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2. Chemical Dynamics : Papers in Honor of Henry Eyring, Volume 21
- Author
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Joseph O. Hirschfelder, Ilya Prigogine, Joseph O. Hirschfelder, and Ilya Prigogine
- Subjects
- Quantum theory, Dynamics, Kinematics
- Abstract
The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.
- Published
- 2009
3. Name Reactions and Reagents in Organic Synthesis
- Author
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Bradford P. Mundy, Michael G. Ellerd, Frank G. Favaloro, Jr, Bradford P. Mundy, Michael G. Ellerd, and Frank G. Favaloro, Jr
- Subjects
- Indicators and test-papers, Chemistry, Organic, Organic compounds--Synthesis, Chemical reactions, Chemical tests and reagents
- Abstract
This Second Edition is the premier name resource in the field. It provides a handy resource for navigating the web of named reactions and reagents. Reactions and reagents are listed alphabetically, followed by relevant mechanisms, experimental data (including yields where available), and references to the primary literature. The text also includes three indices based on reagents and reactions, starting materials, and desired products. Organic chemistry professors, graduate students, and undergraduates, as well as chemists working in industrial, government, and other laboratories, will all find this book to be an invaluable reference.
- Published
- 2005
4. Drawing non-layered tidy trees in linear time
- Author
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Ploeg, A.J. (Atze) van der and Ploeg, A.J. (Atze) van der
- Abstract
The well-known Reingold–Tilford algorithm produces tidy-layered drawings of trees: drawings where all nodes at the same depth are vertically aligned. However, when nodes have varying heights, layered drawing may use more vertical space than necessary. A non-layered drawing of a tree places children at a fixed distance from the parent, thereby giving a more vertically compact drawing. Moreover, non-layered drawings can also be used to draw trees where the vertical position of each node is given, by adding dummy nodes. In this paper, we present the first linear-time algorithm for producing non-layered drawings. Our algorithm is a modification of the Reingold–Tilford algorithm, but the original complexity proof of the Reingold–Tilford algorithm uses an invariant that does not hold for the non-layered case. We give an alternative proof of the algorithm and its extension to non-layered drawings. To improve drawings of trees of unbounded degree, extensions to the Reingold–Tilford algorithm have been proposed. These extensions also work in the non-layered case, but we show that they then cause a O(n2) run-time. We then propose a modification to these extensions that restores the O(n) run-time.
- Published
- 2013
5. Reusable coordinator modules for massively concurrent applications
- Author
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Arbab, F. (Farhad), Blom, C.L. (Kees), Burger, F.J. (Freek), Everaars, C.T.H. (Kees), Arbab, F. (Farhad), Blom, C.L. (Kees), Burger, F.J. (Freek), and Everaars, C.T.H. (Kees)
- Abstract
Isolating computation and communication concerns into separate pure computation and pure coordination modules enhances modularity, understandability and reusability of parallel and/or distributed software. MANIFOLD is a pure coordination language that encourages this separation. We use real, concrete, running ANIFOLD programs to demonstrate the concept of pure coordination modules and the advantage of their reuse in applications of different natures. Performance results for the examples presented in this paper show that the overhead of using MANIFOLD to achieve this enhanced modularity and reusability is in practice small, compared to the more conventional paradigms for the design and programming of parallel and distributed software
- Published
- 1998
6. Nanocomposites : In Situ Synthesis of Polymer-Embedded Nanostructures
- Author
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Luigi Nicolais, Gianfranco Carotenuto, Luigi Nicolais, and Gianfranco Carotenuto
- Subjects
- Nanostructured materials, Polymeric composites
- Abstract
A Step-by-step guide to the synthesis and characterization of metal-polymer nanocomposites Polymer nanocomposites, polymers that are reinforced with nano-sized particles, provide enhanced mechanical, thermal, electrical, and barrier properties. Continued research and development of new polymer nanocomposites promises to provide enhanced materials to a broad range of industries, such as plastics, aerospace, automotive, electronics, packaging, and biomedical devices. Structured as a practical laboratory manual, this book enables readers to expertly synthesize and characterize metal-polymer nanocomposites by clearly setting forth the principles and techniques. Nanocomposites: In Situ Synthesis of Polymer-Embedded Nanostructures features contributions from an international team of materials science and nanotechnology experts. Chapters reflect the authors'critical review of the literature as well as their own laboratory experience working with polymer nanocomposites. The book begins with a detailed introduction to the science, properties, and applications of metal-polymer nanocomposites. Next, it covers such topics as: Morphological and topological concepts Phase separation and nanoparticle aggregation Methods for the synthesis of nanocomposites Morphological control Characterization techniques and data analysis methods Toxicity considerations High-resolution images of metal nanoparticles, created by transmission electron microscopy, are provided throughout the book. There are also plenty of process schemes and detailed drawings, helping readers better understand how to synthesize, characterize, and use these composite materials. A bibliography at the end of each chapter provides a gateway to original research papers and reviews in the field. With its focus on the practical steps of synthesis and characterization, Nanocomposites: In Situ Synthesis of Polymer-Embedded Nanostructures is recommended for both students and practitioners in nanotechnology, polymer science, and materials science and engineering.
- Published
- 2014
7. On the implementation of finite strain plasticity equations in a numerical model
- Author
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Nagtegaal, J.C., Veldpaus, F.E., Nagtegaal, J.C., and Veldpaus, F.E.
- Published
- 1984
8. Polymeric Systems, Volume 94
- Author
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Ilya Prigogine, Stuart A. Rice, Ilya Prigogine, and Stuart A. Rice
- Subjects
- Chemistry, Physical and theoretical, Chemistry, Physical and theoretical--Periodicals, Physics, Physics--Periodicals
- Abstract
It is difficult to imagine how our highly evolved technological society would function, or how life would even exist on our planet, if polymers did not exist. The intensive study of polymeric systems, which has been under way for several decades, has recently yielded new insights into the properties of assemblies of these complex molecules and the physical principles that govern their behavior. These developments have included new concepts to describe aspects of the many body behavior in these systems, microscopic analyses that bring our understanding of these systems much closer to our understanding of simple liquids and solids, and the discovery of novel chemistry that these molecules can catalyze. This special topic volume of Advances in Chemical Physics surveys a number of these recent accomplishments. Supplemented with more than 250 illustrations, it provides a significant, up-to-date selection of papers by inter-nationally recognized researchers. Topics include: • Theory of Polyelectrolyte Solutions • Star Polymers: Experiment, Theory, and Simulation • Tethered Polymer Layers • Living Polymers • Transport and Kinetics in Electroactive Polymers Self-contained, authoritative, and timely, Polymeric Systems makes the cutting edge of polymer research available to scientists in every branch of chemical physics. Contributors to POLYMERIC SYSTEMS JEAN-LOUIS BARRAT, Departement de Physique des Materiaux, Universite Claude Bernard-Lyon l, France A. BAUMGARTNER, Institut fur Festkorperforschung, Germany M. A. CARIGNANO, Department of Chemistry, Purdue University, West Lafayette, Indiana LEWIS J. FETTERS, Corporate Research Science Laboratories, Exxon Research and Engineering Company, Annandale, New Jersey SANDRA C. GREER, Department of Chemical Engineering, University of Maryland at College Park GARY S. GREST, Corporate Research Science Laboratories, Exxon Research and Engineering Company, Annandale, New Jersey JOHN S. HUANG, Corporate Research Science Laboratories, Exxon Research and Engineering Company, Annandale, New Jersey JEAN-FRANCOIS JOANNY, Institut Charles Sadron, France MICHAEL E. G. LYONS, Electroactive Polymer Research Group, Physical Chemistry Laboratory, University of Dublin, Ireland M. MUTHUKUMAR, Department of Polymer Science, University of Massachusetts, Amherst, Massachusetts DIETER RICHTER, Institut fur Festkorperforschung, Germany I. SZLEIFER, Department of Chemistry, Purdue University, West Lafayette, Indiana
- Published
- 2009
9. Advances in Chemical Physics, Volume 92
- Author
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Ilya Prigogine, Stuart A. Rice, Ilya Prigogine, and Stuart A. Rice
- Subjects
- Chemistry, Physical and theoretical--Periodicals, Chemistry, Physical and theoretical, Physics, Physics--Periodicals, Quantum theory
- Abstract
This series provides chemical physics with a forum for critical, authoritative evaluations of advances in every are of the discipline. Volume 92 continues to report recent advances with a significant, up-to-date selection of papers by internationally recognized researchers.
