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Direct dating of vertebrate fossils is difficult due to complex postburial diagenetic processes and the often low and heterogeneous concentration of radioisotopes (e.g., U) in fossilized bone material. Here, we demonstrate a novel approach to dating vertebrate fossils via laser ablation–inductively coupled plasma–mass spectrometry U-Pb dating of early diagenetic calcite cements precipitated within bone cavities of a Jurassic sauropod from the Sichuan Basin, South China. Early diagenetic calcite yielded a U-Pb age of 165.3 ± 3.6/5.6 Ma, in agreement with a maximum depositional age of 165.8 ± 1.0 Ma from detrital zircon ages of the surrounding rocks, suggesting that diagenesis occurred shortly after the death of the sauropod. This new age demonstrates that the best-known Jurassic large sauropod faunas in South China are much older than those in North America and Africa, suggesting the geographical isolation of South China. Authigenic apatite U-Pb dating on the fibrolamellar bones from the same sauropod gave a distinctly younger age, indicating more complex U-Pb system behavior, possibly due to U uptake by residual organic matter and recrystallization of apatite after early diagenesis. Our findings demonstrate that U-Pb dating of calcite cements within bone cavities has significant potential for constraining the burial age of vertebrate fossils, which could aid in constructing a more robust temporal framework for the radiation and evolution of vertebrates. [ABSTRACT FROM AUTHOR]

The Oaxacan Complex Carboniferous-Permian sedimentary cover in southern México records provenance shifts through time, reflecting the collision between Gondwana and Laurentia to amalgamate Pangea. The integration of petrological analysis and LA-ICP-MS U-Pb zircon geochronology from Santiago, Ixtaltepec and Yododeñe formations compared with adjacent terranes suggests that: (1) during the Early Mississippian, the Santiago Formation received sediments mainly from local sources such as the Oaxacan Complex and Tiñu Formation, with minor contributions from adjacent peri-Gondwana sources. The magmatic activity may have started during this time (~359–346 Ma) (2) during the Late Mississippian (Ixtaltepec Formation), detrital zircon grains of Ediacaran-Cambrian age are dominant, derived from sediments either related to the Pan-African/Brasiliano orogeny or the opening of the Iapetus Ocean; (3) during the Late Mississippian-Middle Pennsylvanian, intercalated marine volcaniclastic sandstone (Ixtaltepec Formation) provides the first record of Carboniferous arc-related volcanism reported in southern Mexico, dated between 330 and 308 Ma; (4) the early Permian Yododeñe Formation records the exhumation and erosion of the sedimentary cover during the final stage of Pangea assembly. Rhyodacitic subvolcanic sills and lavas dated at ~282–270 Ma are present throughout the succession. Volcanism and ca. 360–308 Ma detrital zircon grains could be associated with a Carboniferous magmatic arc formed by subduction of the Rheic oceanic plate beneath Gondwana. Slightly younger detrital zircon and subvolcanic rocks dated at ~300–270 Ma are linked to a western Pangea arc developed in response to the subduction of the Paleo-Pacific Ocean following Pangea assembly. Our results suggest that the Carboniferous-Permian units were deposited in a peri-arc basin, sharing sediment provenance with the Maya and Coahuila blocks, the Sierra de Juárez Complex, and northwestern South America. [ABSTRACT FROM AUTHOR]

Two new rock art sites in Irob district of eastern Tigrai, northern Ethiopia, are presented. One of the sites, Ra Bolo, contains images of domestic cattle and human figures while the other, Adhay Bolo, appears to contain only images of caprines, the only example of such a scene not just in the region but in all of Ethiopia. The sites fit well with the already established northern Ethiopian assemblage of paintings and engravings. The paintings belong to the earliest phase of Ethio-Arabian "Surre-Hanakiya" style, an attribution which is supported by other types of archaeological data. These new rock art sites are also compared with other rock art sites in Ethiopia. Archaeological faunal data from northern Ethiopia and elsewhere in Ethiopia is discussed and questions are raised about the validity of the hypothesized ages of the rock art in south-central Ethiopia. [ABSTRACT FROM AUTHOR]

The drift history of the Lhasa terrane from Gondwana to Asia plays a crucial role in understanding the Tethys evolution and true polar wander (TPW). However, few reliable paleomagnetic results from Jurassic strata are currently available for reconstructing its northward journey. We performed a combined paleomagnetic and geochronological study on Bima Formation strata in the Xigaze area. Combined with previous results from the Sangri area, our results reveal a paleolatitude of 8 ± 4°S at ∼180 Ma for the reference point (29.3°N, 90.3°E). Along with other paleomagnetic results from the Triassic to Cretaceous, our new results suggest that the Lhasa terrane motion accelerated from ∼2 cm/yr during ∼220–180 Ma to ∼17 cm/yr during ∼180–170 Ma. Paleolatitude information of the North Qiangtang terrane and Tethyan Himalaya is calculated from paleopoles that meet five criteria, which include (a) structural control, (b) well‐determined rock age, (c) stepwise demagnetizations, (d) a minimum of 25 specimens or 8 sites are contained, and (e) robust field or reversal tests are provided. Both terranes also show significant acceleration during their northward motion, which may be related to oceanic slab subduction. Thus, all Gondwana‐derived microcontinents seem to share a significant acceleration during their northward motion. In addition, recent paleomagnetic results from volcanic rocks dated at ∼155 Ma subdivide the overall northward motion during ∼170–130 Ma into two stages, which include a southward drift during ∼170–155 Ma followed by northward motion during ∼155–130 Ma. These results support the fast Late Jurassic TPW during a ∼10 Myr time span. Plain Language Summary: The Tibetan Plateau is composed of the Qiangtang, Lhasa, and Himalaya terranes that originate from Gondwana, which was an ancient supercontinent located mainly in the southern hemisphere. How these terranes moved northward from Gondwana to Asia remains unclear due to poor paleolatitude constraints. We provide paleomagnetic evidence to show that the Lhasa terrane was located at ∼8°S at ∼180 million years ago (Ma). Together with reliable paleomagnetic data from Late Triassic (∼237–201 Ma) limestones and Middle Jurassic (∼174–163 Ma) sandstones, our results suggest a significant acceleration during Lhasa's northward motion at ∼220–170 Ma. Reliable paleolatitude data show significant accelerations of the Lhasa, North Qiangtang, and Tethyan Himalaya terranes during their northward journey, which may be related to oceanic slab subduction. These significant accelerations may be a common feature of these Gondwana‐derived microcontinents. The drift history of the Lhasa terrane during ∼170–130 Ma can be subdivided into a southward drift during ∼170–155 Ma and a subsequent northward drift during ∼155–130 Ma. The yoyo‐like drift motion of the Lhasa terrane near the equator before and after ∼155 Ma supports a fast Late Jurassic pole motion event (named true polar wander) during a ∼10 Myr time span. Key Points: The Lhasa terrane was located at ∼8°S at ∼180 Ma for the reference point (29.3°N, 90.3°E)Lhasa terrane's motion accelerated from ∼2 cm/yr during ∼220–180 Ma to ∼17 cm/yr during ∼180–170 MaThe Lhasa terrane underwent a yoyo‐like drift motion near the equator at ∼170–130 Ma, supporting the fast Late Jurassic true polar wander [ABSTRACT FROM AUTHOR]

The Urals is one of the reference mobile belts of the mafic type characterized by a wide development of ophiolites which are associated with numerous deposits of chromites of significant industrial importance. In this regard, the estimation of the age of the rocks of the ophiolite association will be useful for analyzing the regularities of the formation of chromite deposits. This work presented the results of age dating of the rocks of the chromite-bearing Kluchevskoy mafic–ultramafic massif, one of the most representative of all the ophiolite-type massifs in the Urals, by two isotopic methods. The U–Pb (SHRIMP-II, VSEGEI) dating of the zircon dominated assemblage from rocks of different composition of both crustal and mantle sections of the Kluchevskoy ophiolite massif yielded similar dates ranging from 456 to 441 Ma. The study of the composition of silicate inclusions in zircon grains of this assemblage showed that they are represented by typical metamorphic minerals: low-T amphibole, albite, and an epidote-group mineral. The P–T conditions of zircon crystallization established via the examination of the composition of minerals in these inclusions showed that the crystallization of the predominant fraction of zircons coincides in time with the lower epidote–amphibolite and upper green-schist facies metamorphism of rocks happening under the decompression conditions, i.e., during their exhumation from the deep crustal level (8–13 km). A small amount of zircons of late generation showed a wide spread in age (277.4–318.1 Ma). The time of their crystallization corresponds to the stage of metamorphism associated with the collision orogeny in the Ural mobile belt. The more ancient 147Sm–143Nd age of 514 Ma should be assumed as the formation time of the rocks (or its upper age boundary). [ABSTRACT FROM AUTHOR]

(1) Background: The widely developed thrust structures in the Jingzhushan Formation of late Cretaceous in Nyima Basin are related to the collision which leads to orogeny between the Lhasa and Qiangtang blocks. Clarifying the tectonic properties of the Nyima Basin is of great significance to characterize the evolution of the collision between the Lhasa block and the Qiangtang block. (2) Methods: Combined with mineralogy and petrology and U-Pb zircon dating of extrusive rocks, a detailed magnetic fabric test and rock magnetic experiment were carried out on the red sandstones of the Late Cretaceous Jingzhushan Formation in Nyima Basin. (3) Results: The sedimentary magnetic fabrics developed at the three sampling locations in the southern part of the basin are related to paleocurrents. The strained magnetic fabrics developed at one sampling site in the north, including pencil-like fabrics and tensile linear fabrics, are related to SE-NW tectonic stress. The average magnetic susceptibility value of the strained fabric with sandstone is lower than that of the sedimentary fabric, and its size is controlled by mica paramagnetic minerals. Ferromagnetic minerals are magnetite or hematite. In addition, the age of sandstone in the Jingzhushan Formation from the Nyima Basin matches the age of the eruptive rock in the Jingzhushan Formation from Coqen Basin, which is 92 Ma. (4) Conclusions: The strained fabric is developed near the thrust fault, which can explain the widely developed thrust structures in the basin. The Nyima Basin of the Jingzhushan Formation in the Late Cretaceous was an ocean-continent transitional foreland basin developed under the background of arc-arc "soft collision". [ABSTRACT FROM AUTHOR]

