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To address the limitations of current dating methods, it is crucial to not only enhance existing techniques like U–Pb zircon dating but also explore alternative tools. This study focuses on three common mineral phases—zircon, apatite, and titanite—in an I-type granite. The goal is to assess their reliability as dating tools and propose improved methods for dating granitic rocks. In the case study of the Mt Stirling pluton within the Mt Buller igneous suite in Southeastern Australia, significant variability in laser ablation U–Pb zircon ages (around 100 million years) was observed. To improve the reliability of zircon age data and reduce non-magmatic-related variabilities, a data filtering protocol is applied. This protocol involves several steps such as trimming zircons with excessive K and Ca, excluding zircons with unusual core–rim age relationships, removing zircons with excessive non-formula elements (Al, Fe, and Mn), identifying hydrothermally altered zircons, and applying a 10% discordance threshold. The filtered Concordia Age (406 ± 1 Ma; mean square weighted deviation (MSWD) = 0.7, n = 80) of the host rock exhibits improved precision and reduced error compared to the unfiltered data (399 ± 2 Ma; MSWD = 9.3, n = 240). The filtered individual dates show less scatter and a mean that is different (i.e. outside statistical uncertainty), noting that their total still spans a considerable time range of ~50 million years, exceeding the individual zircon analytical reproducibility of 2 standard errors (~15 million years of 2 SE). Caution is advised when using the proposed error for the pooled analyses as a definitive precision. Similarly, trace element filtering approaches were applied to apatite and titanite samples from Mt Stirling, two phases that arguably cannot be inherited. For apatite, monitoring Ca and P as well as Zr/Y and Th/U ratios, along with identifying age groupings based on Sr concentrations, was effective in eliminating outliers and enhancing dating precision. In the case of titanite, monitoring Ca and Ti, Sr/Zr and Sr/Th ratios, and Sr/Ca and Zr/Ti ratios successfully enhanced dating precision. Notably, apatite and titanite grains were grouped in distinct Sr concentrations (high-, mid-, and low-Sr), with these groups corresponding to different date groups: high-Sr apatite and high- and low-Sr titanite returned c. 403 Ma, while low-Sr apatite and mid-Sr titanite returned c. 420 and 393 Ma, respectively. The spuriously younger or older dates may indicate an open system and influences from various common-Pb sources. The 403 Ma date coincides with the filtered zircon data, placing further confidence in the coupled approach, and is interpreted here as the igneous intrusion age. Notable is that this age is 25 Myr older than previously reported K–Ar age data, thus far considered to be the age of the intrusion. This study underscores the potential for erroneous zircon dates due to cryptic chemical influences. To enhance the reliability of age interpretation using laser ablation analyses, employing a petrochronological approach using split-stream combined age and trace element data is recommended in addition to the combination of multiple geochronometers. In the case of Mt Buller, it has proven crucial to carefully verify chemical closure of all applied geochronometers by monitoring concomitant trace element concentrations. Applied to other intrusions, petrochronology can play a critical role in obtaining reliable age information, even for igneous rocks that appear pristine. With this, we emphasise the importance of a careful approach towards individual age data interpretation, which can be produced fast and in abundance with modern analytical approaches. [ABSTRACT FROM AUTHOR]

Dating of igneous rocks from paleo-island arc complexes of orogenic belts makes it possible to determine the precise timing of subduction processes that occurred during the formation of the orogen. Within the central (East Transbaikal) part of the Mongol–Okhotsk orogenic belt, the Kamenka island-arc terrane is an example of such a complex. Its intrusive part is included into the Bereya complex, represented by a gabbro-diorite-tonalite-plagiogranite series of rocks demonstrating subduction geochemical characteristics. The dating of zircons from acidic rocks of this complex by the U–Pb classical method showed that they were formed in a narrow time interval of 203 ± 1–205 ± 1 Ma, which corresponds to the Norian–Rhaetian boundary of the Late Triassic. Taking into account the previously obtained age of the diorites (254 ± 5 Ma), the timing of formation of the entire series of the intrusive rocks is about 50 Ma, thus indicating the probable subduction along the northern (in modern coordinates) margin of the Mongol–Okhotsk Paleocean under the Siberian paleocontinent in the Late Permian – Late Triassic. The diorites of the first phase have positive values of εND(254 Ma) = 3.2–3.6 (TNd(DM) = 879–994 Ma), and the plagiogranites have ɛND(205 Ma) = 2.3–3.5 (TNd(DM) = 859–1028 Ma), which points to the relationship between these rocks and the substance of the depleted mantle source and is consistent with the Sm–Nd isotope characteristics of the juvenile crust of the Central Asian orogenic belt. [ABSTRACT FROM AUTHOR]

The process of slab tearing profoundly affects interchanges of material and energy between the lithosphere and asthenosphere and has been invoked as a trigger of magmatism in modern and ancient subduction‐collision systems. Horizontal slab tears may occur after continental collision and subsequent slab break‐off, whereas vertical slab tears may occur in response to along‐strike variations in rollback velocity, thereby ripping the subducting lithosphere. Previous studies have documented tearing of subducting slabs in modern convergent settings using geophysical methods, but in ancient collisional belts, where these methods cannot be applied, detection of slab tearing is more difficult, particularly if the oceanic plate was fully subducted and the geological evidence for subduction is limited. Here, we employ multiproxy element‐isotope imaging, as well as zircon petrochronology and whole‐rock geochemistry, to assess evidence of vertical tearing of the Mianlue slab in the Triassic Qinling Orogen in central China. Our results show evidence of anomalous, inferred tear‐related magmatism east of 107°E, at 225–210 Ma. Vertical tearing of the northward subducting Mianlue slab is recorded by geochemically anomalous igneous rocks, and the recognition of N–S to NE–SW trending boundaries defined by Sr‐Nd‐Hf isotopes, elemental ratios (Nb/Ta, and Ca/Al), Mg#, and reduced crustal thickness between 107° and 108°E. The inferred vertical tear may have been driven by slab rollback of the Mianlue slab at 225–210 Ma. The results show that multiproxy element‐isotope imaging (e.g., of εNd(t), εHf(t), (87Sr/86Sr)i, Nb/Ta, Mg#, and Ca/Al) can be used to reconstruct the evolution of fossil subduction systems. Plain Language Summary: Subduction zones are natural factories for the circulation of material in the Earth as they allow tectonic plates to descend into the mantle. Pieces of subducting plates, normally referred to as slabs, can be torn and segmented, but reconstructing the geometry of such tears in ancient convergent plate boundary settings is difficult. Based on the observation that slab tearing can trigger anomalous magmatism in convergent plate margins, we present a multiproxy geochemical and isotopic imaging method that enables us to understand the process of slab tearing in the Qinling Orogen (China) during the Triassic. We found that igneous rocks from the Qinling Orogen, east of 107°E, are geochemically anomalous (relative to typical arc rocks). These rocks are dated 225–210 Ma. By imaging various geochemical characteristics, our results demonstrate that the subducting Mianlue slab was likely torn at longitude 107°–108°E, thereby producing geochemically and isotopically anomalous mafic and felsic magmatism. Key Points: The geometry of slab tearing in an ancient orogen is constrained by a multiproxy geochemical approachAnomalous arc magmatism dated at 225–210 Ma is identified in the Qinling Orogen east of 107°EThe Mianlue slab underwent southward vertical slab tearing at 107°−108°E in the Late Triassic [ABSTRACT FROM AUTHOR]

