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Ionic rare earth mining has resulted in large amounts of bare soils, and revegetation success plays an important role in mine site rehabilitation and environmental management. However, the mining soils still maintain high NH

Rice cadmium (Cd) contamination is one of the critical agricultural issues. Breeding of low-Cd-accumulating cultivar is an effective approach to reduce Cd bioaccumulation in rice. To investigate the molecular mechanism underlying Cd transport in rice, the functions of nodes in Cd transport are explored. The results show that different nodes have different functions of Cd transport in the rice plant and the physiological structure of the first node under panicle (N1) determine the Cd accumulation in the brown rice. The upper nodes can redistribute the Cd transport in aboveground tissues. The expressions of Cd-efflux transporter genes (OsLCT1 and OsHMA2) located on the plasma-membrane are the main factors affecting the Cd transport form node to brown rice, which are more depended on the node functions but not the node Cd concentrations. Lower expressions of OsLCT1 and OsHMA2 in N1 result in lower Cd transport from node to brown rice. The size of vascular-bundle (VB) areas in the junctional node with the flag leaf can determine the expression of OsHMA2 and the expression of OsLCT1 positively correlated with the Cd transport ability of first node (N1). The expressions of OsVIT2 and OsABCC1 cannot allow Cd to be immobilized into the vacuoles in node. The VB structure and Cd transporter gene expression level of N1 proved that the Cd concentration of N1 can be used as an important indicator for screening low-Cd-accumulating cultivars. The major implication is that selecting or breeding cultivars with lower Cd accumulations in N1 could be an effective strategy to reduce Cd accumulation in rice grains.

Non-ferrous smelting releases lots of heavy metals to the environment. Although numerous studies have focused on pollution in the environment, fewer have studied the adverse health effects. In the current study, samples of food, hair and urine were collected and analyzed for zinc (Zn), iron (Fe), chromium (Cr), nickel (Ni), lead (Pb) and copper (Cu) from residents of 3 villages near the largest copper smelter in China. The estimated daily intake (EDI), target hazard quotient (THQ), and Hazard Index (HI) were used to estimate and analyze the health risks to local residents (children, adults, and seniors). The Zn, Cr, Ni, Fe, Pb and Cu concentrations in food ranged from 16.02 to 61.48 mg kg−1, 0.23–13.64 mg kg−1, 0.10–5.90 mg kg−1, 19.16–170.05 mg kg−1, 0.15–3.62 mg kg−1, and 0.53–2.74 mg kg−1, respectively. Zn, Cr, Ni and Pb concentrations in all vegetables were above the national tolerance limits. Children had higher EDIs of heavy metals than that of adults and seniors. The THQ of single elements and the HI of combined elements indicated that the EDI of Pb and Cu showed the highest potential health risks, followed by the EDI of Zn and Fe, and Ni, Cr. High EDI of heavy metals resulted in much higher concentrations of heavy metals in hair and urine samples than those of normal Chinese residents, showing that residents around the smelter have potential health risks through daily food intake. The main sources of these heavy metals were from the consumption of rice and vegetables and it is imperative that measures should be taken to control this urgent problem.

Phytoremediation is a potential cost-effective technology for remediating heavy metal-contaminated soils. This method was used to evaluate the biomass and accumulation of copper (Cu) and cadmium (Cd) of plant species grown in contaminated soil and their biological and physical effects on the soil. In co-contaminated soils with copper (Cu) and cadmium (Cd), a three-year field experiment was conducted by planting four plant species in the co-contaminated acidic soil treated with hydroxyapatite. The four species produced different amounts of biomass in this order: Pennisetum sp. > Elsholtzia splendens > Setaria lutescens > Sedum plumbizincicola. Over three growing seasons, the best accumulators of Cu and Cd were Elsholtzia splendens and Sedum plumbizincicola, respectively. Overall, Pennisetum sp. was the best species for Cu and Cd removal when biomass was considered. The four plant treatments could improve the content of >0.25 mm mechanically stable (DR0.25) and water-stable (WR0.25) aggregates and significantly improve the aggregate mean mass diameter (MWD) and the geometric mean diameter (GMD). The largest increase was with the treatment of Pennisetum sinese, while the fractal dimension (FD) of mechanically stable aggregates could be significantly reduced by the treatment of Pennisetum sp. Hydroxyapatite and phytoremediation could improve the soil enzyme activity, and Elsholtzia splendens had the best effect in this respect. This study will provide a better understanding of the remediation of heavy metal contaminated soil.

