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The sedimentary sequence in Scladina Cave (Belgium) is well-known for its rich Middle Paleolithic assemblages and its numerous faunal remains. Of particular interest is the presence of a nearly complete mandible of a Neandertal child. To place all these finds in the correct chronostratigraphic context, various dating techniques have been applied over the past decades. This resulted in a reasonably well-constrained age model, roughly spanning the last glacial cycle. Age constraints of the lower part of the Scladina sequence as well as from the underlying Sous-Saint-Paul Cave were however absent until now. Previous attempts to date several speleothem layers in Scladina Cave, using U-Th dating were only partly successful, presumably because diagenetic alteration of speleothem material compromised the ages. In the present study we re-assessed U-Th dating of various speleothem levels in Scladina Cave, applying state-of-the-art U-Th dating, and carefully selecting material that experienced little to no diagenetic alteration. The new results constitute a robust age framework for the Scladina sequence, which provides precisely dated stratigraphic anchor points that improve the previous age model. Furthermore, new U-Th analyses, for speleothems from the lower part of the Scladina sequence and from the Sous-Saint-Paul sequence, document Middle Pleistocene ages, making this one of the longer fossil-rich cave sedimentary sequences in NW Europe. The new data confirm that speleothem deposition predominantly took place in periods of warmer climate, while siliciclastic sediments characterize the colder intervals. New speleothem ages further suggest that the Neandertal mandible found in the sequence, and previously placed in Marine Isotope Stage 5a or 5b, could potentially be as old as Marine Isotope Stage 5d. [ABSTRACT FROM AUTHOR]

We present a 500‐year precipitation‐sensitive record based on co‐varying speleothem δ18O values and Mg/Ca ratios from Larga cave in Puerto Rico. This multi‐proxy record shows that the evolution of rainfall in the northeastern Caribbean was characterized by alternating centennial dry and wet phases corresponding to reduced versus enhanced convective activity. These phases occurred synchronous with relatively cool and warm tropical Atlantic sea‐surface temperatures (SSTs), respectively. While the observed pattern suggests a close link of northeastern Caribbean rainfall to the Atlantic Multidecadal Variability, a regional comparison reveals intermittent regional heterogeneity especially on decadal timescales, which may be related to a superimposing influence of the Pacific and Atlantic basins. Furthermore, the speleothem‐based hydroclimate reconstruction indicates a significant volcanic impact during the past two centuries, and further reveals a potential solar signal in the preceding three centuries. We posit that the forcing likely shifted from solar to volcanic during the eighteenth century in being an important source of multidecadal to centennial Caribbean rainfall variability. The link between convective rainfall and natural forcing may be explained through a modulation of SST variations in the tropical Atlantic and Pacific oceans. Plain Language Summary: Climate change is expected to affect rainfall throughout the Caribbean and Central America, where over 200 million people are heavily dependent upon rain as their main source of freshwater. We have looked at how the amount of rainfall in the Caribbean has changed through time, and possible reasons for these changes, to inform predictions of future rainfall patterns for the region. Cave mineral deposits, also known as speleothems, can be used to assess the amount of regional rainfall in the past by looking at their slight changes over time in the mineral's chemical composition. We created a record of Caribbean rainfall spanning the last five centuries using a speleothem from Puerto Rico. Our results indicate that rainfall changes since the sixteenth century were strongly influenced by changes in temperatures of the surface waters of the Atlantic Ocean. We further found that changes in the sun's brightness and volcanic eruptions may alter Atlantic Ocean sea‐surface temperature, which in turn affect the overall changes in Caribbean rainfall patterns. Key Points: Speleothem‐based Puerto Rican rainfall reconstruction shows prominent multidecadal‐to‐centennial variability during the past five centuriesPuerto Rican rainfall fluctuations are linked to solar variations before the eighteenth century and volcanic forcing thereafterCaribbean Sea‐surface temperature anomalies as part of the Atlantic Multidecadal Variability emerge as robust precursor of rainfall amounts [ABSTRACT FROM AUTHOR]