- Published
- 2009
10. Resonances, Instability, and Irreversibility, Volume 99
- Author
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Ilya Prigogine, Stuart A. Rice, Ilya Prigogine, and Stuart A. Rice
- Subjects
- Physics--Periodicals, Physics, Chemistry, Physical and theoretical, Chemistry, Physical and theoretical--Periodicals
- Abstract
In Resonances, Instability, and Irreversibility: The LiouvilleSpace Extension of Quantum Mechanics T. Petrosky and I. Prigogine Unstable Systems in Generalized Quantum Theory E. C. G. Sudarshan, Charles B. Chiu, and G. Bhamathi Resonances and Dilatation Analyticity in Liouville Space Erkki J. Brandas Time, Irreversibility, and Unstable Systems in QuantumPhysics E. Eisenberg and L. P. Horwitz Quantum Systems with Diagonal Singularity I. Antoniou and Z. Suchanecki Nonadiabatic Crossing of Decaying Levels V. V. and Vl. V. Kocharovsky and S. Tasaki Can We Observe Microscopic Chaos in the Laboratory? Pierre Gaspard Proton Nonlocality and Decoherence in Condensed Matter --Predictions and Experimental Results C. A. Chatzidimitriou-Dreismann'We are at a most interesting moment in the history of science.Classical science emphasized equilibrium, stability, and timereversibility. Now we see instabilities, fluctuations, evolution onall levels of observations. This change of perspective requires newtools, new concepts. This volume invites the reader not to anenumeration of final achievements of contemporary science, but toan excursion to science in the making.'--from the Foreword by I.Prigogine What are the dynamical roots of irreversibility? How can past andfuture be distinguished on the fundamental level of description?Are human beings the children of time --or its progenitors? Inrecent years, a growing number of chemists and physicists haveagreed that the solution to the problem of irreversibility requiresan extension of classical and quantum mechanics. There is, however,no consensus on which direction this extension should take toinclude the dynamical description of irreversible processes. Resonances, Instability, and Irreversibility surveys recentattempts --both direct and indirect --to address the problem ofirreversibility. Internationally recognized researchers report ontheir recent studies, which run the gamut from experimental tohighly mathematical. The subject matter of these papers falls intothree categories: classical systems with emphasis on chaos anddynamical instability, resonances and unstable quantum systems, andthe general problem of irreversibility. Presenting the cutting edge of research into some of the mostcompelling questions that face contemporary chemical physics,Resonances, Instability, and Irreversibility is fascinating readingfor professionals and students in every area of the discipline.
- Published
- 2009
11. Psychological Responses to Eating Disorders and Obesity : Recent and Innovative Work
- Author
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Julia Buckroyd, Sharon Rother, Julia Buckroyd, and Sharon Rother
- Subjects
- Obesity--Psychological aspects, Eating disorders, Food habits
- Abstract
This is an edited book that brings together many of the most distinguished researchers and clinicians in the field of food misuse. The papers included are drawn from the conferences on psychological approaches to eating disorders and obesity held at the University of Hertfordshire in 2005 and 2006. It presents current research while focusing on the application of this new knowledge. It covers both eating disorders and obesity in one volume, thus positioning obesity firmly at one end of the food misuse continuum. Chapters will cover subjects such as psychological and cultural aspects of food use, using CBT for treating eating disorders, and CBT group therapy for obesity.
- Published
- 2008
12. Diabetic Cardiology
- Author
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Miles Fisher, John J. McMurray, Miles Fisher, and John J. McMurray
- Subjects
- Heart--Diseases, Cardiovascular system--Diseases, Diabetes--Complications
- Abstract
With cardiovascular disease becoming the most common cause of death in people with diabetes, interest in the assessment and treatment of heart disease in these patients has been reawakened. This book examines developing topics from a largely cardiological perspective, covering both pharmacological and non-pharmacological interventions. The DIGAMI study on the use of intravenous insulin infusion at the time of myocardial infarction (MI) has stimulated a large number of discussion papers on the best treatment of MI in the diabetic patient. The UKPDS has shown that treatment of Type 2 diabetes does not reduce cardiovascular end-points significantly, but that aggressive treatment of blood pressure can do so. In addition, sub-group analysis from several large cardiovascular trials has shown that treatment with statins, anti-platelet therapy, ACE inhibitors and other drugs will also reduce cardiovascular events in people with diabetes.
- Published
- 2007
13. Response Surfaces, Mixtures, and Ridge Analyses
- Author
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George E. P. Box, Norman R. Draper, George E. P. Box, and Norman R. Draper
- Subjects
- Experimental design, Response surfaces (Statistics), Mixture distributions (Probability theory), Ridge regression (Statistics)
- Abstract
The authority on building empirical models and the fitting of such surfaces to data—completely updated and revised Revising and updating a volume that represents the essential source on building empirical models, George Box and Norman Draper—renowned authorities in this field—continue to set the standard with the Second Edition of Response Surfaces, Mixtures, and Ridge Analyses, providing timely new techniques, new exercises, and expanded material. A comprehensive introduction to building empirical models, this book presents the general philosophy and computational details of a number of important topics, including factorial designs at two levels; fitting first and second-order models; adequacy of estimation and the use of transformation; and occurrence and elucidation of ridge systems. Substantially rewritten, the Second Edition reflects the emergence of ridge analysis of second-order response surfaces as a very practical tool that can be easily applied in a variety of circumstances. This unique, fully developed coverage of ridge analysis—a technique for exploring quadratic response surfaces including surfaces in the space of mixture ingredients and/or subject to linear restrictions—includes MINITAB® routines for performing the calculations for any number of dimensions. Many additional figures are included in the new edition, and new exercises (many based on data from published papers) offer insight into the methods used. The exercises and their solutions provide a variety of supplementary examples of response surface use, forming an extremely important component of the text. Response Surfaces, Mixtures, and Ridge Analyses, Second Edition presents material in a logical and understandable arrangement and includes six new chapters covering an up-to-date presentation of standard ridge analysis (without restrictions); design and analysis of mixtures experiments; ridge analysis methods when there are linear restrictions in the experimental space including the mixtures experiments case, with or without further linear restrictions; and canonical reduction of second-order response surfaces in the foregoing general case. Additional features in the new edition include: New exercises with worked answers added throughout An extensive revision of Chapter 5: Blocking and Fractionating 2k Designs Additional discussion on the projection of two-level designs into lower dimensional spaces This is an ideal reference for researchers as well as a primary text for Response Surface Methodology graduate-level courses and a supplementary text for Design of Experiments courses at the upper-undergraduate and beginning-graduate levels.