Angiotensin converting enzyme 2 (ACE2) is a key regulator of the renin-angiotensin system, but also the functional receptor of the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2). Based on structural similarity with other γ-secretase (γS) targets, we hypothesized that ACE2 may be affected by γS proteolytic activity. We found that after ectodomain shedding, ACE2 is targeted for intramembrane proteolysis by γS, releasing a soluble ACE2 C-terminal fragment. Consistently, chemical or genetic inhibition of γS results in the accumulation of a membrane-bound fragment of ectodomain-deficient ACE2. Although chemical inhibition of γS does not alter SARS-CoV-2 cell entry, these data point to a novel pathway for cellular ACE2 trafficking.

The heritage resources of the air-raid shelter project in Chongqing during the Anti-Japanese War have built the spiritual soul of the city, and should respond to its effective regeneration design and utilization, and lead the optimization of its air defense value, social value, cultural value, and commercial value with the continuation of the spirit. Make it fully integrated with environmental functions in the regeneration design, and enhance the environmental value of the area where it is located.

Ultrasound-guided costoclavicular block (CC-approach) is a recently described brachial plexus block (BPB) and an alternative approach to the supraclavicular approach (SC-approach). The relevant sonoanatomy is analogous in terms of the brachial plexus and its adjacent artery for both approaches. In the present study, we hypothesized that the two approaches will result in similar block dynamics when used the modified double-injection (MDI) technique. One hundred and twelve patients were randomly allocated to receive either a SC- or CC-approach with MDI technique. In the CC group, half the volume was injected adjacent to the medial cord of the brachial plexus, the procedure was guided by ultrasound and verified by nerve stimulator, subsequently the second half was injected close to the lateral cord. In the SC group, the MDI technique was carried out as described in our previous study. Sensory and motor blockade of all four terminal nerves were assessed with a 3-point scale. The primary outcome was the proportion of complete sensory blockade at 15 min with a predefined non-inferiority margin of −13%. The proportion of subjects at 15 min was comparable between the SC group and the CC group (91 vs 87%, absolute difference: −3%). No significant differences were found for complete motor blockade and onset times of the individual nerves within 30 min, and block-related serious adverse events (all P>0.05). We conclude that the MDI technique applied to a costoclavicular and supraclavicular block resulted in similar block dynamics. In addition, it may provide a promising alternative technique when considering the use of multipoint injection.

In an effort to address public concerns of the long-term stability and ecological risk reduction of Cu and Cd in a farmland located at the Guixi, Jiangxi Province, China, containing ∼ 800 mg kg−1 Cu and 0.8 mg kg−1 Cd soil, were treated in situ by attapulgite, apatite, montmorillonite and lime at the rate: 10, 10, 10 and 4 g kg−1 soil, respectively. Field experiment consisted of 2 × 3-m plots arranged in a randomised complete block design with each treatment. Soil and plant samples were collected in sixth years post-treatments and analysed for Cu and Cd bioaccessibility, chemical fraction and Cu, Cd concentration in plant tissue. The results indicated that the apatite and lime treatments significantly reduced bioaccessible and exchangeable fractions Cu and Cd in the soil at sixth years post the treatments. Cu and Cd concentration in plant tissue was positively related to the bioaccessibility of Cu and Cd. The treatment used 10 g apatite kg−1 soil appeared to be most effective for overall risk redu...

