Search

Perylene diimides (PDI) are workhorses in the field of organic electronics, owing to their appealing n-semiconducting properties. Optimization of their performances is widely pursued by bay-atom substitution and diverse imide functionalization. Bulk solids and thin-films of these species crystallize in a variety of stacking configurations, depending on the geometry of the stable conformation of the polyaromatic core. We here demonstrate that 1,7-dibromo-substituted perylene diimides, PDI(H 2 Br 2 ), possessing a heavily twisted conformation in the gas phase, in solution and in the solids, can be easily flattened in the solid state into centrosymmetric molecules if the polyaromatic cores form π-π stabilized chains. This is achieved by using axial residues with low stereochemical hindrance, as guaranteed by a single CH 2 /NH spacer directly linked to the imide function. Structural powder diffraction and DFT calculations on four newly designed species of the PDI(H 2 Br 2 ) class coherently show that, thanks to the flexibility of the N-X-Ar link (X=CH 2 /NH), flat cores are indeed obtained by overcoming the interconversion barrier between twisted atropoisomers, of only 26.5 kJ mol -1 . This strategy may then be useful to induce "anomalously flat" polyaromatic cores of different kinds (substituted acenes/rylenes) in the solid state, towards suitable crystal packing and orbital interactions for improved electronic performances., (© 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)

We have added the {Re IV X 5 } - (X=Br, Cl) synthon to a pocket-based ligand to provide supramolecular design using halogen⋅⋅⋅halogen interactions within an Fe III system that has the potential to undergo spin crossover (SCO). By removing the solvent from the crystal lattice, we "switch on" halogen⋅⋅⋅halogen interactions between neighboring molecules, providing a supramolecular cooperative pathway for SCO. Furthermore, changes to the halogen-based interaction allow us to modify the temperature and nature of the SCO event., (© 2020 The Authors. Published by Wiley-VCH GmbH.)