- Published
- 2007
14. Progress in Inorganic Chemistry, Volume 55
- Author
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Kenneth D. Karlin and Kenneth D. Karlin
- Subjects
- Chemistry, Inorganic
- Abstract
The cutting edge of scientific reporting... PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry experimentation. Progress in Inorganic Chemistry continues in its tradition of being the most respected avenue for exchanging innovative research. This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume offers an in-depth, far-ranging examination of the changing face of the field, providing a tantalizing glimpse of the emerging state of the science.'This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews.'—Journal of the American Chemical Society'[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry.'—Chemistry in Britain CONTENTS OF VOLUME 54: Atomlike Building Units of Adjustable Character: Solid-State and Solution Routes to Manipulating Hexanuclear Transition Metal Chalcohalide Clusters (Eric J. Welch and Jeffrey R. Long) Doped Semiconductor Nanocrystals: Synthesis, Characterization, Physical Properties, and Applications (J. Daniel Bryan and Daniel R. Gamelin) Stereochemical Aspects of Metal Xanthane Complexes: Molecular Structures and Supramolecular Self-Assembly (Edward R. T. Tiekink and Ionel Haiduc) Trivalent Uranium: A Versatile Species for Molecular Activation (Ilia Korobkov and Sandro Gambarotta) Comparison of the Chemical Biology of NO and HNO: An Inorganic Perspective (Katrina M. Miranda and David A. Wink) Alterations of Nucleobase pKa Values upon Metal Coordination: Origins and Consequences (Bernhard Lippert) Functionalization of Myoglobin (Yoshihito Watanabe and Takashi Hayashi)
- Published
- 2007
15. Handbook of Statistical Genetics
- Author
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David J. Balding, Martin Bishop, Chris Cannings, David J. Balding, Martin Bishop, and Chris Cannings
- Subjects
- Population genetics, Linkage (Genetics), Genetics--Statistical methods--Handbooks, manuals, etc, Genetics--Technique
- Abstract
The Handbook of Statistical Genetics is widely regarded as the reference work in the field. However, the field has developed considerably over the past three years. In particular the modeling of genetic networks has advanced considerably via the evolution of microarray analysis. As a consequence the 3rd edition of the handbook contains a much expanded section on Network Modeling, including 5 new chapters covering metabolic networks, graphical modeling and inference and simulation of pedigrees and genealogies. Other chapters new to the 3rd edition include Human Population Genetics, Genome-wide Association Studies, Family-based Association Studies, Pharmacogenetics, Epigenetics, Ethic and Insurance. As with the second Edition, the Handbook includes a glossary of terms, acronyms and abbreviations, and features extensive cross-referencing between the chapters, tying the different areas together. With heavy use of up-to-date examples, real-life case studies and references to web-based resources, this continues to be must-have reference in a vital area of research. Edited by the leading international authorities in the field. David Balding - Department of Epidemiology & Public Health, Imperial CollegeAn advisor for our Probability & Statistics series, Professor Balding is also a previous Wiley author, having written Weight-of-Evidence for Forensic DNA Profiles, as well as having edited the two previous editions of HSG. With over 20 years teaching experience, he's also had dozens of articles published in numerous international journals. Martin Bishop – Head of the Bioinformatics Division at the HGMP Resource CentreAs well as the first two editions of HSG, Dr Bishop has edited a number of introductory books on the application of informatics to molecular biology and genetics. He is the Associate Editor of the journal Bioinformatics and Managing Editor of Briefings in Bioinformatics. Chris Cannings – Division of Genomic Medicine, University of SheffieldWith over 40 years teaching in the area, Professor Cannings has published over 100 papers and is on the editorial board of many related journals. Co-editor of the two previous editions of HSG, he also authored a book on this topic.
- Published
- 2007
16. Statistical Thinking for Non-Statisticians in Drug Regulation
- Author
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Richard Kay and Richard Kay
- Subjects
- Pharmaceutical industry--Statistical methods, Statistics, Drug approval--Statistical methods, Clinical trials--Statistical methods, Drugs--Testing--Statistical methods, Pharmaceutical industry
- Abstract
Written by a well-known lecturer and consultant to the pharmaceutical industry, this book focuses on the pharmaceutical non-statistician working within a very strict regulatory environment. Statistical Thinking for Clinical Trials in Drug Regulation presents the concepts and statistical thinking behind medical studies with a direct connection to the regulatory environment so that readers can be clear where the statistical methodology fits in with industry requirements. Pharmaceutical-related examples are used throughout to set the information in context. As a result, this book provides a detailed overview of the statistical aspects of the design, conduct, analysis and presentation of data from clinical trials within drug regulation. Statistical Thinking for Clinical Trials in Drug Regulation: Assists pharmaceutical personnel in communicating effectively with statisticians using statistical language Improves the ability to read and understand statistical methodology in papers and reports and to critically appraise that methodology Helps to understand the statistical aspects of the regulatory framework better quoting extensively from regulatory guidelines issued by the EMEA (European Medicines Evaluation Agency), ICH (International Committee on Harmonization and the FDA (Food and Drug Administration)
- Published
- 2007
17. Numerical Methods in Finance and Economics : A MATLAB-Based Introduction
- Author
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Paolo Brandimarte and Paolo Brandimarte
- Subjects
- Finance--Statistical methods, Economics--Statistical methods
- Abstract
A state-of-the-art introduction to the powerful mathematical and statistical tools used in the field of finance The use of mathematical models and numerical techniques is a practice employed by a growing number of applied mathematicians working on applications in finance. Reflecting this development, Numerical Methods in Finance and Economics: A MATLAB?-Based Introduction, Second Edition bridges the gap between financial theory and computational practice while showing readers how to utilize MATLAB?--the powerful numerical computing environment--for financial applications. The author provides an essential foundation in finance and numerical analysis in addition to background material for students from both engineering and economics perspectives. A wide range of topics is covered, including standard numerical analysis methods, Monte Carlo methods to simulate systems affected by significant uncertainty, and optimization methods to find an optimal set of decisions. Among this book's most outstanding features is the integration of MATLAB?, which helps students and practitioners solve relevant problems in finance, such as portfolio management and derivatives pricing. This tutorial is useful in connecting theory with practice in the application of classical numerical methods and advanced methods, while illustrating underlying algorithmic concepts in concrete terms. Newly featured in the Second Edition: • In-depth treatment of Monte Carlo methods with due attention paid to variance reduction strategies • New appendix on AMPL in order to better illustrate the optimization models in Chapters 11 and 12 • New chapter on binomial and trinomial lattices • Additional treatment of partial differential equations with two space dimensions • Expanded treatment within the chapter on financial theory to provide a more thorough background for engineers not familiar with finance • New coverage of advanced optimization methods and applications later in the text Numerical Methods in Finance and Economics: A MATLAB?-Based Introduction, Second Edition presents basic treatments and more specialized literature, and it also uses algebraic languages, such as AMPL, to connect the pencil-and-paper statement of an optimization model with its solution by a software library. Offering computational practice in both financial engineering and economics fields, this book equips practitioners with the necessary techniques to measure and manage risk.
- Published
- 2006
18. Optimal State Estimation : Kalman, H Infinity, and Nonlinear Approaches
- Author
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Dan Simon and Dan Simon
- Subjects
- Kalman filtering, Nonlinear systems, Mathematical optimization
- Abstract
A bottom-up approach that enables readers to master and apply the latest techniques in state estimation This book offers the best mathematical approaches to estimating the state of a general system. The author presents state estimation theory clearly and rigorously, providing the right amount of advanced material, recent research results, and references to enable the reader to apply state estimation techniques confidently across a variety of fields in science and engineering. While there are other textbooks that treat state estimation, this one offers special features and a unique perspective and pedagogical approach that speed learning: Straightforward, bottom-up approach begins with basic concepts and then builds step by step to more advanced topics for a clear understanding of state estimation Simple examples and problems that require only paper and pen to solve lead to an intuitive understanding of how theory works in practice MATLAB(r)-based source code that corresponds to examples in the book, available on the author's Web site, enables readers to recreate results and experiment with other simulation setups and parameters Armed with a solid foundation in the basics, readers are presented with a careful treatment of advanced topics, including unscented filtering, high order nonlinear filtering, particle filtering, constrained state estimation, reduced order filtering, robust Kalman filtering, and mixed Kalman/H? filtering. Problems at the end of each chapter include both written exercises and computer exercises. Written exercises focus on improving the reader's understanding of theory and key concepts, whereas computer exercises help readers apply theory to problems similar to ones they are likely to encounter in industry. With its expert blend of theory and practice, coupled with its presentation of recent research results, Optimal State Estimation is strongly recommended for undergraduate and graduate-level courses in optimal control and state estimation theory. It also serves as a reference for engineers and science professionals across a wide array of industries.