New geochemical and geochronological data lead to a fuller understanding of different aspects of the Rajmahal flood basalt province. Earlier work was on surface Rajmahal flows as well as from the nearby Bengal Traps. Samples from a ~300 m borehole near the northwestern corner of the Rajmahal lavas, analyzed herein, reveal the presence of carbonatitic (aillikitic) material. This small province, including the Bengal Traps, thus exhibits quartz and olivine tholeiites, andesitic basalts, alkali basalts as well as carbonatitic material. The Sylhet Traps, lying ~500 km to the east of the surface Rajmahal flows, show geochemical similarities, but were probably formed ~10 Myr after Rajmahal volcanism. Sr–Nd isotopic plots suggest that (a) not all lavas in the Rajmahal Traps were homogenized isotopically prior to eruption and (b) the Sylhet Traps show a much wider variety of isotopic values at eruption, possibly caused by alteration. Published and new 40Ar/39Ar ages for both the Rajmahal and other mafic rocks postulated to have been formed by the Kerguelen Hotspot in the Southern Indian Ocean, are critically examined; emphasis is placed on the freshness of the rocks dated. It is shown that a number of 'ages' for both the Rajmahal Province, and for rocks recovered from the Kerguelen Plateau area, should be rejected as invalid measures of the time of crystallization, as altered material was dated. For the surface Rajmahal material, valid ages span ~120 (quartz tholeiites) to ~116 Ma (andesitic basalts); alkali basalts and olivine tholeiites (Bengal Traps) as well as the aillikite were also formed within this time interval. The postulated genetic link to the Kerguelen Hotspot and basalts in the Southern Indian Ocean appears valid; in particular, a section of the southern Kerguelen Plateau (~58°S; 75°E) has strong geochemical and temporal links to the Rajmahal Traps. [ABSTRACT FROM AUTHOR]

The Guide Basin, located in the West Qinling orogen of central China, is a typical geothermal field. However, the granodiorites occurring in the Zhacanggou area have been poorly restricted. Herein, we report new isotopic compositions of whole‐rock major‐trace elements, zircon U–Pb, and Lu–Hf, on the host granodiorites and their microgranular enclaves (MEs) in the Zhacanggou area. Zircon U–Pb dating for the host rocks (porphyritic granodiorite and granodiorite) revealed ages of 230.5 ± 1.4 Ma and 229.0 ± 1.6 Ma, similar to those (230.5 ± 1.5 Ma and 231.4 ± 1.4 Ma) of the MEs. Zircon Hf isotope analyses for the granodiorite and MEs yielded εHf(t) values from −11.0 to −1.5 and from −7.8 to −0.7, with corresponding TDM2 ages of 1,355–1,959 and 1,304–1,755, respectively. The MEs possess plagioclase phenocrysts, acicular apatites, and chilled borders. They were characterized by relatively low SiO2 (58.39–65.24 wt%) and high Cr, Ni, and MgO contents, leading to relatively high Mg# values (44–59) and low Sr/Y (14.23–19.84) ratios. The host granodioritic rocks show similar adakitic geochemical characteristics with SiO2 = 64.23–68.57 wt%, MgO = 1.29–2.22 wt%, Mg# = 48–53, Sr = 340–596 ppm, Y = 11.3–13.7 ppm, Sr/Y = 28.39–47.89, and no obvious Eu anomalies. These geochemical and isotopic data, combined with the mineralogical features, indicate that the granodiorites in the Zhacanggou area were produced by the mixing of high‐Mg# melts originating from an enriched lithospheric mantle source, and felsic magmas deriving by the partial melting of the normal lower continental crust with the tectonic regime transition from a syn‐collision to a post‐collision setting. [ABSTRACT FROM AUTHOR]

The Xiong'er Group is mainly distributed in western Henan, southern Shanxi, and southeastern Shaanxi. As a set of low-grade metamorphic and low-deformation volcanic rocks formed in the transition period during the tectonic evolution of the North China Craton in the Precambrian, the tectonic and magmatic evolution information of this period are well recorded. The accurate isotopic dating of the Xiong'er Group has great significance to the study of the stratigraphic division and formation of volcanic rocks in the Xiong'er Group and the improved cognition of regional tectonic magmatism. In this study, through the SHRIMP (sensitive high-resolution ion microprobe) zircon uranium-lead (U-Pb) isotope dating of the volcanic rocks of the Xiong'er Group in the Xiong'er Mountain, the research results showed that the age data were separated into two intervals, the magmatic zircon ages from 1836 to 1711 Ma and the inherited zircon ages from 2415 ± 19 to 2193 ± 34 Ma. The isotopic age of magmatic zircon was considered to represent the formation age of the Jidanping Formation in the Xiong'er Mountain, and the isotopic ages of the inherited zircons were consistent with the formation ages of the Taihua Group supracrustal rocks in the lower Xiong'er Group. Combined with previous studies on isotope and rock geochemistry of volcanic rocks in the Xiong'er Group, it was believed that the formation ages of the volcanic rocks of the Xiong'er Group are between 1874 and 1618 Ma, among the ages of the Xushan Formation, Jidanping Formation, and Majiahe Formation, which were concentrated between 1874 and 1800 Ma, 1836 and 1711 Ma, and 1780 and 1618 Ma, respectively. The age of inherited zircon in the volcanic rocks of the Xiong'er Group indicated that the formation of the volcanic rocks of the Xiong'er Group had the addition of stratigraphic materials from the Taihua Group. [ABSTRACT FROM AUTHOR]

• First in-situ apatite U-Pb ages from pseudotachylytes. • The lower crust fails seismically during the early stages of continental collision. • Earthquakes create long-lived fluid pathways in the lower crust. Determining the precise age of fossil earthquakes is essential for understanding the tectonic setting in which they occurred. Pseudotachylytes are quenched frictional melts that occur along coseismic fractures and represent evidence of fossil earthquakes in the rock record. Here, we present the first in-situ apatite U-Pb ages for three samples from Lofoten in the northern Norwegian Caledonides, that occur within and adjacent to lower-crustal pseudotachylytes: a pristine pseudotachylyte, a mylonitized pseudotachylyte, and a mylonite that contains pseudotachylyte transposed into the shear plane. The apatite U-Pb ages are combined with cathodoluminescence and electron backscatter diffraction analysis to provide microstructural constraints on the interpretation of ages. Apatite shows evidence of either fragmentation and annealing, or dislocation creep in response to coseismic rupture. The results suggest that the short-lived thermal pulse generated by the earthquake is sufficient to reset the apatite U-Pb system. The age of 426 ± 19 Ma is interpreted to date lower-crustal seismicity during the early Caledonian orogeny. Later fluid-rock interaction along the same structures led to partial resetting of the apatite U-Pb systematics, indicating that seismic brittle failure of the lower continental crust occurs at the incipient stages of continental collision, and that the resulting structures are preferential pathways for later fluid flow in the otherwise impermeable anhydrous lower crust. [ABSTRACT FROM AUTHOR]

40Ar/39Ar geochronology is one of the most important techniques for constraining the timing of basaltic events due to the paucity of suitable minerals in basalts for other geochronological techniques such as U–Pb (e.g., zircon, baddeleyite). Among a variety of materials from basaltic rocks that have been used for 40Ar/39Ar dating, plagioclase is the most important due to its common presence in basalts as a primary crystallizing phase, and its transparency so that fresh grains can be selected during sample preparation. However, plagioclase 40Ar/39Ar geochronology has often been compromised by alteration (e.g., sericitization by hydrothermal events), which, in practice, is difficult to identify using a petrographic microscope when the amount of alteration is low (e.g., <1%). We used laboratory step-heating experiments and theoretical simulations to characterize the 40Ar/39Ar age and Ca/K spectra of altered plagioclase so that 40Ar/39Ar dating results on altered samples can be identified and better interpreted. The step-heating experiments and theoretical simulations yielded consistent results, and show that with the presence of even a tiny amount of sericite (~0.01% for K-poor samples and ~0.1% for K-rich samples), the plagioclase samples yielded alteration plateau ages that are 3%–4% younger than the crystallization age. The difference between the alteration age of sericitized plagioclase and its crystallization age is primarily controlled by the time lapse between the crystallization and sericitization events, but also by the Ca/K ratios of the plagioclase. For plagioclase samples that experienced the same alteration event, the higher the Ca/K ratio is, the more sensitive the 40Ar/39Ar age is to alteration. We propose that the alteration signatures of plagioclase can be effectively identified through inspecting the 40Ar/39Ar age spectra, the Ca/K spectra, and the degassing curves. We also investigated the effect of sericitization of plagioclase microliths in basaltic groundmass and modelled the 40Ar/39Ar age and Ca/K spectra of altered groundmass samples. We validate our approach by revisiting published 40Ar/39Ar dating results for large igneous provinces, and showed that these dates should have been interpreted as alteration ages (minimum eruption ages) rather than crystallization ages. Finally, we demonstrate that with high degrees of alteration (~50% for K-poor and >70% for K-rich plagioclase samples), the age of hydrothermal alteration can be successfully dated. [ABSTRACT FROM AUTHOR]

Dental cavities or caries is a common disease among modern humans, affecting almost every adult. Caries frequency has been used to study dietary change in humans over time, based on an inferred tie between the incidence of caries and a carbohydrate-rich diet. However, the disease is not unique to our species. Among non-human primates, there is also variation in caries frequency associated with diet, suggesting that this metric may provide a mechanism for studying diet in broader contexts, and across geological time. To date, very few studies have examined caries among fossil mammals, and none have done so among Eocene mammals. Here, we present our analysis of the largest sample to date of fossil caries in a single extinct mammal species, Microsyops latidens, a stem primate from the early Eocene, which is known from over a thousand specimens from the Southern Bighorn Basin of Wyoming (n = 1030). Our results show that Microsyops latidens is characterized by a high prevalence of dental caries (7.48% of individuals), with notable variation through time, reaching 17.24% of individuals from a particular interval. This interval is also associated with a change in overall dental form, as quantified by dental topographic analysis, which measures functional aspects of the chewing surface of teeth. These observations suggest that this species experienced a shift in their diet to include more fruit or other sugar rich-foods for a short period. Our analysis, therefore, suggests that the diet of M. latidens fluctuated over time, as well as providing a framework for assessing caries in other fossil taxa. [ABSTRACT FROM AUTHOR]