In central Victoria, inherited zircon in Devonian igneous rocks and detrital zircon in metasedimentary country rocks and an amphibolite-facies xenolith show that Mesoproterozoic parts of the underlying Selwyn Block cannot be the source for all the silicic magmas. Zircon inheritance in S-type samples reveals significant thermal events at 525–425 Ma and 1200–1100 Ma. Both S- and I-type samples have prominent zircon age peaks at 420–410 Ma, which record high-grade metamorphism of the deep crust during the terminal phases of the Benambran and Bindian orogenies. All I-type rocks have 650–500 Ma peaks, suggesting derivation from an arc-related metavolcanic source in the upper Selwyn Block. Protoliths of the greenschist-facies Ordovician metasediments and the amphibolite-facies Cambrian metasedimentary xenolith were deposited in distal backarc settings. Most inherited zircon cores are metamorphic, and the strongest zircon inheritance occurs in hornblende-bearing I-type rocks, highlighting their largely crustal origin. Zircon populations at ca 1400 Ma, thought to signal sediment derivation from East Antarctica and Rodinia-Nuna, are mostly absent in I-type samples and some S-types. The ca 1400 Ma signal probably applies to the upper, metasedimentary Selwyn Block, so Devonian S-type magmas were sourced mainly in the deeper sections. Zircon inheritance in the Devonian igneous rocks was not influenced by the exposed metasedimentary country rocks. Two samples from one of the smaller plutons have contrasting patterns of zircon inheritance, suggesting relatively small-scale source heterogeneity. Many rounded and corroded cores in zircon crystals yield the same ages as the crystallisation dates for the rocks, and thus are antecrysts. Higher whole-rock Zr contents generally correlate with higher proportions of inherited zircon, and differentiation does not affect this relationship. The degree of partial melting of a magma source and the efficiency of crystal entrainment are critical in governing zircon inheritance. Mesoproterozoic sections of the Selwyn Block cannot be the sources for all the Devonian silicic magmas in central Victoria. I-type rocks have 650–500 Ma zircon age peaks, suggesting derivation from arc-related metavolcanic rocks in the upper Selwyn Block. Hornblende-bearing I-type rocks have the strongest zircon inheritance patterns, indicating the largely crustal origins of I-type magmas. Exposed metasedimentary country rocks were not involved in magma genesis. [ABSTRACT FROM AUTHOR]

(1) Background: The widely developed thrust structures in the Jingzhushan Formation of late Cretaceous in Nyima Basin are related to the collision which leads to orogeny between the Lhasa and Qiangtang blocks. Clarifying the tectonic properties of the Nyima Basin is of great significance to characterize the evolution of the collision between the Lhasa block and the Qiangtang block. (2) Methods: Combined with mineralogy and petrology and U-Pb zircon dating of extrusive rocks, a detailed magnetic fabric test and rock magnetic experiment were carried out on the red sandstones of the Late Cretaceous Jingzhushan Formation in Nyima Basin. (3) Results: The sedimentary magnetic fabrics developed at the three sampling locations in the southern part of the basin are related to paleocurrents. The strained magnetic fabrics developed at one sampling site in the north, including pencil-like fabrics and tensile linear fabrics, are related to SE-NW tectonic stress. The average magnetic susceptibility value of the strained fabric with sandstone is lower than that of the sedimentary fabric, and its size is controlled by mica paramagnetic minerals. Ferromagnetic minerals are magnetite or hematite. In addition, the age of sandstone in the Jingzhushan Formation from the Nyima Basin matches the age of the eruptive rock in the Jingzhushan Formation from Coqen Basin, which is 92 Ma. (4) Conclusions: The strained fabric is developed near the thrust fault, which can explain the widely developed thrust structures in the basin. The Nyima Basin of the Jingzhushan Formation in the Late Cretaceous was an ocean-continent transitional foreland basin developed under the background of arc-arc "soft collision". [ABSTRACT FROM AUTHOR]

Kimberlites are deep and relatively rare mantle‐derived igneous rocks, which provide key insights into the lithospheric mantle composition beneath continents (i.e., from the entrained mantle materials) at the time of magma emplacement. In addition, the temporal distribution of kimberlites throughout Earth's history may reveal secular changes in global geodynamics. However, alteration and abundant exotic material (i.e., xenoliths and xenocrysts) of different ages, both typical of kimberlites, often hinder reliable dating of these rocks. In this study, we investigated zircon xenocrysts and their replacement by desilicification reaction rims (DSRs), which consist mainly of baddeleyite, in the metamorphosed Kimozero kimberlites from the Karelian Craton, Russia. Similar DSRs have been identified previously on mantle‐derived zircons in numerous kimberlites, but the precise timing and location of formation of these rims remain unclear. U–Pb isotope dating of mantle zircon xenocrysts in the Kimozero kimberlites indicates that these rocks were emplaced at ca. 1.97 Ga. DSRs with similar textures and baddeleyite chemistry occur on both the 1.97 Ga mantle and 2.70–2.38 Ga crustal zircon xenocrysts in these kimberlites. Pb–Pb isotope dating of the DSRs yields the same age (i.e., ca. 1.97 Ga) as the mantle zircons. The data constrain the formation of DSRs to crustal levels and, more importantly, indicate that these rims record the timing of kimberlite emplacement. Therefore, we suggest that such baddeleyite reaction rims are a new and promising material for kimberlite geochronology. Plain Language Summary: Kimberlites are magmatic rocks produced by magma that ascended from mantle depths. It is important to obtain accurate kimberlite ages mainly because: (a) mantle rocks and minerals, carried by these magmas, allow assessment of the composition of the lithospheric mantle beneath continents at the time of kimberlite emplacement; and (b) the worldwide distribution of kimberlite ages may record secular changes in global geodynamics. However, kimberlites are readily altered and commonly contain exotic material of different ages and origins, which both hinder reliable kimberlite dating. Here, we investigated xenocrystic zircons and their reaction rims, which consist mainly of baddeleyite, in the strongly altered Kimozero kimberlites. Similar rims have been identified on mantle‐derived zircons in numerous kimberlites, but the timing and location of rim formation is poorly constrained. We found that the rims have replaced zircon xenocrysts of different ages and with both mantle and crustal origins, implying the rims formed at crustal levels. The results of Pb–Pb dating for these rims compared with those obtained from zircon U–Pb dating indicate that the rims record the timing of Kimozero kimberlite emplacement at ca. 1.97 Ga. Therefore, such baddeleyite rims are suggested as a promising material for obtaining reliable kimberlite ages. Key Points: Desilicification (i.e., baddeleyite) rims replace kimberlite‐hosted zircon xenocrysts of mantle and crustal originsThese rims represent a promising material for kimberlite geochronology, as they form at the time of kimberlite emplacementThe Kimozero kimberlites intruded the Karelian Craton at ca. 1.97 Ga [ABSTRACT FROM AUTHOR]

The eastern flank of the Talesh range of western Alborz, northwestern Iran, exposes volumetrically significant Late Cretaceous volcanic and volcaniclastic associations as well as cross-cutting dykes and minor subvolcanic equivalents. The volcanic units appear as massive to pillowed flows interlayered with volcaniclastic beds and subordinate limestones. We present new field data, zircon U Pb ages, bulk-rock major and trace element geochemistry, and Sr Nd isotopes on the igneous rock suite. Geochemical data show that the lava units and dykes are mainly basaltic in composition with minor basaltic andesites and trachytes. They form two contrasting series of arc-related calc-alkaline (Group 1) and OIB-like (Group 2) rocks. The zircon U Pb age of Group 1 rocks is 95.6 ± 1.8 Ma (2σ), whereas for Group 2 rocks, cross-cutting relationships and stratigraphic constraints indicate a somewhat younger age. Group 1 rocks have 87Sr/86Sr (i) varying from 0.7038 to 0.7070 and ε Nd (t) values ranging from +0.5 to +5.0. Group 2 rocks have 87Sr/86Sr (i) = 0.7040–0.7065 and ε Nd (t) from −3.0 to +3.7. Trace element and isotopic modelling shows that the primitive Group 1 magmas were derived from a metasomatized mantle source enriched by the addition of ∼6–10 % sediment melt component, while Group 2 rocks are consistent with melts of an asthenospheric mantle source enriched by ∼1–5 % EMII component. Trace element modelling indicates that Group 1 rocks formed from ∼6–13 % partial melts of a spinel-garnet lherzolite with garnet:spinel ratios of 45:55 to 10:90, whereas primitive Group 2 melts were generated through ∼1–3 % partial melting of a garnet-spinel-lherzolite with garnet:spinel ratios of 90:10 to 80:20. We propose a geodynamic model in which a north-dipping Neotethyan slab beneath the western Alborz (Talesh area) continental margin produced arc assemblages of Group 1 rocks and subsequent slab rollback led to the upwelling of an asthenospheric mantle to generate OIB-like magmatism of Group 2 rocks in an extensional intra-arc to back-arc setting. [Display omitted] • The Talesh magmatic rocks are dominated by basaltic lavas. • They were emplaced during the Late Cretaceous. • The magmatic rocks include both arc-type calc-alkaline and OIB-like alkaline rocks. • The mantle source of arc-type rocks was enriched by slab-derived sediment melts. • Slab rollback triggered asthenospheric melting and formation of OIB-like magmas. [ABSTRACT FROM AUTHOR]

