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Summary: In this paper, a prescribed performance model‐free adaptive platooning sliding mode control (PP‐MFAP‐SMC) problem for the nonlinear vehicular platooning systems (VPSs) under denial‐of‐service (DoS) attacks is studied. Firstly, the partial form dynamic linearization (PFDL) technique is employed to convert the nonlinear VPSs into an equivalent linear data model, in which the nonlinear features of the VPSs are compressed into an unknown time‐varying pseudo gradient (PG) vector. Then, an observer is devised to acquire the estimation value of the unknown time‐varying PG vector. To lower the complication of the design, the constrained tracking error is converted into the unconstrained one. Based on which, the sliding mode control (SMC) strategy is proposed to enhance the robustness of the VPSs. Further, a PP‐MFAP‐SMC algorithm with an attack compensation mechanism is developed to ensure that the vehicular tracking errors of the position and velocity can converge to the predefined regions, respectively. Eventually, the effectiveness of the developed algorithm is demonstrated by an actual VPS with the comparisons. [ABSTRACT FROM AUTHOR]

Temperature is the principal driver of global atmospheric formaldehyde (HCHO) and its primary oxidation precursor biogenic volatile organic compounds (BVOCs). We revisit such a temperature (T‐) dependency globally, leveraging TROPOMI HCHO column data. We find substantial variations in the T‐dependency of biogenic HCHO across plant functional types (PFTs), with the highest over Broadleaf Evergreen Tropical Trees (doubling every 6.0 K ± 4.1 K) and lowest over Arctic C3 Grass (doubling every 30.8 K ± 9.6 K). The GEOS‐Chem model interprets HCHO columns' T‐dependency at the PFT level (r = 0.87), with a 16% discrepancy on average. The discrepancy can be explained by BVOC emissions T‐dependency for Broadleaf Evergreen Tropical Trees and Warm C4 Grass and can be attributed to the insensitivity of HCHO columns to BVOC emissions for other PFTs. Our findings underscore a potentially magnified variation of BVOC emissions by GEOS‐Chem and MEGAN therein, particularly in regions experiencing greater temperature variations. Plain Language Summary: We use remote sensing data from an up‐to‐date monitor to examine the temperature (T‐) dependency of biogenic formaldehyde (HCHO), a proxy of a series of volatile organic gases released by plants, in a global manner. We find that the effect of temperature on HCHO varies significantly between different types of plants, with tropical evergreen trees showing the most sensitivity to temperature and Arctic grasses showing the least. The GEOS‐Chem, a state‐of‐the‐art chemical transport model, interprets such temperature sensitivity among plants with nonnegligible discrepancies. The sensitivity of volatile organic gases released by plants to temperature explains the sensitivity of HCHO to temperature for some plants, such as tropical evergreen trees and warm‐season grasses. Key Points: Temperature (T‐) dependency of biogenic HCHO columns varies substantially across plant functional types (PFTs)The GEOS‐Chem model with the MEGAN module implemented primarily interprets the T‐dependency of HCHO columns at the PFT levelThe T‐dependency of biogenic volatile organic compound (BVOC) emissions mainly accounts for that of HCHO columns in Broadleaf Evergreen Tropical Trees and Warm C4 Grass regions [ABSTRACT FROM AUTHOR]

Textile composites are advanced materials composed of preforms combined with matrix materials. The fiber structure in the preform has a significant impact on the mechanical properties of the composite. Precise control over preform dimensions and internal fiber structural uniformity, termed 'accurate shape control', is essential to ensure reliable and stable composite component mechanical properties. This paper reviews current research progress on fabric deformation mechanisms, focusing on experimental characterization and numerical simulation. Experimental methods for fabric deformation include tensile, compression, bending, and shear deformation, whereas numerical methods encompass macroscopic continuum, discrete, and semi‐discrete models. The insights offered in this paper will aid a greater understanding of fabric deformation mechanisms, enabling an accurate prediction of complex shape molding and effective process parameter design, ultimately facilitating the structural design and engineering applications of textile composites. Highlights: Recent trends and challenges in the study of fabric deformation mechanisms are presented.The experimental methods for fabric deformation were summarized and evaluated.Representative numerical modeling techniques and simulation methods are discussed.Some recommendations on potential future research directions are detailed. [ABSTRACT FROM AUTHOR]