Foliar spraying with silicon (Si) and selenium (Se) can regulate the accumulation of cadmium (Cd) in rice (Oryza sativa L.), but the effects on different cultivars and the main determining factors remain unknown. Field experiments were conducted to investigate the ability of foliar spraying with Si, Se, and mixture of Si and Se to decrease Cd accumulation and translocation in rice cultivars WYHZ, NJ5055, and ZF1Y. All three spray treatments significantly decreased the Cd concentration in WYHZ brown rice, but had no such effect in NJ5055 or ZF1Y, relative to controls. WYHZ had a higher ability to translocate Cd than the other two cultivars. Foliar spraying changed this pattern by decreasing Cd translocation from roots to stems and from stems to brown rice, and increasing Cd translocation from stems to leaves. Foliar spraying also increased the photosynthetic rate, stomatal conductance, and transpiration efficiency in WYHZ. Structural equation modelling revealed the negative effects of photosynthetic rate, transpiration efficiency, and leaf Cd concentration, and the positive effects of stem and root Cd concentration on brown rice Cd concentration. Structural equation modelling further highlighted the significant role of stem Cd concentration in determining brown rice Cd concentration, which had the highest standardized total effects (direct plus indirect effects). These findings demonstrate that foliar spraying with Si and Se is effective in reducing Cd accumulation in rice cultivars with high Cd translocation ability, mainly by reducing stem Cd concentrations and ameliorating plant photosynthetic processes.

Copper (Cu) smelting released large amounts of Cu and contaminated the environment. However, few studies have investigated the Cu exposure risks for people located near Cu smelters. In this study, atmospheric bulk deposition, food from local families, drinking water and biological samples (hair and urine) were collected in three villages near the largest flash Cu smelter in China. The objective of the current study was to investigate how non-ferrous metals smelting affect the human health. Total atmospheric Cu depositions (56–767 μg m−2 yr−1) were one or two orders of magnitude greater than that of unpolluted rural areas. The Cu concentrations in locally grown vegetables and dietary chronic daily intake (CDI) of local residents showed a consistently decreasing trend with atmospheric Cu depositions. Dietary intake of vegetables and rice were the two major pathways of total CDI, which accounted for >93% totally. The Cu exposure showed higher potential non-carcinogenic risk to human health of local residents, especially children living around the Cu smelter through food consumptions. Health impact monitoring data revealed that mean Cu concentrations in hair and urine samples were ranged from 5.13 to 28.85 mg kg−1 and 19.90 to 54.61 μg L−1 in the three villages, respectively. Significant correlation between hair Cu concentrations and the CDI of Cu indicated food ingestion had adverse effects on the health of the local residents. The result suggested that nonferrous metal smelter should be away from residential area and locally produced crops became unsuitable for consumption. Therefore, effective measures on Cu pollution management and control in the surrounding area should be formulated and implemented.

Sepsis is a common complication of solid organ transplant procedures and, in particular, can affect the prognosis of orthotopic liver transplantation (OLT). This retrospective study determined the pre-, peri-, and postoperative risk factors for sepsis after OLT, using as reference the 2016 Third International Consensus Definitions for Sepsis and Septic Shock (Sepsis-3). Pre-, peri-, and postoperative clinical data of the sepsis-positive (n=85) and sepsis-negative (n=41) groups were analyzed for potential risk factors of OLT-related sepsis. The sepsis-positive patients had a significantly higher rate of dialysis (49.4%), longer time under mechanical ventilation (1.5 d), higher hospitalization costs (0.41 million RMB), and worse survival rate (68.5%), compared with the sepsis-negative patients (4.8%, 1 d, 0.30 million RMB, and 73.1%, resp.). The multivariate logistic analysis identified the following as risk factors for OLT-related sepsis: preoperative Child-Pugh grade C (OR 10.43; 95% CI 2.081–52.292; P=0.004), preoperative hypercalcemia (OR 6.372; 95% CI 1.693–23.98; P=0.006), and perioperative acidosis (OR 6.364; 95% CI 1.196–33.869; P=0.030). Patients with preoperative Child-Pugh grade C, preoperative hypercalcemia, or perioperative acidosis are at higher risk for developing sepsis after OLT. When any of these problems occur, timely sepsis management should be planned.

