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Purpose: Paper aims to evaluate the efficiency of traditional chitosan, nano chitosan, and chitosan nanocomposites for consolidating aged papyrus samples. Cellulose-based materials, such as papyrus sheets and paper, which are the most common types of writing supports for works of art in many museums and archive. They are subjected to different types of deterioration factors that may lead to many conservation problems. Consolidation treatment is one of the most common conservation treatments, which should have perform after much testing to select the appropriate consolidants. Design/methodology/approach: This research paper aims to evaluate the resistance of traditional chitosan, nanochitosan and chitosan/zinc oxide nanocomposite as an eco-friendly papyrus strengthening. Untreated and treated papyrus was thermally aged and characterized via scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FTIR). Antimicrobial activity of the papyrus specimens was also determined against four tested pathogenic bacteria by disc diffusion method: MRSA, Staphylococcus aureus, E. coli and P. aeruginosa. Findings: The results revealed that chitosan nanocomposite showed a remarkable enhancement of papyrus tensile properties and presence of ZnO prevents the effects of biodeterioration. Originality/value: Zinc oxide nanoparticles enhance the optical properties and increase the chemical reactions between the consolidating material and the treated papyrus. [ABSTRACT FROM AUTHOR]

Microplastics (MPs) are ubiquitous and evasive in nature. They can be found in complex agricultural matrices like soil and compost. In the literature, extracting MPs from soil is more prevalent; nonetheless, the same instruments in extraction in soil samples can also be used to assess MPs in compost despite the high levels of organic material. MPs in agricultural environments have recently become a focus of research due to their status as emerging pollutants. However, the lack of standardized instruments and techniques for analysis is a major challenge in assessing MPs. Despite this limitation, this review article identified and suggested some important factors to consider when selecting suitable methods or instruments for MP analysis. This article also categorized instrumental analysis in MP studies as destructive and non-destructive and highlighted the advantages and disadvantages of methods and instruments such as visual inspection, Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy (RS), and Scanning Electron Microscope (SEM). These highlights will provide researchers with a useful guide to help them choose the most appropriate method and instrumentation technique for their MP analytical research. Additionally, the article discusses the combination of two or more of these analytical instruments to improve efficiency. [ABSTRACT FROM AUTHOR]

The treatment method of natural fiber is one of the factors that influences its properties. There are several reports on sodium hydroxide (NaOH) treatment of many natural fiber. Though there are works on NaOH treatment of the fruits fiber, however, works on Borassus flabellifer Leaf fiber (BFLF) is sparsely reported. Hence no report on the optimum conditions for sodium hydroxide treatment of Borassus Flabellifer Leaf fiber. Therefore, this study aimed at establishing the optimum concentration and time for alkaline treatment on the properties of BFLF. The fiber extraction was carried out using water retting method for 24 h. Experimental design was carried out using Design Expert 12.0 adopting Central composite design in response surface methodology. NaOH concentration of 0–5 wt% and time of 1–12 h were used as the independent variables. The responses were water absorption, elongation (%), modulus of elasticity and tensile strength. The surface morphology of the fiber was studied using scanning electron microscope (SEM) and the functional group changes established using Fourier transform infrared (FTIR) spectroscopy to indicate effect of NaOH treatment (FTIR) spectroscopy to show the functional group changes due to NaOH treatment. The optimum concentration and treatment time was established as 2 wt% NaOH and 4 h, respectively, with corresponding responses of water absorption, tensile strength, modulus of elasticity and elongation (%) were 2.07%, 977.378 MPa, 6971.02 MPa, 5.178%, respectively. Using these optimum treatment conditions of time and NaOH concentration, the responses were validated to be 1.88%, 920.019 MPa, 6943.73 MPa, 4.99 mm having a desirability of 0.963. The SEM revealed rough surfaces and increased porosity for the treated fiber compared to the untreated. The FTIR spectra showed reduction in peaks representing lignin at wavelength of 3321.1 cm−1 to 3306.1 cm−1, which indicated that the NaOH treatment resulted to decrease in lignin in the fiber. The properties of the BFLF obtained at the optimum treatment conditions were within range of other fibers used in composite materials development, hence, BFLF treated at these conditions is suitable for composite development. [ABSTRACT FROM AUTHOR]

In order to enhance storage capacity and prevent electrical short circuits in electrochemical storage devices, it is essential and challenging to design and build Lithium ion batteries with flexible solid polymer electrolyte possessing strong ionic conductivity. This study details the use of solution-cast technique to create nano composite doped lithium solid polymer electrolytes (n-LSPEs), from polymer complex of poly (vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP), polyethylene oxide (PEO), and Lithium trifluoromethanesulfonate (LiCF3SO3), with nano ZrO2 (n-ZrO2). Electrochemical impedance spectroscopy (EIS) was utilised to describe the ionic conductivity values in presence of alternating fields. The ionic conductivity of n-LSPEs are enhanced nearly four times (1.54 × 10─1 mS/cm to 5.996 × 10─1 mS/cm) due to addition of n-ZrO2. By incorporating chronoamperometry (CA) and cyclic voltammetry (CV), we were able to analyse the transference number, ionic strength, and the accumulation of charge carriers in optimized n-LSPE membrane. Scanning electron microscope (SEM) images of n-LSPE membranes reveal a structure that is consistent with interconnecting pores between the polymer complex and the nano filler. The stable monoclinic phase of n-ZrO2 interaction with polymer segmental motion was confirmed by X-ray diffraction (XRD). By examining Fourier transform infrared spectroscopy (FTIR), we performed a quick analysis of the complexation of functional group investigations, bond length and force constant calculations, interaction of functional groups of n-LSPE films. Our FESD's discharge characteristics were investigated at 4.8 mA average discharge current for 25 hours, as indicated by a 0.04C rating. [ABSTRACT FROM AUTHOR]

Purpose: The purpose of this study is to investigate surface treatments and fiber types on adhesion properties polylactic acid (PLA) three-dimensional (3D) parts printed on woven fabrics. Design/methodology/approach: The cotton, flax and jute fabrics were exposed to alkali, hydrogen peroxide, stearic acid and ionic liquid treatments to modify surface characteristics before PLA 3D printing. The modification efficiency was assessed with Fourier transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM) analyses. Then, fused deposition modeling (FDM) printer and PLA filament were used for 3D printing onto the untreated and treated fabrics. The adhesion strength between the fabrics and PLA 3D parts were tested according to DIN 53530 via universal tensile tester. Findings: The fabric structure is effective on adhesion force and greater values were observed for plain weave fabrics. Maximum separation forces were obtained for alkali pretreated fabrics among jute and cotton. Hydrogen peroxide treatment also increased adhesion forces for jute and cotton fabrics while decreasing for flax fabrics. Stearic acid and ionic liquid treatments reduced adhesion forces compared to untreated fabrics. Treatments are effective to alter adhesion via changing surface chemistry, surface morphology and fabric physical properties but display different effects related to fabric material. Originality/value: This study provides experimental information about effects of different fiber types and surface treatments on adhesion strength of PLA 3D parts. There is limited research about comprehensive observation on 3D printing on cellulosic-woven fabrics. [ABSTRACT FROM AUTHOR]