- Published
- 2006
19. Rheometry of Pastes, Suspensions, and Granular Materials : Applications in Industry and Environment
- Author
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Philippe Coussot and Philippe Coussot
- Subjects
- Amorphous substances, Rheology
- Abstract
A comprehensive examination of rheometry theory and its practical applications This publication enables readers to understand and characterize the flow properties of complex fluids and, with this knowledge, develop a wide range of industrial and consumer products. The author fills a gap in the current literature by presenting a comprehensive description of the rheological behavior of pastes, suspensions, and granular materials and by offering readers the rheometrical techniques needed to effectively characterize these materials. With his extensive experience in both academic and industrial research, the author is able to take the field to a new level in: • General schematic classification of the behavior of pastes,suspensions, and granular materials • Systematic review, analysis, and quantification of experimental problems with complex fluids • Insight into the flow behavior of complex fluids gained through the most recent discoveries and research techniques • Comprehensive rheometrical analysis of data obtained from research across a broad range of industries In addition to gaining a thorough understanding of the theory underlining rheometry, readers discover its many practical applications. Throughout the publication, specific examples are provided that illustrate how theory is applied, including examples involving food, civil engineering, cosmetics, pharmaceuticals, paper coatings, paint and ink, ceramics, sewage sludges, granular materials, and natural materials. In summary, this publication provides a comprehensive review of the behavior of pastes, suspensions, and granular materials as well as detailed analysis of rheometrical techniques. Everything needed to determine the behavior and movement of complex fluids is provided. It is, therefore, a recommended resource for rheologists, engineers, and researchers, as well as students who deal with complex fluids in product formulation, quality and process control, and process plant design.
- Published
- 2005
20. Progress in Inorganic Chemistry, Volume 54
- Author
-
Kenneth D. Karlin and Kenneth D. Karlin
- Subjects
- Chemistry, Inorganic
- Abstract
The cutting edge of scientific reporting... PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry experimentation. Progress in Inorganic Chemistry continues in its tradition of being the most respected avenue for exchanging innovative research. This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume offers an in-depth, far-ranging examination of the changing face of the field, providing a tantalizing glimpse of the emerging state of the science.'This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews.'-Journal of the American Chemical Society'[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry.'-Chemistry in Britain CONTENTS OF VOLUME 54 • Atomlike Building Units of Adjustable Character: Solid-State and Solution Routes to Manipulating Hexanuclear Transition Metal Chalcohalide Clusters (Eric J. Welch and Jeffrey R. Long) • Doped Semiconductor Nanocrystals: Synthesis, Characterization, Physical Properties, and Applications (J. Daniel Bryan and Daniel R. Gamelin) • Stereochemical Aspects of Metal Xanthane Complexes: Molecular Structures and Supramolecular Self-Assembly (Edward R. T. Tiekink and Ionel Haiduc) • Trivalent Uranium: A Versatile Species for Molecular Activation (Ilia Korobkov and Sandro Gambarotta) • Comparison of the Chemical Biology of NO and HNO: An Inorganic Perspective (Katrina M. Miranda and David A. Wink) • Alterations of Nucleobase pKa Values upon Metal Coordination: Origins and Consequences (Bernhard Lippert) • Functionalization of Myoglobin (Yoshihito Watanabe and Takashi Hayashi)
- Published
- 2005
21. Cavity Quantum Electrodynamics : The Strange Theory of Light in a Box
- Author
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Sergio M. Dutra and Sergio M. Dutra
- Subjects
- Quantum optics, Quantum electrodynamics
- Abstract
What happens to light when it is trapped in a box? Cavity Quantum Electrodynamics addresses a fascinating question in physics: what happens to light, and in particular to its interaction with matter, when it is trapped inside a box? With the aid of a model-building approach, readers discover the answer to this question and come to appreciate its important applications in computing, cryptography, quantum teleportation, and opto-electronics. Instead of taking a traditional approach that requires readers to first master a series of seemingly unconnected mathematical techniques, this book engages the readers'interest and imagination by going straight to the point, introducing the mathematics along the way as needed. Appendices are provided for the additional mathematical theory. Researchers, scientists, and students of modern physics can refer to Cavity Quantum Electrodynamics and examine the field thoroughly. Several key topics covered that readers cannot find in any other quantum optics book include: • Introduction to the problem of the'vacuum catastrophe'and the cosmological constant • Detailed up-to-date account of cavity QED lasers and thresholdless lasing • Examination of cavities with movable walls • First-principles discussion about cavity QED in open cavities • Pedagogical account of microscopic quantization in dielectrics Complementing the coverage of the most advanced theory and techniques, the author provides context by discussing the historical evolution of the field and its discoveries. In that spirit,'recommended reading,'provided in each chapter, leads readers to both contemporary literature as well as key historical papers. Despite being one of many specialties within physics, cavity quantum electrodynamics serves as a window to many of the fundamental issues of physics. Cavity Quantum Electrodynamics will serve as an excellent resource for advanced undergraduate quantum mechanics courses as well as for graduate students, researchers, and scientists who need a comprehensive introduction to the field.
- Published
- 2005
22. Lightwave Technology : Telecommunication Systems
- Author
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Govind P. Agrawal and Govind P. Agrawal
- Subjects
- Optical communications, Electrooptics
- Abstract
The state of the art of modern lightwave system design Recent advances in lightwave technology have led to an explosion of high-speed global information systems throughout the world. Responding to the growth of this exciting new technology, Lightwave Technology provides a comprehensive and up-to-date account of the underlying theory, development, operation, and management of these systems from the perspective of both physics and engineering. The first independent volume of this two-volume set, Components and Devices, deals with the multitude of silica- and semiconductor-based optical devices. This second volume, Telecommunication Systems, helps readers understand the design of modern lightwave systems, with an emphasis on wavelength-division multiplexing (WDM) systems. • Two introductory chapters cover topics such as modulation formats and multiplexing techniques used to create optical bit streams • Chapters 3 to 5 consider degradation of optical signals through loss, dispersion, and nonlinear impairment during transmission and its corresponding impact on system performance • Chapters 6 to 8 provide readers with strategies for managing degradation induced by amplifier noise, fiber dispersion, and various nonlinear effects • Chapters 9 and 10 discuss the engineering issues involved in the design of WDM systems and optical networks Each chapter includes problems that enable readers to engage and test their new knowledge to solve problems. A CD containing illuminating examples based on RSoft Design Group's award-winning OptSim optical communication system simulation software is included with the book to assist readers in understanding design issues. Finally, extensive, up-to-date references at the end of each chapter enable students and researchers to gather more information about the most recent technology breakthroughs and applications. With its extensive problem sets and straightforward writing style, this is an excellent textbook for upper-level undergraduate and graduate students. Research scientists and engineers working in lightwave technology will use this text as a problem-solving resource and a reference to additional research papers in the field.