[Display omitted] • Ediacaran-Cambrian series of Cap de Creus studied through Nd isotopic sources. • Eastern Pyrenees series (Cap de Creus) show Nd model ages ranging 1.4–1.6 Ga. • Coeval series from different Iberian terranes show contrasted Nd isotopic sources. • These data suggest different original locations along the Gondwana margin. • Isotopic tracers are a useful tool to check the provenance in paleoreconstructions. The North African margin of Gondwana formed by subduction and accretion during Ediacaran to Cambrian times. Sections of this active margin were incorporated during the late Paleozoic to the Variscan and Appalachian orogens. In the Variscan realm, these sections define in some regions a Cadomian basement comprising thick metasedimentary series associated with coeval subduction-related magmatic rock dated in the range 650–500 Ma. In the Cap de Creus Massif (Eastern Pyrenean domain), the Cadomian metasedimentary rocks formed from sediments derived from mixed felsic and intermediate/mafic sources, intruded by granitoid and minor mafic igneous rocks. These series were formed in a peri -Gondwanan volcanic arc setting, like other Cadomian series described in the SW of the Iberian Massif, such as Serie Negra Group of the Ossa Morena Complex. However, the Nd model ages of the Cap de Creus metasedimentary samples range from 1431 to 1620 Ma and are younger than those of their SW Iberia equivalents. This result can be interpreted as an indication of an eastern location in the Ediacaran - Cambrian peri -Gondwanan magmatic arc. Furthermore, the Cadomian series in the Central Iberian Zone have even younger Nd model ages than those of SW and NE Iberia. We present two end-member paleogeographic models consistent with reconstruction of the initial location of the Cap de Creus Massif and its relations with other domains (Ossa Morena Complex and Central Iberian Zone) in this sector of the North African Gondwanan margin. [ABSTRACT FROM AUTHOR]

Abstract Apatite is an accessory mineral that is frequently found in both igneous and clastic sedimentary rocks. It is conventionally considered to be characterized by a closure temperature range between 375 and 600 °C and hence has been employed to address mid-temperature thermochronology questions relevant to the reconstruction of thermal events in the middle to lower crust. However, questions remain as to whether apatite faithfully records thermally-activated volume diffusion profiles, or rather is influenced by recrystallization and new growth processes. We present a case study of two apatite samples from the Akia Terrane in Greenland that help chart some of the post magmatic history of this region. Apatite in a tonalitic gneiss has distinct U-enriched rims and its U-Pb apparent ages correlate with Mn chemistry, with a high Mn group yielding an age of c. 2813 Ma. The U-Pb and trace element chemistry and morphology support an interpretation in which these apatite crystals are originally igneous and record cooling after metamorphism, with subsequent generation of discrete new rims. Epidote observed in the sample implies a <600 °C fluid infiltration event associated with apatite rims. The second sample, from a granitic leucosome, contains apparently homogeneous apatite, however U-Pb analyses define two distinct discordia arrays with different common Pb components. An older, c. 2490 Ma, component is associated with elevated Sr, whereas a younger, c. 1800 Ma, component has lower Sr concentration. A depth profile reveals an older core with progressively younger ages towards a compositionally discrete late Paleoproterozoic rim. The chemical and age profiles do not directly correspond, implying different diffusion rates between trace elements and U and Pb. The variation in core ages is interpreted to reflect radiogenic-Pb loss from a metamorphic population during new rim growth. The younger, c. 1800 Ma U-Pb age is interpreted to date new apatite growth from a compositionally distinct reservoir driven by tectonothermal and fluid activity, consistent with regional mica Ar-Ar ages. Results from these two samples show that recrystallization, dissolution and regrowth processes likely formed the younger rim overgrowths, and at temperatures below those often considered to be closure temperatures for Pb diffusion in apatite. The results from these samples imply many apatite grains may not record simple thermally activated Pb diffusion profiles and cautions against inversion of apatite U-Pb data to thermal histories without detailed knowledge of the grain growth/alteration processes. Highlights • Present U-Pb apatite geochronology from the Akia Terrane Greenland • Apatites from the same sample may incorporate different common Pb. • Chemical and age zoning in apatite need not correlate • Dissolution and regrowth forming high U rims is prevalent. • Recrystallization may dominate over Pb diffusion in apatite. [ABSTRACT FROM AUTHOR]

This paper presents new zircon LA-ICP-MS U-Pb ages and whole-rock geochemical data for two granitic plutons and rhyolites of the Baiyingaolao Formation in the western Xing’an range (NE China). The two syenogranite granitic plutons yield identical zircon U-Pb age of 142 ± 1 Ma, and the Baiyingaolao rhyolites yield zircon U-Pb age of 138 ± 2 Ma. The granites contain some hornblendes, and show low Zr and Zr + Nb + Ce + Y contents, and low A/CNK (0.98-1.11), Mg# (6-55), and FeOT/MgO values. Rhyolite samples show similar geochemical characteristics with A/CNK of 0.99-1.10 and Mg# of 14-21. In combination with the high K2O contents (4.43-5.61 wt%) and negative correlations between P2O5 and SiO2, both the granites and rhyolites were classified as high-K calc-alkaline I-type granitoids. All samples give high zirconium saturation temperature of 794-964 °C with few initially inherited zircons, and belong to high-temperature I-type granitoids. They were generated by dehydration melting of biotite/muscovite from sub-alkaline meta-basalts in lower crust depth, leaving garnet, amphibole, and plagioclase as the major residual minerals. The syenogranites and rhyolites are likely formed in Mongol-Okhotsk oceanic subduction setting. Incorporating other lower crust-originated felsic rocks in Erguna and Xing’an massifs and Songliao basin, it is argued that lower crustal reworking is pronounced in NE China during Early Cretaceous. [ABSTRACT FROM AUTHOR]

Andradite-rich garnet is a common U-bearing mineral in a variety of alkalic igneous rocks and skarn deposits, but has been largely neglected as a U-Pb chronometer. In situ laser ablation-inductively coupled plasma mass spectrometry U-Pb dates of andradite-rich garnet from a syenite pluton and two iron skarn deposits in the North China craton demonstrate the suitability and reliability of the mineral in accurately dating magmatic and hydrothermal processes. Two hydrothermal garnets from the iron skarn deposits have homogenous cores and zoned rims (AdGr to AdGr) with 22-118 ppm U, whereas one magmatic garnet from the syenite is texturally and compositionally homogenous (AdGr to AdGr) and has 0.1-20 ppm U. All three garnets have flat time-resolved signals obtained from depth profile analyses for U, indicating structurally bound U. Uranium is correlated with REE in both magmatic and hydrothermal garnets, indicating that the incorporation of U into the garnet is largely controlled by substitution mechanisms. Two hydrothermal garnets yielded U-Pb dates of 129 ± 2 (2 σ; MSWD = 0.7) and 130 ± 1 Ma (2 σ; MSWD = 0.5), indistinguishable from zircon U-Pb dates of 131 ± 1 and 129 ± 1 Ma for their respective ore-related intrusions. The magmatic garnet has a U-Pb age of 389 ± 3 Ma (2 σ; MSWD = 0.6), consistent with a U-Pb zircon date of 388 ± 2 Ma for the syenite. The consistency between the garnet and zircon U-Pb dates confirms the reliability and accuracy of garnet U-Pb dating. Given the occurrence of andradite-rich garnet in alkaline and ultramafic magmatic rocks and hydrothermal ore deposits, our results highlight the potential utilization of garnet as a powerful U-Pb geochronometer for dating magmatism and skarn-related mineralization. [ABSTRACT FROM AUTHOR]