Ash produced by biomass power plants has great potential for the removal of heavy metal ions from aqueous solution. The pollution of toxic heavy metals to water is a worldwide environmental problem. Discharges containing copper, in particular, are strictly controlled because the excessive copper can cause serious harm to the environment and human health. This work aims to investigate the adsorption characteristics of copper ions in aqueous solution by biomass ash and the modified products, and to evaluate their potential application in water pollution control. The biomass ash was modified with a mesoporous siliceous material and functionalized with 3-aminopropyltriethoxysilane. The surface properties of the biomass ash and the new matrix were studied to evaluate their adsorption property for Cu2+ ions at different pHs, initial metal concentrations and the thermodynamic and kinetic were studied. The chemical and morphological properties of this modified material are analyzed; the specific surface area of the modified biomass ash was nine times that of the initial ash. Both of the two materials showed a strong affinity for Cu2+, and the Langmuir model could best represent the adsorption characteristics of Cu2+ on the two kinds of materials. The adsorption capacity of copper on the material increased with the increase of pH and pH 6 was the optimum pH. Thermodynamic analysis results showed that the adsorption of Cu2+ was spontaneous and endothermic in nature. The adsorptions of Cu2+ onto the modified biomass ash followed pseudo-second-order kinetics.

To explore the combined remedy effect of alkaline materials and plants on the distribution of heavy metals in whole soil and aggregates, a 3 year in situ experiment was carried out in a dual copper (Cu)/cadmium (Cd)-contaminated farmland in this study. Treatment was applied by the addition of soda residue (11.2 t ha−1), apatite (22.3 t ha−1), or lime (4.45 t ha−1), respectively, into the heavy metals-contaminated soil as a single application; Elsholtzia splendens was continually planted for 3 years in all the experimental plots. The total metals amounts and distributions of Cu and Cd in the whole soil and aggregates were then investigated. Our results showed that (1) although the total concentrations of Cu and Cd were slightly increased in the whole soil, their exchangeable concentrations were significantly reduced in both abovementioned treatments; (2) all the abovementioned 3 treatments significantly increased the stability of the dry and wet aggregates when compared with the control treatment; (3) similar to the whole soil, combined remediation groups slightly increased the concentrations of Cu and Cd in the aggregates, but decreased their available and exchangeable concentrations observably. Specifically, the highest concentrations of Cu and Cd were found in the aggregates sized 0.25 mm. In total, the combined remediation adopted in our study dramatically decreased the available concentrations of both Cu and Cd in the whole soil and aggregates. The distribution variations of Cu and Cd caused by passivator-plant combined remediation in the whole soil might be because more metal ions have been transformed into less mobile fractions, whereas the heavy metal distribution differences in the aggregates might be not only correlated with the size of the soil wet aggregates, but also possibly controlled by the soil organic carbon.

Micro-/nano-hydroxyapatite (MHA/NHA) has been used to reduce the concentration of available heavy metals and increase soil pH in the remediation of heavy metal-contaminated soils. However, little is known about the effects of MHA and NHA on soil fungal communities and function. In this study, fungal community composition was characterized from copper-contaminated soils amended with MHA, NHA and three other classic amendments combined with Elsholtzia splendens during a 3-year immobilization experiment. High-throughput sequencing results showed that applications of MHA increased the richness and diversity of the fungal community, which was opposite the results of NHA. SIMPER analysis indicated that both the relative abundance of fungi associated with biosorption and plant growth promotion increased, whereas the relative abundance of fungi related to bioleaching and potential pathogens decreased after applying MHA. Redundancy (RDA) analysis revealed that the soil pH was a crucial environmental factor in the succession of fungal communities. In addition, the results of functional prediction via FUNGuild suggested that the application of MHA had the potential to reduce the risk of pathogens infecting animals and plants in the soil but that NHA had some environmental risks. Overall, fungal community showed a synergistic effect of immobilization with the test amendments, and MHA was better for the remediation of heavy metal-contaminated soils than the other test amendments.