The first direct Pb–Pb dating of carbonate rocks of the Kamo Group has been carried out. The Pb–Pb age of carbonates of the lower units (the Madra, Jurubchen, Kuyumba, and Vingold formations) of this sedimentary sequence is 1510 ± 50 Ma, while the age of the upper unit (the Iremeken Formation) is 1490 ± 50 Ma. The ages obtained show that all the carbonate formations of the Kamo Group are Lower Riphean (Early Mesoproterozoic), and their deposition continued for a period of no longer than several tens of millions of years. The new geochronological data allow us to correlate the Riphean deposits of the Baikit Anteclise with the rocks of the Riphean cover of the Anabar Uplift. [ABSTRACT FROM AUTHOR]

The Bengge biotite aegirine‐augite syenite (BAS) is located in the southern part of Yidun Arc, eastern margin of the Tibetan Plateau area. It is an integral part of the Bengge ultrapotassic rocks (UPR), an alkalic complex mainly consisting of BAS, biotite pyroxene syenite (BPS), and biotite syenite (BS). Geochronological studies including zircon LA‐ICPMS U–Pb dating and biotite 40Ar/39Ar dating have been conducted on the Bengge BAS to constrain its emplacement age. The zircon U–Pb dating yields a wide range of ages from 209 ± 2 Ma to 239 ± 2 Ma, with the concordia 206Pb/238U age being 228 ± 8.9 Ma (MSWD = 0.13). Meanwhile, the biotite 40Ar/39Ar dating yields a plateau age of 205.7 ± 1.5 Ma. The whole‐rock Zr‐saturation temperature (Tzir‐sat) of the Bengge BAS has shown to be very low (86 ± 13°C to 634 ± 13°C), which is much lower than Ti‐in‐zircon temperature (>758°C) of the zircons used for U–Pb dating. This indicates that the zircons in the Bengge BAS are inherited, and they were already present in the BAS melts before the melts became Zr‐saturated. Similarly, the Tzir‐sat of the Bengge BPS and BS are 346 ± 14°C ~ 549 ± 13°C and 281 ± 14°C ~ 525 ± 13°C, respectively, which is also too low for magmatic zircon crystallization in the melts. The inherited zircons of Bengge BAS have typical features of magmatic zircon, with high (Sm/La)N ratios (2.54–819), Ce/Ce* ratios (4.77–304) and low La concentration. Low εHf (T) values (−5.0 to 0.42) and high U/Yb (0.67–12.6) values imply that the inherited zircons (209–239 Ma) in the Benge BAS are derived from an early arc‐magma system of the Yidun Arc. The biotite 40Ar/39Ar dating constrains the Bengge BAS emplacement age at 205.7 ± 1.5 Ma, the time when the arc‐magma activity had ceased, and a regional geodynamic transition in the Yidun Arc from convergence to back‐arc spreading had started. [ABSTRACT FROM AUTHOR]

Mafic rocks are the most common type of igneous rocks on Earth, however, constraining the crystallization age of mafic rocks can be challenging. Apatite is a common accessory phase in mafic rocks and is amenable to dating using the U–Pb system. However, the U–Pb system in apatite has a relatively low closure temperature (∼350°-550 °C) and is therefore prone to resetting by later thermal and metasomatic events. Here, a recently developed Lu Hf dating method using laser ablation reaction-cell mass spectrometry is applied to apatite from mafic rocks. The Lu Hf system in apatite has a higher closure temperature (∼650°-750 °C) compared to U–Pb, increasing the chances of obtaining primary crystallization ages. Furthermore, the laser-ablation method allows rapid data collection compared to traditional solution-based Lu Hf dating techniques. Four study areas were selected to compare the Lu Hf vs U–Pb systematics of apatite in mafic igneous rocks: the Paleoproterozoic Sudbury Igneous Complex (Canada), the Neoproterozoic Borborema Province (NE Brazil), the Paleoproterozoic Fennoscandian Shield (Finland), the Archean Yilgarn Craton and adjacent Mesoproterozoic Albany Fraser Orogen (Western Australia). For all analyzed samples that have apatite trace element compositions typical of an undisturbed primary mafic igneous lithology, the Lu Hf system retains primary igneous apatite crystallization ages, whereas the U–Pb system in the same grains often records isotopic disturbance or a cooling age. In few cases, the Lu Hf system has also been disturbed in response to recrystallization, however, such disturbance is readily detected with trace element data. Hence, this study demonstrates the potential of laser ablation apatite Lu Hf dating to obtain primary crystallization ages for otherwise difficult to date mafic rocks. • First study on Lu-Hf systematics for apatite from mafic rocks • U U-Pb system in apatite readily resets by thermal and metasomatic events • Lu Lu-Hf system is robust to volume diffusion < ∼660–730 °C, retaining primary crystallization ages. • Deformation leading to recrystallization 'resets' both U U-Pb and Lu Lu-Hf systems in apatite. • Apatite trace element data to differentiate isotopic disturbances related to recrystallisation versus volume diffusion [ABSTRACT FROM AUTHOR]

The Lengshuikeng Ag‐Pb‐Zn ore field is located in the North Wuyi Mesozoic volcanic belt south of the Qinzhou–Hangzhou suture zone between the Yangtze and Cathaysia paleo‐plates. Previous zircon U–Pb geochronological studies on ignimbrites and tuffs from this area have yielded conflicting ages of 157–161 Ma (Early Upper Jurassic) and 137–144 Ma (Early Lower Cretaceous). Volcanic rocks in the ore field have even been proposed to include both ages. Our SHRIMP zircon U–Pb dating of the ignimbrite and tuff samples from the ore field, along with field observations and results from geochronological work on other volcanic and sub‐volcanic rocks in the region, shows that two populations of magmatic zircons, one autocrystic and the other xenocrystic, are present in the pyroclastic rocks. The autocrystic zircons have ages suggesting formation/eruption at approximately 140 Ma, whereas the xenocrystic zircons give ages of 155–159 Ma, indicating intrusion of granitic porphyries in the Early Upper Jurassic. Therefore, the pyroclastic rocks in the Lengshuikeng Ag–Pb–Zn ore field formed in the Early Lower Cretaceous. The youngest zircon U–Pb ages from pyroclastic rocks may not represent the formation/eruption ages of the host rock, depending most likely on the existence and/or abundance of juvenile or vitric pyroclasts in the rocks. [ABSTRACT FROM AUTHOR]

The geologic and tectonic history of the Memnonia-Sirenum region of Mars has been reconstructed on the basis of geologic mapping and relative-age dating of rock units and structures using crater counts and superposition relations. Comparisons between the ages of rock unit formation and the orientations of the earliest structures associated with Tharsis demonstrate a strong interplay among tectonic, magmatic, and aqueous activity in the Memnonia-Sirenum region. Early Noachian geologic activity identified within this region includes the formation of large northeast-trending, extensional basins. Stratigraphic and tectonic evidence suggests that these basins formed concurrently with the early formation of Tharsis when the dynamo and associated magnetosphere were still in operation. In addition to the ancient basins, later Tharsis-influenced activity includes prominent tectonic fault systems associated with the formation of Tharsis and Arsia Mons. Detailed mapping of the faults indicates that structures associated with Memnonia and Sirenum Fossae resulted from the formation of Tharsis during the Middle to Late Noachian. Late-stage (Amazonian) activity also identified within this region includes valley networks and collapse depressions that are linked and/or occur among Tharsis-centered faults that cut features throughout this region, including Mangala Valles. • The Memnonia-Sirenum region contains some of the oldest stratigraphic units of the western hemisphere region of Mars. • The northeast trending basins and ranges identified appear to be the result of the initial Tharsis upwelling phase. • Continued upwelling resulted in the formation of the ridges and radial faults associated with the center of the uplift. • Basin development was influenced by changing hydrologic conditions linked to the formation of Tharsis. [ABSTRACT FROM AUTHOR]

• A continuum of Paleoproterozoic heritage, seen in Nd model ages, from N to S in the Bushmanland Domain (BD), with the Buffels River shear zone simply a regional discontinuity. • The southern BD (SBD) has a greater juvenile component than the northern BD (NBD), becoming more dominant post-1.10 Ga. • Orthogneisses derived from crustal magmas with subduction-influenced signatures with mixed Meso- to Paleoproterozoic model ages. The SBD Koperberg Suite derived from low degrees of melting of enriched SCLM, but at deeper levels than those of the NBD. • The paragneisses derived from largely reworked, mixed Meso- to Paleoproterozoic felsic to intermediate sources. • Paragneisses derived from largely reworked, mixed Meso- to Paleoproterozoic felsic to intermediate sources. • SBD Koperberg Suite derived from low degrees of melting of enriched SCLM, but at somewhat deeper levels than NBD Koperberg magmas. • D 2 deformation constrained to ~ 1.11-1.09 Ga, with peak M 3 metamorphism at ~ 1.05-1.02 Ga. The timing of tectonomagmatic events and petrogenesis of ortho- and paragneisses within the high-grade southern Bushmanland Domain (SBD) of the Namaqua Metamorphic Province is, largely, poorly constrained. U-Pb age dating and whole rock lithogeochemistry of the rocks of the upper granulite facies Kliprand dome provide constraints with regards to the evolution of the SBD during the 1.2–1.0 Ga Namaquan Orogeny. The SBD has a greater juvenile component, particularly added between ∼1.1 and 1.02 Ga, compared to the northern Bushmanland Domain (NBD). This is reflected in marginally younger T DM model ages (1.60–1.95 Ga) than for the NBD (∼1.9–2.4 Ga), and higher ε Nd(t) values for magmatic rocks, particularly for the late- to post-tectonic Spektakel Suite (SS), concentrated in the SBD. The ∼1.06 Ga Klein Lieslap Charnockite of the SS was derived from reworking of radiogenic Paleoproterozoic arc crust, but has a large juvenile depleted component compared to that of the ∼1.19 Ga Grootberg Gneiss of the syn-tectonic Little Namaqualand Suite. SBD mafic magmas were derived from low degrees of partial melting of subduction-influenced enriched subcontinental lithospheric mantle. The pre-tectonic ∼1.17 Ga Oorkraal Suite shows limited crustal contamination of mantle-derived melts. The post-tectonic ∼1.05 Ga Koperberg Suite was derived from deeper mantle melting than that in the NBD, but shows less crustal contamination. The supracrustal Kamiesberg Group was derived from mixed, reworked Meso- to Paleoproterozoic crust that showed a more dominant depleted component compared to that in the NBD. Incongruent anatexis of the paragneisses gave rise to crosscutting garnetiferous quartzofeldspathic segregations, notably the strongly peraluminous ∼1.07 Ga Ibequas Leucogranite. D 2 deformation, at ∼1.11–1.09 Ga, resulted in penetrative foliation. D 3 deformation, related to the development of a sub-vertical foliation in the limbs of F 2 folds, is constrained to ∼1.07–1.06 Ga, between emplacement of the Ibequas Leucogranite and the Koperberg Suite. Peak granulite facies M 3 metamorphism occurred at ∼1.05–1.02 Ga. These age constraints are similar to those of the NBD reflecting a synchronous tectonomagmatic and kinematic history. The SBD represents a deeper crustal level with a greater mantle influence than the NBD. [ABSTRACT FROM AUTHOR]