Age determinations of rocks by in-situ Rb-Sr dating of minerals has the advantage of providing spatially resolved analysis without time-consuming preparation, but is hampered by isobaric and polyatomic interferences on Sr isotopes, especially 87Rb. LA-ICP-MS/MS using N 2 O as a reaction gas allows online chemical separation of 87Rb from 87Sr by measuring SrO+. Here, the method for in-situ Rb-Sr is optimized and applicability demonstrated for geological samples ranging from late Archean to 20 Ma in age. Rb-Sr isotopes of multiple reference materials and geological samples have been analyzed by LA-ICP-MS/MS to evaluate the method for dating rocks throughout the geological record. The quality of Sr isotopic data can be greatly improved by external calibration of mass bias. For internal calibration, better accuracy is obtained with the addition of H 2 as a trace molecular gas. The elemental fractionation of Rb and Sr during LA-ICP-MS/MS analysis varies for different reference materials. We find that the matrix of NIST SRM 610 renders it unsuitable for correction of 87Rb/86Sr. The Mica-Mg reference material is preferred for calibration of 87Rb/86Sr of micas despite showing significant Rb-Sr fractionation. In-situ Rb-Sr ages were determined for igneous samples ranging in age from 20 Ma to Mesoproterozoic, confirming accurate application of the method to samples of widely differing ages. The most accurate isochron ages were obtained with 87Rb/86Sr calibrated against Mica-Mg. Application to two metamorphic gneisses with late Archean protoliths from Labrador and Finland reveal thermal events at 1.66–1.70 Ga when they were part of a large Paleoproterozic active margin along the southern edge of Laurentia-Baltica. Data collected for minerals with differing closure temperatures for the Rb-Sr system allow detection of thermal events not recorded by other geochronological systems, indicating a huge potential of this technique not only for accurately dating samples, but also for providing previously inaccessible information on metamorphic histories. [ABSTRACT FROM AUTHOR]

The Wuliangshan Group occurs to the east of the Lancang giant igneous zone in SW Yunnan, and is mainly composed of low-grade metamorphosed sedimentary rocks. The group has been considered as the syn-orogenic product of the Baoshan with Simao-Indochina blocks. However, its depositional time and provenance remain to be poorly constrained. This paper presents zircon U-Pb dating and Lu-Hf-isotopic data for five representative sandstone samples from the Wuliangshan Group. The detrital grains yield a major age-peak at ∼259 Ma, and four subordinary age-peaks at ∼1 859, ∼941, ∼788, and ∼447 Ma, respectively. Our results suggest that the Wuliangshan metasedimentary sequence was deposited after Middle Triassic rather than previously-thought Cambrian. The detrital zircon age spectrum, along with in-situ Lu-Hf isotopic data suggest that the Wuliangshan Group might be a syncollisional sedimentary product related to the collision of Baoshan with Simao-Indochina blocks. It is inferred that the provenance of the Wuliangshan Group is mainly from the Simao/Yangtze blocks to the east rather than the Baoshan Block or Lancang igneous zone to the west. [ABSTRACT FROM AUTHOR]

It is shown that the granitoids of the Main Kolyma Batholith Belt do not penetrate into the Upper Jurassic deposits of the Yana-Kolyma mesozoids. The applicability of U-Pb SHRIMP zirconometry to the Mesozoic period of geological history is subject to critical analysis. It is concluded that analytical limitations preclude the solution of the concordance-discordance alternative of the obtained datings in the Mesozoic U-Pb isotopic systems by computational approaches. The U-Pb isotopic system is established as highly sensitive to the superimposed processes. Based on the reconciliation of the U-Pb, Rb-Sr, Ar-Ar, and K-Ar geochronometric data, the granitoids of the Kolyma Main Batholith Belt intruded 170-160 Ma ago, while their isotopic systems were transformed 150-140, 135-125, and 100-80 Ma ago. The local SHRIMP zirconometry combined with other isotopic methods can be applied to date igneous rocks by the relic dates, to set the time of intrusion into their isotopic systems, and to predict thermal events not identified yet. The U-Pb SHRIMP zirconometry should not be considered as arbitrary. [ABSTRACT FROM AUTHOR]

The Mesoarchean chromitites in the Singhbhum craton provide the main source of chromium in India. We report here results of dating zircon grains that were found in the chromitite of ultramafic rocks belonging to the southern part of the Archean Baula Complex. The chromite-bearing ultramafic rocks are cut by a gabbronorite intrusion, which had earlier been dated by SHRIMP at 3.12Ga. We have performed isotopic analysis of the zircon grains by Laser Ablation Multicollector Inductively Coupled Plasma Mass Spectrometry (LA-MC-ICP-MS) and obtained an age of 2.84Ga, which is inconsistent with the previous age reported for the gabbronorite. We have also determined the Pb isotopic composition of galena found in the chromitite and found out it was highly radiogenic given the Archean age of its host rock. We discuss the potential reasons for these results, such as later Neoarchean or even Proterozoic tectono-magmatic/hydrothermal events, and stress the importance of future detailed petrographic, mineralogical and isotopic studies to solve the dilemmas. [ABSTRACT FROM AUTHOR]

The Paleo-Tethyan arc belt is host to a small number of porphyry Cu deposits the key controls on which remains poorly understood. It has been hypothesized that the Paleo-Tethyan arc magmas were reduced and therefore less fertile for porphyry Cu formation but few studies have been conducted to directly assess the magmatic oxygen fugacity. We investigate the magma fertility of eastern Paleo-Tethyan arc igneous rocks in the Sanjiang region, SW China, represented by the Maoding (268.3 ± 2.3 Ma), Suwalong (275.6 ± 1.4 Ma to 264.7 ± 1.4 Ma) and Baimaxueshan (255.7 ± 1.5 Ma to 249.3 ± 1.1 Ma) granitoids. They have geochemical features consistent with typical continental arc rocks, formed from partial melting of the mantle wedge, with increasing contamination of crust-derived melts over time. The presence of amphibole, high Sr/Y ratios (35 ± 20, n = 17), and lack of negative Eu anomalies (Eu N /Eu N ⁎ = 1.04 ± 0.3, n = 17) are consistent with derivation from hydrous magmas. Zircons from the intrusive rocks have relatively low Eu N /Eu N ⁎ (mostly <0.4) ratios and calculated ΔFMQ values (−2.1 ± 1.2, n = 86). Combined with apatite microphenocrysts with extremely low sulfur contents (< 0.12 wt% SO 3), it suggests that the intrusions originated from water-rich but reduced arc magmas, that were less fertile for porphyry Cu formation. Our study highlights that magmatic f O 2 is probably a critical control on the prospectivity of arc systems and confirms that zircon and apatite compositions can be used to evaluate porphyry Cu fertility. • The Paleo-Tethyan arc igneous rocks were dated from ~275 to 249 Ma. • They were derived from partial melting of mantle wedge during MASH processes. • These arc magmas were reduced and less fertile for porphyry Cu formation. • Zircon and apatite compositions can be used to evaluate porphyry Cu fertility. [ABSTRACT FROM AUTHOR]

