradiation in combination with the presence of H2 O2 , and the catalytic mechanism was investigated. The results showed that the construction of heterojunction significantly improved the catalytic activity of ZnFe2 O4 @g-C3 N4 catalyst prepared by hydrothermal method. The degradation rate of tetracycline at 40 mg L−1 was 92.6% within 60 min, and the degradation rate was 0.06 min−1 , which was nearly six times higher than that of pure ZnFe2 O4 . The results of free radical trapping experiments and electron spin resonance technique indicated that hydroxyl radicals (·OH) and superoxide radicals (·O2 − ) played important roles in the photo-Fenton degradation of tetracycline. Notably, the catalyst maintained a high degradation rate (87.2%) after five cycles. The heterojunction designed in this thesis may provide a promising strategy for achieving maximum light absorption and is authoritative in meeting environmental requirements in the future. [ABSTRACT FROM AUTHOR]- Published
- 2024
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