Search

The Oaxacan Complex Carboniferous-Permian sedimentary cover in southern México records provenance shifts through time, reflecting the collision between Gondwana and Laurentia to amalgamate Pangea. The integration of petrological analysis and LA-ICP-MS U-Pb zircon geochronology from Santiago, Ixtaltepec and Yododeñe formations compared with adjacent terranes suggests that: (1) during the Early Mississippian, the Santiago Formation received sediments mainly from local sources such as the Oaxacan Complex and Tiñu Formation, with minor contributions from adjacent peri-Gondwana sources. The magmatic activity may have started during this time (~359–346 Ma) (2) during the Late Mississippian (Ixtaltepec Formation), detrital zircon grains of Ediacaran-Cambrian age are dominant, derived from sediments either related to the Pan-African/Brasiliano orogeny or the opening of the Iapetus Ocean; (3) during the Late Mississippian-Middle Pennsylvanian, intercalated marine volcaniclastic sandstone (Ixtaltepec Formation) provides the first record of Carboniferous arc-related volcanism reported in southern Mexico, dated between 330 and 308 Ma; (4) the early Permian Yododeñe Formation records the exhumation and erosion of the sedimentary cover during the final stage of Pangea assembly. Rhyodacitic subvolcanic sills and lavas dated at ~282–270 Ma are present throughout the succession. Volcanism and ca. 360–308 Ma detrital zircon grains could be associated with a Carboniferous magmatic arc formed by subduction of the Rheic oceanic plate beneath Gondwana. Slightly younger detrital zircon and subvolcanic rocks dated at ~300–270 Ma are linked to a western Pangea arc developed in response to the subduction of the Paleo-Pacific Ocean following Pangea assembly. Our results suggest that the Carboniferous-Permian units were deposited in a peri-arc basin, sharing sediment provenance with the Maya and Coahuila blocks, the Sierra de Juárez Complex, and northwestern South America. [ABSTRACT FROM AUTHOR]

New geochemical and geochronological data lead to a fuller understanding of different aspects of the Rajmahal flood basalt province. Earlier work was on surface Rajmahal flows as well as from the nearby Bengal Traps. Samples from a ~300 m borehole near the northwestern corner of the Rajmahal lavas, analyzed herein, reveal the presence of carbonatitic (aillikitic) material. This small province, including the Bengal Traps, thus exhibits quartz and olivine tholeiites, andesitic basalts, alkali basalts as well as carbonatitic material. The Sylhet Traps, lying ~500 km to the east of the surface Rajmahal flows, show geochemical similarities, but were probably formed ~10 Myr after Rajmahal volcanism. Sr–Nd isotopic plots suggest that (a) not all lavas in the Rajmahal Traps were homogenized isotopically prior to eruption and (b) the Sylhet Traps show a much wider variety of isotopic values at eruption, possibly caused by alteration. Published and new 40Ar/39Ar ages for both the Rajmahal and other mafic rocks postulated to have been formed by the Kerguelen Hotspot in the Southern Indian Ocean, are critically examined; emphasis is placed on the freshness of the rocks dated. It is shown that a number of 'ages' for both the Rajmahal Province, and for rocks recovered from the Kerguelen Plateau area, should be rejected as invalid measures of the time of crystallization, as altered material was dated. For the surface Rajmahal material, valid ages span ~120 (quartz tholeiites) to ~116 Ma (andesitic basalts); alkali basalts and olivine tholeiites (Bengal Traps) as well as the aillikite were also formed within this time interval. The postulated genetic link to the Kerguelen Hotspot and basalts in the Southern Indian Ocean appears valid; in particular, a section of the southern Kerguelen Plateau (~58°S; 75°E) has strong geochemical and temporal links to the Rajmahal Traps. [ABSTRACT FROM AUTHOR]