Applying hydroxyapatite to immobilize heavy metals may cause a decline in soil quality, whereas phytoextraction has been shown to be a slow process under normal agronomic conditions. The benefits of combining hydroxyapatite application and phytoextraction are unclear for improving the soil ecosystem at the same time as remediating heavy metals. A three-year field experiment was conducted to test the combined effects of hydroxyapatite application and phytoextraction (Sedum plumbizincicola, Elsholtzia splendens, and Pennisetum sp.) on remediating cadmium (Cd) and copper (Cu) and improving the soil microbial community structure in a smelter-impacted site. Total Cd and Cu were fractionated using a sequential extraction procedure. Soil microbial biomass and community composition were measured by phospholipid-derived fatty acid (PLFA) analysis. The results showed that hydroxyapatite addition (1%) increased soil pH and decreased the exchangeable fraction of Cu and Cd compared with the control. Combining with hydroxyapatite application, the growth of phytoextractors increased organic matter content and decreased total Cu and Cd concentrations in the soil. Hydroxyapatite application disturbed the soil microbial PLFA composition by increasing fungal PLFA, whereas a combination with plant growth reduced the trend of soil fungal growth. Combining hydroxyapatite with Pennisetum sp. particularly improved Gram-negative and Gram-positive bacterial biomass and reduced the ratio of fungi to bacteria. In conclusion, combining hydroxyapatite with suitable phytoextractors is a promising approach for remediating heavy metals (e.g., Cu and Cd) and simultaneously improving soil microbial community structure and the ecological environment in contaminated areas.

The cultural heritage of the Dunhuang Mogao Caves is a valuable as set for China, but the site is located in Gansu Province in northern China, where the ecological environment is fragile, the environmental space is relatively small and the environmental carrying capacity is limited. In the process of accelerating the tourism development and construction of Mogao Caves cultural heritage, the ecological balance of the environment has been upset and problems have emerged. This paper investigates the ecological and environmental management and enhancement of the site, as well as the conservation and protection of the non-renewable resources of the Mogao Caves cultural heritage.

Heavy metals contamination of soil has been considered as a global environmental problem, and consequently various soil amendments have been widely used in immobilization. Previous studies have reported that micro-/nano-hydroxyapatite (MHA/NHA) as a novel chemical material could alleviate soil acidity and reduce the bioavailability of heavy metals. However, the mechanism of soil microorganism responding to the application of MHA/NHA is little studied. Presently, an in-situ field experiment was conducted to determine the effects of MHA/NHA and the other three traditional amendments including alkali slag (AS), lime (L) and apatite (AP) on soil copper (Cu) bioavailability and dominate bacterial population. The results showed that the application of MHA/NHA effectively increased soil pH and decreased soil available Cu content, and showed the highest increasing effects on the activities of urease, catalase and acid phosphatase. Compared with the control, MHA/NHA significantly changed the soil bacterial community structure and increased the bacterial abundance and diversity. Besides, analysis of the dominate population showed that the application of MHA/NHA decreased the relative abundance of acidophiles and the indicator of soil degradation. Additionally, the relative abundance of potential plant growth promoting bacteria increased with the addition of MHA/NHA, which was confirmed by the characteristics (the ability of producing indole acetic acid and siderophore) of bacterial strains. These results suggested that these dominate bacterial populations with significant changes may be regarded as the biomarkers for the recovery of soil ecological environment, which provides a theoretical basis for the ecological evaluation of MHA/NHA.