A conical-shaped atmospheric pressure plasma jet (CS-APPJ) was developed to overcome a standard limitation of APPJs, which is their small treatment area. The CS-APPJs increase the treatment area but use the same gas flow. In the present work, polypropylene samples were treated by CS-APPJ and characterized by scanning electron microscope (SEM), the contact angle, Fourier-transformed infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). It was observed that the treatment co-occurs on the face directly in contact with the plasma and on the opposite face (OF) of the samples, i.e., no contact. However, the treatment changed the chemical composition on each side; the OF is rougher than the direct contact face (DCF), probably due to the oxygen groups in excess at the DCF and nitrogen in quantity at the OF. Although simultaneous treatment of both sides of the sample occurs for most atmospheric plasma treatments, this phenomenon is not explored in the literature. [ABSTRACT FROM AUTHOR]

In this work, hydrothermal synthesis of NiO nanoparticles in aqueous solutions at higher temperatures was used. An investigation of its optical and electrical capabilities might be done in many ways. As a result, the size and structure of NiO nanoparticles were characterised using a scanning electron microscope. A powder X-ray diffractometer was used to measure experimentally the crystallite grain size and dislocation density, which were computed using the Scherer formula. The functional groups of the title nanoparticles were easily distinguishable in the FTIR spectrum. After optical absorption analyses, NiO nanoparticles were shown to have optimised UV-Visible transmittance. The density functional theory (B3LYP) was used to compute the bonding of molecular properties of NiO in the ground state using the basis sets 6-311+G (d, p) and 6-311++G (d, p). There is evidence of charge transfer in molecules based on the computed molecular electrostatic potential (MESP), Thermodynamic properties, HOMO and LUMO energies determined. The scientific applications of this NiO nanomaterial would be well served by this material. [ABSTRACT FROM AUTHOR]

The study aimed to investigate the structure, physical properties, and antifungal activity of ZnTe single-layer, ZnTe/Cu/ZnTe (ZCZ), and ZnTe/Ag/ZnTe (ZAZ) multilayer films. The ZAZ multilayer had the greatest antifungal efficacy, with ZCZ and ZnTe following in descending order of effectiveness. We observed that ZCZ had a MIC of 0.30 mol/ML and that ZAZ had a MIC of 20 mol/L. An X-ray diffraction (XRD) test confirmed a cubic crystal structure for all films, indicating that the crystals were mainly arranged along the (111) plane. For ZnTe films, the average size of crystallites was estimated to be roughly 15 nm, while for ZAZ and ZCZ films, it remained relatively constant at around 14.2 nm and 14.1 nm, respectively. We determined the particle size of ZnTe, ZCZ, and ZAZ using a scanning electron microscope (SEM) and ImageJ analysis. The obtained sizes were 98 nm, 200 nm, and 81 nm for ZnTe, ZCZ, and ZAZ, respectively. We used Swanepoel method and the Cauchy equation to determine the refractive index (n), film thickness (d), and refractive index as a function of wavelength. We used the Tauc equation to find that the optical band gaps (E g) of the films were 1.67 eV for ZnTe, 1.5 eV for ZCZ, and 1.55 eV for ZAZ. We analyzed six new frequency bands found through FTIR analysis. These bands showed important information about the chemical structure of the films. [Display omitted] • ZAZ films have superior antifungal activity. • The Ag middle layer boosts ZAZ composite efficacy. • Enhanced understanding of ZnTe multilayer's antifungal properties. [ABSTRACT FROM AUTHOR]

Although several sample preparation methods for analyzing microplastics (MPs) in environmental matrices have been implemented in recent years, important uncertainties and criticalities in the approaches adopted still persist. Preliminary purification of samples, based on oxidative digestion, is an important phase to isolate microplastics from the environmental matrix; it should guarantee both efficacy and minimal damage to the particles. In this context, our study aims to evaluate Fenton's reaction digestion pre-treatment used to isolate and extract microplastics from environmental matrices. We evaluated the particle recovery efficiency and the impact of the oxidation method on the integrity of the MPs subjected to digestion considering different particles' polymeric composition, size, and morphology. For this purpose, two laboratory experiments were set up: the first one to evaluate the efficacy of various digestion protocols in the MPs extraction from a complex matrix, and the second one to assess the possible harm of different treatments, differing in temperatures and volume reagents used, on virgin and aged MPs. Morphological, physicochemical, and dimensional changes were verified by Scanning Electron Microscope (SEM) and Fourier Transformed Infrared (FTIR) spectroscopy. The findings of the first experiment showed the greatest difference in recovery rates especially for polyvinyl chloride and polyethylene terephthalate particles, indicating the role of temperature and the kind of polymer as the major factors influencing MPs extraction. In the second experiment, the SEM analysis revealed morphological and particle size alterations of various entities, in particular for the particles treated at 75 °C and with major evident alterations of aged MPs to virgin ones. In conclusion, this study highlights how several factors, including temperature and polymer, influence the integrity of the particles altering the quality of the final data. [ABSTRACT FROM AUTHOR]

Electrospun biocompatible fiber mats were made with Poly Vinyl Alcohol (PVA) using a biocompatible solvent Dimethylsulfoxide (DMSO), because of its compatibility. We have also used the herb "Thespesia populnea" to produce herbal doped electrospun mats. Five samples are produced by varying the percentages of PVA and herbal and the parameters in electrospinning machine. Among those samples, fiber is formed properly when PVA and herbal are taken in the ratio of 5% and 10%, respectively and when Distance, Flow rate, Voltage are set as 15 cm, 0.05 mL/h and 14 kV, respectively. The PVA fiber formation is investigated using a scanning electron microscope (SEM). Fourier Transform Infrared Spectroscopy (FTIR) has been done to confirm the presence of functional group of the herbal and PVA in the mat. Antibacterial testing was done for the samples, and the zone of inhibition was found to be 8–12 mm. Drug release test revealed that the drug from the electrospun mat was better around 70%. In vitro cytotoxicity test was done, and the result obtained was negative since a large amount of DMSO was used for dissolving the herbal. Hence it can be controlled by reducing the usage of DMSO. [ABSTRACT FROM AUTHOR]