- Published
- 2005
23. Advances in Chemical Physics, Volume 126
- Author
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Ilya Prigogine, Stuart A. Rice, Ilya Prigogine, and Stuart A. Rice
- Subjects
- Chemistry, Physical and theoretical
- Abstract
The latest edition of the leading forum in chemical physics Edited by Nobel Prize winner Ilya Prigogine and renowned authority Stuart A. Rice, the Advances in Chemical Physics series provides a forum for critical, authoritative evaluations in every area of the discipline. In a format that encourages the expression of individual points of view, experts in the field present comprehensive analyses of subjects of interest. Volume 126 covers a wide range of subjects, with significant, up-to-date chapters by internationally recognized researchers. The editors collect innovative papers on'Calculations of Nonlinear Optical Properties for the Solid State,''Itinerant Oscillator Models of Fluids,''Statistical Mechanics of Static and Low-Velocity Kinetic Friction,'and several other related topics. Advances in Chemical Physics remains the premier venue for presentations of new findings in its field.
- Published
- 2003
24. The Role of Degenerate States in Chemistry, Volume 124
- Author
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Michael Baer, Gert Due Billing, Michael Baer, and Gert Due Billing
- Subjects
- Chemistry, Physical and theoretical
- Abstract
Edited by Nobel Prize-winner Ilya Prigogine and renowned authority Stuart A. Rice, the Advances in Chemical Physics series provides a forum for critical, authoritative evaluations in every area of the discipline. In a format that encourages the expression of individual points of view, experts in the field present comprehensive analyses of subjects of interest. This stand-alone, special topics volume, edited by Gert D. Billing of the University of Copenhagen and Michael Baer of the Soreq Nuclear Research Center in Yavne, Israel, reports recent advances on the role of degenerate states in chemistry. Volume 124 collects innovative papers on'Complex States of Simple Molecular Systems,''Electron Nuclear Dynamics,''Conical Intersections and the Spin-Orbit Interaction,'and many more related topics. Advances in Chemical Physics remains the premier venue for presentations of new findings in its field.
- Published
- 2002
25. Advances in Chemical Physics, Volume 123
- Author
-
Ilya Prigogine, Stuart A. Rice, Ilya Prigogine, and Stuart A. Rice
- Subjects
- Chemistry, Physical and theoretical
- Abstract
The latest edition of the leading forum in chemical physics Edited by Nobel Prize winner Ilya Prigogine and renowned authority Stuart A. Rice. The Advances in Chemical Physics series provides a forum for critical, authoritative evaluations in every area of the discipline. In a format that encourages the expression of individual points of view, experts in the field present comprehensive analyses of subjects of interest. This stand-alone, special topics volume reports recent advances in electron-transfer research, with significant, up-to-date chapters by internationally recognized researchers. Volume 123 collects innovative papers on'Transition Path Sampling,''Dynamics of Chemical Reactions and Chaos,''The Role of Self Similarity in Renormalization Group Theory,'and several other related topics. Advances in Chemical Physics remains the premier venue for presentations of new findings in its field.
- Published
- 2002
26. Dynamical Systems and Irreversibility : Proceedingsof the XXI Solvay Conference on Physics, Volume 122
- Author
-
Ioannis Antoniou and Ioannis Antoniou
- Subjects
- Chemistry, Physical and theoretical--Congresses
- Abstract
Leading research, perspectives, and analysis of dynamical systems and irreversibility Edited by Nobel Prize winner Ilya Prigogine and renowned authority Stuart A. Rice, the Advances in Chemical Physics series provides a forum for critical, authoritative evaluations in every area of the discipline. In a format that encourages the expression of individual points of view, experts in the field present comprehensive analyses of subjects of interest. Volume 122 collects papers from the XXI Solvay Conference on Physics, dedicated to the exploration of'Dynamical Systems and Irreversibility.'Ioannis Antoniou, Deputy Director of the International Solvay Institutes for Physics and Chemistry, edits and assembles this cutting-edge research, including articles such as'Non-Markovian Effects in the Standard Map,''Harmonic Analysis of Unstable Systems,''Age and Age Fluctuations in an Unstable Quantum System,'and discussion of many more subjects. Advances in Chemical Physics remains the premier venue for presentations of new findings in its field.
- Published
- 2002
27. Real-Time Systems : Scheduling, Analysis, and Verification
- Author
-
Albert M. K. Cheng and Albert M. K. Cheng
- Subjects
- Computer systems, Real-time data processing
- Abstract
The first book to provide a comprehensive overview of the subject rather than a collection of papers. The author is a recognized authority in the field as well as an outstanding teacher lauded for his ability to convey these concepts clearly to many different audiences. A handy reference for practitioners in the field.
- Published
- 2002
28. Progress in Inorganic Chemistry, Volume 49
- Author
-
Kenneth D. Karlin and Kenneth D. Karlin
- Subjects
- Metals, Chemistry, Inorganic
- Abstract
Breakthrough research and innovative science... PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry. This fascinating series provides the field of inorganic chemistry with a forum for critical and authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume of Progress in Inorganic Chemistry continues to report the most recent advances with an innovative, cutting-edge style.'This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews.'-Journal of the American Chemical Society'[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry.'-Chemistry in Britain CONTENTS OF VOLUME 49 • Nonclassical Metal Carbonyls (Anthony J. Lupinetti and Steven H. Strauss, Colorado State University, Fort Collins, Colorado, and Gernot Frenking, Philipps-Universitat Marburg, Germany) • The Influence of Ligands on Dirhodium(II) on Reactivity and Selectivity in Metal Carbene Reactions (Michael P. Doyle, University of Arizona, Tucson, Arizona, and Tong Ren, University of Miami, Coral Gables, Florida) • Coordination Chemistry of Transition Metals with Hydrogen Chalcogenide and Hydrochalcogenido Ligands (Maurizio Peruzzini and Isaac De Los Rios, Instituto per lo Studio della Stereochimica ed Energetica dei Composti de Coordinazione, CNR, Firenze, Italy, and Antonio Romerosa, Universidad de Almeria, Spain) • The Coordination Chemistry of Phosphinines, Their Polydentate and Macrocyclic Derivatives (Nicolas Mezailles, Francois Mathey, and Pascal le Floch, Ecole Polytechnique, Palaiseau Cedex, France) • Texaphyrins: Synthesis and Development of a Novel Class of Therapeutic Agents (Tarak D. Mody and Lei Fu, Pharmacyclics, Inc., Sunnyvale, California, and Jonathan L. Sessler, University of Texas at Austin, Texas) • The Chemistry of Synthetic Fe-Mo-S Clusters and Their Relevance to the Structure and Function of the Fe-Mo-S Center in Nitrogenase (Steve M. Malinak, Albion College, Michigan, and Dimitri Coucouvanis, University of Michigan, Ann Arbor, Michigan)
- Published
- 2001
29. Advances in Photochemistry
- Author
-
Douglas C. Neckers, Günther von Bünau, William S. Jenks, Douglas C. Neckers, Günther von Bünau, and William S. Jenks
- Subjects
- Photochemistry
- Abstract