U–Pb zircon ages of igneous and metaigneous rocks in orogenic belts provide important information concerning the occurrence and duration of magmatic and metamorphic events whereas detrital zircon ages of metasedimentary sequences place constrains on the sources and deposition ages of supracrustal rocks. With these data, it is possible to compare and establish correlations between different provinces or between domains of the same province. A sufficiently large dataset of U–Pb ages is now available from the Borborema Province, northeastern Brazil, allowing the use of statistical methods to identify age peaks. 210 U–Pb crystallization ages from magmatic rocks and ca. 2300 U–Pb zircon ages of detrital grains from metasedimentary rocks were compiled. The igneous age spectrum shows two large age clusters. The first spans about 300 Ma, from 2.25 Ga to 1.97 Ga. Orthogneissic complexes in the Rio Grande do Norte Domain have ages mainly between 2.22 and 2.15 Ga whereas in the remainder of the province they more commonly range from 2.18 to 2.0 Ga. The long duration of this magmatism is comparable to that of Neoproterozoic and Phanerozoic accretionary/collisional orogens and is inferred to have resulted from amalgamation of preexisting crustal blocks and juvenile material to the active margin of the Rio Grande do Norte Domain. The other large cluster of ages is much narrower, from 650 Ma to 550 Ma, which is more consistent with the duration of orogenesis in collisional belts. Orogenic granitoids older than 600 Ma were not yet identified in the Rio Grande do Norte Domain, perhaps reflecting a thicker lithosphere that delayed initiation of the Brasiliano Orogeny. In contrast with the igneous rock-zircon record, the detrital zircon record requires sources with ages that span almost the whole Proterozoic eon. The presence of zircons ages in the 1.5–1.0 Ga and 0.85–0.65 Ga intervals, which contrasts with their absence, in the first case, or rarity, in the second case, amongst the igneous rocks, may be explained by derivation from igneous sources as yet undiscovered or removed by erosion, and/or by provenance from distal sources. The occurrence of 2.15–2.05 Ga-old detrital zircons in the Rio Grande do Norte Domain and of Tonian zircons in this domain and in the Ceará Central and Médio Coreaú domains imply the inexistence of physical barriers separating the northern and southern domains of the Borborema Province during the Neoproterozoic. The results are consistent with deposition in an intracratonic setting that became the site of lithospheric extension in response to far-field stresses. The ages of the youngest detrital zircons (650–630 Ma) indicate that deposition ended just before or at the beginning of the Brasiliano Orogeny. [ABSTRACT FROM AUTHOR]

García et al. (2021) analyzed paleomagnetic data from the Trans-Mexican Volcanic Belt (TMVB) for paleosecular variation analysis and stated that their work was the first systematic approach of that kind since 2005. This is incorrect, as Rodriguez-Trejo et al. (2019) published a much more comprehensive study, both in terms of the number of paleomagnetic data and their spatial extension within the TMVB, and this work was not even cited by Garcia et al. (2021). Additionally, Garcia et al. (2021) reported 11 allegedly new paleomagnetic directions from lava flows of monogenetic volcanoes and did not mention that 7 of these had been studied before by the same group (Maciel et al., 2014). Results are often similar, but in some cases dramatically different, now interpreted as being related to geomagnetic excursions or of different polarity. Such appalling differences between repeat studies of the same monogenetic volcano or lava flow must be declared, discussed, and in case of only minor differences statistical tests should be applied to check if such results could be combined into one direction. If such data are boldly different, they must be explained convincingly or otherwise resolved by additional sampling of the corresponding volcano. We also report numerous errors in the references, text, figures, and tables of that work. [ABSTRACT FROM AUTHOR]

Abstract: The Sillai Patti carbonatite complex represents the second largest carbonatite body of the Peshawar Plain Alkaline Igneous Province of northern Pakistan. It is situated about 20 km west of Malakand, near Sillai Patti village. Here, the carbonatite occurs along a fault in the form of a sheet striking in the NNE–SSW direction and dipping towards south. The carbonatite body is about 12 km long and 2–20 m thick, predominantly intruded along the faulted contact of metasediments and granite gneiss but locally, within the metasediments. A fission-track age of 29.40 ± 1.47 Ma was obtained for the Sillai Patti carbonatite complex. Close resemblance of fission-track apatite age of this study with the fission-track as well as other high temperature radiometric ages from the same and the neighboring carbonatite complexes of the alkaline belt of northern Pakistan suggests emplacement of the Sillai Patti carbonatite complex at higher crustal level and subsequent extremely fast cooling to near ambient temperatures (<60 °C) required for the complete retention of fission tracks in apatite. The age data also point out that the fission-track age of 29.40 ± 1.47 Ma of this study is the age of intrusion of the carbonatitic magma of Sillai Patti carbonatite complex to shallow, near-surface level. Comparison of the uplift induced denudation rates of the region with the world data clearly reflects the presence of a post collisonal extensional environment in the region south of Main Mantle Thrust during Oligocene time. This strongly negates the idea of the earlier workers of emplacement of the carbonatite complexes of the Loe-Shilman and Sillai Patti areas along thrust faults during Oligocene. [Copyright &y& Elsevier]

To decipher the thermal history of mineralized systems across the Freegold Mountain area (Yukon, Canada), a combined geochronology (zircon U-Pb and hornblende, biotite, and whole rock Ar-Ar) and thermochronology (apatite and zircon (U-Th)/He) study was carried out. Previous U-Pb data combined with new U-Pb and Ar-Ar data show that intrusive bodies across the Freegold Mountain were emplaced during two protracted episodes, the first spanning from 109.6 to 98 Ma and the second between 79 and 68 Ma. Overprinting of the first intrusive event by a second magmatic hydrothermal event is suggested by a zircon U-Pb age of 108.7 ± 0.4 Ma for a chlorite-altered dyke and a whole rock Ar-Ar plateau age of 76.25 ± 0.53 Ma. Zircon (U-Th)/He data are between 66 and 89 Ma, whereas apatite (U-Th)/He data are scattered (38.7-109.9 Ma) and bracket the two magmatic emplacement events. Our combined data reveal a complex history of reheating that led to resetting of numerous chronometers. In most of the investigated magmatic hydrothermal systems, early fast cooling from igneous emplacement through hydrothermal alteration (between 900 and 200 °C) was followed by later and slower cooling accompanying post mineralization uplift and erosion (between 200 and 70 °C). Preliminary models indicate intrusive bodies associated with the Stoddart Cu-Mo ± W prospect cooled slowly (23 °C/Ma) compared with the ones spatially associated with the Revenue Au-Cu prospect (43 °C/Ma), and the similarity of the zircon U-Pb and (U-Th)/He ages from Revenue dyke further supports a rapid cooling from 700 to 180 °C. Erosion rates of 0.035-0.045 mm/year are consistent with tectonic quiescence during the Late Tertiary combined with the lack of Pleistocene glaciation in central Yukon. Such low rates of exhumation favour the formation and preservation of supergene mineralization, such as that found north of Freegold Mountain. [ABSTRACT FROM AUTHOR]

Abstract: New U–Pb SHRIMP zircon ages and Sm–Nd isotopic results identify early Mesoarchean (∼3150Ma) granitic crust cropping out in the eastern Gawler Craton, southern Australia. These rocks are more than 500 million years older than the oldest previously dated rocks from the Gawler Craton, and challenge the view that pre-3.0Ga crust in Australia is restricted to the Yilgarn and Pilbara Cratons of Western Australia. We interpret these new data to indicate the presence of ∼3150Ma crust at or near the surface throughout a wedge-shaped region covering an area of at least ∼1500km2. The region is characterised by high surface heat flow, and contains Paleo- and Mesoproterozoic intrusive rocks with evolved Nd isotopic compositions and high radiogenic heat production values. The newly identified Mesoarchean rocks provide an obvious source for the evolved Nd signatures, and are themselves relatively enriched in heat producing elements, particularly considering their age. We speculate that the presence of relatively radiogenic Mesoarchean crust underlies much of the area covered by the South Australian Heat Flow Anomaly. Identification of Mesoarchean crust near the eastern margin of the Gawler Craton prompts consideration of links with other Australian Cratonic elements. As far as we are aware, no direct age equivalents of these rocks have been identified elsewhere in Australia, although we note that some recent models for Australian Proterozoic geodynamic evolution may be used to predict the presence of equivalent aged crust in the North Australian Craton. [Copyright &y& Elsevier]