• First in-situ apatite U-Pb ages from pseudotachylytes. • The lower crust fails seismically during the early stages of continental collision. • Earthquakes create long-lived fluid pathways in the lower crust. Determining the precise age of fossil earthquakes is essential for understanding the tectonic setting in which they occurred. Pseudotachylytes are quenched frictional melts that occur along coseismic fractures and represent evidence of fossil earthquakes in the rock record. Here, we present the first in-situ apatite U-Pb ages for three samples from Lofoten in the northern Norwegian Caledonides, that occur within and adjacent to lower-crustal pseudotachylytes: a pristine pseudotachylyte, a mylonitized pseudotachylyte, and a mylonite that contains pseudotachylyte transposed into the shear plane. The apatite U-Pb ages are combined with cathodoluminescence and electron backscatter diffraction analysis to provide microstructural constraints on the interpretation of ages. Apatite shows evidence of either fragmentation and annealing, or dislocation creep in response to coseismic rupture. The results suggest that the short-lived thermal pulse generated by the earthquake is sufficient to reset the apatite U-Pb system. The age of 426 ± 19 Ma is interpreted to date lower-crustal seismicity during the early Caledonian orogeny. Later fluid-rock interaction along the same structures led to partial resetting of the apatite U-Pb systematics, indicating that seismic brittle failure of the lower continental crust occurs at the incipient stages of continental collision, and that the resulting structures are preferential pathways for later fluid flow in the otherwise impermeable anhydrous lower crust. [ABSTRACT FROM AUTHOR]

The study of geological sea-level proxies formed during previous interglacials is a common approach to assess how global sea level will evolve under warmer climate conditions. Over the last decades, technical advancements in both survey and geochronology have allowed improving our knowledge of past sea-level highstands. This is of prime importance to refine our understanding of processes contributing to sea-level changes, and ultimately to improve both local and global sea-level projections. Last Interglacial sea-level proxies in the Western Indian Ocean (and more specifically the island nation of Madagascar), have been less investigated than in other intertropical oceans over the last decades. As a result, paleo sea-level data in this region are less abundant and less precise than elsewhere. Here, we report the results of two field campaigns aimed at studying the site of Lembetabe, southwest Madagascar, where a fossil reef was first described by the researcher René Battistini more than 50 years ago. We estimate paleo relative sea level history in space and time from 15 new U-series ages from a fossil reef platform mapped with differential GNSS and drone photogrammetry. Our data suggest that, between 129 ka and 115 ka, paleo relative sea level at this location was about 3.4 ± 1.4 m above modern. Once corrected for glacial isostatic adjustment, we find that paleo global mean sea level did not exceed 3 m above modern. Only slight crustal subsidence would reconcile the peak Last Interglacial sea level measured at Lembetabe with the 5–10 m range reported in the literature. • Fossil reef dated to the Last Interglacial in southwest Madagascar. • Stable paleo relative sea level during the LIG at about 3.4 ± 1.4 m above modern. • Interplay between glacial isostatic adjustment and global mean sea level. [ABSTRACT FROM AUTHOR]

The Hegenshan–Heihe Suture (HHS) is an important suture zone between the Xing'an and Songliao–Xilinhot blocks in the eastern Central Asian Orogenic Belt (CAOB). Many studies have examined the northern and southern parts of this suture zone, but the middle segment remains under-researched and controversial. This paper presents new research into Permian felsic rocks along the middle segment of the HHS, including alkaline granites, rhyolites, and granodiorites. Zircon U–Pb dating of these rocks yielded precise Permian ages of 300.4 ± 2.5, 292.8 ± 2.7, and 293.1 ± 2.2 Ma. The alkaline granites and the rhyolites are A-type rocks that were derived from lower crustal protoliths, with the melting of these protoliths caused by asthenospheric upwelling associated with lithospheric delamination. In comparison, the granodiorites are I-type granites were generated from a mantle-derived magmatic source. The petrogenesis of these granites also involved the assimilation of sedimentary rocks and fractional crystallization. This Permian magmatism occurred during post-collisional extension following the amalgamation of the Xing'an and Songliao–Xilinhot blocks. [ABSTRACT FROM AUTHOR]