Bagworm silk proteins, which contain crystalline structures with large β‐nanocrystal sizes, are ideal candidates for biosynthetic high‐performance fibers. However, the extremely high glycine content and greater molecular weight limit their heterologous expression efficiency and further application exploration. Here, a multi‐module assembly strategy is developed to engineer novel chimeric structural proteins by incorporating the mechanical functional domains of bagworm silk proteins with the C‐terminal self‐assembly domains of spider silk proteins. By selecting a single repetitive unit of the functional region of bagworm silk proteins, the challenge of low heterologous expression efficiency is successfully addressed. Furthermore, the content and ordering of β‐sheet structure are enhanced in the chimeric proteins through the alignment mediated by the spider silk C‐terminal domain and ligation facilitated by split inteins, resulting in a remarkable Young's modulus of ≈15 GPa. This surpasses many artificial protein fibers, synthetic polymer fibers, and even natural spider silk. Notably, these protein fibers are drawn into surgical sutures and demonstrate superior wound healing effects compared to clinical suture in a skin wound model. This research presents a novel strategy for developing high‐performance protein fibers, which will expand the scope of their mechanically demanding applications. [ABSTRACT FROM AUTHOR]

The layer charge density of layered double hydroxides (LDHs) significantly affects interlayer spacing, the arrangement of interlayer anions and water molecules, thermal stability, as well as adsorption performance. However, traditional methods for evaluating the layer charge density of LDHs are complex, prone to large errors, and impacted by numerous factors, rendering these methods unable to facilitate direct comparisons of layer charge density across different LDH compositions. Consequently, this study proposes a novel approach based on the host‐guest supramolecular interactions in LDHs to investigate the layer charge density by analyzing changes in the position of the infrared absorption peaks of interlayer guest species. The shifts in infrared absorption peak positions are employed to assess the layer charge density of MgAl‐LDHs with varying molar ratios (M2+/M3+=2, 2.5, 3, 3.5, 4). The validity of using infrared peak position shifts is corroborated through a combination of techniques, including Raman spectroscopy, TG‐DTG, XRD, Zeta potential, and adsorption analyses. Furthermore, the layer charge density of NiAl, CoAl, MgFe, and NiFe‐LDHs are evaluated, confirming the universality of the infrared method. By ranking layer charge density of LDHs with different compositions and ratios, this study resolves the challenge of comparing LDHs with diverse layer compositions. [ABSTRACT FROM AUTHOR]

In this paper, a series of silicon hybrid polyurethane‐imides (SPUI) with high stability were constructed by introducing diphenylsilanediol (DPSD) and imidization effect, in which the segment character and hydrogen bonding were adjusted. Various "sea‐island" microphase separations, similar evolution from blooming flower to bud like microdomains was originating from the hard segment clusters, where the segment distribution was labeled and visualized by the stacking of silicon heteroatom. Comparing with pure polyurethane (PU), tensile strength and elongation at break for SPUIs increased from 0.71 ± 0.04 to 17.67 ± 1.84 MPa and from 84.39% ± 6.79% to 202.38% ± 14.50%, respectively. Interestingly, the silicon‐induced aggregates of hard segments in SPUI/graphite flakes (SPUI/GFs), densely crowded around GFs except for some dispersions, revealing similar coupling agent characters of SPUI and self‐affinity with GFs. Thus, the high performance was achieved due to adjustable percolation and cross‐linking networks. Percolation thresholds were decreased from 2.04 to 0.61 wt% and the conductivity of 1.0 × 100 S/m at GFs contents of 5.0 wt% for SPUIz/GFs‐500 was achieved, 2–3 orders of magnitude higher than that of SPUIz/GFs‐2000 except for high stability in conductivity, far lower than those of reported composites. Finally, this study was of great significance for developing functional PU materials with high performance. [ABSTRACT FROM AUTHOR]

Transition metal phosphides (TMPs) have emerged as an alternative to precious metals as efficient and low‐cost catalysts for water electrolysis. Elemental doping and morphology control are effective approaches to further improve the performance of TMPs. Herein, Fe‐doped CoP nanoframes (Fe‐CoP NFs) with specific open cage configuration were designed and synthesized. The unique nano‐framework structured Fe‐CoP material shows overpotentials of only 255 and 122 mV at 10 mA cm−2 for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), respectively, overwhelming most transition metal phosphides. For overall water splitting, the cell voltage is 1.65 V for Fe‐CoP NFs at a current density of 10 mA cm−2, much superior to what is observed for the classical nanocubic structures. Fe‐CoP NFs show no activity degradation up to 100 h which contrasts sharply with the rapidly decaying performance of noble metal catalyst reference. The superior electrocatalytic performance of Fe‐CoP NFs due to abundant accessible active sites, reduced kinetic energy barrier, and preferable *O‐containing intermediate adsorption is demonstrated through experimental observations and theoretical calculations. Our findings could provide a potential method for the preparation of multifunctional material with hollow structures and offer more hopeful prospects for obtaining efficient earth‐abundant catalysts for water splitting. [ABSTRACT FROM AUTHOR]

