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New carbon isotopic data from the Devonian of Ardennes (Belgium) and partly from the Holy Cross Mountains (Poland) highlight an abrupt and high-amplitude negative excursion in the punctata conodont Zone. Published information from Moravia and China suggests that this Middle Frasnian negative excursion, jointly with the preceding large-scale positive shift, should be used as a global chemostratigraphic marker. Causation scenarios for this negative 'punctata Event' are correlated neither with major biota turnover nor major sea-level changes, but may be related to: (1) the Alamo Impact Event, that led to (2) the massive dissociation of methane hydrates and (3) the rapid onset of global warming. Keywords: punctata Event, Frasnian, carbon isotopes, Ardennes, Belgium.

Five varieties of Belgian black marbles are investigated in order to discriminate them. Their age ranges from Frasnian (Golzinne) to Visean (Dinant, Theux, Basècle, Lives). Three methods were used: petrography, magnetic susceptibility and geochemistry of major elements and Rare Earth Elements (REE). The petrographic analyze reveals 16 microfacies reflecting very quiet environments, sporadically perturbed by more energetic phenomena like turbidites or storms. These microfacies are integrated in two depositional models: a quiet offshore setting, below or close to the storm wave base (Salet, Basècles) and a shallow but very restricted zone, protected from waves and currents (Lives and Golzinne). The magnetic susceptibility results show that all the black marbles are characterized by very low, even slightly negative values, except the Golzinne one which shows higher values. Geochemical data allow to discriminate between the Theux black marble (low SiO2 content), and the Basècles samples (low Al2O3, K2O and REE contents). These methods could be useful to determine/refine the origin of archaeological stones, even if all these analyses are destructive. Two archeologic samples were investigated in order to identify their possible origin. [ABSTRACT FROM AUTHOR]

Describes a case regarding the removal of a knotted flow-directed catheter by a nonsurgical method. Medical profile of the patient; Background on catheter knotting; Description of the nonsurgical technique performed during the surgery.

Abstract: The northern part of the N–S-trending basin of the Limagne graben, located in the northern part of the Massif Central (France), contains Oligocene and Miocene calcareous lacustrine deposits. The area is known for its stromatolite reefs surrounded by marl, clay and uncemented carbonate sand with oncolites. Because the origin of the carbonate accumulated by cyanobacteria has long been debated, the clayey deposits associated with the stromatolites were analysed using XRD, SEM and K–Ar dating methods. The results show a monotonous assemblage of carbonates, dioctahedral smectite, illite–smectite (Reichweite) R=0, glauconitic illite and abundant orthoclase. Detrital minerals such as quartz and detrital illite are found near the basin''s borders but are very scarce in its central part, indicating a lack of detrital input from the regional basement. Hence, the abundant orthoclase found in all the clayey deposits of the Limagne Basin cannot be linked to erosion of the surrounding Hercynian basement. The SEM analysis showed the orthoclase crystals to have a tabular morphology with sharp boundaries and to be embedded within a clay matrix, whilst the K–Ar dating of the orthoclase and glauconitic illite yielded ages ranging from 90 to 66±2Ma, i.e. Turonian to Maastrichtian. These two results clearly indicate that the fill of the Limagne Basin, composed mainly of carbonate, clay and orthoclase, must have been partly due to the erosion of an Upper Cretaceous sedimentary blanket once covering the Massif Central basement. This cover was probably constituted of chalk, dioctahedral smectite, I/S and glauconitic illite, associated with authigenic orthoclase and flint. Flints are found reworked in the alluvial formations of the Late Pliocene Lower Bourbonnais sands and clays (‘Sables et argiles du Bourbonnais’) and in the Pleistocene terraces. Moreover, relicts of the Upper Cretaceous cover were preserved during the sedimentary filling of the Cenozoic Limagne Basin. Authigenic orthoclase of similar shape has been described in the Chalk Group of the Paris Basin and from localities in northern France and Belgium. The mineral is rare in the Turonian chalk but increases rapidly at the base of the Coniacian to Campanian chalk; it has also been noted that the number of orthoclase crystals increases as the quantity of clastic components decreases. Similar orthoclase crystals were found associated with dioctahedral smectite in the decarbonated residues of the Coniacian to Santonian chalk from Fécamp and Etretat (northern France). Moreover, our results are consistent with other data from within and around the Paris Basin, such as the palaeogeography and facies distribution of the Chalk formations, the residual flints in the clay-with-flints of the southern Paris Basin and around the Morvan, and apatite fission-track thermochronology data from the Hercynian basement of the Massif Central and the Morvan. All these data indicate a major connection between the Paris Basin and the Tethys, and an extensive palaeocover on the Massif Central and Morvan basement. [Copyright &y& Elsevier]