The production of a large volume of agricultural residue during the processing of fruits has resulted in environmental problems. Therefore, the production of bioactive compounds from agricultural residue will provide a direction to overcome these issues. These residues are a potential source of many bioactive compounds, such as pectin. The present study deals with the extraction and characterization of pectin from the Bael pulp residue produced during the processing of Bael fruit. Pectin was extracted by using hot acid extraction methods and evaluated for its physicochemical properties by using Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), X-ray diffractometer (XRD), and the values of moisture content, ash content, equivalent weight, methoxyl content, total anhydrouronic acid content, and degree of esterification. The results were compared with those of commercial pectin. Bael pulp residue yielded 24.02 ± 0.63% of pectin by using HCl and 22.1 ± 0.7% by using H2SO4. The physicochemical characterization of extracted pectin, such as equivalent weight (852.32 ± 8.43), methoxyl content (8.28 ± 0.35%), total anhydrouronic acid (67.69 ± 0.35%), and degree of esterification (69.39 ± 0.57%), was within the acceptable range and comparable with the commercial pectin. The values of moisture content (4.62 ± 1.14%) and ash content (5.22 ± 0.66%) indicated that the extracted pectin was in pure form. SEM and XRD patterns observed the rough and amorphous nature of extracted pectin. The antioxidant activity of pectin and total phenolic content were also observed. The IC50 value was found to be 15.74 µg/mL, showing an adequate amount of antioxidant activity in isolated pectin with a total phenolic content of 58.5 mg Gallic acid equivalent (GAE)/g. Additionally, the prebiotic potential of extracted pectin was confirmed by the viability assay of two probiotics (Bacillus clausii and Saccharomyces boulardii). Based on these results, Bael pulp residue could be a good alternative source of high-value pectin that could be used to make health products and other biological applications. [ABSTRACT FROM AUTHOR]

Considering the long-term working performance of recycled concrete (RC) members, there is a need to compensate for the performance deficiencies of RC. In this study, the mechanical properties of RC were improved by two different modification methods, and the reinforcement effects of RC modified by Silane Coupling Agent (KH560)/Ethylene vinyl acetate copolymer (EVA) and RC modified by EVA alone were compared and analyzed. The effects of separate modification and co-modification on RC were analyzed through multi-scale methods in terms of macro-mechanical properties, microstructure, chemical composition and molecular mechanism, respectively. The results of macroscopic mechanical experiments showed that the compressive and shear strength of EVA/KH560 synergistic modification is higher than that of EVA alone. Scanning Electron Microscope (SEM) data showed that the surface density of the old and new concrete interfaces was higher under EVA/KH560 co-modification. X-ray diffraction (XRD) and Fourier Transform Infrared (FTIR) data showed that more cement gel will be produced under EVA/KH560 synergistic modification. Molecular dynamics (MD) simulations show that EVA single modification can produce hydrogen and ionic bonds at the interface of old and new concrete, while EVA/KH560 synergistic modification not only produces them, but also forms a stable Si-O-Si chemical bond. [Display omitted] • Compared with EVA modification, EVA/KH560 synergistic modification has better effect. • EVA/KH560 produces a large number of reticulated cement gel at the weak interface. • The stable Si KH560 -O KH560 -Si CSH is formed between KH560 and cement. • EVA/KH560 enhance the interfacial adhesion by the stable hydrogen and chemical bonds. [ABSTRACT FROM AUTHOR]

This study is aimed to synthesize zinc oxide nanoparticles (ZnO NPs) from Aloe barbadensis Miller leaf extract using the green synthesis method at room temperature. The biosynthesized NPs are characterized by X‐ray diffraction (XRD), UV–vis spectroscopy (UV–vis), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscope (SEM). The XRD pattern has revealed the hexagonal wurtzite structure with a crystallite size of 16 nm for synthesized ZnO NPs. The FTIR results display the formation of ZnO NPs and the presence of other functional groups. The UV–vis absorption spectrum shows an absorption band at 347 nm and the value of the bandgap is found to be 3.75 eV. The surface morphology of synthesized NPs is visualized by SEM images, it is observed that most of the NPs are needle in shape. Further, these NPs will find applications in biosensing and photocatalytic activity. [ABSTRACT FROM AUTHOR]

In the present scenario, the searching for novel plant fibers able to be used as reinforcement of polymer composites is highly appreciable. This study deals with extraction and characterization of Eleusine indica grass fibers extracted from its stem by manual retting process. From this study, it was found that the Eleusine indica has higher cellulose of 61.3 wt% content, density of 1143 kg/m3, average tensile strength and Young's modulus equal to 22 MPa and 10.75 GPa, respectively. From the XRD studies, it was noted that the Crystallinity Index (CI) of Eleusine indica was 45%. The surface morphology of Eleusine indica grass was examined using a Scanning Electron Microscope (SEM) and Chemical functional group were confirmed by Fourier transform infrared spectroscopy (FT-IR). The thermal stability of EIF was evaluated using TG and DTG curves from Thermogravimetric (TG) analysis. The characterization results confirmed that Eleusine indica grass could be used for the production of sustainable fiber-reinforced polymer composites. [ABSTRACT FROM AUTHOR]

M-type Hexa-ferrites powders of chemical composition Ba 0.5 Sr 0.1 Zn 0.4 Fe 12 O 19 was prepared by the use of the co-precipitation technique. The heat treatment of this ferrite composition was done at various temperatures (700, 800, 900, 1000, 1100, and 1200 °C) for 6 h. The X-ray diffraction (XRD) analysis of all the prepared powder samples confirmed the emergence of a hexagonal structure. The high-intensity peaks of the samples were indexed and showed a single phase. The size of crystallite was obtained within the range of 21–42 nm. The surface morphology was carried out with a Scanning electron microscope (SEM). The grain size showed the hexagonal shape, and average grain sizes were in the range of ~ 211 nm. Spectral information was found using the Fourier transform infrared (FTIR) spectroscopy to confirm the phase of M-type hexaferrite. The dielectric parameters were measured within the high-frequency range of 5 MHz - 3 GHz. The dielectric constant was increased with an increase in temperature. The dielectric studies were found by the establishment of space charge polarization as per the two-layer model provided by Maxwell-Wagner and the study of phenomena of Koop's theory. The magnetic characteristics including coercivity (HcB) and retentivity (Br) were measured from BH/JH hysteresis loops. The enhancement of coercivity was observed from 1.23 × 10+3 Oe to 1.50 × 10+3 Oe, while the retentivity increased from 1.334 × 10+3 G to 1.598 × 10+3 G with an increase in temperature. Outstanding properties of synthesized materials suggested their use in large-frequency applications, including recording media and permanent magnets. [ABSTRACT FROM AUTHOR]