Abstract A next-generation, high-flux DD neutron generator has been designed, commissioned, and characterized, and is now operational in a new facility at the University of California Berkeley. The generator, originally designed for 40Ar/39Ar dating of geological materials, has since served numerous additional applications, including medical isotope production studies, with others planned for the near future. In this work, we present an overview of the High Flux Neutron Generator (HFNG) which includes a variety of simulations, analytical models, and experimental validation of results. Extensive analysis was performed in order to characterize the neutron yield, flux, and energy distribution at specific locations where samples may be loaded for irradiation. A notable design feature of the HFNG is the possibility for sample irradiation internal to the cathode, just 8 mm away from the neutron production site, thus maximizing the neutron flux (n/cm 2 /s). The generator’s maximum neutron flux at this irradiation position is 2.58 × 10 7 n/cm 2 /s ± 5% (approximately 3 × 10 8 n/s total yield) as measured via activation of small natural indium foils. However, future development is aimed at achieving an order of magnitude increase in flux. Additionally, the deuterium ion beam optics were optimized by simulations for various extraction configurations in order to achieve a uniform neutron flux distribution and an acceptable heat load. Finally, experiments were performed in order to benchmark the modeling and characterization of the HFNG. [ABSTRACT FROM AUTHOR]

Observations of discordant ages, meaning that an age given by one mineral geochronometer is different from the age given by another geochronometer from the same rock, began in the early days of geochronology. In the late 1950s and 1960s, discordant U-Pb zircon ages were unquestioningly attributed to Pb diffusion at high temperature. Later, the mineralogical properties and the petrogenesis of the zircon crystals being dated was recognized as a key factor in obtaining concordant U-Pb ages. Advances in analytical methods allowed the analysis of smaller and smaller zircon multigrain fractions, then the analysis of individual grains, and even pieces of grains, with higher degrees of concordancy. Further advances allowed a higher analytical precision, a clearer perception of accuracy, and a better statistical resolution of age discordance. As for understanding the cause(s) of discordance, belief revision followed the coupling of imaging, cathodoluminescence (CL), and backscattered electrons (BSE), to in situ dating by secondary ion mass spectrometry (SIMS) or by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Discordant zircon and other accessory minerals (e.g., monazite, apatite, etc.) often consist of young rims accreted onto/into older cores. Age gradients are sharp, and no Pb diffusion gradients are observed. As U-Pb discordance in crystalline, non-radiation damaged grains is caused by diachronous, heterochemical mineral generations, interpretations of mineral ages, based on the exclusive role of diffusion, are superseded, and closure temperatures of zircon and monazite are irrelevant in geological reality. Other isotopic systems (Rb-Sr, K-Ar) were believed, since the 1960s, to be similarly controlled by the diffusivity of radiogenic daughters. When zircon and monazite discordance were recognized as zone accretion/reaction with sharp boundaries that showed little or no high-temperature diffusive re-equilibration, the other chronometric systems were left behind, and interpretations of mineral ages based on the exclusive role of diffusion survived. The evidence from textural-petrologic imaging (CL, BSE) and element mapping by electron probe microanalyzer (EPMA) or high spatial resolution SIMS or LA-ICP-MS provides the decisive constraints. All microcline and mica geochronometers that have been characterized in detail document patchy textures and evidence for mineral replacement reactions. It is important not to confuse causes and effects; heterochemical microstructures are not the cause of Ar and Sr loss; rather, they follow it. Ar and Sr loss by dissolution of the older mineral generation occurs first, heterochemical textures form later, when the replacive assemblage recrystallizes. Heterochemical mineral generations are identified and dated by their Ca/Cl/K systematics in 39Ar-40Ar. Replacive reactions adding or removing Cl, such as, e.g., sericite overgrowths on K-feldspar, retrograde muscovite intergrowths with phengite, etc. are detected by Cl/K vs. Ar/K isotope correlation diagrams. Ca-poor reaction products, such as, e.g., young biotite intergrown with older amphibole, adularia replacing microcline, etc., can be easily identified by Ca/K vs. Ar/K diagrams supported by EPMA analyses. Mixed mineral generations are observed to be the cause of discordant, staircase-shaped age spectra, while step-heating of crystals with age gradients produces concordant plateaus. Age gradients are therefore unrelated to staircase age spectra. There is a profound analogy between the U-Pb, Rb-Sr, and K-Ar systems. Pb and Ar diffusion rates are both much slower than mineral replacement rates for all T < 750 °C. Patchy retrogression textures are always associated with heterochemical signatures (U/Th ratios, REE patterns, Ca/Cl/K ratios). As a rule, single-generation minerals with low amounts of radiation damage give concordant ages, whereas discordance is caused by mixtures of heterochemical, resolvably diachronous, mineral generations in petrologic disequilibrium. This can also include (sub-)grains that have accumulated significant amounts of radiation damage. For accurate geochronology the petrologic characterization with the appropriate technique(s) of the minerals to be dated, and the petrologic context at large, are as essential as the mass spectrometric analyses. [ABSTRACT FROM AUTHOR]