The study of geological sea-level proxies formed during previous interglacials is a common approach to assess how global sea level will evolve under warmer climate conditions. Over the last decades, technical advancements in both survey and geochronology have allowed improving our knowledge of past sea-level highstands. This is of prime importance to refine our understanding of processes contributing to sea-level changes, and ultimately to improve both local and global sea-level projections. Last Interglacial sea-level proxies in the Western Indian Ocean (and more specifically the island nation of Madagascar), have been less investigated than in other intertropical oceans over the last decades. As a result, paleo sea-level data in this region are less abundant and less precise than elsewhere. Here, we report the results of two field campaigns aimed at studying the site of Lembetabe, southwest Madagascar, where a fossil reef was first described by the researcher René Battistini more than 50 years ago. We estimate paleo relative sea level history in space and time from 15 new U-series ages from a fossil reef platform mapped with differential GNSS and drone photogrammetry. Our data suggest that, between 129 ka and 115 ka, paleo relative sea level at this location was about 3.4 ± 1.4 m above modern. Once corrected for glacial isostatic adjustment, we find that paleo global mean sea level did not exceed 3 m above modern. Only slight crustal subsidence would reconcile the peak Last Interglacial sea level measured at Lembetabe with the 5–10 m range reported in the literature. • Fossil reef dated to the Last Interglacial in southwest Madagascar. • Stable paleo relative sea level during the LIG at about 3.4 ± 1.4 m above modern. • Interplay between glacial isostatic adjustment and global mean sea level. [ABSTRACT FROM AUTHOR]

The Hegenshan–Heihe Suture (HHS) is an important suture zone between the Xing'an and Songliao–Xilinhot blocks in the eastern Central Asian Orogenic Belt (CAOB). Many studies have examined the northern and southern parts of this suture zone, but the middle segment remains under-researched and controversial. This paper presents new research into Permian felsic rocks along the middle segment of the HHS, including alkaline granites, rhyolites, and granodiorites. Zircon U–Pb dating of these rocks yielded precise Permian ages of 300.4 ± 2.5, 292.8 ± 2.7, and 293.1 ± 2.2 Ma. The alkaline granites and the rhyolites are A-type rocks that were derived from lower crustal protoliths, with the melting of these protoliths caused by asthenospheric upwelling associated with lithospheric delamination. In comparison, the granodiorites are I-type granites were generated from a mantle-derived magmatic source. The petrogenesis of these granites also involved the assimilation of sedimentary rocks and fractional crystallization. This Permian magmatism occurred during post-collisional extension following the amalgamation of the Xing'an and Songliao–Xilinhot blocks. [ABSTRACT FROM AUTHOR]

Abstract A next-generation, high-flux DD neutron generator has been designed, commissioned, and characterized, and is now operational in a new facility at the University of California Berkeley. The generator, originally designed for 40Ar/39Ar dating of geological materials, has since served numerous additional applications, including medical isotope production studies, with others planned for the near future. In this work, we present an overview of the High Flux Neutron Generator (HFNG) which includes a variety of simulations, analytical models, and experimental validation of results. Extensive analysis was performed in order to characterize the neutron yield, flux, and energy distribution at specific locations where samples may be loaded for irradiation. A notable design feature of the HFNG is the possibility for sample irradiation internal to the cathode, just 8 mm away from the neutron production site, thus maximizing the neutron flux (n/cm 2 /s). The generator’s maximum neutron flux at this irradiation position is 2.58 × 10 7 n/cm 2 /s ± 5% (approximately 3 × 10 8 n/s total yield) as measured via activation of small natural indium foils. However, future development is aimed at achieving an order of magnitude increase in flux. Additionally, the deuterium ion beam optics were optimized by simulations for various extraction configurations in order to achieve a uniform neutron flux distribution and an acceptable heat load. Finally, experiments were performed in order to benchmark the modeling and characterization of the HFNG. [ABSTRACT FROM AUTHOR]

The Jurassic magmatic and volcanic rocks are widespread along the west central Lhasa subterrane. However, the petrogenesis of these rocks is poorly understood because of lacking high-quality geochronology and geochemical data. Here, we present new zircon U-Pb age and Hf isotopic data, whole-rock geochemical and Sr-Nd-Pb isotopic data for the Songduole and Qiangnong plutons in Geji area. LA-ICP-MS dating of zircon yield crystallization ages of 172.1 ± 1.9 and 155.9 ± 1.2 Ma for the Songduole and Qiangnong plutons, respectively. Geochemically, Songduole and Qiangnong granodiorite are characterized by high MgO (2.63-3.49 wt%), high Mg# (49-50), and low TiO2 (0.48-0.57 wt%). Besides, all rocks show metaluminous, calc-alkaline signatures, with strong depletion of Nb, Ta, and Ti, enrichment of large-ion lithophile (e.g. Rb, Th, K), and a negative correlation between SiO2 and P2O5. All these features are indicative of arc-related I-type magmatism. Five samples from the Songduole granodiorite have whole rock (87Sr/86Sr)i of 0.71207-0.71257, εNd(t) values of −15.1 to −13.9, zircon εHf(t) values of −17.4 to −10.5, (206Pb/204Pb)t ratios of 18.402-18.854, (207Pb/204Pb)t ratios of 15.660-15.736, and (208Pb/204Pb)t ratios of 38.436-39.208. Samples from the Qiangnong granodiorite have (87Sr/86Sr)i of 0.71230-0.71252, εNd(t) values of −15.1 to −14.2, zircon εHf(t) values of −12.6 to −6.4, (206Pb/204Pb)t ratios of 18.688-18.766, (207Pb/204Pb)t ratios of 15.696-15.717, and (208Pb/204Pb)t ratios of 38.546-39.083. These geochemical signatures indicate that the two plutons most likely originated from partial melting of the ancient Lhasa lower crust with obvious inputs of mantle-derived melts. Combined with regional geology, our results indicate that the Jurassic magmatism in the west central Lhasa subterrane most likely resulted from the southward subduction of the Bangong Ocean lithosphere beneath the central Lhasa terrane. [ABSTRACT FROM AUTHOR]

Luminescence dating of rock surfaces is an emerging and exciting branch of research in geochronology with great application potential [1-3]. Originally, luminescence dating has been developed to constrain the burial age of fine-grained (i.e. sand to silt sized) Quaternary sediments, and today plays a key role in the geological and archaeological sciences. In contrast, luminescence dating of rock surfaces still undergoes substantial methodological development and testing [e.g. 4-7], yet, the technique holds great promises to constrain the age of hitherto undatable geological and archaeological materials or geomorphological landscape elements. As such, luminescence-based rock surface dating (RSD) is highly complementary to OSL sediment burial and other Quaternary dating techniques. RSD basically comes in two variants: rock surface burial dating (RSbD) and rock surface exposure dating (RSeD) and over the last decade has evolved into a highly active and promising geochronological research field. Meanwhile numerous ways of analyzing RSb and RSe luminescence data exist and different approaches to calculate rock surface ages have been introduced, yet no standardized way of handling RSb or RSe luminescence data has been put forward. Here we present an open-source software package that is based on the software language Python©. The program enables users to evaluate their rock surface luminescence data via a simple graphical user interface (GUI). The program allows processing of data which originate either from CCD or EMCCD images or from the conventional "drilling and slicing" approach and takes various types of OSL, IRSL and IRPL signals into account. We incorporated all currently available and stat-of-the art bleaching models into the software package and provide the user with maximum degree of flexibility for normalizing luminescence signals. In the case of RSeD a novel calibration procedure option is implemented, deemed to generate robust RSe ages [7]. Ultimately, the software allows single as well as multiple exposure and burial ages from rock surfaces to be derived. [ABSTRACT FROM AUTHOR]

The Juiz de Fora Complex (JFC) in the Araçuaí-Ribeira orogenic system, southeastern Brazil, is a basement unit displaying a variety of rock types that is tectonically imbricated with the supracrustal rocks of the Raposos Group in the Upper Thrust System of the Occidental Terrane, Ribeira Belt. Here we report new petrological, geochemical, and zircon U–Pb and Lu–Hf isotopic data on mafic garnet-granulites from the JFC with a view to evaluate the timing and P-T conditions of the collisional event as well as protolith formation. This work presents the most comprehensive metamorphic study on the Juiz de Fora Complex rocks to date. Metamorphic P-T estimates for the metamorphic peak conditions of 800–900 °C and 8–9 kbar in basic garnet-bearing granulites were obtained for the JFC, indicating that metamorphism took place at deeper crustal levels. Geochemical, zircon U–Pb geochronology, whole-rock Sm–Nd, Rb–Sr isotopes, and Lu–Hf isotopic data of mafic granulites yielded U–Pb ages of ca. 2201 Ma, and moderately juvenile εNd(t) = −0.5 and were obtained from the JFC marking the timing of volcanic arc magmatism during the Rhyacian period. This arc-related stage was followed by the post-collisional period during the Early Paleoproterozoic with ca. 1.94 Ga E-MORB signature granulites that shows evidence of magma sourced from Neoarchean (∼2.8 Ga) crust with addition of juvenile components. The high-grade metamorphism is possibly related to the final collision of the Congo and São Francisco Cratons at 590–560 Ma, which placed the Neoproterozoic metasediments and the JFC rocks at the same level. The integrated information sheds light on two collisional episodes where the oldest is represented by arc-related granulites during the Rhyacian Orogeny and the youngest is the higher-pressure Neoproterozoic overprint during the Brasiliano Orogeny. • The garnet-bearing mafic granulites formed under 800–900 °C with pressures of 8–9 kbar. • Rhyacian and Brasiliano orogenic cycles imprinted the Juiz de Fora Complex rocks. • Zircon data and metamorphic textures indicate a complicated evolution over the two orogenic cycles. [ABSTRACT FROM AUTHOR]