The present study involved the processing of raw Ukpor clay from Anambra State, Nigeria to kaolin as a precursor for the development of Y-type zeolite. The clay was first subjected to pretreatment by separating the foreign bodies from it using deflocculant (Sodium hexametaphosphate and Sodium hydrogen carbonate). Subsequently, the pretreated clay was calcined at 850°C for 6 hours at atmospheric pressure. The calcined clay was formulated by adding sodium hydroxide and sodium metasilicate to produce a gel aged at room temperature for 12 hours. The gel was subsequently heated in a laboratory oven at 100°C for 9hrs to produce the Y-type zeolite in a process called crystallization and a product with Si/Al molar ratio of 4.07 was achieved which is suiting for a typical Zeolite Y. The formulated samples were characterized using X-ray Fluorescence (XRF), Fourier Transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscope (SEM). The results showed possible synthesis of Y-type zeolite from Ukpor kaolinite having a molar ratio of 15Na2O:Al2O3:15SiO2:450H2O. The synthesized product with Si/Al ratio of 4.07, an agglomerated euhedral morphology, and FTIR spectra peak at wavelengths of 719cm-1 and 3424cm-1, are the basis upon which the conclusion of possible development of Y-type zeolite is drawn. [ABSTRACT FROM AUTHOR]

This study investigated the sorption selectivity of bentonite and its thermally treated forms, at 150, 300 and 600 °C, for 226Ra and 210Pb. Characterisation of adsorbents was performed by applying Fourier transform infrared spectroscopy and a scanning electron microscope. Adsorption data showed the materials illustrated comparable behaviour for 210Pb, but varied when chemical containments existed in solution. Bentonite heated at 600 °C (B-600) was the best adsorbent for 226Ra. Influence of macro contaminants revealed K+ was the greatest inhibitor for 226Ra and Ca2+ for 210Pb. The data conclude B-600 would be the preferable mineral for constructing engineered disposal facilities. [ABSTRACT FROM AUTHOR]

It is essential to establish an appropriate conservation method to reduce the deterioration of leather-made artifact and extend its lifetime. The restoration and consolidation of historic leather have always been a challenge for conservators. This paper discussed the new conservation treatment by applying skin collagen hydrolysate as the consolidation material while glutaraldehyde and tannin as cross-linking agents onto the degraded leather. The fresh leather samples were artificially aged to simulate the deterioration of historical leather. Then the simulated samples were treated with the skin collagen hydrolysate and cross linked by glutaraldehyde and tannin to improve the collagen fiber structures and thermal stability. The analytical approaches combining Ultra-depth three-dimensional Microscope, Scanning Electron Microscope (SEM), Fourier Transform Infrared Spectroscopy (FTIR) and Differential Scanning Calorimetry (DSC) were undertaken to identify the significant differences of the collagen fiber structures and thermal stability between untreated and treated leather samples. The results indicated that the thermal stability and the fibers cohesion of the treated sample were improved. It overall confirmed the use of the skin collagen hydrolysate isan effective consolidation strategy for the degraded leather. [ABSTRACT FROM AUTHOR]

Impact of Swift Heavy Ion (SHI) irradiation is an effective way to tailor the properties of materials to enhance their applicability toward high-end applications. In the present investigation, hydrothermally synthesized Fe-BTC metal-organic frameworks (MOFs) were irradiated with 197Au8+ ion beam, 100 MeV at fluence range of 1×1011 ions/cm² and 1×1012 ions/cm². Hydrothermally synthesized Fe-BTC MOFs were characterized by X-ray diffractometer, UVVisible spectroscopy, Fourier-transform infrared spectroscopy (FTIR), Scanning electron microscope (SEM), Raman spectroscopy, and Atomic Force Microscopy (AFM). The significant modifications were observed as ion fluence increases, viz. decrease of crystallite size, increase of energy bandgap, reduction in average surface roughness, and the formation of new functional group (C-H) at a higher fluences 1×1012 ions/cm². [ABSTRACT FROM AUTHOR]

Applicability of natural fiber-reinforced composites in automobile, aerospace like sectors has been increasing as more number of research works is concentrating on natural fibers owing to their eco-friendly nature. Biodegradability of natural fibers is main advantage of them over artificial fibers. Natural fiber-reinforced composite possesses good thermal and mechanical properties besides other requirements. For this reason, investigation of one such natural fiber-reinforced composites has been the focus of the present study. In the present work, composites made up of abutilon indicum fiber reinforced with epoxy have been prepared. Mechanical, morphological, thermal, and spectroscopic studies on the test specimens prepared using the above composites were carried out to evaluate their respective strengths. Also, the effect of alkali treatment (NaOH) for the fibers was studied and evaluated. Scanning electron microscope results indicated that the composite made up of alkali-treated fibers possessed better mechanical properties. Using differential thermal analysis–thermogravimetric analysis apparatus thermal behavior of the composites and using Fourier transform infrared spectroscopic studies, the presence of function groups like C–O, C–H was determined. Thus, characterization of abutilon indicum fiber-reinforced epoxy composites has been carried and properties are evaluated for their applicability to automotive, aerospace similar industries. [ABSTRACT FROM AUTHOR]

The LiAlSiO 4 :Ce3+ (0–11 mol%) nanocomposites are synthesized by low temperature solution combustion method using aloe vera gel as a fuel. The prepared samples are characterized by powder X-ray diffraction (XRD) to know the crystallite size, optical energy band gap by Kubelka-Munk (K-M) plot and surface morphology by scanning electron microscope (SEM) coupled with energy dispersive X-ray (EDX) analysis for elemental confirmation. The stretching frequency of all nanocomposites is confirmed by Fourier transform infrared (FTIR) spectra. The Raman spectroscopy provides a structural fingerprint by which molecules can be identified. The current-voltage (I–V) characteristics showed that the prepared samples obey Ohm's law. DC conductivity is studied for temperature ranging from 30 - 450 οC and activation energy is calculated by Arrhenius plot. Further, the present method was reliable, environmental friendly and alternative to economical routes. [ABSTRACT FROM AUTHOR]

Doxorubicin (DOX) is widely used for anticancer, and it regards as one of the effective therapeutic drugs for solid tumors, such as carcinomas, sarcomas, and hematological malignancies. In this work, multiwall carbon nanotubes (MWCNTs) were selected as carriers to load DOX. The concentrations of (20mg) functionalization -CNTs as a nanocarrier were added to 100 ml of DOX aqueous solution (100 ppm). Each mixture was stirred for 24 hours at 25oC under dark conditions. The functionalization CNTs/DOX mixture was isolated by centrifuging for 15 min at a rate of 6000 rpm. Fourier Transform Infrared (FTIR) and Scanning Electron Microscope (SEM) were used to investigate the characterization of the nanocarrier. The results showed that the used dosage of CNT (1mg/ml) showed good loading ability for DOX over CNTs. [ABSTRACT FROM AUTHOR]