A speleothem collected from Palco Cave (Puerto Rico) spans the 8.2 ka event, a time interval associated with fluctuations of Atlantic Ocean circulation and possible drying in the Caribbean region. While stalagmite δ18O, δ13C, and Mg/Ca data do not show a sustained change in mean state over the 8.2 ka event, the proxies provide robust evidence for three abrupt fluctuations toward drier conditions in rapid succession, each lasting less than two decades, occurring at 8.20, 8.14, and 8.02 ka BP. A cave monitoring program at Palco Cave supports the interpretation of the speleothem proxy records. Because changes in the position of the Intertropical Convergence Zone (ITCZ) are directly coupled to sea-surface temperature variations in the North Atlantic, we hypothesize that cold events in the North Atlantic temporarily limited the northward migration of the ITCZ and tropical rain belt in boreal summer during these abrupt drying periods. The speleothem record suggests that the 8.2 ka event was associated with rapid rainfall fluctuations in the northern Caribbean followed by a comparably warm and wet phase after the 8.2 ka event. This enhanced variability during the transitional period of the deglaciation appears to be linked to a fast coupling between interacting oceanic and atmospheric processes. This involves, in particular, the Atlantic Meridional Overturning Circulation in modulating interhemispheric heat transport. [ABSTRACT FROM AUTHOR]

On glacial‐interglacial time scales, changes in the Earth's orbital configuration control climate seasonality and mean conditions. Tropical coral skeletons can be sampled at a sufficient resolution to reconstruct past seasonality. Here, last deglacial Porites skeletons from Integrated Ocean Drilling Program Expedition 310 to Tahiti are investigated and, supported by a modern calibration, monthly resolved time series in geochemical proxies (Sr/Ca, δ18O, δ13C) are constructed. For most of the deglaciation, Sr/Ca seasonality was similar to modern (0.139 ± 0.010 mmol mol−1; 2.8 ± 0.2°C) reflecting the small change in insolation seasonality. However, during the Younger Dryas, high values in Sr/Ca seasonality (0.171 ± 0.017 mmol mol−1; 3.4 ± 0.3°C) suggest a reduced mixed layer depth and enhanced influence of the South Pacific Subtropical Gyre due to South Pacific Convergence Zone (SPCZ) inactivity. Furthermore, high amplitudes in Younger Dryas skeletal δ18O (0.40 ± 0.22 ‰) and δ13C (0.86 ± 0.22 ‰) seasonality compared to modern (δ18O = 0.29 ± 0.08 ‰; δ13C = 0.27 ± 0.08 ‰) point to elevated winter‐summer discrepancies in rainfall and runoff. Mean coral Sr/Ca variability suggests an influence of Northern Hemisphere climate events, such as the Younger Dryas cooling (+0.134 ± 0.012 mmol mol−1;−2.6 ± 0.2°C), or the Bølling–Allerød warming (+0.032 ± 0.040 mmol mol−1; −0.6 ± 0.4°C). Deglacial mean coral Δδ18O (δ18Oseawater contribution to skeletal δ18O), corrected for the ice volume effect, was elevated pointing to more saline, thus dryer conditions, likely due to a northward migration of the SPCZ. Seasonal cycles in coral δ13C were likely caused by variations in linear extension rates that were reduced during the last deglaciation (1.00 ± 0.6 cm year−1) compared to today (1.6 ± 0.3 cm year−1). Plain Language Summary: Changes in the Earth's movement around the sun are the primary cause of changes in the annual cycle and annual mean of environmental conditions during the last glacial‐interglacial periods. Distinct from most climate archives, the annual bands of coral skeletons can be sampled at a monthly resolution that allows for reconstructions of past seasonal cycles. In this study, the chemical composition of coral skeletons from the genus Porites that grew during the last deglaciation at Tahiti (∼15,000–9,000 years ago) was analyzed to infer seasonal variations and mean conditions in past sea surface temperature and salinity. Prior to application, the methods were successfully calibrated using modern coral skeletons from Tahiti. Results showed that sea surface temperature seasonality was similar to today during most of the deglaciation. However, for the Younger Dryas, a particular cold interval, a marked increase in sea surface temperature seasonality suggests that Tahiti was at that time located outside the South Pacific Convergence Zone, a rain band extending across the tropical Southwest Pacific. Furthermore, coral reconstructions revealed that, although distant, North Atlantic last deglacial climate events influenced mean climate conditions at Tahiti. In addition, we show that last‐deglacial coral growth rates were reduced compared to today. Key Points: Last deglacial changes in Tahiti coral Sr/Ca suggest an influence of Northern‐Hemisphere climate events on the tropical South PacificVariations in last deglacial Tahitian climate were modulated by meridional migrations of the South Pacific Convergence ZoneLast deglacial Porites corals revealed reduced linear extension rates (1.0 ± 0.6 cm year−1) compared to today (1.6 ± 0.3 cm year−1) [ABSTRACT FROM AUTHOR]