Detecting supercooled water clouds (SWCs) is essential for enhancing artificial rainfall, preventing aircraft ice accretion, and developing a better understanding of radiative energy balance. The 1.37 μm channel, known as strong water vapor absorbing, was made polarized in the polarized multi‐angle imager (PMAI) onboard FengYun‐3G satellite. The infight data shown that the new 1.37 μm polarized channel could be used to detect SWCs. The cloudbow is observed around the 140° scattering angle in the 1.37 μm polarization image, with a maximum polarization reflectance of approximately 0.04–0.06. The indicated water clouds with spherical particles in the high‐level altitude could be SWCs. Then, the SWCs detected by 1.37 μm polarized channel is verified using polarized reflectance of other channels, the reflectance difference of channels, and thermal infrared bright temperature. The presence of cloudbow in 1.03 and 1.64 μm channels indicate liquid water cloud. The reflectance difference between 1.03 and 1.64 μm of SWCs agree with characteristic of water cloud. The thermal infrared channels from the imager on the same platform indicate cold cloud with the brightness temperature far below 273.16 K. Therefore, the only use of 1.37 μm polarized channel could perform the identification of SWCs. PMAI provides a powerful tool for monitoring supercooled water clouds. Plain Language Summary: In this study, cloudbow is observed by the 1.37 μm polarized channel of PMAI onboard FY‐3G satellite. Combination of polarization and water vapor absorbing information, the indicated water clouds with spherical particles in the upper altitude could be identified as SWCs. The identification of SWCs by 1.37 μm polarization channel is verified by other polarized channels, reflection channels, and thermal infrared channels. Therefore, the 1.37 μm polarized channel provides a new and fast way to accurately identify SWCs. Further, the SWCs identified by the 1.37 μm polarized channel could be used to determine the threshold, or be reference of cloud phase identification and verification for traditional methods. Key Points: Cloudbow is first observed in the 1.37 μm polarized channel of the polarized multi‐angle imager onboard FY‐3G satelliteThe 1.37 μm polarized channel (1370P) can be used to detect supercooled water cloudsThe identification of supercooled water clouds by 1370P was verified [ABSTRACT FROM AUTHOR]

Modern scanning electron imaging (SEM) has become an essential tool in various fields. In order to obtain high‐quality images with minimal vibration and drift, the multi‐frame stacking technique is commonly used. However, one aspect that has been overlooked in this process is the electron beam‐induced temperature effect. This study aims to explore the impact of the temperature effect on SEM contrast for a single spherical nanoparticle, specifically a gold nanosphere on a carbon substrate. Through Monte‐Carlo simulation, we investigated how the number of frames in multi‐frame stacking mode affects two types of electron signals: secondary electrons (SE) and backscattering electrons (BSE). Our findings revealed that the SEM contrast is indeed sensitive to the number of frames used in the stacking process. It is observed that the SE contrast decreases while the BSE contrast increases compared to cases without considering temperature effects. It is also found that when using the large primary electron beam energy, the impact of temperature effect was less significant. The electron‐solid interaction theory was utilized to systematically explain the underlying mechanism. This study not only sheds light on how temperature effects can influence SEM imaging but also provides valuable insights for optimizing image acquisition techniques. [ABSTRACT FROM AUTHOR]

Dithieno[3,2‐b:2',3'‐d]thiophene (DTT) derivative contains three annulated thiophene rings, which have attracted great attention in the field of materials due to its planar and conjugated molecular, structural rigidity, and increased solubility. Herein, the one‐step modular construction of a series of structurally well‐defined 2,6‐disubstituted dithieno[3,2‐b:2',3'‐d]thiophenes (2,6‐DTT) involves Pd/Cu(I)‐catalyzed Sonogashira coupling and LiNH2‐mediated ring‐closing reaction with element sulfur was reported. The method allows the selective and straightforward introduction of different aryl substitution into DTT without otherwise tedious separation and purification processes. The preliminary study of the thermal and photophysical properties demonstrated that the introduction of substituent in phenyl has great impact for the parent molecule, which enable this protocol to synthesis high‐performance 2,6‐DTT through the different alkynes. [ABSTRACT FROM AUTHOR]