More than a simple survey of the current literature, Advances in Photochemistry offers critical evaluations written by internationally recognized experts. These pioneering scientists offer unique and varied points of view of the existing data. Their articles are challenging as well as provocative and are intended to stimulate discussion, promote further research, and encourage new developments in the field. This series provides photochemists a forum for critical, authoritative evaluations of advances in every area of photochemistry, including organic, inorganic, and biological topics. Volume 26 continues to report recent advances with a significant, up-to-date selection of papers by internationally recognized researchers. Topics include: Photochemistry of triarylmethane dye leuconitrites. Structure and reactivity of organic intermediates as revealed by time-resolved infrared spectroscopy. Semiconductor photocatalysis for organic synthesis. Photophysical probes of DNA sequence-directed structure and dynamics
- Published
- 2001
30. The Total Synthesis of Natural Products, Volume 11, Part B : Bicyclic and Tricyclic Sesquiterpenes
- Author
-
Michael C. Pirrung, Andrew T. Morehead, Jr, Bruce G. Young, David Goldsmith, Michael C. Pirrung, Andrew T. Morehead, Jr, Bruce G. Young, and David Goldsmith
- Subjects
- Natural products--Synthesis
- Abstract
The past two decades have seen an explosion in research on the synthesis of sesquiterpenes, an important class of hydrocarbons commonly found in oils, resins, and balsams. Volume Eleven in The Total Synthesis of Natural Products series continues to review this dynamic area of chemistry. It features systematic, A-to-Z coverage of sesquiterpenes synthesized between 1979-1994-a sesquidecade. Focusing on bicyclic and tricyclic compounds in sesquiterpene synthesis, this authoritative work complements Volume Ten's coverage of acyclic and monocyclic sesquiterpenes. The authors comb through the hundreds of sesquiterpene syntheses already developed, consolidating the multitude of research papers, and providing extensive references as well as author and subject indexes. To keep the presentation manageable, they emphasize literature where natural products were prepared, leaving out natural ring systems or compounds whose structures were misassigned. This volume presents multiple syntheses of the same compound in chronological order, making the various steps of the synthetic strategy easily accessible. In addition, it addresses one of the most important developments in sesquiterpene research, namely the increase in compound targets prepared in an optically active form. And while syntheses of racemates are not specifically marked, legends for synthesis schemes producing optically active compounds include their absolute configurations, signs of optical rotation, or both. An important resource for organic chemists, pharmaceutical and medicinal chemists, natural prod-ucts chemists, and biochemists, The Total Synthesis of Natural Products offers valuable insight into the structure and makeup of sesquiterpenes while serving as a practical tool for locating any of the major classes of sesquiterpene compounds. An invaluable guide for the chemist interested in natural products. Providing a fascinating, comprehensive look at sesquiterpene synthesis, Volume Eleven of The Total Synthesis of Natural Products reviews sesquiterpenes synthesized in the period 1979-1994, continuing the coverage begun with Volume Ten in the series (see below). This authoritative work: Focuses on bicyclic and tricyclic sesquiterpenes. Explains the structure and makeup of this important class of hydrocarbons. Serves as a useful, practical tool for researchers interested in locating any of the major classes of sesquiterpene compounds. Provides multiple syntheses of the same compound chronologically, clearly showing the evolution of the synthetic strategy. Also available...THE TOTAL SYNTHESIS OF NATURAL PRODUCTS Volume Ten, Edited by David Goldsmith. A complement to this work, Volume Ten examines compounds with acyclic and monocyclic ring structures in sesquiterpene synthesis. 1997 (0-471-59679-5) 173 pp.
- Published
- 2000
31. Solid-Phase Organic Synthesis
- Author
-
Kevin Burgess and Kevin Burgess
- Subjects
- Organic compounds--Synthesis, Solid-phase synthesis
- Abstract
Solid-Phase Organic Synthesis Edited by Kevin Burgess, Texas A & M University Efficient, high-throughput chemistry is now the focus of many research laboratories. Solid-phase organic syntheses are central to many of these combinatorial and parallel screening methodologies. Consequently, they have been a major scientific theme of the 1990s and promise to remain prominent for the first part of the new millennium. Indeed, a bewildering number of papers have entered the literature on this topic; some report minor modifications enabling transformation of solution-phase methods to a solid support, while others report major innovations. Solid-Phase Organic Synthesis collects, highlights, and critiques some of the key developments in the field. Leading practitioners explain different perspectives on diverse aspects of the area. Specific topics covered include: • Syntheses of guanidines • Palladium-catalyzed C-C bond forming reactions • S_nAr reactions for the formation of heterocycles • Sequence-specific arylalkyne oligomers • Resin-supported capture agents and other reagents • Synthesis on pins • Monitoring of supported reactions using IR • Solid-phase syntheses of natural product derivatives Of related interest. Combinatorial Chemistry and Molecular Diversity in Drug Discovery Eric M. Gordon and James F. Kerwin 1998 (0-471-15518-7) 544 pp. Combinatorial Chemistry Synthesis and Application Stephen R. Wilson and Anthony W. Czarnik 1997 (0-471-12687-X) 288 pp.
- Published
- 2000
32. Progress in Inorganic Chemistry, Volume 48
- Author
-
Kenneth D. Karlin and Kenneth D. Karlin
- Subjects
- Metals, Chemistry, Inorganic
- Abstract
Straight from the frontier of scientific investigation... Nowhere is creative scientific talent busier than in the world of inorganic chemistry. And the respected Progress in Inorganic Chemistry series has long served as an exciting showcase for new research in this area. With contributions from internationally renowned chemists, this latest volume reports the most recent advances in the field, providing a fascinating window on the emerging state of the science.'This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews.'—Journal of the American Chemical Society'[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry.'—Chemistry in Britain CONTENTS OF VOLUME 48: Synthesis, Structure, and Properties of Organic-Inorganic Perovskites and Related Materials (David B. Mitzi, IBM T. J. Watson Research Center, Yorktown Heights, New York). Transition Metals in Polymeric 1 - Conjugated Organic Frameworks (Richard P. Kingsborough and Timothy M. Swager, Massachusetts Institute of Technology, Cambridge, Massachusetts). The Transition Metal Coordination Chemistry of Hemilabile Ligands (Caroline S. Slone, Dana A. Weinberger, and Chad A. Mirkin, Northwestern University, Evanston, Illinois). Organometallic Fluorides of the Main Group Metals Containing the C-M-F Fragment (Balaji R. Jagirdar, Eamonn F. Murphy, and Herbert W. Roesky, Universität Göttingen, Germany). Coordination Complex Impregnated Molecular Sieves-Synthesis, Characterization, Reactivity, and Catalysis (Partha P. Paul, Southwest Research Institute, San Antonio, Texas). Advances in Metal Boryl and Metal-Mediated B-X Activation Chemistry (Milton R. Smith III, Michigan State University, East Lansing, Michigan).
- Published
- 1999
33. Forecasting with periodic autoregressive time-series models
- Author
-
Philip Hans Franses, Richard Paap, Erasmus School of Law, and Econometrics
- Subjects
Nonlinear autoregressive exogenous model ,Autoregressive conditional heteroskedasticity ,Econometrics ,SETAR ,Autoregressive integrated moving average ,Time series ,Moving-average model ,STAR model ,Mathematics ,Order of integration - Abstract
textabstractThis paper is concerned with forecasting univariate seasonal time series data using periodic autoregressive models. We show how one should account for unit roots and deterministic terms when generating out-of-sample forecasts. We illustrate the models for various quarterly UK consumption series.