The carbon isotopic signature inherited from soil and epikarst processes may be modified by degassing and prior calcite precipitation (PCP) before its imprint on speleothem calcite. Despite laboratory demonstration of PCP effects on carbon isotopes and increasingly sophisticated models of the governing processes, to date, there has been limited effort to deconvolve the dual PCP and soil–epikarst components in measured speleothem isotopic time series. In this contribution, we explore the feasibility, advantages, and disadvantages of using trace element ratios and δ44 Ca to remove the overprinting effect of PCP on measured δ13 C to infer the temporal variations in the initial δ13 C of drip water prior to degassing and PCP. In nine examined stalagmites, the most widely utilized PCP indicators Mg/Ca and δ44 Ca covary as expected. However, Sr / Ca does not show consistent relationships with δ44 Ca so PCP is not the dominant control on Sr / Ca. From δ44 Ca and Mg/Ca , our calculation of PCP as fCa , the fraction of initial Ca remaining in solution at the time the stalagmite layer is deposited, yields multiple viable solutions depending on the assumed δ44 Ca fractionation factor and inferred variation in DMg. Uncertainty in the effective fractionation of δ13 C during degassing and precipitation contributes to uncertainty in the absolute value of estimated initial δ13 C. Nonetheless, the trends in initial δ13 C are less sensitive to these uncertainties. In coeval stalagmites from the same cave spanning the 94 to 82 ka interval, trends in calculated initial δ13 C are more similar than those in measured δ13 C and reveal a common positive-anomaly initial δ13 C during a stadial cooling event. During deglaciations, calculated initial δ13 C implies a trend of greater respiration rates and higher soil CO 2 , although the higher interglacial drip water saturation favors more extensive PCP. Initial δ13 C can be estimated for active and fossil speleothems from a range of settings, wherever there is confidence that Mg/Ca and/or δ44 Ca provides a quantitative indication of past changes in PCP. Further study of Mg partitioning in speleothems will improve the robustness of Mg/Ca as a PCP proxy. [ABSTRACT FROM AUTHOR]

The Kurai Fault Zone (KFZ) is one of the most hazardous seismogenic structures in the Gorny Altai (Russia), which bounds the largest Kurai and Chuya intermontane basins from the north. Trenching studies, radiocarbon dating of colluvial wedge deposits, and 230Th-U dating of seismogenic travertine of the Meshtuyaryk field showed that the fault scarp in the northwestern part of the Chuya Depression was formed by earthquakes that occurred ca. 9.5, 7.7, 5.8, and 4.8–3.4 ka BP. The last two palaeoearthquakes are younger than 3.2 ka BP. The parameters of seismogenic ruptures, as well as the distances between coeval seismogenic travertines along the KFZ, yielded estimates of the Mw of the four oldest palaeoearthquakes as 6.8–7.6 and ESI 2007 shaking intensities of VIII–XI. The results of 230Th-U dating suggest that deposition of the Meshtuyaryk travertines was triggered by three strong palaeoearthquakes at ca. 9.5, 7.7, and 4.8–3.4 ka BP, which activated faults and caused a rapid rise along them of ambient-temperature bicarbonate groundwaters previously sealed in deep-seated limestone aquifers. [ABSTRACT FROM AUTHOR]