Our objective in this work consists in the synthesis, the characterization, the elaboration, the formulation, and the rheological study of the new phosphoric epoxy resin: pentaglycidyl ether pentaphenoxy of phosphorus (PGEPPP). Thus, we identified this polymer by Fourier transform infrared spectroscopy. Then, its chemical structure was confirmed by nuclear magnetic resonance of proton (1H NMR) and carbon (13C NMR). Furthermore, the rheological analyzes of the epoxy resin and their composite (PGEPPP/MDA/PN) were determined by the RHM01-RD HAAKE rheometer. Moreover, this epoxy polymer and their composite have been applied in flow phenomena and implementation. Finally, we proceeded to the morphological of the composite (PGEPPP/MDA/PN) using the scanning electron microscope, in order to confirm the dispersion of the natural phosphate load incorporated into the prepared composite. [ABSTRACT FROM AUTHOR]

Petroleum-based polymers have raised significant environmental concerns. It is critical to create compostable, good biocompatibility, and nontoxic polymers to replace petroleum-based polymers. Thus, this research was performed to extract the gelatin from fish waste cartilage and coated it over the surface of spherical shaped pre-synthesized ZnNPs along with a suitable plasticizer to produce the biodegradable film. The presence of gelatin on the surface of ZnNPs was first confirmed using UV–visible spectrophotometers, as well as the characteristic functional groups involved in the coating were investigated using Fourier-Transform Infrared Spectroscopy (FTIR). The morphological appearance of gelatin coated ZnNPs was ranged from 41.43 to 52.31 nm, the shape was found as platonic to pentagonal shape, and the fabricated film was observed through Scanning Electron Microscope (SEM). The thickness, density, and tensile strength of fabricated film were found to be 0.04–0.10 mm, 0.10–0.27 g/cm3, and 31.7 kPa. These results imply that the fish waste cartilage gelatin coated ZnNPs-based nanocomposite can be used for film preparation as well as a wrapper for food and pharmaceutical packaging. • Gelatin has been harvested successfully from fish waste cartilage. • The gelatin effectively coated the ZnNPs, resulting in the formation of a nanocomposite. • The size of the gelatin coated ZnNPs was found as 41.43–52.31 nm & platonic shape. • Thickness & density of the fabricated film were found as 0.10 mm & 0.27 g/cm3. • The tensile strength of the gelatin-coated ZnNPs-based biodegradable film was 31.7 kPa. [ABSTRACT FROM AUTHOR]

The study compared the antibacterial activity of synthesized ZnO nanoparticles (NPs) from fresh leaf and fresh stem bark aqueous extracts of Carica papaya against five selected microbes: Staphylococcus aureus, (Gram positive (+ve)), Escherichia coli (Gram negative (-ve)), Acinetobacter baumanni (Gram-ve), Exiguobacterium aquaticum (Gram+ve), and Klebsielia pneumonia (Gram +ve). The morphological features of the biosynthesized ZnO NPs were analyzed using transmission electron microscope (TEM) and scanning electron microscope (SEM); the Fourier-transform infrared spectrometer (FTIR) technique was used to observe the surface functional groups. The experimental results indicated that ZnO NPs were successfully synthesized using modified hydrothermal technique, which showed agglomerated flake-like or petal-like shapes with the organic extract surrounding the formed particles. The average particle size of the synthesized ZnO nanoparticles determined by SEM ranged between 54-97 nm with the width and length of the petal-like structures been 30 nm and 62 nm respectively. The average ZnO NPs from fresh stem bark extract of Carica papaya with higher concentrations (100-1000 ppm) demonstrated a higher antibacterial activity than the fresh leaf extracts. On the other hand, ZnO NPs from fresh leaf extracts of lower concentrations (25-50 ppm) rather showed a suitable result than the fresh stem bark. In general, ZnO NPs showed a positive antibacterial result towards the selected microbes. This shows that, the synthesized ZnO NP can be a substitute to chemical methods. [ABSTRACT FROM AUTHOR]

In the present investigation, long term service performance of silicone rubber based polymeric insulators under DC stress with controlled climatic conditions is attempted. Simultaneous application of UV, thermal, humidity with DC electrical stress is applied to polymeric insulators enclosed in a specially fabricated climatic chamber. The stresses are applied for 1000 h for an adopted cycle to simulate close service life conditions. The leakage current is regularly monitored and recorded. After the experimentation, samples of the aged specimen are subjected for post analysis and psycho-chemical analysis like Scanning Electron Microscope (SEM) to monitor morphological changes, Energy Dispersive X-Ray analysis (EDAX) to observe elemental presence over the surface, Fourier Transform Infra-Red (FTIR) spectroscopy to examine chemical changes in the material, Thermo-gravimetric analysis (TGA) to understand the role of filler in aged insulator specimen and loss of Loss of hydrophobicity was measured. Investigations with long duration DC stress reveal material degradation, depolymerization and loss of ATH; this could result in low thermal stability and accelerate the thermal erosion and early failures. [ABSTRACT FROM AUTHOR]

The main aim of the present study was to produce natural chitosan with different deacetylation degree from shrimp shells. Three deacetylation degrees of chitosan were obtained through boiling the chitin in NaOH (50% (w/v)) at 110 °C for 4 h. The samples were labelled as NCS1, NCS2 and NCS3 according to the number of times they were treated with alkaline solution. The functional groups of the obtained products and the degree of deacetylation were determined through Fourier transformed infra-red spectroscopy. Scanning electron microscope was employed to characterise the morphology of the produced materials. Cell viability assay was carried out using mesenchymal stem cells cultured on the samples for 7 days. The results showed that the deacetylation degree of chitin, NCS1, NCS2 and NCS3 became 50.1, 73.5, 82.3 and 82.5%, respectively. The natural chitin had carnation-like morphology. NCS1, NCS2 and NCS3 had the raised hills with the smaller and denser Gulbergs, however, there was no significant difference between NCS2 and NCS3 regarding the structure and deacetylation degree. Moreover, the result of the cell culture experiment indicated that the number of cells on the NCS1 was less than that of the NCS2 after 7 days. [ABSTRACT FROM AUTHOR]

In this study, ozonation as an environmentally friendly bleaching method was studied for decolorization of leather products. The effect of ozonation time (3, 5, 10, 15 and 30 min) and water pick-up value (WPV) (0%, 20%, 40%, 60%, 80% and 100%) were investigated on decolorization effect. For this aim, the color measurement and tensile strength tests were performed, and also structural changes were determined by scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FTIR) after ozonation process. The results of color measurements showed that 30 min for ozonation and 60% WPV were optimum parameters to obtain maximum decolorization effect. SEM images of the ozonated leathers showed some deformations on the collagen fibers and resulted with the slightly decreases in tensile strength of the products. On the other hand, decreases in the tensile strength values were not statistically important levels. [ABSTRACT FROM AUTHOR]