There is an increasing evidence linking protective effect of selenium (Se) against Pb toxicology; however, Pb exposure risk assessments usually consider only the environmental Pb contamination and dietary intake. Based on the current understanding of mechanisms of Se Pb interactions, the physiological function/toxicology of Se and the toxicology of Pb, a new criterion for Se and Pb exposure assessment is developed. Additionally, seven existing criteria were also used to assess the resident health risks around a smelter in China. The Pb concentrations in locally-produced foods exceeded the national tolerance limits of China and the Se in the foods were similar to those in areas with adequate Se levels. In accordance with the illustrated assessments of the new criterion and seven existing criteria, we found a large knowledge gap between the new and traditional assessments of exposure to Pb and/or Se. The new assessment criteria suggested that almost all the residents were facing the Se deficiency and 58% of the residents not only had the adverse health of Se deficiency, but also had the health risks of Pb toxicity. The Pb and Se in the hair and urine may partly support the new criterion. This study suggested that the process of Se counteracting the Pb toxicity may result in Se deficiency. Pb exposure combined Se intake should be considered in future assessments of Pb exposure (or Se intake).

Ash produced by biomass power plants has great potential for the removal of heavy metal ions from aqueous solution. The pollution of toxic heavy metals to water is a worldwide environmental problem. Discharges containing copper, in particular, are strictly controlled because the excessive copper can cause serious harm to the environment and human health. This work aims to investigate the adsorption characteristics of copper ions in aqueous solution by biomass ash and the modified products, and to evaluate their potential application in water pollution control. The biomass ash was modified with a mesoporous siliceous material and functionalized with 3-aminopropyltriethoxysilane. The surface properties of the biomass ash and the new matrix were studied to evaluate their adsorption property for Cu

Natural biomass ash of agricultural residuals was collected from a power plant and modified with hexagonal mesoporous silica and functionalized with 3-aminopropyltriethoxysilane. The physicochemical and morphological properties of the biomass ash were analyzed by ICP-OES, SEM, TEM-EDS, FTIR, and BET analysis. The adsorption behavior of the modified product for Cd2+ in aqueous solution was studied as a function of pH, initial metal concentration, equilibrium time, and temperature. Results showed that the specific surface area of the modified product was 9 times that of the natural biomass ash. The modified biomass ash exhibited high affinity for Cd2+ and its adsorption capacity increased sharply with increasing pH from 4.0 to 6.0. The maximum adsorption capacity was 23.95 mg/g in a pH 5 solution with an initial metal concentration of 50 mg/L and a contact time of 90 min. The adsorption of Cd2+ onto the modified biomass ash was well fitted to the Langmuir model and it followed pseudo-second-order kinetics. Thermodynamic analysis results showed that the adsorption of Cd2+ was spontaneous and endothermic in nature. The results suggest that the modified biomass ash is promising for use as an inexpensive and effective adsorbent for Cd2+ removal from aqueous solution.

Many amendments have been applied to immobilize heavy metals in soil. However, little information is available on the changes of immobilization efficiencies of heavy metals in contaminated soils over time. This work investigated the immobilization efficiencies of copper (Cu) and cadmium (Cd) in contaminated soils in situ remediated with one-time application of three amendments for 1 year and 4 years. Apatite, lime, and charcoal were mixed with the topsoil of each plot with the amounts of 22.3, 4.45, and 66.8 t/ha, respectively. Soil chemical properties and fractions of Cu and Cd were examined after in situ remediation for 1 year and 4 years. Soil sorption and retention capacities and desorption proportions for Cu and Cd were investigated by batch experiments. The addition of amendments significantly increased soil pH, but decreased exchange acid and aluminum (Al). The amendments significantly decreased the CaCl2 extractable Cu and Cd and transformed them from active to inactive fractions. After the application of amendments for 1 year, the maximum sorption capacities ranged from 35.6 to 38.8 mmol/kg for Cu and from 14.4 to 17.0 mmol/kg for Cd, which were markedly higher than those of the application of amendments for 4 years (Cu, 29.6–34.7 mmol/kg; Cd, 10.9–16.4 mmol/kg). Desorption proportions (D) of Cu and Cd using three extractants followed the order of $$ {D}_{{\mathrm{NaNO}}_3} R lime > R charcoal, resulting in higher Cu and Cd in the amended soils than the untreated soil. Apatite, lime, and charcoal increased the soil sorption and retention capacities of Cu and Cd and resulted in higher immobilization efficiencies in the amended soils than the untreated soil. However, the immobilization efficiencies of Cu and Cd decreased with the decrease of sorption capacities after 4 years. It was concluded that apatite had the best effect on the long-term stability of immobilized Cu and Cd and can be applied to immobilize heavy metals in contaminated soils.

