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Separation membranes with homogeneous charge channels are the mainstream to reject charged mass by forming electrical double layer (EDL). However, the EDL often compresses effective solvent transport space and weakens channel‐ion interaction. Here, built‐in electric fields (BIEFs) are constructed in lamellar membranes by assembling the heterostructured nanosheets, which contain alternate positively‐charged nanodomains and negatively‐charged nanodomains. We demonstrate that the BIEFs are perpendicular to horizontal channel and the direction switches alternately, significantly weakening the EDL effect and forces ions to repeatedly collide with channel walls. Thus, highly efficient rejection for charged mass (salts, dyes, and organic acids/bases) and ultrafast water transport are achieved. Moreover, for desalination on four‐stage filtration option, salt rejection reaches 99.9 % and water permeance reaches 19.2 L m−2 h−1 bar−1. Such mass transport behavior is quite different from that in homogeneous charge channels. Furthermore, the ion transport behavior in nanochannels is elucidated by validating horizontal projectile motion model. [ABSTRACT FROM AUTHOR]

The GLK gene family plays a crucial role in the regulation of chloroplast development and participates in chlorophyll synthesis. However, the precise mechanism by which GLK contributes to citrus's chlorophyll synthesis remains elusive. The GLK gene family causes variations in the photosynthetic capacity and chlorophyll synthesis of different citrus varieties. In this study, we identified tissue-specific members and the key CcGLKs involved in chlorophyll synthesis. A total of thirty CcGLK transcription factors (TFs) were discovered in the citrus genome, distributed across all nine chromosomes. The low occurrence of gene tandem duplication events and intronic variability suggests that intronic variation may be the primary mode of evolution for CcGLK TFs. Tissue-specific expression patterns were observed for various GLK family members; for instance, CcGLK12 and CcGLK15 were specifically expressed in the skin, while CcGLK30 was specific to the ovary, and CcGLK10, CcGLK6, CcGLK21, CcGLK2, CcGLK18, CcGLK9, CcGLK28, and CcGLK8 were specifically expressed in the leaves. CcGLK4, CcGLK5, CcGLK11, CcGLK23, CcGLKl7, CcGLK26, and CcGLK20 may participate in the regulation of the ALA, prochlorophylate, protoporphyrin IX, Mg-protoporphyrin IX, Chl b, T-Chl, MG-ProtoIX ME, and POR contents in citrus. [ABSTRACT FROM AUTHOR]

Radio frequency fingerprint identification (RFFI) is a promising technique for smartphone identification. However, we find that the temperature of the RF front end in smartphones can significantly impact the RF features, including the carrier frequency offset (CFO) and statistical RF features. The unstable RF features caused by temperature changes can negatively affect the performance of state-of-the-art RFFI approaches. To this end, we propose the RF-TESI solution for smartphone identification under temperature variation. First, we construct a dataset by extracting temperature and RF features. In the dataset, the extracted temperature values constitute a set of temperature values and each registered temperature value corresponds to a group of RF features. Next, we evaluate the distinctiveness of RF features across smartphones to select the most suitable RF fingerprint. Then, we train multiple random forest models, each tagged with a registered temperature. In addition, because there are still many temperatures out of the temperature set, we design an RF fingerprint estimation method to estimate RF fingerprints at unregistered temperatures. Finally, the experiments show RF-TESI demonstrates satisfactory performance under different scenarios, taking into account variations in temperature, time and position. Besides, our proposed approach is better than all state-of-the-art approaches in smartphone identification. [ABSTRACT FROM AUTHOR]

Lithium–sulfur (Li–S) batteries are one of the most promising next-generation energy storage systems due to their ultrahigh theoretical specific capacity. However, the sluggish redox kinetics and shuttle effect of lithium polysulfide of sulfur cathodes remain obstacles to their development. Herein, we synthesize a thin laminar composite TpPa-SO3H/2-Methylol-15-crown-5 solid-state electrolyte (TpPa-SO3H/15-C-5-OH SSE) by encapsulating the crown ether into nanoscale pores (1.2 nm) of TpPa-SO3H covalent organic framework (COF) through low-pressure filtration. Importantly, the hydrogen-bonding interaction between TpPa-SO3H COF and 15-C-5-OH largely enhances the stable existence of 15-C-5-OH in pores of TpPa-SO3H COF. The 15-C-5-OH confined in pores of TpPa-SO3H COF can form a long-range ordered cavity channel for effective Li+ transport. This endows TpPa-SO3H/15-C-5-OH SSE with high ionic conductivity of 1.31 × 10–5 S cm–1 at 30 °C and satisfactory Li+ transference number (tLi+) of 0.75. In addition, the negative charge of the sulfonate group on the TpPa-SO3H COF can repel the polysulfide anions efficiently through an electrostatic repulsion interaction, thereby blocking the migration of polysulfide. As a result, the Li–S battery with TpPa-SO3H/15-C-5-OH SSE presents superior cycling stability, which preserves a capacity of 739.9 mA h g–1 with a retention of 82.9% after 400 cycles at 60 and 0.5C. [ABSTRACT FROM AUTHOR]

Purpose: Healthcare professionals (HCP) perform various needle procedures that can be distressing and painful for children and adults. Even though many strategies have been proven effective in reducing distress and pain, topical anesthetic use before needle procedures is uncommon. However, there are limited studies in the existing literature comparing specifically liposomal lidocaine and tetracaine hydrochloride topical creams. Source: This systematic review analyzed studies on the use of two anesthetic creams, Liposomal Lidocaine (Maxilene®) and Tetracaine hydrochloride (AmetopTM), in children and adults undergoing a needle-related procedure. Databases searched: PubMed, CINAHL, ClinicalTrials. Only randomized controlled trials (RCT) and Controlled Clinical Trials (CCT) studies were included. Cochrane Collaboration's Risk of Bias assessment tool was used. Strictly minimally invasive procedures were included to standardize different skin needle interventions. Principal findings: Only one study with 60 participants was available to be included in this review. No statistically significant difference was found in the mean pain score among both interventions. The outcomes of selfreported distress during cannulation and on HCP satisfaction were not reported. However, physiological characteristics associated with stress/ anxiety and on cannulation success rate were reported and did not show statistical significance. Conclusion: Little to no evidence regarding the most efficient cream between liposomal lidocaine and tetracaine hydrochloride for pain management during needle-related procedures was found. Further studies, particularly RCT with larger sample sizes and standardized outcome measures, are needed to confirm the relative efficacy of either anesthetic cream. [ABSTRACT FROM AUTHOR]