CdZnO composite coated films were deposited on glass substrate by screen printing method at the sintering temperature of 450 °C and 550 °C. The morphological and structural details of composite films were characterized by Scanning Electron microscope (SEM), Powder X-Ray Diffraction (XRD) and Fourier Transform Infrared (FTIR) techniques. Similarly, optical properties were analyzed by UV–vis and Photoluminescence (PL) spectroscopy. XRD patterns revealed increase in crystallite size with increasing sintering temperature. SEM images clearly show agglomeration and increase in the grain size of the nanoparticles in high temperature sintered film. Similarly, FTIR spectra exhibit a slight shift in peak positions and increase in intensity of peaks with increase in sintering temperature. The optical absorption measurements have been used to evaluate the values of refractive index, extinction coefficients of these direct- energy band gap semiconductor films with energy band gaps distributed in the range of ∼2.81 eV at 450 °C and ∼2.70 eV at 550 °C. The imaginary and real parts of dielectric constants are also calculated, while PL spectra showed band emission shifting towards the higher side (red shift) with increase in sintering temperature. These studies revealed that on increasing sintering temperature the crystallinity of the film improves with reduction in lattice deformations in such composite films. [ABSTRACT FROM AUTHOR]

• The ARA could enhance the road performance of the LFSMA-13 for different ages and decrease the performance sensitivity to age. • The lignin fibers physically interact with the asphalt, while the ARA could chemically interact with the asphalt mixture. • The peak area of the imino and methyl in the asphalt decreases, and the peak area of the carbonyl and sulfoxide increases with age. • The correlation between the peak areas of imino, methyl, carbonyl, and sulfoxide, and the physical property indices of the LFSMA-13 and ALSMA-13 is good. This paper aims to analyze the long-term road performance of anti-rutting agent (ARA) reinforced asphalt mixture, and reveal its road performance from the micro morphology and chemical perspective. ARA was used to modify the lignin fiber-reinforced SMA-13 asphalt mixture (LFSMA-13). The unaged, and the short and long-term aged specimens were used to test the road performance (high and low-temperature properties, water stability, and anti-cracking) of the LFSMA-13 and ARA modified LFSMA-13 (ALSMA-13). In addition, the micromorphology of the additives and asphalt mixture and the chemical property of asphalt in the mixture were analyzed using the scanning electron microscope (SEM) test and Fourier transform infrared (FTIR) test. The relationship between road performance and chemical property was also analyzed. The results showed that the performance of the ALSMA-13 was better with age than the LFSMA-13. The SEM images showed that the lignin fiber and the ARA could form a network structure in the SMA-13 mixtures. The FTIR test indicated that the ARA's amino group (–NH–) could chemically interact with the asphalt in SMA-13. The peak area of the carbonyl and sulfoxide chemical group increased, and the imino and methyl decreased with age. The results showed a good correlation between the FTIR parameters and road performance. [ABSTRACT FROM AUTHOR]

The aim of this paper is to examine and analyze a wooden face that was covered with a transparent layer of wax after finishing the mask. The use of wax and encaustic painting was used in Ancient Egypt during the Greco - Roman period, but it was an extremely rare technique in the Egyptian dynasties. The wooden face that was chosen for this study was carefully examined using light microscopy to identify the wood, which proved to be native sycomore fig (Ficus sycomorus). Digital microscope and Scanning Electron Microscope (SEM) were used to assess decay of the outer exposed surface that had been covered in the past with a preparation layer composed of calcium carbonate. SEM micrographs showed clear decay of the cell walls due to the penetration of both the preparation layer and fungal hyphae. Microbiological investigation indicated the presence a bacterial and fungal infestation. The wood was infected infected by Aspergillus niger and Ulocladium sp fungi and Pediococcus dextrinicus bacteria. Further assessment was done by X- Ray Diffraction (XRD) to calculate the decrease of cellulose crystallinity according to Segal and Fourier Transform spectroscopy (FTIR) to detect the changes of the main wood components (cellulose, hemicellulose, lignin). [ABSTRACT FROM AUTHOR]

We report a multi-instrument characterization of the carbon particles in carbon/polymer/nanodiamond core-shell materials used for high-performance liquid chromatography. These particles are prepared by the carbonization/pyrolysis of poly(divinylbenzene) (PDVB) microspheres. Scanning electron microscopy showed that the particles (4.9 µm initially) decreased in size after air oxidation (to 4.4 µm) and again after carbonization (down to 3.5 µm) but remained highly spherical. Brunauer-Emmett-Teller measurements showed low surface areas initially (as received: 1.6 m2/g, after air oxidation: 2.6 m2/g) but high values after carbonization (445 m2/g). Fourier transform infrared spectroscopy revealed the changes in the functional groups after air oxidation (C = O and C-O stretches appear), carbonization (carbon-oxygen containing moieties disappear), and acid treatment (reintroduction of carbon-oxygen containing moieties). X-ray photoelectron spectroscopy (XPS) and elemental analysis revealed the surface and bulk oxygen contents before and after treatments. By XPS, the atom percent oxygen for the as received, air oxidized, carbonized, and acid treated particles are 8.7, 16.6, 3.7, and 13.8, respectively, and by elemental analysis, the percent oxygen in the materials is 0.6, 8.1, 0.9, 16.9, respectively. A principal components analysis of time-of-flight secondary ion mass spectrometry data identified ions that were enhanced in the different materials, where almost 90% of the variation in the analyzed peak areas was captured by two principle components. X-ray diffraction and Raman spectroscopy suggested that the carbonized PDVB was disordered. Thermogravimetric analysis showed significant differences between the differently treated PDVB microspheres. This work applies directly to a commercial product and the process for preparing it. Copyright © 2015 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

This research was performed to evaluate the silver nanoparticles (AgNPs) fabricating potential of aqueous shoot extract of Aristolochia bracteolata and also assess the free radicals scavenging potential of synthesized AgNPs. The results obtained from this study showed that the aqueous shoot extract of A. bracteolata has the potential to synthesize the AgNPs and it was initially confirmed by color change in the reaction blend as yellow to dark brownish. Subsequently, a clear absorbance peak was found at 425 nm in UV–visible spectrum analysis. The functional groups involved in the capping and stabilization of AgNPs were confirmed by Fourier Transform-Infrared spectroscopy (FTIR) analysis and recorded about 10 sharp peaks 3688, 3401, 2980, 2370, 1948, 1642, 1480, 1280, 782, and 628 cm−1. The Scanning Electron Microscope (SEM) and Transmission Electron Microscope (TEM) observations revealed that the predominant shape of the AgNPs was spherical and size ranged from 41.43 to 60.51 nm. Interestingly, the green fabricated AgNPs showed significant free radicals scavenging activity and were confirmed with ferric reducing assay, 1, 1-diphenyl-2-picryl-hydrazyl (DPPH), H 2 O 2 radicals, and 2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) radicals scavenging activity. Thus, after a few in-vivo antioxidant studies, Aristolochia bracteolata -mediated AgNPs can be considered as an antioxidant agent. • The shoot extract of Aristolochia bracteolata has the potential to synthesize AgNPs. • Synthesized AgNPs were spherical in shape and size ranging from 41.43 to 60.51 nm. • The first report on AgNPs synthesized from A. bracteolata aqueous shoot extract. • AgNPs mediated by A. bracteolata demonstrated excellent antioxidant activity. • On antioxidant assays, the IC 50 of AgNPs ranged from 54.64 to 78.00 g mL−1 [ABSTRACT FROM AUTHOR]