The Xiaoyao tungsten polymetallic skarn deposit in the eastern Jiangnan Massif of Yangtze Block is located at the contact between a granodiorite pluton and Sinian–Cambrian limestone. The intrusions in the tungsten-rich district comprise the Xiaoyao and other granodiorite plutons and granite porphyry dikes. The age determinations by LA–ICP–MS U–Pb dating of zircons indicate that the granodiorite formed at 149.4 ± 1.1 Ma, whereas the granite porphyry was emplaced at 133.2 ± 0.7 Ma. Re–Os dating of molybdenite from the skarn orebodies yielded a weighted average age of 148.7 ± 2.3 Ma (n = 5). These ages indicate that the tungsten mineralization is temporally related to the granodiorite. The granodiorites are metaluminous (A/CNK = 0.86–0.98) and in the high-K calc-alkaline series. They contain hornblende and have a negative correlation between P 2 O 5 and SiO 2 , indicating that they are typical I-type intrusions. The granite porphyries exhibit high alkali contents (Na 2 O + K 2 O = 7.97–9.53%), elevated FeO T /(FeO T + MgO) ratios (0.83–0.94), high concentrations of Zr, Nb, Ce, and Y, and high Zr saturation temperatures (average of 812 °C); thus, they are geochemically similar to A-type intrusions. The initial 87 Sr/ 86 Sr and ε Nd (t) values range respectively from 0.7074 to 0.7083 and from − 7.9 to − 1.3 for the granodiorite, and from 0.7008 to 0.7083 and from − 6.3 to − 4.7 for the granite porphyry. In addition, two-stage Nd model ages (T 2DM ) of 1.0–1.6 Ga for the granodiorite and 1.3–1.4 Ga for the granite porphyry indicate that the Proterozoic crustal rocks of the Shangxi Group could have contributed to the Xiaoyao magmas. The rhenium contents of the molybdenite grains vary from 32 to 136 ppm, suggesting that the molybdenum was derived mainly from a mixture of mantle and crustal sources. Based on the new geochemical data and regional geological investigations, we propose that the Late Jurassic mineralization-related I-type granodiorite was derived from the Neoproterozoic Shangxi metamorphic rocks with some additional input of mantle material. The magmatism was triggered by asthenospheric upwelling induced by slab tearing during oblique subduction of the paleo-Pacific plate beneath the South China Block. [ABSTRACT FROM AUTHOR]

Observations of discordant ages, meaning that an age given by one mineral geochronometer is different from the age given by another geochronometer from the same rock, began in the early days of geochronology. In the late 1950s and 1960s, discordant U-Pb zircon ages were unquestioningly attributed to Pb diffusion at high temperature. Later, the mineralogical properties and the petrogenesis of the zircon crystals being dated was recognized as a key factor in obtaining concordant U-Pb ages. Advances in analytical methods allowed the analysis of smaller and smaller zircon multigrain fractions, then the analysis of individual grains, and even pieces of grains, with higher degrees of concordancy. Further advances allowed a higher analytical precision, a clearer perception of accuracy, and a better statistical resolution of age discordance. As for understanding the cause(s) of discordance, belief revision followed the coupling of imaging, cathodoluminescence (CL), and backscattered electrons (BSE), to in situ dating by secondary ion mass spectrometry (SIMS) or by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Discordant zircon and other accessory minerals (e.g., monazite, apatite, etc.) often consist of young rims accreted onto/into older cores. Age gradients are sharp, and no Pb diffusion gradients are observed. As U-Pb discordance in crystalline, non-radiation damaged grains is caused by diachronous, heterochemical mineral generations, interpretations of mineral ages, based on the exclusive role of diffusion, are superseded, and closure temperatures of zircon and monazite are irrelevant in geological reality. Other isotopic systems (Rb-Sr, K-Ar) were believed, since the 1960s, to be similarly controlled by the diffusivity of radiogenic daughters. When zircon and monazite discordance were recognized as zone accretion/reaction with sharp boundaries that showed little or no high-temperature diffusive re-equilibration, the other chronometric systems were left behind, and interpretations of mineral ages based on the exclusive role of diffusion survived. The evidence from textural-petrologic imaging (CL, BSE) and element mapping by electron probe microanalyzer (EPMA) or high spatial resolution SIMS or LA-ICP-MS provides the decisive constraints. All microcline and mica geochronometers that have been characterized in detail document patchy textures and evidence for mineral replacement reactions. It is important not to confuse causes and effects; heterochemical microstructures are not the cause of Ar and Sr loss; rather, they follow it. Ar and Sr loss by dissolution of the older mineral generation occurs first, heterochemical textures form later, when the replacive assemblage recrystallizes. Heterochemical mineral generations are identified and dated by their Ca/Cl/K systematics in 39Ar-40Ar. Replacive reactions adding or removing Cl, such as, e.g., sericite overgrowths on K-feldspar, retrograde muscovite intergrowths with phengite, etc. are detected by Cl/K vs. Ar/K isotope correlation diagrams. Ca-poor reaction products, such as, e.g., young biotite intergrown with older amphibole, adularia replacing microcline, etc., can be easily identified by Ca/K vs. Ar/K diagrams supported by EPMA analyses. Mixed mineral generations are observed to be the cause of discordant, staircase-shaped age spectra, while step-heating of crystals with age gradients produces concordant plateaus. Age gradients are therefore unrelated to staircase age spectra. There is a profound analogy between the U-Pb, Rb-Sr, and K-Ar systems. Pb and Ar diffusion rates are both much slower than mineral replacement rates for all T < 750 °C. Patchy retrogression textures are always associated with heterochemical signatures (U/Th ratios, REE patterns, Ca/Cl/K ratios). As a rule, single-generation minerals with low amounts of radiation damage give concordant ages, whereas discordance is caused by mixtures of heterochemical, resolvably diachronous, mineral generations in petrologic disequilibrium. This can also include (sub-)grains that have accumulated significant amounts of radiation damage. For accurate geochronology the petrologic characterization with the appropriate technique(s) of the minerals to be dated, and the petrologic context at large, are as essential as the mass spectrometric analyses. [ABSTRACT FROM AUTHOR]

This study presents a new laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) based U-Pb geochronometric method for dating grossular-andradite (grandite) garnet. Grandite is a primary skarn mineral, therefore dating its growth directly dates hydrothermal activity. As zircon U-Pb geochronometry provides a high-resolution record of magmatic processes, grandite U-Pb dating has the potential to provide a complementary record for hydrothermal systems. This study characterizes four garnets of variable grossular-andradite content and age as potential reference materials for LA-ICPMS U-Pb geochronology: Willsboro Andradite (~ 1020 Ma, Adirondacks, USA), Red and Yellow Mali Grandite (~ 200 Ma, Southern Mali) and Lake Jaco Grossular (~ 35 Ma, Coahuila, Mexico). Isotope dilution-thermal ionization mass spectrometry (ID-TIMS) U-Pb analyses of Willsboro andradite yield a mean 206 Pb/ 238 U date of 1022 ± 16 Ma. We use Willsboro Andradite as a primary reference material for LA-ICPMS U-Pb characterization of the two other garnets. The non-radiogenic Pb (Pbc) concentration in grandite is variable between specimens. Willsboro Andradite and Mali Grandites contain almost purely radiogenic Pb (Pb*), however Lake Jaco Grossular has a higher Pbc concentration comparatively and yields discordant U/Pb ratios. For specimens with highly variable Pb*/Pbc, linear regression is employed to derive a lower-intercept age. LA-ICPMS U-Pb dates for Yellow Mali Grandite (202 ± 2 Ma; 206 Pb/ 238 U weighted mean) and Lake Jaco Grossular (35 ± 2 Ma; lower intercept) agree with independent ID-TIMS U-Pb (202.0 ± 1.2 Ma) and (U-Th)/He dates (35 ± 5 Ma) derived for each specimen. The precision of LA-ICPMS U-Pb dates varies between 1–10% (2σ) for the analyzed garnets. Considering the short estimated lifespans of pluton-related hydrothermal systems (tens of thousands to a few million years), Neogene skarns present the best opportunity to test for and resolve separate episodes of garnet growth at these precision levels. As a performance test for the method, we present new U-Pb andradite data from a Late Miocene skarn system on Serifos Island, Greece. This garnet yields a lower-intercept age of 9.15 ± 0.36 Ma, in agreement with biotite Rb-Sr and zircon U-Pb dates from the causative pluton. [ABSTRACT FROM AUTHOR]

Few facies analysts or stratigraphers would argue against the contention that the transition to facies-driven sequence stratigraphic correlations represents one of the most important paradigm shifts in modern stratigraphy. What is less commonly appreciated is that most of the fundamental underpinnings of sequence stratigraphy were derived from a relatively small number of pioneers in the early to mid-1900s;most of them largely unknown or underappreciated by the current generation of sequence stratigraphers. Chief among these are Eliot Blackwelder, Amadeus Grabau, Joseph Barrell, John Rich, and Harry Wheeler. Blackwelder was perhaps the first to point out the presence and significance of regional unconformities in the packaging of strata inNorthAmerica,whichwould later come to form the basis of the well-known cratonic megasequences of Larry Sloss. However, Blackwelder is best appreciated as the mentor and colleague of not only these other pioneers, but also of keyworkerswho themselves ultimately mentored some of themost renowned sequence stratigraphers of the 1970s and 1980s. Amadeus Grabau focused his attention on expounding the law of the correlation of facies of JohannesWalther and bringing facies-driven correlations into stratigraphy; an approach at odds with the then prevailing view of lithostratigraphy as the principal physical stratigraphic framework. Grabau recognized that the rock record contains numerous temporal gaps that partition facies successions, for which he defined the term "hiatus". His Pulsation theory was used to explain the cycles of deposition and hiatal erosion/bypass, and although the mechanism is different, the net outcome of such "oscillations" is broadly similar to the effects of eustacy and tectonism thatwe assign to such changes today. Joseph Barrell developed the concept of base level and explored its role in controlling erosion versus deposition. Like Grabau, Barrell insisted that sedimentation was not continuous, leading to a stratigraphy that is replete with breaks of varying durations. For these he coined the term "diastems" for the small but more numerous breaks, which could be contrasted with those reflecting longer breaks which he referred to as "discontinuities". John Rich evaluated depositional topography, for which he coined the terms clinoform, undaform and fondoform. He recognized that such depositional bodies necessarily link genetically related associations of sediment deposited from the shoreline to the basin center; what today we regard as the depositional system. The resulting architectures bounded by these surfaces form the underpinning of all systems tracts in modern sequence stratigraphy. Harry Wheeler formalized the concept of time-stratigraphy, demonstrating that temporal gaps in stratigraphy are as important in understanding the rock record as the rocks themselves. His novel approach of developing stratigraphic cross-sections with time on the vertical axis pioneered the concept of chronostratigraphy through the development of what are now referred to asWheeler Diagrams. His resurrection of the base-level concept expounded by earlier workers was instrumental in defining sequences as unconformity-bounded units, re-establishing the concepts pioneered by Blackwelder himself. In concert, these stratigraphic visionaries erected a stratigraphic framework focused on the understanding of the stratigraphic record as opposed to its simple lithostratigraphic mapping or biostratigraphic dating. These unsung pioneers put into place virtually all components of modern sequence stratigraphy more than two decades before its popularization in the scientific community. [ABSTRACT FROM AUTHOR]