Highlights This research involved the modification of carbon fiber (CF) through electrochemical anodizing under different conditions and focused on analyzing the impact of modifying CF surface and examining the interfacial characteristics of thermoset polyimide (PI) composites. The process of electrochemically oxidizing CF consists of two distinct stages. The oxidation stage mainly occurs under the conditions of low current intensity and low electrolyte concentration, at the graphite boundary defects on CF surface. The etching effect stage intensifies on CF surface under high current intensity and electrolyte concentration, resulting in the fracture and detachment of the carbon rings. Electrochemical oxidation improves CF roughness and the quantity of active functional groups, which enhances mechanical interlocking and chemical bonding between CF and PI. Furthermore, the introduction of reactive hydrogen groups can contribute to the PI curing process, significantly improving the weak interface bonding problem between CF and PI. The interfacial shear strength (IFSS) of the composites increased from 82.08 to 104.33 MPa and 114.08 MPa in acidic and alkaline electrolyte environments, respectively. Improved interfacial compatibility between CF and polyimide resin through electrochemical oxidation The relationship between the physical morphology and chemical composition of the surface of CF and their interfacial properties was investigated. The interfacial shear strength of CF/PI was increased by 38.99% without any loss in mechanical properties of the CF. The electrochemical oxidation mechanism of CF under different electrolytes was revealed. [ABSTRACT FROM AUTHOR]

The Indonesian Throughflow (ITF) thermocline, as exclusive water source for the "warm water route" of the Atlantic Meridional Overturning Circulation (AMOC), provides waters that exit the Indian Ocean and join the AMOC upper limb via the Agulhas Leakage (AL). Hence, investigating long‐term variations in the ITF thermocline and its implications on the AL is important for understanding dynamics of the AMOC. Here, the thermohaline history of the ITF thermocline was reconstructed for the last ∼410 kyr based on δ18O and Mg/Ca of planktonic foraminifera from International Ocean Discovery Program Site U1483. By integrating the new and published records, we found that precession drives variation of the ITF thermocline through modulating the intensity of the Australian‐Indonesian winter monsoon, El Niño‐Southern Oscillation‐like states and formation of the North Pacific Tropical Water, in turn exerting a transoceanic influence on the amount of the AL and seawater temperature and salinity of the South Atlantic thermocline. Plain Language Summary: It is widely acknowledged that the Indonesian Throughflow (ITF), a key component of the global thermohaline circulation, plays an important role in the global climate and ocean circulation. However, in contrast to concentrating on the factors that shaped the ITF in the geological history, few studies considered the ITF as a factor to influence climate and ocean circulation, especially on long timescales. In this study, we utilized shell δ18O and Mg/Ca of a planktonic foraminiferal thermocline‐dwelling species from the Timor Sea, the main outflow passage of the ITF, to reconstruct the temperature and salinity changes of the ITF thermocline during the past ∼410 kyr. By integrating the new and published paleo‐oceanographic and ‐climatological records, we found that the ∼20‐kyr wobbles of the Earth's axis (precession) induced variations in the flow strength and seawater temperature and salinity of the ITF thermocline, and in turn regulated the amount of the Agulhas Leakage and seawater temperature and salinity of the South Atlantic thermocline. Our results underscore the essential role of the ITF in the connectivity among the oceans. Key Points: Precession drove variations in the ITF thermocline by modulating the intensity of the Australian‐Indonesian winter monsoon, ENSO‐like states and formation of the North Pacific Tropical WaterVariations in the ITF thermocline regulated the amount of AL and seawater temperature and salinity of South Atlantic thermocline [ABSTRACT FROM AUTHOR]

The correlation between liver disease and the progression of ulcerative colitis (UC) has remained elusive. In this study, it demonstrates that liver injury is intricately linked to the heightened severity of UC in patients, and causes more profound intestinal damage during DSS‐induced colitis in mice. Metabolomics analysis of plasma from liver cirrhosis patients shows liver injury compromising nicotinamide supply for NAD+ biosynthesis in the intestine. Subsequent investigation identifies intestinal group 2 innate lymphoid cells (ILC2s) are responsible for liver injury‐exacerbated colitis. Reconstitution of ILC2s or the restoration of NAD+ metabolism proves effective in relieving liver injury‐aggravated experimental colitis. Mechanistically, the NAD+ salvage pathway regulates gut ILC2s in a cell‐intrinsic manner by supporting the generation of succinate, which fuels the electron transport chain to sustaining ILC2s function. This research deepens the understanding of cellular and molecular mechanisms in liver disease‐UC interplay, identifying a metabolic target for innovative treatments in liver injury‐complicated colitis. [ABSTRACT FROM AUTHOR]