Calcium doped Copper ferrite (Ca x Cu 1-x Fe 2 O 4 , x = 0.0, 0.1, 0.2, 0.3) nanoparticles were prepared by co-precipitation method. The effect of calcium doping in structural, elastic and magnetic properties of copper ferrite were explored by X-ray diffraction (XRD), Scanning electron microscope (SEM), Fourier transform infrared (FTIR), and Vibrating Sample magnetometer (VSM). X-ray diffraction verified the single phase cubic spinel structure and hematite phase also present in x = 0.02 with the space group Fd3m. The average crystallite size ranged in 44–58 nm and increased with increasing Ca concentration. Scanning electron microscope images showed that the ferrite particles seem in spherical shape with agglomeration. The Fourier transform infrared spectrum showed the two main absorption bands of spinel structure in the wavenumber scale of 476–576 cm−1 assigned to the stretching vibration of A and B sites. The three types of moduli of elasticity, Poisson's ratio, velocities of elastic waves and Debye temperature estimated using FTIR. Vibrating Sample magnetometer exhibited the room temperature ferromagnetic behavior and coercivity decreases with Ca concentration while saturation magnetization increases. • Ca-doped copper ferrite nanoparticles were synthesized by co - precipitation method. • The ionic radii, bond lengths, and hopping lengths were determined using XRD. • Different elastic parameters were estimated using FTIR. • Ca-doping improved the magnetic properties of Copper ferrite nanoparticles. • The RT ferromagnetism was observed in all samples. [ABSTRACT FROM AUTHOR]

Low density polyethylene films blended (LDPE) with mixed Ferrous ricinoleate maleic dextrose additive have been exposed to accelerated UV and biotic environments. The films were accelerated UV light for 70 h before being mixed with water and municipal solid compost. The photo degraded and biodegraded LDPE films were examined by infrared spectroscopy and also to study the photodegraded film attacked by mitochondria β oxidation process of microorganism and its morphological study by SEM analysis and degree of crystallinity behaviour by XRD analysis. [ABSTRACT FROM AUTHOR]

Highlights: [•] Spherical shape and 99% purity of biosilica were identified in SEM–EDS. [•] The XRD patterns were analyzed and compared the phase nature of ashes and biosilica. [•] The functional groups of biosilica were recorded by FTIR. [ABSTRACT FROM AUTHOR]

Abstract: Alkaline pretreatment with NaOH was used to improve biogas production from softwood pine. The pretreatments were carried out with 8.0%w/w NaOH solution at two temperatures (0 and 100°C) for different periods of time (10, 30 and 60min). By anaerobic digestion of the treated and untreated materials to biogas, significant effects of the pretreatments on the yield of methane were clearly observed. The best improvement was achieved by the treatment at 100°C for 10min, which resulted in 181.2% improvement in the methane production yield. The treatment at 0°C was also effective, in which 60min treatment resulted in 118.6% improvement in the methane yield compared to the untreated wood. Fourier transform infrared (FTIR) was used to analyze the changes in chemical structure and physical characteristics of lignin, hemicellulose, and cellulose of the treated wood, which indicated a reduction of crystallinity of cellulose due to the pretreatment. Furthermore, scanning electron microscopic images revealed that disruption of the recalcitrant structure of the pine wood could be responsible for the improvement of methane yield. [Copyright &y& Elsevier]

The effects of using sodium dodecyl sulfate (SDS) and a modified polyacrylic acid solution (MPA) on a soybean meal adhesive were investigated. Three-ply plywood specimens were fabricated to measure the water resistance of the adhesive (three-cycle soak test). The viscosity and solid content of the adhesive were measured. The cross-section and functional groups of the cured adhesive were evaluated using scanning electron microscope (SEM) and Fourier transform infrared (FTIR) spectroscopy, respectively. The results showed that using SDS improved the water resistance of the soybean meal adhesive by 30%. After incorporating MPA, the water resistance of the soybean meal/SDS/MPA adhesive was further improved by 60%, the viscosity of the adhesive was reduced by 81%, and the solid content of the adhesive increased by 15%. The plywood bonded by the soybean meal/SDS/MPA adhesive met the interior plywood requirements. SEM results showed no holes and cracks on the cross-section of the cured soybean meal/SDS/MPA adhesive. FTIR analysis indicated that more peptide linkages were formed in the cured adhesive as MPA was incorporated. [ABSTRACT FROM AUTHOR]

Pr3+ and Tm3+ (0.2 mol %) ions doped magnesium calcium bismuth titanate [(MgCa)2 Bi4Ti5O20] ceramics were synthesized by conventional solid state reaction method. The structural and morphological properties of prepared ceramic powders were studied by using XRD and SEM profiles. The elemental analysis and FTIR spectra of the prepared ceramics have been analyzed. Emission spectrum of Pr3+: (MgCa)2Bi4Ti5O20 ceramic powder has shown strong red emission at 614 nm (3P0 → 3H6) with an excitation wavelength λexci = 452 nm (3H4 → 3P2) and Tm3+: (MgCa)2Bi4Ti5O20 ceramic powder has shown blue emission at 477 nm (1G4 → 3H6) with an excitation wavelength λexci = 367 nm (3H6 → 1D2). [ABSTRACT FROM AUTHOR]

Hybrid materials, which consist of organic-inorganic materials, are of profound interest owing to their unexpected synergistically derived properties. These hybrid materials replaced the pristine polymers due to their higher strength and stiffness in the recent years. In the present work, studies concerning the preparation of poly (methyl methacrylate) (PMMA), PMMA/SiO2, and PMMA/TiO2 nanocomposites are reported. These nanocomposite polymers were synthesized by means of free radical polymerization of methyl methacrylate using benzoyl peroxide as an initiator in a water medium. Further 'sol-gel' transformation based hydrolysis and condensation of Ti and Si alkoxides were used to prepare the inorganic phase during the polymerization process of MMA. [ABSTRACT FROM AUTHOR]