The Tiegelongnan Cu (Au) deposit is the largest copper deposit newly discovered in the Bangong-Nujiang metallogenic belt. The deposit has a clear alteration zoning consisting of, from core to margin, potassic to propylitic, superimposed by phyllic and advanced argillic alteration. The shallow part of the deposit consists of a high sulphidation-state overprint, mainly comprising disseminated pyrite and Cu-S minerals such as bornite, covellite, digenite, and enargite. At depth porphyry-type mineralization mainly comprises disseminated chalcopyrite, bornite, pyrite, and a minor vein molybdenite. Mineralization is disseminated and associated with veins contained within the porphyry intrusions and their surrounding rocks. The zircon U-Pb ages of the mineralized diorite porphyry and granodiorite porphyry are 123.1 ± 1.7 Ma (2σ) and 121.5 ± 1.5 Ma (2σ), respectively. The molybdenite Re-Os age is 121.2 ± 1.2 Ma, suggesting that mineralization was closely associated with magmatism. Andesite lava (zircon U-Pb age of 111.7 ± 1.6 Ma, 2σ) overlies the ore-bodies and is the product of post-mineralization volcanic activity that played a critical role in preserving the ore-bodies. Values of −4.6 ‰ to + 0.8 ‰ δ34S for the metal sulfides (mean − 1.55 ‰) suggest that S mainly has a deep magmatic source. The H and O isotopic composition is (δD = −87 ‰ to −64 ‰; δ18OH2O = 5.5 ‰ to 9.0 ‰), indicating that the ore-forming fluids are mostly magmatic-hydrothermal, possibly mixed with a small amount of meteoric water. The zircon εHf(t) of the diorite porphyry is 3.7 to 8.3, and the granodiorite porphyry is 1.8 to 7.5. Molybdenite has a high Re from 382.2 × 10−6 to 1600 × 10−6. Re and Hf isotope composition show that Tiegelongnan has some mantle source, maybe the juvenile lower crust from crust-mantle mixed source. Metallogenesis of the Tiegelongnan giant porphyry system was associated with intermediate to acidic magma in the Early Cretaceous (~120 Ma). The magma provenance of the Tiegelongnan deposit has some mantle-derived composition, possibly mixed with the crust-derived materials. [ABSTRACT FROM AUTHOR]

The use of magnetic polarity stratigraphy has allowed Upper Miocene and Plio-Pleistocene Siwalik sediments in the eastern Potwar Plateau to be dated precisely by direct correlation to the world-wide magnetic polarity time scale. Three examples are illustrated where measured sections calibrated by paleomagnetics allow geologic time to be extrapolated across broad areas to create new time maps based on the ability to see stratigraphic strike line patterns on Google Earth imagery. These maps allow precise dating of fossils as well as robust interpretations of the influence of growing folds and faults on the evolving fluvial geomorphology and depositional patterns of the region. [ABSTRACT FROM AUTHOR]

The extrusive component of the Karoo Large Igneous Province, the Drakensberg Continental Flood basalts of South Africa and Lesotho, is mainly composed of altered tholeiitic basalts without uraniferous mineral phases that are suitable for high-precision dating (e.g. baddeleyite or zircon), and thus dating is restricted to 40Ar/39Ar groundmass and plagioclase. Previous 40Ar/39Ar dates of plagioclase span from 178.9 ± 4.2 Ma to 189.2 ± 3.3 Ma, while most dates range between 180 and 183 Ma (Jourdan et al., 2007b ; Moulin et al., 2011 ; Moulin et al., 2017). Dating mafic rocks can be hindered by the presence of plagioclase xenocrysts (inherited 40Ar), and the ubiquitous presence of alteration phases. Separation protocols and acid leaching are used to minimize the effect of these issues, although previous 40Ar/39Ar studies of the Drakensburg lavas did not interpret their dates within a petrochronological context, and thus they are open to inaccuracy. We have used cathodoluminescence imaging, QEMSCAN analysis and optical petrology of thin sections to show that two distinct generations of plagioclase occur within the lavas, and at least two different phases of K-rich (adularia and K-rich clays) and Ca- alteration have occurred. 40Ar/39Ar dates have been obtained from some acid-leached and unleached aliquots of groundmass and both plagioclase generations. Our results show that i) large, cluster-forming plagioclase yield older 40Ar/39Ar dates and are interpreted to be xenocrystic, ii) apparently unaltered plagioclase in thin sections hosts secondary Ar reservoirs related to alteration, and iii) alteration and leaching can enhance the effects of 37,39Ar recoil in plagioclase. We conclude that the most accurate date for the Drakensburg lavas that applies to the entire thickness of the lava stacks is 184.4 ± 1.2 Ma, which was obtained from the matrix-forming plagioclase that contains the highest proportion of non-inherited radiogenic 40Ar, is least affected by secondary alteration and did not apparently suffer the effects of Ar isotope recoil. [ABSTRACT FROM AUTHOR]

Age determinations of rocks by in-situ Rb-Sr dating of minerals has the advantage of providing spatially resolved analysis without time-consuming preparation, but is hampered by isobaric and polyatomic interferences on Sr isotopes, especially 87Rb. LA-ICP-MS/MS using N 2 O as a reaction gas allows online chemical separation of 87Rb from 87Sr by measuring SrO+. Here, the method for in-situ Rb-Sr is optimized and applicability demonstrated for geological samples ranging from late Archean to 20 Ma in age. Rb-Sr isotopes of multiple reference materials and geological samples have been analyzed by LA-ICP-MS/MS to evaluate the method for dating rocks throughout the geological record. The quality of Sr isotopic data can be greatly improved by external calibration of mass bias. For internal calibration, better accuracy is obtained with the addition of H 2 as a trace molecular gas. The elemental fractionation of Rb and Sr during LA-ICP-MS/MS analysis varies for different reference materials. We find that the matrix of NIST SRM 610 renders it unsuitable for correction of 87Rb/86Sr. The Mica-Mg reference material is preferred for calibration of 87Rb/86Sr of micas despite showing significant Rb-Sr fractionation. In-situ Rb-Sr ages were determined for igneous samples ranging in age from 20 Ma to Mesoproterozoic, confirming accurate application of the method to samples of widely differing ages. The most accurate isochron ages were obtained with 87Rb/86Sr calibrated against Mica-Mg. Application to two metamorphic gneisses with late Archean protoliths from Labrador and Finland reveal thermal events at 1.66–1.70 Ga when they were part of a large Paleoproterozic active margin along the southern edge of Laurentia-Baltica. Data collected for minerals with differing closure temperatures for the Rb-Sr system allow detection of thermal events not recorded by other geochronological systems, indicating a huge potential of this technique not only for accurately dating samples, but also for providing previously inaccessible information on metamorphic histories. [ABSTRACT FROM AUTHOR]

The Nan-Uttaradit suture is marked by a narrow N-S trending and discontinuous ophiolite belt in northern Thailand. This suture zone is a mélange composed of gabbro, tholeiitic metabasalt, andesite and radiolarian chert. Samples of gabbro and meta-basalt in the Nan-Uttaradit suture yield zircon U-Pb ages of 311±10 and 316±3 Ma, respectively, interpreted as the crystallization ages of the rocks, suggesting the Nan-Uttaradit Ocean existed in the Late Carboniferous. Our results indicate that the Nan-Uttaradit Ocean co-existed with the Ailaoshan-Jinshajiang Ocean to the north and was probably an along-strike extension of the latter. [ABSTRACT FROM AUTHOR]

This study reports zircon U-Pb and Hf isotopes and whole-rock elemental data for granodiorites from the East Kunlun orogen. The zircon U-Pb dating defines their crystallization age of 235 Ma. The rocks are characterized by high-K calc-alkaline, magnesian and metaluminous with (KO+NaO)=6.38 wt.%-7.01 wt.%, Mg#=42-50 [Mg#=100×molar Mg/(Mg+FeO)], A/CNK=0.92-0.98, coupled with high ε( t) values from -0.65 to -1.80. The rocks were derived from partial melting of a juvenile mafic crustal source within normal crust thickness. The juvenile lower crust was generated by mixing lithospheric mantle-derived melt (55%-60%) and supracrustal melt (40%-45%) during the seafloor subduction. Together with available data from the East Kunlun, it is proposed that the studied Middle Triassic granodiorites were formed in post-collisional extension setting, in which melting of the juvenile lower crust in response to the basaltic magma underplating resulted in the production of high-K granodioritic melts. [ABSTRACT FROM AUTHOR]

