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1. Rhodium(III)-Catalyzed Synthesis of Skipped Enynes via C(sp 3 )-H Alkynylation of Terminal Alkenes.

Author

Della-Felice F, Zanini M, Jie X, Tan E, and Echavarren AM

Abstract

The Rh III -catalyzed allylic C-H alkynylation of non-activated terminal alkenes leads selectively to linear 1,4-enynes at room-temperature. The catalytic system tolerates a wide range of functional groups without competing functionalization at other positions. Similarly, the vinylic C-H alkynylation of α,β- and β,γ- unsaturated amides gives conjugated Z-1,3-enynes and E-enediynes., (© 2021 Wiley-VCH GmbH.)

Published
2021
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