Ovarian cancer is of the most lethal malignancy and causes serious threat to women health worldwide. A deep understanding of molecular mechanisms underlying ovarian cancer progression is critical for the development of promising therapeutic strategies. In this study, we aimed to employ immunohistochemistry to determine the protein level of HDAC7 in patient tissues, our data showed HDAC7 levels are upregulated in tumour tissues. In addition, we also performed Kaplan–Meier survival analysis to investigate the association between HDAC7 expression and clinical prognosis, and found that HDAC7 expression was associated with poor prognosis in ovarian cancer patients. Inhibition of HDAC7 cells resulted in lower cell proliferation, invasion and colony formation. Furthermore, we also found that HDAC7 inhibition suppressed PI3K/AKT/mTOR pathway. In contrast, exogenous HDAC7 expression activated the PI3K/AKT/mTOR pathway in HDAC7 knockout cells and rescued the cell proliferation, invasion and colony formation. However, inhibition of p‐AKT induced lower cell proliferation, metastasis and colony formation abilities. In murine model, HDAC7 KO significantly decreased the tumour burden. These data indicate that HDAC7 is involved in regulation of PI3K/AKT/mTOR pathway and targeting of HDAC7 could be potential therapeutic strategy in the treatment of ovarian cancer. [ABSTRACT FROM AUTHOR]

Black carbon (BC) is a highly persistent yet poorly understood component of forest soil carbon reservoirs, while its inventory, distribution, and determining factors in forest soils on a large geographic scale remain unclear. Here, we characterized soil BC across 68 Chinese forest sites using benzene polycarboxylic acid method and developed machine learning (ML) models to predict and interpret potential impacts of soil organic matter (SOM) properties, soil physiochemical properties, meteorological conditions, wildfire history, and microbial diversity on BC. Results revealed that SOM properties were the most critical in predicting BC, complemented by the negative impact of mean annual temperature and alkaline mineral composition. The superior prediction accuracy for BC with higher condensed aromaticity (more benzene hexa‐ and penta‐carboxylic acid monomers) likely results from its simpler sources and greater resistance to transformation. This study introduces an effective ML model for predicting and interpreting soil BC inventory to better understand BC cycling. Plain Language Summary: The black carbon (BC) derived from incomplete biomass combustion serves as a potential reservoir to store carbon in land ecosystems. Despite BC's significance in carbon sequestration, its inventory and distribution on a large geographic scale remains elusive. As such, we characterized both the quantity and quality of soil BC for forest sites across China. We find that soil BC content averaged 1.99 ± 1.94 mg C g−1 and constituted 8.8% ± 4.9% of soil organic carbon, without showing a clear geographic distribution pattern. Besides the well‐acknowledged predictive power of machine learning (ML) methodologies, they were introduced to determine the impacts of soil properties and environmental parameters in controlling the BC distribution. We discovered that soil organic matter properties were the most important parameters in predicting BC content, accounting for over 50% of the contribution in model construction based on mean absolute Shapley value. Alongside meteorological conditions, they were further extracted as the key parameters for predicting BC content to simplify the ML model. As a promising complement to traditional geochemical approaches, this research highlights the potential of leveraging ML to predict and interpret BC inventory on a global scale. Key Points: The black carbon (BC) inventory and distribution in Chinese forest soils on a large geographic scale were first determinedMachine learning (ML) models exhibited superior prediction accuracy for BC with higher condensed aromaticitySoil organic matter properties were the most critical in predicting BC content [ABSTRACT FROM AUTHOR]