This paper reports geochronological data of detrital zircons from the country rock and sedimentary xenoliths of the Cilincuo pluton (79±0.7 Ma) in the southern Yidun arc belt and the inherited zircons from the Late Triassic granites in the eastern Yidun arc belt, eastern Tibet Plateau. Detrital zircons ages from the sedimentary xenoliths have four prominent peaks at 2.5-2.4 Ga, 1.9-1.8 Ga, 480-400 Ma, and 350-300 Ma, whereas those from the country rock exhibit another four prominent peaks at 1.9-1.8 Ga, 850-700 Ma, 480-400 Ma, and 300-250 Ma. Based on comparison with age data from previous studies, we suggest that the sedimentary xenoliths are from the Lanashan Formation and the major provenance of them is Qiangtang Block, Zhongza massif and South China Block, whereas the country rock belongs to the Lamaya Formation and the major provenance of them is similar to those of the neighbouring Songpan-Garzê terrane. In addition, the inherited zircons from the Late Triassic granites in the eastern Yidun arc belts have a prominent Neoproterozoic age population (900-700 Ma), which suggests that there is an old basement with west Yangtze Craton affinity beneath the Triassic sediments. Combining with previous studies, we propose that the provenances of the formations vary from the Lanashan Formation to the Lamaya Formation which may indicate a record of the final closure of the Garzê-Litang Ocean. [ABSTRACT FROM AUTHOR]

This integrated study on the pressure-temperature-deformation-time record of the Goszów light quartzites from the Młynowiec-Stronie Group (Sudety Mts., SW Poland) provides new data that improve our understanding of the structure and geodynamic development of the Orlica-Śnieżnik Dome (OSD) as a Gondwana-derived unit involved in the formation of the Variscan orogen. The structural and metamorphic record of the Goszów light quartzites, when compared to the under- and overlying rock formations, indicates that the whole Młynowiec-Stronie Group in the eastern part of the Saxothuringian terrane functioned as a single, integral lithotectonic unit with no visible structural or metamorphic discontinuities. The sequence of structures and thermodynamic modelling indicate that the light quartzites underwent the same polyphase tectonometamorphic evolution as the adjacent rocks belonging to the Młynowiec-Stronie Group. The development of tight, N-S-trending folds and axial penetrative metamorphic foliation was related to metamorphic progression from 500 °C to 640 °C at 6-7 kbar. Subsequently, under the retrogressive conditions below 540 °C, the foliation was reactivated as a result of subsequent N-S-directed ductile shearing and extension. Therefore, the study of the light quartzites exemplifies the penetrative structures in the OSD, and the metamorphic foliation and N-S-trending lineation are composite structures. The monazite metamorphic ages of ca. 364 Ma and 335 Ma may be related to the approximately E-W- and N-S-oriented tectonic movements, respectively, which occurred during the amalgamation of the Saxothuringian terrane with Brunovistulia. In contrast, the previously unknown early Palaeozoic monazite age of ca. 494 Ma is interpreted as the protolith age of the light quartzites. Copyright © 2015 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

We deduce the timing of the rift-induced collisional event between two orogenies in the central Aravalli–Delhi Fold Belt using monazite chemical dating and metamorphic P – T estimates from metapelites of the Mangalwar Complex (MC), and the overlying Pur-Banera (PB) supracrustals. The MC rocks preserve evidence of three regional metamorphic events, while the PB rocks record the last event. The M 1 metamorphism attained its peak P – T at ∼5.5 kbar and 520–550 °C in the MC rocks at ∼1.82 Ga, followed by the M 2 event with peak P – T of ∼7.5 kbar and 580–660 °C at ∼1.35 Ga. The youngest high-pressure M 3 metamorphism attained a peak P – T of ∼8.0 kbar and 590–640 °C at ∼0.99 Ga. Thermobarometry coupled with ages of included monazites in chemically zoned garnet from the MC metapelites indicate preservation of ages spanning between ∼1.82 Ga and ∼0.99 Ga from different zones (i.e., core to rim), implying episodic garnet growth during supercontinent cycle. The PB metapelites constitute two prominent ages of ∼1.37 Ga and ∼1.05 Ga. The youngest high-pressure metamorphism (M 3 ) in the PB rocks with maximum P – T of ∼8.0 kbar, and 580–670 °C during the Neoproterozoic has overprinted their earlier metamorphic records. Based on monazite geochronology, we assign the ∼1.82 Ga and ∼1.37–1.35 Ga ages to the amalgamation and breakup of the Columbia supercontinent respectively. The youngest age record of ∼1.05–0.99 Ga indicates evidence of Rodinia formation in and around the Pur-Banera basin. [ABSTRACT FROM AUTHOR]

Absolute dating of sedimentary rocks and fossils from the Mesozoic are still rare, mainly due to the difficulties arising from diagenetic changes. Diagenesis promotes changes in the primary structure and chemical composition of biomineralization, which should remain unchanged from the time of deposition and fossilization. Three bioapatite teeth extracted from a jaw fragment of Cladocyclus gardneri from the Romualdo Formation, Araripe Basin, Northeastern Brazil were dated by the U/Pb method in order to obtain an absolute age. The rocks that contain this fossil are dated to Aptian by biostratigraphy of palynomorphs (Sergipea variverrucata biozone, Petrobras P-270), ostracods (Damonella grandiensis biozone, Petrobras) and from the international biozoning of planktonic foraminifera Microhedbergella miniglobularis. The teeth were mounted in 25 mm epoxy resin rounds, imaged by optical microscope and SEM and dated with a Nu Instruments AttoM single-collector ICP-MS coupled to an NWR193nm UC (Ultra Compact) ArF excimer laser system. A Discordia U–Pb date obtained from three separate Cladocyclus gardneri dentine is 110.5 ± 7.4 Ma (2s, MSWD = 2.6), consistent with the biostratigraphic age. This date was based on 155 integrations of line scan analyses (spot size of 30 μm, scan moved at 2 μm per second/100 μm in total length). 238U/206Pb ratios that differed from the mean value by more than 2SD for each tooth were excluded based on the likelihood they reflect U-redistribution during fossilization/post-fossilization fluid alteration. Remaining variations in 238U/206Pb and 207Pb/206Pb ratios along the Discordia reflect variable contributions from common Pb, both within and between the three teeth. They reflect primary U/Pb compositions given that they date the expected age of fossilization. • Direct dating on fossils is still a challenge to be overcome in Geochronology. • Biomineralized parts are more likely to be preserved in the fossilization. • First absolute dating result for the Romualdo Formation, Araripe Basin. • The U–Pb dating corroborates biostratigraphy data. [ABSTRACT FROM AUTHOR]

The snowball Earth hypothesis predicts globally synchronous glaciations that persisted on a multimillion year time scale. Geochronological tests of this hypothesis have been limited by a dearth of reliable age constraints bracketing these events on multiple cratons. Here we present four new Re-Os geochronology age constraints on Sturtian (717-660 Ma) and Marinoan (635 Ma termination) glacial deposits from three different paleocontinents. A 752.7 ± 5.5 Ma age from the base of the Callison Lake Formation in Yukon, Canada, confirms nonglacial sedimentation on the western margin of Laurentia between ca. 753 and 717 Ma. Coupled with a new 727.3 ± 4.9 Ma age directly below the glacigenic deposits of the Grand Conglomerate on the Congo craton (Africa), these data refute the notion of a global ca. 740 Ma Kaigas glaciation. A 659.0 ± 4.5 Ma age directly above the Maikhan-Uul diamictite in Mongolia confirms previous constraints on a long duration for the 717-660 Ma Sturtian glacial epoch and a relatively short nonglacial interlude. In addition, we provide the first direct radiometric age constraint for the termination of the Marinoan glaciation in Laurentia with an age of 632.3 ± 5.9 Ma from the basal Sheepbed Formation of northwest Canada, which is identical, within uncertainty, to U-Pb zircon ages from China, Australia, and Namibia. Together, these data unite Re-Os and U-Pb geochronological constraints and provide a refined temporal framework for Cryogenian Earth history. [ABSTRACT FROM AUTHOR]

The study of volcanism near unstable plate triple junctions (TJs) offers a unique opportunity to investigate the interactions between mantle dynamics and lithospheric deformation in relation to short-term plate reconfiguration. From combined geochronological and geochemical analyses on Terceira, S. Jorge and Faial volcanic islands, we evidence contrasted modes of melt generation near the Azores Triple Junction during the last 1.3 Myr. The oldest lavas (> 800 ka) erupted along N150 elongated volcanic systems in S. Jorge and Faial have homogeneous isotopic compositions which partly overlap the compositional field of MORBs from the adjacent Mid-Atlantic Ridge (MAR). In contrast, the younger lavas (< 750 ka) erupted along the N110 main structural direction on the three islands are significantly more enriched in LILE and LREE, and have more variable and generally more radiogenic Sr, Pb, Nd and Hf isotopic ratios. Altogether, our data do not support the presence of an active mantle plume under the central Azores. Instead, they suggest that magma generation results from decompression melting of a heterogeneously fertilized mantle (fossil plume?). The higher geochemical heterogeneity of the lavas erupted during the last 750 kyr likely reflects low-degree partial melting promoted by recent reactivation of pre-existing MAR Fracture Zones. We propose that the sub-aerial volcanism over the last 1.3 Myr in the central Azores records a sudden change in the conditions of melt generation, due to a major reconfiguration in regional deformation associated with the recent reorganization of the Eurasia–Nubia plate boundary. [ABSTRACT FROM AUTHOR]

An ash-rich volcaniclastic sandstone immediately underlying dinosaur-rich material from the Danek Bonebed in the Horseshoe Canyon Formation (HCF), Edmonton, Alberta, Canada, contains accessory zircon, which have been dated employing U-Pb geochronology. Both laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and chemical abrasion isotope dilution thermal ionization mass spectrometry (ID-TIMS) U-Pb analyses have been conducted. The zircon age distributions are complex with U-Pb dates ranging from Precambrian to Cretaceous. We consider the youngest ID-TIMS 206Pb/238U date of 71.923 ± 0.068 Ma as the maximum deposition age of the ash-rich sandstone, placing the overlying Danek bonebed in the early Maastrichtian. This age is compatible with the paleontological assemblage from the Danek Bonebed and the regional stratigraphy. The zircon age distribution also implies that the HCF had a complex provenance of the detritus with some Archean and Proterozoic zircons, a group of Mesozoic, and a large compliment of Cretaceous grains. The results highlight the importance of high precision geochronology in constraining the age of important fossil deposits such as the Danek Bonebed. [ABSTRACT FROM AUTHOR]