Abstract: We present a new, reliably dated Mesoproterozoic paleopole for Siberia, based on a combined geochronological and paleomagnetic study of mafic rocks within the Mesoproterozoic Sololi Group of the Olenek Uplift in northern Siberia. Ion microprobe (SHRIMP) U–Pb analysis yields crystallisation ages of 2036±11Ma for zircon from a basement granite and 1473±24Ma for baddeleyite from a large dolerite sill within the Kyutingde Formation. The baddeleyite result indicates that the lower Sololi Group is significantly older than was suggested by previous K–Ar results. Paleomagnetic analysis of the dolerite sill and related mafic intrusive rocks yields a paleopole at 33.6°N, 253.1°E, A 95 =10.4°. A positive baked-contact test between the Kyutingde sill and sedimentary country rocks shows that the magnetisation is primary. Comparison of this paleopole with coeval results for Laurentia provides a revised reconstruction between Siberia and Laurentia, and implies that these two continents were parts of a single Mesoproterozoic supercontinent since at least 1473Ma. We argue that Siberia, Laurentia, and Baltica belonged to the same supercontinent between 1473Ma and mid-Neoproterozoic time. [Copyright &y& Elsevier]

A diverse suite of spatially and temporally juxtaposed igneous rocks ranging from alkaline lamprophyres to granites intruded south-central Colorado during late Oligocene and early Miocene time. In addition to the stocks of the East and West Spanish Peaks, there are three types of dikes exposed in the region, based on orientation: radial, subparallel (striking approximately east-west), and independent dikes. The most striking features of this area are the numerous dikes radiating out from West Spanish Peak, some rising several tens of meters above the surrounding terrain and discontinuously exposed for tens of kilometers. New results from 40Ar/39Ar dating indicate that magmatism in the Spanish Peaks region began about 26.6 Ma and continued until about 21.8 Ma. Field evidence suggests that the initial intrusions were subparallel alkaline lamprophyre dikes south of the Spanish Peaks. A subsequent period of sub-alkaline magmatism occurred, producing West Spanish Peak (24.6 ± 0.13 Ma), East Spanish Peak (23.9 ± 0.08 Ma), and the radial dikes focused on West Spanish Peak. The final phase of magmatism included subparallel sub-alkaline lamprophyre dikes northeast of the Spanish Peaks. The 40Ar/39Ar results of this study substantiate the intrusive history derived from field relationships and establish the order of intrusion as West Spanish Peak, East Spanish Peak, and radial dikes, respectively. This study has implications for both the timing and style of the initiation of the Rio Grande rift, as well as the petrogenetic relationship between alkaline and sub-alkaline rocks in relatively stable cratonic areas. [ABSTRACT FROM AUTHOR]

This study presents the results of radiometric K-Ar measurements on separated amphiboles from the andesite of the Dubie complex dyke. The data obtained cover the period of (291.3 ± 6.4) Ma, which corresponds to Carboniferous-Permian transition. The age is contemporaneous to the rhyodacitic and basaltoid volcanism of the Krakow region. [ABSTRACT FROM AUTHOR]

An extensive set of north- to northwest-trending diabase dykes, termed the Lac Esprit swarm, is identified in the Superior Province east of James Bay based on geological mapping and a distinctive paleomagnetic pole (61.7°N, 169.1°E, dm = 7.7°, dp = 5.5°). The Lac Esprit swarm yields a U–Pb baddeleyite age of 2069 ± 1 Ma similar to that of the 2076+5–4 Ma Fort Frances swarm of the western Superior Province. Their paleomagnetic declinations differ by 23° ± 12° after correction to a common reference locality. The difference is likely due mainly to counterclockwise rotation about a vertical axis of the Fort Frances area relative to the Lac Esprit area. Differential rotation of 10°–20° has been proposed more locally across the Kapuskasing Structural Zone separating the eastern and western Superior Province in earlier paleomagnetic studies of ca. 2450 Ma Matachewan and 2170 Ma Biscotasing dyke swarms. Thus, relative rotation may have involved the entire eastern and western Superior Province, perhaps in response to collisional events associated with the Trans-Hudson Orogen to the north or the Penokean orogen to the south, or in response to rifting beneath Hudson Bay. Other dykes in the study area are interpreted from a combination of paleomagnetism, trend, and geochemistry to belong to the Senneterre, Matachewan, and Mistassini swarms. The 2216 Ma Senneterre dykes form part of a giant swarm that fans across the eastern Superior Province. Paleomagnetic directions and geometry of this swarm rule out substantial block rotations within the eastern Superior Province since dyke emplacement. [ABSTRACT FROM AUTHOR]

The Maomaogou nepheline syenite is located at the inner zone of the Emeishan large igneous province and exhibits Intrusive contact with the Emeishan basalts. SHRIMP U-Pb dating on zircons from this syenite yields an age of 261.6±4.4 Ma, in agreement with the age of the Panzhihua layered intrusion and the eruption age of the Emeishan basalts as constrained by stratigraphic data. Geochemical data further suggest that the Maomaogou syenite has a source analogue to the Emeishan basalt, and may have been formed by partial melting of gabbroic cumulates underplated in the lower crust. As s result, temporal and spatial relationships and petrogenetic constraints provide evidence for the genetic link between basalts, mafic/ultramafic and Intermediate/acidic intrusives in the Panxi area. [ABSTRACT FROM AUTHOR]

The arc sequence in the lower Shyok area comprises volcanics (Shyok Volcanics) and intra-arc basin sediments (Hundiri, Saltoro Flysch and Saltoro Molasse formations). Biostratigraphic investigations on the Hundiri Formation indicate that this lithounit contains several Aptian-early Albian orbitolinids comprising Mesorbitolina, Orbitolina, Praeorbitolina, Palorbitolinoides, Palorbitolina, ?Neorbitolinopsis and Paracoskinolina. The orbitolinid taxa from the Shyok tectonic belt are comparable with those known to occur in Ladakh, Chitral, Burzil Pass (Indo-Pak region), Afghanistan, South Tibet and Myanmar. Fossil data suggest the existence of transgressive Neo-Tethys sea during Early Cretaceous, north of the Indian Plate. [ABSTRACT FROM AUTHOR]

Recent advances in U–Pb geochronology allow unprecedented levels of precision in the determination of geological ages. However, increased precision has also illuminated the importance of understanding subtle sources of open-system behavior such as Pb-loss, inheritance, intermediate daughter product disequilibria, and the accuracy of the model assumptions for initial Pb. Deconvolution of these effects allows a much richer understanding of the power and limitations of U–Pb geochronology and thermochronology. In this study, we report high-precision ID-TIMS U–Pb data from zircon, baddelleyite, titanite and apatite from the McClure Mountain syenite, from which the 40Ar/39Ar hornblende standard MMhb is derived. We find that excess 206Pb in zircon due to inclusions of high-Th minerals and elevated Th/U in titanite and apatite jeopardize the utility of the 238U–206Pb system in this rock. Strongly air-abraded zircons give dates that are younger than chemical-abraded zircons, which yield a statistically robust 207Pb/235U date of 523.98±0.12 Ma that is interpreted as the crystallization age. We explore the best method of Pbc correction in titanite and apatite by analyzing the U–Pb isotopes of K-feldspar and using 2-D and 3-D regression methods—the latter of which yields the best results in each case. However, the calculated compositions of Pbc for titanite, apatite and K-feldspar are different, implying that using a single Pbc correction for multiple U–Pb thermochronometers may be inaccurate. The U–Pb thermochronological results are used to predict a closure time for Ar in hornblende of 522.98±1.00 Ma. Widely cited K–Ar and 40Ar/39Ar dates overlap with the U–Pb date, and relatively large errors make it impossible to verify whether U–Pb dates are systematically ≤1% older than K–Ar and 40Ar/39Ar dates. [ABSTRACT FROM AUTHOR]