- Published
- 2007
34. Reusable coordinator modules for massively concurrent applications
- Author
-
Arbab, Farhad, Blom, Kees, Burger, Freek, Everaars, Kees, Computer Security, and Distributed and Interactive Systems
- Subjects
coordination ,reusability ,distributed computation ,performance measurements ,parallism - Abstract
Isolating computation and communication concerns into separate pure computation and pure coordination modules enhances modularity, understandability and reusability of parallel and/or distributed software. MANIFOLD is a pure coordination language that encourages this separation. We use real, concrete, running ANIFOLD programs to demonstrate the concept of pure coordination modules and the advantage of their reuse in applications of different natures. Performance results for the examples presented in this paper show that the overhead of using MANIFOLD to achieve this enhanced modularity and reusability is in practice small, compared to the more conventional paradigms for the design and programming of parallel and distributed software
- Published
- 1998
35. A quantitative investigation on the X-ray small angle scattering of cellulose fibers. Part II. The scattering power of various cellulose fibers
- Author
-
A. Weidinger, Derk D Heikens, and PH Hermans
- Subjects
Materials science ,Scattering ,business.industry ,Analytical chemistry ,Absorbance ,chemistry.chemical_compound ,Cellulose fiber ,Optics ,chemistry ,Gravimetric analysis ,Fiber ,Cellulose ,Small-angle scattering ,Biological small-angle scattering ,business - Abstract
This paper reports on quantitative measurements of the small angle scattering of various rayons and ramie fibers as functions of moisture content using a three slit vacuum camera and monochromatic radiation. The scattered intensity was normalized on sample thickness and primary intensity through determination of the absorbance of the sample and of the intensity of the transmitted beam measured in arbitrary units. From these data the scattering power as defined by Porod, being the mean square of the fluctuations of the electron density, was calculated. This quantity was then converted into electron units through calibration of the procedure with exposures of noble metal sols of known composition and thus of computable scattering power. The exprimental results were compared with the scattering power calculated for cellulose fibers when regarded as submicro tow-phase systems consisting of crystalline cellulose imbedded in a homogeneous mixture of noncrystalline cellulose and water. In the air-dry state a few of the rayon speciman examined exhibited a scattering power of magnitude consistent with theory. The majority yielded much higher values, up to six times larger (so does dry ramie). This is interpreted by the occurrence of submicro voids to a volume fracton of less than 0.75%, variable from fiber to fiber. This explanation is corroborated by the existenc of a distinct correlation between scattering power and gravimetric density of the fiber. In conclusion, microvoids are the principal scattering “particles” in dry fibers. The values of the scattering power of water swollen rayons and ramie can be interpretated on the basis of a three-pahse model, with the phases consisting of crystalline cellulose, a homogeneous mixture of amorphous cellulose with water, and water, respectively.
- Published
- 1959
- Full Text
- View/download PDF
36. Mechanism of polymerization of h-caprolactam. II. Polymerization in the presence of water
- Abstract
In this first-paper of a series of publications on the mechanism of the polymerization of ¿-caprolactam (CL), an investigation of the kinetics of the polymerization initiated by ¿-aminocaproic acid (ACA) is reported. Experiments were performed at 254°C. for three different initial ratios (ACA/CL)0:0.05, 0.022, and 0.011 mole/mole. The concentration (x) of unconverted CL and that of end groups (c) were determined by extraction with water at room temperature and by potentiometric titration, respectively. The method of kinetic evaluation consists in the direct checking of rate equations making use of the quantities dx/dt and dc/dt which were determined graphically from the curves of x and c versus time. In this way tedious integration procedures are avoided and the testing of rather different mechanisms is much easier. Moreover, it is not necessary to make the assumption of constant rate coefficients which, of course, will seldom apply. Thus the inadequacy of the "polycondensation mechanism" has been proved for every time instant separately, although accidentally the rate constant of the main reaction is fairly constant. In this polycondensation mechanism it is assumed that polymer formation can take place only by polycondensation of ACA, the supply of which is provided for by the reaction of CL with water formed in the process of polycondensation. It turns out that even when the rate of hydrolysis of CL is so high that the polycondensation reaction is rate determining, this latter rate is to small by a factor of 10 or more to account for the rate of CL conversion observed. It is shown that this difficulty can be overcome only by incorporating a third reaction in the mechanism, a reaction which must provide for the main consumption of CL. We have assumed this reaction to be a reversible polyaddition reaction, i.e., a reaction in which CL is added to one of the end groups of the polymer molecules. The rate constant for this reaction derived from the experiments appears to be in good agreement with the value derived from the experiments on the polymerization of CL initiated with water.
- Published
- 1958
37. Diffusion in Solids : Field Theory, Solid-State Principles, and Applications
- Author
-
Martin Eden Glicksman and Martin Eden Glicksman
- Abstract
This book offers a modern treatment of diffusion in solids, covering such core topics as the transport of mass through the lattice of a crystalline solid. Part I of the book develops basic concepts in diffusion field theory and illustrates them with several applications, while Part II focuses on key solid-state principles needed to apply diffusion theory to real materials.
- Published
- 2022
38. Flight Theory and Aerodynamics : A Practical Guide for Operational Safety
- Author
-
Joseph R. Badick, Brian A. Johnson, Joseph R. Badick, and Brian A. Johnson
- Abstract
FLIGHT THEORY AND AERODYNAMICS GET A PILOT'S PERSPECTIVE ON FLIGHT AERODYNAMICS FROM THE MOST UP-TO-DATE EDITION OF A CLASSIC TEXT The newly revised Fourth Edition of Flight Theory and Aerodynamics delivers a pilot-oriented approach to flight aerodynamics without assuming an engineering background. The book connects the principles of aerodynamics and physics to their practical applications in a flight environment. With content that complies with FAA rules and regulations, readers will learn about atmosphere, altitude, airspeed, lift, drag, applications for jet and propeller aircraft, stability controls, takeoff, landing, and other maneuvers. The latest edition of Flight Theory and Aerodynamics takes the classic textbook first developed by Charles Dole and James Lewis in a more modern direction and includes learning objectives, real world vignettes, and key idea summaries in each chapter to aid in learning and retention. Readers will also benefit from the accompanying online materials, like a test bank, solutions manual, and FAA regulatory references. Updated graphics included throughout the book correlate to current government agency standards. The book also includes: A thorough introduction to basic concepts in physics and mechanics, aerodynamic terms and definitions, and the primary and secondary flight control systems of flown aircraft An exploration of atmosphere, altitude, and airspeed measurement, with an increased focus on practical applications Practical discussions of structures, airfoils, and aerodynamics, including flight control systems and their characteristics In-depth examinations of jet aircraft fundamentals, including material on aircraft weight, atmospheric conditions, and runway environments New step-by-step examples of how to apply math equations to real-world situations Perfect for students and instructors in aviation programs such as pilot programs, aviation management, and air traffic control, Flight Theory and Aerodynamics will also appeal to professional pilots, dispatchers, mechanics, and aviation managers seeking a one-stop resource explaining the aerodynamics of flight from the pilot's perspective.
- Published
- 2021
39. Statistics for Spatial Data
- Author
-
Noel Cressie and Noel Cressie
- Subjects
- Spatial analysis (Statistics)
- Abstract
The Wiley Classics Library consists of selected books that have been made more accessible to consumers in an effort to increase global appeal and general circulation. With these new unabridged softcover volumes, Wiley hopes to extend the lives of these works by making them available to future generations of statisticians, mathematicians, and scientists. Spatial statistics — analyzing spatial data through statistical models — has proven exceptionally versatile, encompassing problems ranging from the microscopic to the astronomic. However, for the scientist and engineer faced only with scattered and uneven treatments of the subject in the scientific literature, learning how to make practical use of spatial statistics in day-to-day analytical work is very difficult. Designed exclusively for scientists eager to tap into the enormous potential of this analytical tool and upgrade their range of technical skills, Statistics for Spatial Data is a comprehensive, single-source guide to both the theory and applied aspects of spatial statistical methods. The hard-cover edition was hailed by Mathematical Reviews as an'excellent book which will become a basic reference.'This paper-back edition of the 1993 edition, is designed to meet the many technological challenges facing the scientist and engineer. Concentrating on the three areas of geostatistical data, lattice data, and point patterns, the book sheds light on the link between data and model, revealing how design, inference, and diagnostics are an outgrowth of that link. It then explores new methods to reveal just how spatial statistical models can be used to solve important problems in a host of areas in science and engineering. Discussion includes: Exploratory spatial data analysis Spectral theory for stationary processes Spatial scale Simulation methods for spatial processes Spatial bootstrapping Statistical image analysis and remote sensing Computational aspects of model fitting Application of models to disease mapping Designed to accommodate the practical needs of the professional, it features a unified and common notation for its subject as well as many detailed examples woven into the text, numerous illustrations (including graphs that illuminate the theory discussed) and over 1,000 references. Fully balancing theory with applications, Statistics for Spatial Data, Revised Edition is an exceptionally clear guide on making optimal use of one of the ascendant analytical tools of the decade, one that has begun to capture the imagination of professionals in biology, earth science, civil, electrical, and agricultural engineering, geography, epidemiology, and ecology.