Inactive shorelines represent valuable records for sea level change, shoreline variations and tectonics if we can constrain the timing of their formation. Where the associated beaches are cobble dominated, luminescence rock surface dating is a promising alternative to established dating approaches, since unlike other techniques it offers the potential to identify clasts unaffected by inherited ages. While luminescence rock surface dating has successfully been used on Holocene and Late Pleistocene beach ridges previously, in this study the potential of IRSL rock surface dating is evaluated for the magmatic cobbles of uplifted Pleistocene terraces along the tectonically active coast of northern Chile. Cobbles from an active beach were used to investigate the influence of cobble lithology on IRSL signal properties and the effectiveness of IRSL signal resetting in the rock. While alkaline and andesitic cobbles yield low IRSL intensities and limited signal resetting due to strong light attenuation, more favourable characteristics for dating were observed for some diorite and granite cobbles. Their IRSL signals were well reset in the uppermost few mm without any systematic difference between upper and lower surface. Some of them revealed bleaching plateaus with inherited ages close to zero after correction for laboratory residuals. For dating, cobbles from three Pleistocene marine terraces, for which new uranium‑thorium and ESR control ages on molluscs provide age control, were targeted. None of the associated IRSL rock surface burial ages agrees with the MIS 5 control ages of the terraces. Most of the selected cobbles are either too dark to allow for effective signal resetting or yield IRSL properties unsuitable for dating. Only one of the targeted cobbles shows both signs of signal resetting at its surface and sensitive IRSL signals, but its signal was already in field saturation due to dose rates >6 Gy/ka. In conclusion, our data indicate that beach cobbles with granitic to dioritic lithology combine appropriate IRSL properties and sufficient IRSL signal resetting for dating Holocene landforms. Last interglacial terraces may already be beyond the limit of IRSL dating for most cobbles of this lithology since they show large dose rates compared to IRSL sediment dating. • Successful evaluation of luminescence rock surface dating for modern beach cobbles from Chile • Signal-depth profiles for the IRSL and post-IRSL signals in modern beach cobbles of different lithology • Application of luminescence rock surface dating to last interglacial marine cobbles from Chile • Comparison of luminescence rock surface ages for marine cobbles with ESR- and U-series ages of molluscs [ABSTRACT FROM AUTHOR]

Dating the timing of motion on crustal shear zones is of tremendous importance for understanding the assembly of orogenic terranes. This objective is achieved in this paper by combining petrological and structural observations with novel developments in in situ U-Th-Pb geochronology of allanite. A greenschist facies shear zone within the Mont Blanc Massif is documented. Allanite is synkinematic and belongs to the mylonitic assemblage. LA- ICP- MS U-Th-Pb isotope analyses of allanite reveal high contents and highly radiogenic isotopic compositions of the common-Pb component. The use of measured Pb-isotope compositions of associated minerals (feldspars and chlorite) is critical for accurate common-Pb correction, and provides a powerful mechanism for linking allanite growth to the metamorphic assemblage. A mean 208Pb/232Th age of 29.44 ± 0.95 Ma is accordingly taken for synkinematic allanite crystallisation under greenschist facies conditions. This age reflects the timing of the Mont Blanc underthrusting below the Penninic Front and highlights the potential of directly dating deformation with allanite. [ABSTRACT FROM AUTHOR]

New reliable palaeomagnetic data from the Siberian platform help in deciphering its palaeogeography during ∼450–400 Ma. Geochronology of late Devonian mafic sills provides time constraints for tectonic deformation along the southern margin of the Siberian Platform and thus a minimum age for the regional magnetic overprint. From a late Ordovician–Silurian sedimentary section of the Nyuya syncline in the southern part of the Siberian platform with the Devonian sills hosted nearby in early Palaeozoic sediments, pre-folding presumably primary magnetization was isolated from the sediments during stepwise thermal cleaning. High unblocking temperatures imply that haematite is the main carrier of magnetization. The sample-mean direction for 37 Ordovician samples from nine sites in stratigraphic coordinates is Ds = 168.5, Is = −5, ks = 22.3 and α95 = 5.1 and for 77 Silurian samples from six sites is Ds = 193.9, Is = 20.9, ks = 16 and α95 = 4.2. Another component recorded in both the Silurian and Ordovician samples is pre-folding, with a sample-mean direction of Ds = 204.4, Is = 37.9, ks = 27.2 and α95 = 2.7 for 104 samples from eight sites. This component was probably formed during a regional remagnetization event, which took place in post-early Silurian time. Putting this secondary component into a framework with available Palaeozoic data and geochronology further constrains its age to be early Devonian.The isolated components yield new late Ordovician, early Silurian and early-middle Devonian palaeomagnetic poles. The revised middle Palaeozoic segment of the apparent polar wander path (APWP) for the Siberian platform provides new palaeogeographic constraints. Our data suggest that in late Ordovician the platform was situated in equatorial latitudes and was rotated 180° with respect to its present position. During middle-late Ordovician time, the platform did not experience any notable latitudinal drift. It started drifting to the north in the late Ordovician, and by the late Silurian it had travelled ∼1500 km northwards and had rotated ∼30° counter-clockwise (CCW). During late Silurian time, the platform continued northward drift and CCW rotation, and by the early Devonian it had drifted ∼1100 km northwards and rotated 10° CCW relative to its Silurian position. After that, the rotation of the platform changed to clockwise (CW), and by the late Devonian had drifted another 1500 km to the north and had rotated ∼60° CW.We evaluated palaeomagnetically viable positions from 450–400 Ma of the three largest Laurasian cratons, Siberia, Baltica and Laurentia, based on the new data and previously published APWPs. Contrary to several published reconstructions, the Siberian platform could not have been situated to the north of the Caledonian suture in mid-Silurian time, but was probably located either at the eastern or the western side of Laurussia. The new data are compatible with an early Devonian position of Siberia similar to the modern Eurasian configuration. They also support the post- early or middle Devonian relative rotation between the Aldan and Angara blocks of the Siberian platform. [ABSTRACT FROM AUTHOR]

Abstract: Systematic 40Ar/39Ar dating of granitoids and surrounding metamorphic rocks has been performed in the Limousin area (W of French Massif Central) in order to provide new constrains concerning its late-orogenic thermal and tectonic evolution. The same 40Ar/39Ar age of ca. 335–338Ma is found on the present-day outcrop surface for most of the Limousin metamorphic rocks, hence indicating that the entire massif was uniformly cooled down at this period. These ages are very close to the 40Ar/39Ar ages proposed in the Sioule and Brevenne areas in the literature, but also to the coupled tectonic and magmatic activity in the south Limousin. These results help to document the existence of two exhumation stages, each one associated with an extensional stage. A first exhumation stage, has been active at ca. 335–340Ma. Available data indicate that this extension and associated exhumation and cooling occurred over a distance of more than 200km in the internal zones of the belt, whereas compression was still active in the northern and southern parts of the belt. A second exhumation stage may be related to the late-orogenic extension and collapse of the belt, at ca. 310–305Ma, and is characterized by the uplift of the St. Sylvestre complex by unroofing of the overlying metamorphic and granitoidic formations. [Copyright &y& Elsevier]

U Pb dating of hydrogenic and fossil material can be a significant challenge because samples often contain low U levels and variable amounts of non-radiogenic Pb. Line scans using LA-ICPMS provide the widest range of ratios available for defining the radiogenic to common Pb mixing line, hence the best age estimate, but extracting this information requires processing many low-count data. Conventional least-squares regression of ratios based on such data can give inconsistent results. A new approach is introduced where data are regressed as count rates in a 3D space rather than ratios on a 2D plot. This is a maximum likelihood approach in that mixing planes covering a range of ages and common 207Pb/206Pb ratios (PbC) are compared to the data set and used to determine a relative probability density surface whose maximum should fix the best-fit age and common 207Pb/206Pb ratio. 95% confidence errors are determined from T and PbC values that cut off 2.5% of the area to the left and right of 2D plots generated by integration of the 3D plot over PbC and age, respectively. Results from a rugose coral fossil show that this approach gives age results similar to regressions of concordia data and more accurate than Tera-Wasserburg regressions on data from natural samples. Tests on randomly generated synthetic data do not show significant discrepancy between Isoplot ages but they do between values of PbC. The 3D approach is the only one that gives accurate results for both age and PbC. [ABSTRACT FROM AUTHOR]

The article discusses the geochronological study of the trachyrhyolites of the Ulkan Group. It states that the volcanic deposits overlie metamorphic rocks of the Early Proterozoic era. It mentions that Riphean deposit sequence is considered as Siberian hypostratotype. It adds that isochronous Rb-Sr method was used to identify the age of the crust located at the base of Lower Riphean Uyan Group. Furthermore, the chemical composition of volcanites correspond to igneous rocks while associated granites and acid volcanites correspond to granites which are A-type.

Abstract: Lacustrine sedimentary successions provide exceptionally high-resolution records of continental geological processes, responding to tectonic, climatic and magmatic influences. These successions are therefore essential for correlating geological and climatic phenomena across continents and furthermore the globe. Producing accurate geochronological frameworks within lacustrine strata is challenging because the stratigraphy is often bereft of biostratigraphy and directly dateable tuff horizons. The rhenium–osmium (Re–Os) geochronometer is a well-established tool for determining precise and accurate depositional ages of marine organic-rich rocks. Lake systems with stratified water columns are predisposed to the preservation of organic-rich rocks and thus should permit direct Re–Os geochronology of lacustrine strata. We present Re–Os systematics from one of the world''s best documented lacustrine systems, the Eocene Green River Formation, providing accurate Re–Os depositional dates that are supported by Ar–Ar and U–Pb ages of intercalated tuff horizons. Precision of the Green River Formation Re–Os dates is controlled by the variation in initial 187Os/188Os and the range of 187Re/188Os ratios, as also documented in marine systems. Controls on uptake and fractionation of Re and Os are considered to relate mainly to depositional setting and the type of organic matter deposited, with the need to further understand the chelating precursors of Re and Os in organic matter highlighted. In addition to geochronology, the Re–Os data records the 187Os/188Os composition of lake water (1.41–1.54) at the time of deposition, giving an insight into continental runoff derived from weathering of the geological hinterland of the Green River Formation. Such insights enable us to evaluate fluctuations in continental climatic, tectonic and magmatic processes and provide the ability for chemostratigraphic correlation combined with direct depositional dates. Furthermore, initial 187Os/188Os values can be used as a diagnostic tool to distinguish between lacustrine and marine depositional settings when compared to known oceanic 187Os/188Os values. [Copyright &y& Elsevier]