Hells Bells are underwater secondary carbonates discovered in sinkholes (cenotes) southeast of Cancun on the north-eastern Yucatán peninsula, Mexico. These authigenic calcite precipitates, reaching a length of up to 4 m, most likely grow in the pelagic redoxcline. Here we report on detailed 230Th/U-dating and in-depth geochemical and stable isotope analyses of specimens from cenotes El Zapote, Maravilla and Tortugas. Hells Bells developed since at least ~ 8000 years ago, with active growth until present day. Initial (234U/238U) activity ratios (δ234U0) in Hells Bells calcite decreas from 55 to 15‰ as sea level converges toward its present state. The temporal evolution of the geochemistry and isotope composition of Hells Bells calcites thus appears to be closely linked to sea-level rise and reflects changing hydrological conditions (desalinization) of the aquifer. We suggest that decelerated leaching of excess 234U from the previously unsaturated bedrock traces Holocene relative sea-level rise. Considering this proxy, the resulting mean sea-level reconstruction contains half as much scatter, i.e. improves by a factor of two, when compared to previously published work for the period between 8 and 4 ky BP. [ABSTRACT FROM AUTHOR]

The south-eastern Gorny Altai is one of the most hazardous seismogenic area in the north of Central Asia. We present a synthesis of field, 230Th-U geochronological, mineralogical and geochemical data collected on seven Quaternary travertines. All travertines occur within the zones of active faults that border the Chuya and Kurai intermontane basins. Travertine cement mainly comprises calcite (with minor amounts of aragonite), which cements alluvial, alluvial fan, and colluvial deposits. The results of 230Th-U dating suggest that deposition of the travertines was triggered by large paleoearthquakes in the last eight thousand years. Several stages of travertine formation with ages 9–11 ka BP correspond to the known period of strong paleoseismicity in the region (8–16 ka BP). The 123 ka BP travertine resulted from a slip triggered by the Middle Pleistocene deglaciation, while that of 400 ka BP represents seismic motions likely associated with the main Cenozoic orogenic phase. All travertine forming events fall within warm and wet climatic phases (interglacials). Large earthquakes activated faults and caused a rapid rise along them of ambient-temperature bicarbonate groundwater, which was previously sealed in deep-seated Upper Neoproterozoic–Paleozoic limestone-dolostone aquifers. Rapid CO2 degassing of the spring water was the most important control of calcite or aragonite precipitation. Such travertines represent an important tool for paleoseismological research in seismically active regions. [ABSTRACT FROM AUTHOR]

The carbon isotopic signature inherited from soil/epikarst processes may be modified by degassing and prior calcite precipitation (PCP) before its imprint on speleothem calcite. Despite laboratory demonstration of PCP effects on carbon isotopes and increasingly sophisticated models of the governing processes, to date, there has been limited effort to deconvolve the dual PCP and soil/epikarst components in measured speleothem isotopic time series. In this contribution, we explore the feasibility, advantages, and disadvantages of using trace element ratios and δ44Ca to remove the overprinting effect of PCP on measured δ13C to infer the temporal variations in the initial δ13C of dripwater. In 8 examined stalagmites, the most widely utilized PCP indicators Mg/Ca and δ44Ca covary as expected. However, Sr/Ca does not show consistent relationships with δ44Ca so PCP is not universally the dominant control on Sr/Ca. From δ44Ca and Mg/Ca, our calculation of PCP as fCa, fraction of initial Ca remaining at the deposition of the stalagmite layer, yields multiple viable solutions depending on the assumed δ44Ca fractionation factor and inferred variation in DMg. Uncertainty in the effective fractionation of δ13C during degassing and precipitation contributes to uncertainty in the absolute value of estimated initial δ13C. Nonetheless, the trends in initial δ13C are less sensitive to these uncertainties. In coeval stalagmites from the same cave spanning 94 to 82 ka interval, trends in calculated initial δ13C are more similar than those in measured δ13C, and reveal a common positive anomaly initial δ13C during a stadial cooling event. During deglaciations, the trend of greater respiration rates and higher soil CO2 is captured in the calculated initial δ13C, despite the tendency of higher interglacial dripwater situation to favor more extensive PCP. [ABSTRACT FROM AUTHOR]