Augmented reality (AR) games offer significant potential to enhance learning experiences, yet the impact of when these games are introduced during the educational process remains underexplored. This study explored how the timing of providing the AR game influenced learners' achievement, satisfaction and acceptance. Using a quasi‐experimental design, 68 second‐graders engaged with the AR game AR Easy Sign Language: Grams and Kilograms, either before class or in class. Additionally, perspectives from eight students, one teacher and 24 parents (from the before‐class group) were collected. Results indicated that providing the AR game in class significantly improved learners' achievement and acceptance compared to providing it before class. While overall satisfaction was unaffected by timing, students' cognitive focus differed: in‐class participants emphasised the game's educational value, whereas those using it before class viewed it more as an entertaining tool with educational functionality. Both the teacher and parents acknowledged the educational value of AR games but expressed concerns regarding the cost and potential health issues. This study contributes to theoretical understanding and practical implementation strategies for AR games in education, particularly in optimising their timing for maximal impact. Practitioner notes What is already known about this topic AR games integrate the advantages of augmented reality and games, enabling learners to interact with virtual and physical objects in a fun way, bringing a new dynamic to education. Prior research has shown that AR games contribute to the improved learning process and learning outcomes. However, applying technologies such as AR games to authentic educational contexts is still challenging, as it involves many decision‐making issues to be investigated. One key issue that remains unresolved is determining the optimal timing of providing AR games. What this paper adds Providing AR games in class significantly enhanced students' learning achievement and acceptance, emphasising the need to carefully time such interventions. The timing of providing AR games influenced students' cognition, with in‐class use promoting a focus on learning, while before‐class use emphasised entertainment. Teachers and parents acknowledged the educational value of AR games for students, but they had concerns regarding potential visual health risks and the associated costs. Implications for practice and/or policy Educators should determine the timing of providing AR games depending on the desired goal. Providing AR games before class allows students to focus more on the game experience while providing AR games in class allows for a focus on learning through the game and enhancing learning achievement. Students' cognition of technology may influence their usage and outcomes. Developers should design AR games with mechanisms that guide learners' cognition of educational content, while researchers should explore the effectiveness of such designs to achieve better learning outcomes. Educational institutions should select devices with built‐in eye protection features and enforce screen time limits to mitigate visual health risks, addressing concerns raised by teachers and parents. AR games incorporating sign language have the potential to improve students' learning achievement, holding promise for applications in special education. What is already known about this topic AR games integrate the advantages of augmented reality and games, enabling learners to interact with virtual and physical objects in a fun way, bringing a new dynamic to education. Prior research has shown that AR games contribute to the improved learning process and learning outcomes. However, applying technologies such as AR games to authentic educational contexts is still challenging, as it involves many decision‐making issues to be investigated. One key issue that remains unresolved is determining the optimal timing of providing AR games. What this paper adds Providing AR games in class significantly enhanced students' learning achievement and acceptance, emphasising the need to carefully time such interventions. The timing of providing AR games influenced students' cognition, with in‐class use promoting a focus on learning, while before‐class use emphasised entertainment. Teachers and parents acknowledged the educational value of AR games for students, but they had concerns regarding potential visual health risks and the associated costs. Implications for practice and/or policy Educators should determine the timing of providing AR games depending on the desired goal. Providing AR games before class allows students to focus more on the game experience while providing AR games in class allows for a focus on learning through the game and enhancing learning achievement. Students' cognition of technology may influence their usage and outcomes. Developers should design AR games with mechanisms that guide learners' cognition of educational content, while researchers should explore the effectiveness of such designs to achieve better learning outcomes. Educational institutions should select devices with built‐in eye protection features and enforce screen time limits to mitigate visual health risks, addressing concerns raised by teachers and parents. AR games incorporating sign language have the potential to improve students' learning achievement, holding promise for applications in special education. [ABSTRACT FROM AUTHOR]

The loss of freshwater fish habitats, exacerbated by climate change and dam constructions, poses a critical environmental concern. The upper Yangtze River basin, noted for its abundant fish fauna and concentrated dam development, serves as a crucial locale for investigating the impacts of climate shifts and dam construction. This study aims to disentangle the impacts of hydroelectric dams and climate change on fish habitat distribution by analyzing species presence data across different periods. Species distribution models were constructed using Maxent for Coreius guichenoti (a warm‐water endangered fish) and Schizopygopsis malacanthus (a cold‐water endangered fish). The model accuracy was assessed using the area under the curve of the receiver operating characteristic. Habitat distribution modeling and prediction for the pre‐dam period (1970–2000) and post‐dam period (2001–2020), as well as future climate change under two shared socioeconomic pathways scenarios, were conducted. The impacts of climate change and dam construction on the habitat suitability of two fish species were quantified. The results revealed dam construction predominantly diminished habitat suitability and range, with high‐suitability habitats in the post‐dam period decreasing by 56.3% (720.18 km) and 67.0% (1665.52 km) for the two fishes, respectively. Climate change would enhance the habitat suitability of Coreius guichenoti, while it would decrease the habitat suitability of Schizopygopsis malacanthus. The impact of dam construction is greater that of climate change for them. This study underscores the profound impacts of dam construction on fish habitats, particularly for cold‐water species, and highlights the critical need for habitat restoration in sustainable hydropower development. Our method of disentangling these factors also provides a new approach to evaluating environmental impacts in large river basins. [ABSTRACT FROM AUTHOR]