With the rapid development of nanotechnology, hydroxyapatite-based nanoparticles have been applied in wastewater and soil remediation. However, limited studies have been conducted on the remediation of heavy metal-contaminated soils by microhydroxyapatite (MHA) and nanohydroxyapatite (NHA). Thus, we investigated the effects of MHA and NHA on soil pH values and fractions of copper (Cu) and cadmium (Cd). The changes of soil enzymes with application of MHA and NHA were also evaluated. Pots contained 200 g of the soil with MHA and NHA ranging from 1 % to 5 % incubated for 60 days under greenhouse condition, and maintained at 60 % of soil water holding capacity by adding deionized water. Soil pH, catalase, urease, and acid phosphatase were analyzed at incubation times of 7, 14, 30, and 60 days by chemical assays. The fractions of Cu and Cd were analyzed after 60 days by a sequential extraction procedure. Application of MHA and NHA significantly increased soil pH values. Especially, we found for the first time that soil pH values with 3 % (pH > 7.90) and 5 % (pH > 8.83) application rates of MHA were larger than that of MHA itself (pH = 7.71). MHA was more effective than NHA in immobilizing Cu and Cd by significantly decreasing exchangeable fractions of Cu and Cd and transforming them from active to inactive fractions. Soil catalase and urease significantly increased, but acid phosphatase apparently decreased with increasing application rates of MHA. However, three enzymes activities changed slightly for NHA treatments. MHA was more effective than NHA in immobilizing Cu and Cd. MHA had a more positive effect on soil catalase and urease activities than NHA. Furthermore, Pearson’s correlation coefficients showed that soil pH value was a key factor to influence the bioavailability of Cu and Cd and the activity of soil enzymes. The results of this study provided an efficient method for the remediation of heavy metal-contaminated soils.

Atmospheric dry deposition is an important nitrogen (N) input to farmland ecosystems. The main nitrogen compounds in the atmosphere include gaseous N (NH3, NO2, HNO3) and aerosol N (NH4 +/NO3 −). With the knowledge of increasing agricultural effects by dry deposition of nitrogen, researchers have paid great attention to this topic. Based on the big-leaf resistance dry deposition model, dry N deposition velocities (V d) in a typical red soil agro-ecosystem, Yingtan, Jiangxi, Southeastern China, were estimated with the data from an Auto-Meteorological Experiment Station during 2004–2007. The results show that hourly deposition velocities (V dh) were in the range of 0.17–0.34, 0.05–0.24, 0.57–1.27, and 0.05–0.41 cm/s for NH3, NO2, HNO3, and aerosol N, respectively, and the V dh were much higher in daytime than in nighttime and had a peak value around noon. Monthly dry deposition velocities (V dm) were in the range of 0.14–0.36, 0.06–0.18, and 0.07–0.25 cm/s for NH3, NO2, and aerosol N, respectively. Their minimum values appeared from June to August, while their maximum values occurred from February to March each year. The maximum value for HNO3 deposition velocities appeared in July each year, and V dm(HNO3) ranged from 0.58 to 1.31 cm/s during the 4 years. As for seasonal deposition velocities (V ds), V ds(NH3), V ds(NO2), and V ds(aerosol N) in winter or spring were significantly higher than those in summer or autumn, while V ds(HNO3) in summer were higher than that in winter. In addition, there is no significant difference among all the annual means for deposition velocities (V da). The average values for NH3, NO2, HNO3, and aerosol N deposition velocities in the 4 years were 0.26, 0.12, 0.81, and 0.16 cm/s, respectively. The model is convenient and feasible to estimate dry deposition velocity of atmospheric nitrogen in the typical red soil agro-ecosystem.