This study reports zircon U-Pb and Hf isotopes and whole-rock elemental data for granodiorites from the East Kunlun orogen. The zircon U-Pb dating defines their crystallization age of 235 Ma. The rocks are characterized by high-K calc-alkaline, magnesian and metaluminous with (KO+NaO)=6.38 wt.%-7.01 wt.%, Mg#=42-50 [Mg#=100×molar Mg/(Mg+FeO)], A/CNK=0.92-0.98, coupled with high ε( t) values from -0.65 to -1.80. The rocks were derived from partial melting of a juvenile mafic crustal source within normal crust thickness. The juvenile lower crust was generated by mixing lithospheric mantle-derived melt (55%-60%) and supracrustal melt (40%-45%) during the seafloor subduction. Together with available data from the East Kunlun, it is proposed that the studied Middle Triassic granodiorites were formed in post-collisional extension setting, in which melting of the juvenile lower crust in response to the basaltic magma underplating resulted in the production of high-K granodioritic melts. [ABSTRACT FROM AUTHOR]

U Pb dating of hydrogenic and fossil material can be a significant challenge because samples often contain low U levels and variable amounts of non-radiogenic Pb. Line scans using LA-ICPMS provide the widest range of ratios available for defining the radiogenic to common Pb mixing line, hence the best age estimate, but extracting this information requires processing many low-count data. Conventional least-squares regression of ratios based on such data can give inconsistent results. A new approach is introduced where data are regressed as count rates in a 3D space rather than ratios on a 2D plot. This is a maximum likelihood approach in that mixing planes covering a range of ages and common 207Pb/206Pb ratios (PbC) are compared to the data set and used to determine a relative probability density surface whose maximum should fix the best-fit age and common 207Pb/206Pb ratio. 95% confidence errors are determined from T and PbC values that cut off 2.5% of the area to the left and right of 2D plots generated by integration of the 3D plot over PbC and age, respectively. Results from a rugose coral fossil show that this approach gives age results similar to regressions of concordia data and more accurate than Tera-Wasserburg regressions on data from natural samples. Tests on randomly generated synthetic data do not show significant discrepancy between Isoplot ages but they do between values of PbC. The 3D approach is the only one that gives accurate results for both age and PbC. [ABSTRACT FROM AUTHOR]

The Phanerozoic tectonic evolution of the Chuya-Kurai zone was studied by means of zircon U/Pb-dating, apatite fission track (AFT) and apatite (U-Th)/He (AHe) thermochronology performed on basement rocks. Our results suggest that multiple magmatic episodes during the Paleozoic, related to the accretion-collision tectonics in Central Asia, affected our study area. Mesozoic and Cenozoic basement cooling events are interpreted as periods of tectonic reactivation. A new tectonic model for Late Cenozoic evolution of the Chuya-Kurai zone is proposed. [ABSTRACT FROM AUTHOR]