In the present communication, grafting of acrylamide onto a water-soluble food grade polysaccharide, Tamarind mucilage, initiated by ceric ion in aqueous medium has been studied under N 2 atmosphere. A ceric ion initiated solution polymerization technique was found to be satisfactory for the formation of copolymer. The effect of monomer concentration, initiator concentration, reaction time, and temperature in terms of grafting efficiency (%GE) and percent of grafting (PG) have been investigated. The graft copolymers were characterized by FTIR, scanning electron microscope (SEM), differential scanning calorimetry (DSC), thermo gravimetric analyzer (TGA), and biodegradation studies. [ABSTRACT FROM AUTHOR]

The nanoalumina particles were produced by the wire explosion process. The size and the shape of the particles were measured using Transmission Electron Microscope (TEM) studies. The Scanning Electron Microscope (SEM) studies were carried out to confirm that the particles are of sub-micron size. The compositions of the material were characterized through the Energy Dispersive Angle X-ray Analysis (EDAX) results. The Wide Angle X-ray Diffraction (WAXD) and the Fourier Transform Infra-Red (FTIR) results confirmed the nanosize powder formed by the process as crystalline γ-Al2O3 powder. The thermal characteristics were analyzed using Thermo-gravimetric Differential thermal analysis (TG-DTA). It is identified that the local temperature of the medium at the time of formation of nanopowder decides the phase characteristics of the powder material. The formation mechanism of nanopowder by wire explosion technique was explained in detail. The mechanism of nanopowder formation and the characteristic changes that occur during the explosion process were recorded using a high-speed digital camera. [ABSTRACT FROM AUTHOR]

• Improved fresh properties were found by introducing MCSW and FA in HSSCC. • FA used up to 25% in ternary mixes resulted in comparable compressive strength with the 5SF mix. • Combined use of MCSW up to 10% and FA up to 15% along with 5% SF resulted in better resistance to water absorption. • SEM analysis indicated improved microstructure by combined use of MCSW up to 10% and FA up to 15% along with 5% SF. Disposal of marble cutting slurry waste (MCSW) has acquired a disastrous proportion and is a leading cause of environmental and health-related issues. On the other hand, high strength self-compacting concrete (HSSCC) is being widely used which requires a higher quantity of cement and ultimately resulting in the substantial CO 2 emission to the environment. The aim of this study is to produce economical and eco-efficient HSSCC using MCSW, fly ash (FA), and silica fume (SF). This would help to beneficially use MCSW and minimize the need to use large quantities of cement in HSSCC production, thus significantly reducing CO 2 emissions. Total sixteen number of HSSCC mixes in binary, ternary and quaternary form were prepared by incorporating MCSW, FA, and SF as a replacement of cement. Among all HSSCC mixes, one mix was prepared with a 100% cement binder which was named as control mix. The impact on fresh properties was assessed by slump flow, T 500 time, V-funnel time, fresh density, L-box height ratio, J-ring flow, and J-ring step height. Mechanical performance in terms of compressive strength, and other properties like percentage of water absorption, percentage of voids, and dry bulk density were also examined. The microstructural investigation was carried out using the Scanning electron microscope (SEM) and Fourier transform infrared radiation (FTIR) techniques. It was observed that the incorporation of MCSW and FA improved the fresh properties of HSSCC. A combined use of 10% MCSW and 15% FA with 5% SF as cement replacement resulted in enhanced mechanical performance and amended microstructure. [ABSTRACT FROM AUTHOR]

Tailoring the metamaterial structure using Laser writer lithography system offers a feasible way to accomplish the fine cross grating structures. The main focus of this work is to fabricate a metamaterial for absorption in the far infrared (far-IR) spectrum. Fabrication was carried out using homemade laser writer working at 405 nm in S1813 photoresist coated upon chromium on glass followed by its etching in the exposed regions. A 40 × 40 array of unit cells with dimension in the order of 28 μm ± 1 μm were achieved. The structural characterization was carried out using scanning electron microscope (SEM) and Optical Microscope. We could observe clear absorption in the far-IR region. The results here would be favorable for the development of devices based on artificial material whose properties are not readily accessible in nature (metamaterials). • Fabrication of a frequency selective metamaterial surface. • Absorption achieved in the far-IR spectrum. • Fabrication performed using low cost in house laser writer. • Structural characterization using SEM-EDS and optical microscope. • Optical characterization using FTIR. [ABSTRACT FROM AUTHOR]

Introduction: Radiotherapy is a frequently used treatment for oral cancer. Although radiation therapy may promote healing, head and neck-irradiated patients are susceptible to oral complications. Radiation caries is one of the highest indirect and late effects of radiation in the head and neck region damaging the structural and mechanical properties of tooth Enamel & Dentin. The weakened Enamel and Dentin are more susceptible to caries formation. So far, very little is known about the influence of irradiation on the tribological properties of enamel. Therefore, this study is aimed investigate the effect of electron beam radiation on the endodontically treated tooth. Material & Methods: A total number of 20 Intact teeth samples were selected for the study. The samples were endodontically treated and further used for the analysis. Microhardness test, scanning electron microscope (SEM) analysis were used to evaluate the structural and Morphological properties of enamel and dentin before and after irradiation treatment. X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) were performed to analyse the changes in crystallography and chemical composition induced by irradiation. Results: The results showed that irradiation resulted in decreased micrhardness values and loss of prism orientation in both the tissue layers. Also, the variations in mechanical and morphological properties were closely related to changes in the crystallography and chemical composition of the dental tissues. Conclusion: Altogether, the test measurements indicated that irradiation had a direct deleterious effect on the mechanical and morphological properties of human tooth enamel along with the resultant variation in the tissue composition. [ABSTRACT FROM AUTHOR]

The present work investigated the preparation of valine of polyaspartic acid (Val-PASP) and leucine of poly aspartic acid (Leu-PASP) by using polysuccinimide. PASP compounds were used as corrosion and scale inhibitors. The prepared derivatives in this study were characterized by using Fourier transform infrared spectroscopy and nuclear magnetic resonance 1HNMR. The electrochemical behavior of the synthesized compounds was studied on carbon steel surface using potentiodynamic polarization and electrochemical impedance spectroscopy techniques. The morphology of the C-steel specimens was surveyed using scanning electron microscopy and energy dispersive analysis of X-rays investigations. Scale agglomeration inhibition was evaluated using different concentrations of the inhibitors using standard scale test method. The highest corrosion inhibition efficiency for Val-PASP and Leu-PASP reaches 86.94 and 88.62% respectively at 250 ppm concentration, while their scale inhibition efficiency reaches 92.3 and 94.1% respectively at 125 ppm concentration. [ABSTRACT FROM AUTHOR]