1. Quantum Confinement Observation of Milled Potassium Chloride.
- Author
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Rashad, M., El-Zaidia, E. F. M., AL Garni, S. E., and Darwish, A. A. A.
- Subjects
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POTASSIUM chloride , *MECHANICAL alloying , *ABSORPTION coefficients , *SCANNING electron microscopes , *REFRACTIVE index , *OPTICAL properties - Abstract
Potassium chloride (KCl) nanoparticles were synthesized by ball milling technique with different milling time. The effect of milling time on structural and optical properties was investigated. The structural properties of the purchased samples are characterized by Raman spectroscopy, scanning electron microscope and X-ray diffraction techniques. The Raman spectroscopy of the KCl hints at an excellent alloying behavior of those compounds and a preferred crystal structure for certain composition. The optical band is calculated by analyzing the spectral behavior of the absorption coefficient in the absorption region which revealed direct transitions. The value optical band increases (4.02–5.11 eV) with increasing milling time (0–15 h) due to quantum confinement after the ball milling process. The refractive and absorption indices were calculated for all samples. The model of Wemple–DiDomenico was used to calculate the dispersion parameters. The nonlinear susceptibility of the third order and the nonlinear refractive index were calculated by linear optical parameters using the generalized Miller rule. Mechanical milling for different milling times (0, 5, 10 and 15 h) by a planetary ball mill with zirconium oxide balls has been carried out for milling KCl. The images of as-purchased KCl have regular uniformly grains distributed like cubic particles with size of around 10 μm. By increasing the milling time to 15 h, these individual regular shapes form a smaller reasonably dense having a size less than 500 nm. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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