This study investigates the influence of the sample inherent temperature on the line‐scan profile for a silicon trapezoid line with different sidewall angles by Monte–Carlo simulation. This study demonstrates that the profile varies with temperature, particularly focusing on the 'shoulder', which becomes more pronounced with larger sidewall angles. The contrast of the secondary electron profile increases at low primary electron energy but decreases at relatively high PE energy as the temperature rises. The trend of the backscattering electron profile is similar but less noticeable. The underlying mechanism is discussed in detail. This study has potential to provide valuable insights into thermometry in nanostructures using SEMs. [ABSTRACT FROM AUTHOR]

The rapid development of wearable electronics requires energy storage devices capable of withstanding both static and dynamic deformations. The versatility of textile supercapacitors renders them promising candidates, but their low electrochemical performance especially under mechanical deformation, poses many limitations for practical use. In this study, MXene‐based textile supercapacitors are designed and fabricated using hierarchical spacer fabrics as the skeleton to provide robust mechanical support and stable performance. Ti3C2Tx MXene is adopted as the current collector and active material for the spacer fabric supercapacitor, resulting in an impressive areal capacitance of 415 mF cm−2 with a MXene loading of 4.2 mg cm−2. Remarkable stability and durability are achieved in the form of three‐dimensional (3D) textile supercapacitors, even under both static and dynamic deformations. The compressive behaviors of these supercapacitors can be easily adjusted (e.g., from 10 to 168 KPa at 50% compression) by altering the spacer fabric structure, demonstrating their energy‐absorption (damping of kinetic energy) capability and their potential to meet the requirements of various wearable applications. [ABSTRACT FROM AUTHOR]

Background: The number of cycles of neoadjuvant therapy programmed cell death 1 (PD‐1) inhibitor for locally advanced non‐small cell lung cancer (NSCLC) remains controversial. Methods: From October 2019 to March 2022, neoadjuvant chemoimmunotherapy followed by radical surgery for NSCLC patients with stage II–III were retrospectively reviewed in Shanghai Pulmonary Hospital. The radiologic response was assessed according to the Response Evaluation Criteria for Solid Tumors version 1.1. The major pathological response was defined as no more than 10% residual tumor. Student's t‐test, chi‐square test, and Mann‐Whitney test were used for univariate analysis, logistic regression analysis was used for multivariate analysis. All statistical analyses were calculated by SPSS software (version 26). Results: Among 108 patients, the number of patients who received 2‐cycle (2‐cycle group) and more than 2‐cycle (>2‐cycle group) neoadjuvant chemoimmunotherapy were 75 (69.4%) and 33 (30.6%), respectively. Compared with patients in the >2‐cycle group, patients in the 2‐cycle group had significantly smaller diagnostic radiological tumor size (37.0 mm vs. 49.6 mm, p = 0.022) and radiological tumor regression rate (36% vs. 49%, p = 0.007). However, no significant difference in pathological tumor regression rate was observed between patients in the 2‐cycle group and >2‐cycle group. Further logistic regression analysis demonstrated that the neoadjuvant chemoimmunotherapy cycle could independently affect the radiographic response (odds ratio [OR]: 0.173, 95% confidence interval [CI]: 0.051–0.584, p = 0.005) but not for pathological response (OR: 0.450, 95% CI: 0.161–1.257, p = 0.127). Conclusions: For patients diagnosed with stage II–III NSCLC, the number of neoadjuvant cycles administered can significantly influence the radiographic efficacy of chemoimmunotherapy. [ABSTRACT FROM AUTHOR]

A new type of Ni/Al2O3 self‐supporting catalysts, with high specific surface area, was fabricated by blow‐spinning technology. These Ni/Al2O3 self‐supporting catalysts are hollow flexible fibers and were utilized for the dry reforming of methane. The Ni/Al2O3 catalysts exhibited exceptional catalytic performance, maintaining their activity for over 150‐h at a high temperature of 800°C. The Ni nanoparticles disputed on the hollow fibers demonstrated remarkable resistance to sintering and coking during high‐temperature catalysis. This was a noteworthy feature, as sintering and coking are common challenges faced by catalysts during high‐temperature reactions. Furthermore, the catalysts retained its activity even after a rigorous 150‐h test at 800°C, indicating its durability and stability. Importantly, the Ni/Al2O3 self‐supporting could be successfully reactivated after the test, further highlighting its reusable nature. This study offers promising new avenues for the development of high‐temperature, self‐supporting, and reactivatable catalysts. [ABSTRACT FROM AUTHOR]