Eclogites from the deepest structural levels beneath the Semail ophiolite, Oman, record the subduction and later exhumation of the Arabian continental margin. Published ages for this high pressure event reveal large discrepancies between the crystallisation ages of certain eclogite-facies minerals and apparent cooling ages of micas. We present precise U-Pb zircon (78.95 ± 0.13 Ma) and rutile (79.6 ± 1.1 Ma) ages for the eclogites, as well as new U-Pb zircon ages for trondhjemites from the Semail ophiolite (95.3 ± 0.2 Ma) and amphibolites from the metamorphic sole (94.48 ± 0.23 Ma). The new eclogite ages reinforce published U-Pb zircon and Rb-Sr mineral-whole rock isochron ages, yet are inconsistent with published interpretations of older 40Ar/39Ar phengite and Sm-Nd garnet dates. We show that the available U-Pb and Rb-Sr ages, which are in tight agreement, fit better with the available geological evidence, and suggest that peak metamorphism of the continental margin occurred during the later stages of ophiolite emplacement. [ABSTRACT FROM AUTHOR]

Metabasic rocks from different parts of the Antrona ophiolites, Western Alps, as well as from the Misox zone, Central Alps, were dated using ion microprobe (SHRIMP) U-Pb analyses of zircon, in association with cathodoluminescence (CL) imaging. HP metamorphism must have affected at least the major part of the Antrona ophiolites, although HP relics are rarely preserved, probably due to the Lepontine metamorphic overprint. HP metamorphism has affected also the area of the Misox zone. The origin of the Antrona ophiolites is arguable. They were interpreted as part of both the Piemont–Ligurian (PL) and the Valais ocean, the two main oceans in the area of the Alps before Alpine convergence. SHRIMP-analyses of co-magmatic zircon domains from the Antrona ophiolites (Guggilihorn, Passo del Mottone and Quarata areas) yielded identical (within uncertainty) weighted mean206 Pb/238U ages of 155.2±1.6 Ma, 158±17 Ma (or 163.1±2.4 Ma: one analysis; 1σ error) and 155.6±2.1 Ma, respectively, interpreted as the time of crystallization of the magmatic protoliths. These Late Jurassic ages fit well to the time span considered for the formation of Piemont–Ligurian oceanic crust. The metagabbro of the Misox zone (Hinterrhein area), for which a Valaisan origin is generally accepted, gave also a Late Jurassic, PL protolith age of 161.0±3.9 Ma. The metamorphic zircon domains from the amphibolitized eclogite of Mottone yielded an age of 38.5±0.7 Ma, interpreted as the time of HP metamorphism. This age is in good agreement with the time of metamorphism reported from previous zircon SHRIMP-data for eclogites and amphibolites of other parts in the Valais domain. In order to bring in line the PL protolith ages with the Valaisan metamorphic ages, we suggest a scenario involving emplacement of part of the PL oceanic crust to the north of the newly formed Briançonnais peninsula, inside the Valais geotectonic domain. This paleotectonic configuration was probably established when younger Valaisan oceanic crust formed by spreading and re-rifting, partly within PL oceanic crust. [ABSTRACT FROM AUTHOR]

Various shaped mafic microgranular enclaves (MMEs) together with several mafic massifs are developed within the Yuegelu granitoid pluton in the eastern part of the Eastern Kunlun. On the basis of detailed field geological surveying and of the results of the petrological and geochemical studies it is suggested that there must be some genetic relationship among the granodiorite host, the MMEs and the hornblende (Hb)-gabbro massifs. Magmatic zircon grains are extracted from samples of granodiorite host rock, Hb-gabbro and the MMEs for U-Pb dating. The U-Pb ages are determined by using SHRIMP II technique, which yields the ages of 242±6 Ma, 239±6 Ma and 241±5 Ma, respectively. The overall correspondence in the U-Pb dating results of them excludes the possibility that the MMEs in the granitoids are solid refractory relics from the source region or that they are xenoliths from the wall rocks. It can also rule out the possibility of a later emplacement of basic magma after the solidification of the granitoids. This dating result indicates that they are the products of magma mixing in early-mid Triassic epoch. Among them the granitoid host is chemically akin to the acidic end member during the magma mixing process, the Hb-gabbro is akin to the basic ones while the MMEs are the incompletely mixed basic magma clots trapped in the acidic magma. Combined with the results from other researches on this pluton it is reasonable to consider that in the mid-Triassic the Eastern Kunlun granitoid belt had undergone a process of magma mixing between the mantle-derived basic magma and the crustal acidic magma which indicates that the injection of mantle materials and energy into the crust and the reactions between them played an important role in the formation of the granitoid rocks. [ABSTRACT FROM AUTHOR]

Volcanic ash beds from shallow- to deep-water facies strata of the Sinian-Early Cambrian (Meishucunian) on the Yangtze Platform consist of bentonites and tuffites which are readily recognized in the field by their physical features and confirmed by geochemical analyses. Geochemistry suggests that the volcanic ash beds in Meishucunian time are rhyolite and rhyodacite while those in the Qiongzhusian and Sinian are andesite and trachyandesite. The ash beds in the time-equivalent strata, even in different areas display rather similar geochemical features, whereas the ash beds in different strata even in the same areas show large chemical difference. The results suggest that these ash beds can be used for intra- and extra-basinal correlations of the Sinian-Early Cambrian interval on the Yangtze Plat-form. Additionally, these ash beds suggest high potentials for further U-Pb dating strategies. [ABSTRACT FROM AUTHOR]

Reports on K-Ar dating of late Mesozoic volcanism in the Dabie orogenic belt. Identification of two eruption episodes; K-Ar dating of the volcanic rocks in the North Huaiyang belt (NHB); The earlier volcanic suite termed Maotanchang Fm. (Fm.) occurring at Jinzhai, Xianhualing and Maotanchang, etc. and erupting from 149 Ma to 138 Ma; The Xiaotian Fm. occurring at Xiaotian, Shucheng, etc. forming between 132 Ma and 116 Ma; The two volcanic suites depositing a volcano-sedimentary conglomerate layer during the eruption gap; Composition of the multi-compositional gravels, which included the North Dabie orthogneiss complex (NDOC), volcanic gravels, etc.; Volcanic gravels in the conglomerate layer showing identical geochemical and isotopic compositions (87Sr/86Sr(t) = 0.7084-0.7092, εNd (t) = -21.8-24.4) to the Maotanchang Fm. volcanic rocks (87Sr/86Sr = 0.7086-0.7102, εNd = -19.2 to -24.4); Distinction from those of Xiaotian Fm. (87Sr/86Sr = 0.7076-0.7084, εNd = -17.2 to -19.2); Indication from K-Ar dating that underlying and overlying volcanic sequences in the conglomerate layers were deposited at ∼135 Ma and the NDOC rapidly exhumed to the surface during or shortly before this time to become the volcano-sedimentary basins in the NHB; Division of the NHB sequence from base to top into Fanghushan Fm., Yuantongshan Fm., Maotanchang Fm. and Xiaotian Fm.

Rocks from the Sulphur Springs Group, a newly identified stratigraphic succession hosting volcanogenic massive sulphide (VMS) base-metal deposits in the Soanesville Belt, Pilbara Craton, northwestern Australia, have been analyzed by sensitive high-resolution ion microprobe (SHRIMP) U–Pb zircon mass-spectrometry to determine their age and tectonostratigraphic relationships. Most volcanism occurred between 3238 and 3235 Ma, distinctly different from the time interval spanned by the Wyman Formation (type section is 3315 Ma, other dates ∼3325 Ma) with which it was previously correlated. Outlying volcanic rocks with similar geochemistry at the Bernts and Obelix prospects also produce dates from 3240 to 3235 Ma and are, therefore, best interpreted as structurally-detached fragments of the Sulphur Springs Group. The Strelley Granite, an intrusion which shares geochemical characteristics with the overlying volcanic rocks, also yields similar ages, thus extending the period of temporally-linked extrusive–intrusive silicic magmatism in the evolution of the Pilbara Craton. Model Pb–Pb dating of galena from the Zn–Cu mineralization at the various VMS prospects has yielded ages consistent with the zircon U–Pb ages of the host rocks, indicating that the hydrothermal mineralizing systems were contemporaneous with and apparently initiated by igneous activity. An epicontinental tectonic setting for the Sulphur Springs Group during VMS mineralization is implied by the broad range of old zircon ages obtained from a tuff at the base of the volcanic pile. As the igneous episode coincides with the peak regional metamorphic event recorded in other east Pilbara supracrustal rocks and with voluminous intrusive activity in nearby granitoid complexes, it marks a major event in the crustal evolution of the eastern Pilbara Craton. [Copyright &y& Elsevier]

Investigates single crystals of dispersed trace pyrite using laser probe method. Comparison of age results to step heating ages of amphibole and phlogopite; Observation of internal isochrons in step-heated crystals; Application to the dating of ores,sediments,and hydrocarbon migration.