- Published
- 1991
40. Advanced Organic Chemistry : Reactions, Mechanisms, and Structure
- Author
-
Jerry March and Jerry March
- Subjects
- Chemistry, Organic
- Abstract
After four editions, it's still the reference students and professionals count on. Advanced Organic Chemistry Fourth Edition Only one reference has brought consistently incisive, up-to date, and comprehensive coverage of the most useful reactions in organic chemistry directly to the fingertips of both students and professionals: Advanced Organic Chemistry. Organized by reaction type, a feature that makes clear the basic principles underlying the nearly 580 reactions described, Advanced Organic Chemistry offers instant access to each reaction's scope, limitations, and mechanisms. Balancing timely detail and informative breadth, this new updated Fourth Edition: Describes the structure of organic compounds, including chemical bonding and stereochemistry Reviews general reaction mechanisms, including ordinary reactions and photochemical reactions Includes a survey of reactions, arranged by reaction type and by which bonds are broken and formed Includes IUPAC's newest system for designating reaction mechanisms Features an index to the methods used for preparing given types of compounds Contains more than 15,000 references-5,000 new to this edition-to original papers
- Published
- 1992
41. Progress in Inorganic Chemistry, Volume 31
- Author
-
Stephen J. Lippard and Stephen J. Lippard
- Subjects
- Chemistry, Inorganic, Mineralogical chemistry
- Abstract
This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.
- Published
- 1984
42. Progress in Inorganic Chemistry, Volume 47
- Author
-
Kenneth D. Karlin and Kenneth D. Karlin
- Subjects
- Transition metals, Organometallic chemistry, Chemistry, Inorganic
- Abstract
Straight from the frontier of scientific investigation... PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry. And the respected Progress in Inorganic Chemistry series has long served as an exciting showcase for new research in this area. With contributions from internationally renowned chemists, this latest volume reports the most recent advances in the field, providing a fascinating window on the emerging state of the science.'This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews.'--Journal of the American Chemical Society.'[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry.'--Chemistry in Britain. CONTENTS OF VOLUME 47 Terminal Chalcogenido Complexes of the Transition Metals (Gerard Parkin, Columbia University) • Coordination Chemistry of Azacryptands (Jane Nelson, Vickie McKee, and Grace Morgan, The Queen's University, Northern Ireland) • Polyoxometallate Complexes in Organic Oxidation Chemistry (Ronny Neumann, Hebrew University of Jerusalem, Israel) • Metal-Phosphonate Chemistry (Abraham Clearfield, Texas A&M University) • Oxidation of Hydrazine in Aqueous Solution (David M. Stanbury, Auburn University) • Metal Ion Reconstituted Hybrid Hemoglobins (B. Venkatesh, J. M. Rifkind, and P. T. Manoharan, Sophisticated Instrumentation Centre, IIT, Madras, India) • Three-Coordinate Complexes of'Hard'Ligands: Advances in Synthesis, Structure, and Reactivity (Christopher C. Cummins, Massachusetts Institute of Technology) • Metal-Carbohydrate Complexes in Solution (Jean-Francois Verchere and Stella Chapelle, Universite de Rouen, France; Feibo Xin and Debbie C. Crans, Colorado State University).
- Published
- 1998
43. Progress in Inorganic Chemistry, Volume 39
- Author
-
Stephen J. Lippard and Stephen J. Lippard
- Subjects
- Chemistry, Inorganic
- Abstract
The series'Progress in Inorganic Chemistry'provides a forum for critical, authoritative evaluations of advances in every area of the discipline. Each volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. All volumes feature a complete subject index, and the series includes a cumulative index.
- Published
- 1991
44. Progress in Inorganic Chemistry, Volume 40
- Author
-
Stephen J. Lippard and Stephen J. Lippard
- Subjects
- Chemistry, Inorganic
- Abstract
This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.
- Published
- 1992
45. Advances in Chemical Physics, Volume 57
- Author
-
Ilya Prigogine, Stuart A. Rice, Ilya Prigogine, and Stuart A. Rice
- Subjects
- Chemistry, Physical and theoretical
- Abstract
Part of an open-ended series which helps readers obtain information on a wide variety of topics in chemical physics. Volume LVII features papers by outstanding specialists in such areas as the local mode picture, multimode molecular dynamics, Jahn-Teller trajectories, and the structure, dynamics, and dissipation in hard core molecular liquids.
- Published
- 1984
46. Progress in Inorganic Chemistry, Volume 35
- Author
-
Stephen J. Lippard and Stephen J. Lippard
- Subjects
- Chemistry, Inorganic
- Abstract
This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.
- Published
- 1987
47. Progress in Inorganic Chemistry, Volume 34
- Author
-
Stephen J. Lippard and Stephen J. Lippard
- Subjects
- Chemistry, Inorganic
- Abstract
This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.
- Published
- 1986
48. Proteins : A Theoretical Perspective of Dynamics, Structure, and Thermodynamics, Volume 71
- Author
-
Charles L. Brooks, Martin Karplus, B. Montgomery Pettitt, Charles L. Brooks, Martin Karplus, and B. Montgomery Pettitt
- Subjects
- Biophysics, Proteins--Conformation, Proteins--Structure, Thermodynamics
- Abstract
Presenting a wide-ranging view of current developments in protein research, the papers in this collection, each written by highly regarded experts in the field, examine various aspects of protein structure, functions, dynamics, and experimentation. Topics include dynamical simulation methods, the biological role of atom fluctuations, protein folding, influences on protein dynamics, and a variety of analytical techniques, such as X-ray diffraction, vibrational spectroscopy, photodissociation and rebinding kinetics. This is part of a series devoted to providing general information on a wide variety of topics in chemical physics in order to stimulate new research and to serve as a text for beginners in a particular area of chemical physics.
- Published
- 1988
49. Introduction to the Theory of Error-Correcting Codes
- Author
-
Vera Pless and Vera Pless
- Subjects
- Error-correcting codes (Information theory)
- Abstract
A complete introduction to the many mathematical tools used to solve practical problems in coding. Mathematicians have been fascinated with the theory of error-correcting codes since the publication of Shannon's classic papers fifty years ago. With the proliferation of communications systems, computers, and digital audio devices that employ error-correcting codes, the theory has taken on practical importance in the solution of coding problems. This solution process requires the use of a wide variety of mathematical tools and an understanding of how to find mathematical techniques to solve applied problems. Introduction to the Theory of Error-Correcting Codes, Third Edition demonstrates this process and prepares students to cope with coding problems. Like its predecessor, which was awarded a three-star rating by the Mathematical Association of America, this updated and expanded edition gives readers a firm grasp of the timeless fundamentals of coding as well as the latest theoretical advances. This new edition features: • A greater emphasis on nonlinear binary codes • An exciting new discussion on the relationship between codes and combinatorial games • Updated and expanded sections on the Vashamov-Gilbert bound, van Lint-Wilson bound, BCH codes, and Reed-Muller codes • Expanded and updated problem sets. Introduction to the Theory of Error-Correcting Codes, Third Edition is the ideal textbook for senior-undergraduate and first-year graduate courses on error-correcting codes in mathematics, computer science, and electrical engineering.
- Published
- 1998
50. Progress in Inorganic Chemistry, Volume 41
- Author
-
Kenneth D. Karlin and Kenneth D. Karlin
- Subjects
- Chemistry, Inorganic
- Abstract
This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.
- Published
- 1994
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