Geochronology studies in South Australia were developed in three Adelaide institutions. (i) University of Adelaide: (ia) Department of Geology and Mineralogy, where four single chemical measurements were reported in 1923-1955 and 14 lead-alpha measurements in 1961; MSID Rb-Sr work began in 1972 followed by zircon U-Pb about 1980 and Sm-Nd later; (ib) luminescence equipment was developed in the Department of Physics and is used to date recent sediments. (ii) Flinders University, where alpha spectrometry disequilibrium dating of recent sediments was active during 1972-2000; and (iii) AMDEL, which supplied a variable commercial service of K-Ar, Rb-Sr and zircon dating during period 1972-1999. [ABSTRACT FROM AUTHOR]

Zircon LA-ICP MS U-Pb dating of six metamorphic rocks and a metagranite (breccia) from southern basement of the Songliao Basin are reported In order to constrain the formation ages of basement. The basement metamorphic rocks in the Songliao Basin mainly consist of metagabbro (L45-1), amphibolite (SN117), metarhyolitical tuff (G190), sericite (Ser) schist (N103), chlorite (ChI) schist (T5-1), blotite (Bi)-actlnolite (Act)-quartz (Q) schist (Y205), and metagranite (L44-1). The cathodoluminesence (CL) Images of the zircons from metagabbro (L45-1) and metagranite (L44-1) Indicate that they have cores of magmatic origin and rims of metamorphic overgrowths. Their U-Pb isotopic ages are 1808±21 Ma and 1873±13 Ma, respectively. The zircons with oscillatory zoning from amphibolite (SN117) and Chi schist (T5-1), being similar to those of mafic igneous rocks, yield ages of 274 ± 3.4 Ma and 264 ± 3.2 Ma, respectively. The zircons from metarhyolitical tuff (G190) and Ser schist (N103) display typical magmatic growth zoning and yield ages of 424 ± 4.5 Ma and 287 ± 5.1 Ma, respectively. Most of zircons from Bi-Act-Q schist (Y205) are round in shape and different in absorption degree in the CL Images, Implying their sedimentary detritals. U-Pb dating yield concordant ages of 427 ± 3.1 Ma, 455 ± 12 Ma, 696 ± 13 Ma, 1384±62 Ma, 1649±36 Ma, 1778±18 Ma, 2450±9 Ma, 2579±10 Ma, 2793±4 Ma and 2953±14 Ma. The above-mentioned results indicate that the Precambrian crystalline basement (1808-1873 Ma) exists in the southern Songliao Basin and could be related to tectonic thrust, and that the Early Paleozoic (424-490 Ma) and Late Paleozoic magmatisms (264-292 Ma) also occur in the basin basement, which are consistent with the ages of the detrital zircons from Bi-Act-Q schist in the basement. [ABSTRACT FROM AUTHOR]

We present coupled textural observations and trace element and geochronological data from metasomatic monazite and zircon, to constrain the timing of high-grade Na-metasomatism (albitization) of an Archean orthogneiss in southwest Montana, USA. Field, mineral textures, and geochemical evidence indicate albitization occurred as a rind along the margin of a ~3.2 Ga granodioritic orthogneiss (Pl + Hbl + Kfs + Qz + Bt + Zrn) exposed in the Northern Madison range. The metasomatic product is a weakly deformed albitite (Ab + Bt + OAm + Zrn + Mnz + Ap + Rt). Orthoamphibole and biotite grew synkinematically with the regional foliation fabric, which developed during metamorphism that locally peaked at upper amphibolite-facies during the 1800–1710 Ma Big Sky orogeny. Metasomatism resulted in an increase in Na, a decrease in Ca, K, Ba, Fe, and Sr, a complete transformation of plagioclase and K-feldspar into albite, and loss of quartz. In situ geochronology on zoned monazite and zircon indicate growth by dissolution–precipitation in both phases at ~1750–1735 Ma. Trace element geochemistry of rim domains in these phases are best explained by dissolution–reprecipitation in equilibrium with Na-rich fluid. Together, these data temporally and mechanistically link metasomatism with high-grade tectonism and prograde metamorphism during the Big Sky orogeny. [ABSTRACT FROM AUTHOR]