The Upper Triassic successions in the Qiangtang Basin are important targets for petroleum exploration, although they are poorly understood at present. The black mudstones collected from well QZ-16 are the deepest Upper Triassic source rocks to date and have over-mature organic matter (OM) (R o > 2). In this study, the total organic carbon (TOC) and systematic inorganic geochemistry were determined to reconstruct depositional conditions (palaeoclimate, palaeosalinity, primary productivity, redox conditions, sedimentation rate, and detrital influx) and to assess the OM accumulation mechanism. The TOC contents of the Bagong Fm. mudstones first decrease and then increase from bottom to top (Unit A to Unit D), and Unit C has the lowest TOC contents. These mudstones have relatively obvious correlations between TOC content and the palaeosalinity proxy (Sr/Ba), redox indexes (U/Al, V/Al, Mo/Al, U/Th, and V/Cr) and sedimentation rate indicator ((La/Yb) N), which indicate that OM accumulation was dominated by both high salinity and a slow sedimentation rate in a dysoxic environment. The high Al 2 O 3 /TiO 2 ratios indicate that the provenance of these mudstones was primarily from felsic igneous rocks. High detrital influx of felsic igneous rock provenance would have diluted the OM and inhibited OM preservation, as evidenced by the negative correlations between TOC content and detrital influx parameters, including SiO 2 , Al 2 O 3 , TiO 2 , and K 2 O. The primary productivity (P/Al and Ba/Al) is poorly correlated with TOC for these mudstones, suggesting that its effect on OM accumulation was negligible or limited. The relatively high TOC contents of mudstones from Units A and B are mainly related to the interaction of dysoxic conditions, a high-salinity water column, slow sedimentation rates, and a low detrital influx. An oxidizing water column with low salinity and a relatively high detrital influx and sedimentation rate upward in Unit C led to greater OM degradation and dilution and the lowest TOC contents. The significant TOC content fluctuations in Unit D may be related to vertical variations in the depositional conditions. [Display omitted] • OM accumulation mechanism of the over-mature source rocks are presented in detail. • The effect of primary productivity on OM accumulation was limited in these mudstones. • Preservation conditions were the main factors controlling the OM accumulation. [ABSTRACT FROM AUTHOR]

The radiometric data available in the Trans-Mexican Volcanic Belt enables a quasi-continuous record of the Earth's magnetic field over the last million years to be obtained. Here, we analyze 149 well-defined paleomagnetic directions supported by an equal number of isotope ages. Eleven new paleomagnetic directions from the Tacambaro-Puruaran area (the Michoacán Guanajuato Volcanic Field) are incorporated into the database. Global mean paleomagnetic directions are calculated for one Ma after discarding transitional lavas. The mean direction agrees with the expected paleomagnetic directions obtained from the Pliocene-Quaternary reference poles within the range of uncertainty. The secular variation rate estimated through the scattering of the calculated virtual geomagnetic poles, and the inclination anomaly, both agree with recently reported latitudinal distribution models. An interesting feature of the paleomagnetic direction compilation is the possible evidence of relatively short geomagnetic events or excursions within Matuyama and Brunhes chrons, which may help to refine the geomagnetic instability time scale (GITS). • 149 well-defined paleomagnetic directions supported by an equal number of isotope ages. • The mean direction agrees with the expected paleomagnetic directions retrieved from the Pliocene-Quaternary reference poles. • Analysis of the paleosecular variation for the last 1 Ma. • Possible evidence of relatively short geomagnetic events or excursions within Matuyama and Brunhes chrons. [ABSTRACT FROM AUTHOR]

Presents a study which aims to present zircon-lead and uranium lead ages for samples of charno-enderbite form the Magondi belt, Zimbabwe. Field relations and petrography of charno-enderbites; Evaporation and digestion techniques used in the; Results and discussions; Conclusions.

A growing awareness of life in deep igneous crust expands our appreciation for life's distribution in the upper geosphere through time and space, and extends the known inhabitable realm of Earth and possibly beyond. For most of life's history, until plants colonized land in the Ordovician, the deep biosphere was the largest reservoir of living biomass. This suggests that deep crustal habitats played an important role in the evolution and development of the biosphere. Paradoxically, the paleo-perspective of deep life has been largely neglected in the exploration of the deep biosphere as well as in paleontology as a whole. Here, we review the collective understanding of the fossil record in igneous crust with the aim to highlight a rising research field with great potential for substantial findings and progress in the near future. We include new results that emphasize the importance of direct or indirect dating of fossils and introduction of new techniques into the field. Currently, an incoherent record of morphological fossils- and chemofossils stretching from present to ~2.4 Ga implies the presence of an abundant and rich, yet largely unexplored, fossil record. Further investigations of deep paleo-environments will most certainly result in substantial insights into the distribution and development of biospheres throughout life's history, the early evolution of prokaryotes and eukaryotes, and Earth's early biogeochemical cycles. We emphasize the fossil record of igneous rock to give it the same status as the fossil record in sedimentary rocks, and to implement fossil investigations as standard procedures in future international drilling campaigns. [ABSTRACT FROM AUTHOR]

Identifying basement rocks is critical to understanding the continent formation and evolution during orogenesis. Despite two decades of research, the age and composition of the basement rocks of the Southern Qiangtang Terrane/Microcontinent (SQT), Central Tibet are still unclear. In this study, zircon U–Pb ages and Hf–O isotopes, as well as whole-rock Nd isotopes are presented for the oldest known igneous rocks in the SQT. Precise SIMS zircon U–Pb dating of these rocks reveals that these early Paleozoic granites were crystallized at ca. 480‐465 Ma. They exhibit a wide range of isotopic values, with unradiogenic whole rock ε Nd (t) and zircon ε Hf (t) values ranging between −8.3~−7.7 and −8.2~−2.3, respectively, and by high δ18O zircon values of +8.1~+11.4‰. These results reveal that the early Paleozoic granites were crystallized from magmas that were almost entirely sediment-derived. When viewed in concert with regional data and constraints on the tectonic evolution of northern Gondwana, the sources for the early Paleozoic granites are herein proposed to have been deposited in an extensional basin, implying that these early Paleozoic granites were generated in an extensional setting within an accretionary orogen. Thus, the early Paleozoic granites are considered to represent the basement of the SQT. After a long period of attachment to northern Gondwana, the SQT became a small microcontinent when it was rifted and detached from northern Gondwana during Early Permian. After this time, it drifted northwards to Asia, and collided with the Northern Qiangtang Terrane to form a unified Qiangtang terrane in the Late Triassic. Thus, the SQT records a complete Wilson cycle from construction, rifting and departure, drifting to collision. • Pure sedimentary-derived early Paleozoic granites reported in Southern Qiangtang. • The basement of the SQT formed during early Paleozoic. • The SQT recorded a whole Wilson cycle from construction, rifting to collision. [ABSTRACT FROM AUTHOR]

The article attempts to describe the geological history of the early earth through the examination of igneous zircons. According to the author, zircons are the oldest minerals on earth, dating as much as 4.4 billion years ago. Several studies have been performed in order to analyze the geochemistry of the said mineral in order to generate significant information regarding the conditions on early Earth as well as the composition of its early crust. Further information regarding the relativity of the minerals to the earth's geologic history is provided.