Aqueous MXene dispersion suffers from a bottleneck issue of oxidation, leading to its gradual deterioration and ultimately compromised physicochemical characteristics. Herein, Tris‐HCl buffer is employed to stabilize the diluted Ti3C2Tx‐MXene dispersion (0.05 mg mL−1) through the synergy of its potent pH‐regulation capability and capping effect toward oxidation‐susceptible defects/edges. Tris‐HCl functionalized Ti3C2Tx maintained its original morphology, structure, and favorable dispersity even after 150 days of aging under naturally aerated conditions. The pH‐regulation nature of Tris‐HCl is elucidated through solution monitoring of Ti3C2Tx dispersion, while the adsorption of Tris‐HCl onto defects/edges is revealed by spectral analysis and multi‐scale simulations. Tris‐HCl at the neutral pH can bind to the negatively charged basal plane of Ti3C2Tx via +HTris moiety, while the other moiety (Tris) interacts with the exposed edge‐based Ti atoms and/or intrinsic defects, forming a Ti─N bond that prevents MXene from attack by H2O and O2. Besides, Tris‐HCl stabilized Ti3C2Tx exhibited nearly identical capacitive characteristics to its freshly‐etched counterpart, indicating the minimal impact of Tris‐HCl on electrochemical performance of Ti3C2Tx during long‐term storage. This study provides practical guidance for stabilizing MXene in their native aqueous dispersion without compromising the inherent properties. [ABSTRACT FROM AUTHOR]

Cascade reactions are described as efficient and versatile tools, and organized catalytic cascades can significantly improve the efficiency of chemical interworking between nanozymes. They have attracted great interest in many fields such as chromogenic detection, biosensing, tumor diagnosis, and therapy. However, how to selectively kill tumor cells by enzymatic reactions without harming normal cells, as well as exploring two or more enzyme‐engineered nanoreactors for cascading catalytic reactions, remain great challenges in the field of targeted and specific cancer diagnostics and therapy. The latest research advances in nanozyme‐catalyzed cascade processes for cancer diagnosis and therapy are described in this article. Here, various sensing strategies are summarized, for tumor‐specific diagnostics. Targeting mechanisms for tumor treatment using cascade nanozymes are classified and analyzed, "elements" and "dimensions" of cascade nanozymes, types, designs of structure, and assembly modes of highly active and specific cascade nanozymes, as well as a variety of new strategies of tumor targeting based on the cascade reaction of nanozymes. Finally, the integrated application of the cascade nanozymes systems in tumor‐targeted and specific diagnostic therapy is summarized, which will lay the foundation for the design of more rational, efficient, and specific tumor diagnostic and therapeutic modalities in the future. [ABSTRACT FROM AUTHOR]

Background: Altered mitophagy has been observed in various neurological disorders, such as epilepsy. The role of mitophagy in causing neuronal damage during epileptic episodes is significant, and recent research has indicated that GLS2 plays a crucial role in regulating autophagy. However, exactly how GLS2 affects epilepsy is still unclear. Aims: To investigate the expression and distribution characteristics of GLS2 in epilepsy, and then observed the changes in behavior and electrophysiology caused by overexpression of GLS2 in epileptic mice, and determined whether GLS2 regulated seizure‐like changes in the mouse model through the protective mechanism of mitophagy. Results: The expression of GLS2 in a kainic acid (KA)‐induced epileptic mouse model and aglutamate‐inducedneuronal excitatory damage in HT22 cells model was downregulation. In brief, overexpression of GLS2 can alleviate epileptic activity. Subsequently, we demonstrated that GLS2 interacts with mitophagy‐related proteins in a KA‐induced epilepsy mouse model. Mechanistically, overexpression of GLS2 inhibited mitophagy in epileptic mice, downregulating the expression of LC3 and reducing ROS production. Conclusions: This study proves the GLS2 expression pattern is abnormal in epileptic mice. The function of mitophagy in hippocampal neurons is affected by GLS2, and overexpression of GLS2 can reduce the occurrence of seizure‐like events (SLEs) by altering mitophagy function. Thus, GLS2 might control seizures, and our findings provide a fresh avenue for antiepileptic treatment and offer novel insights into treating and preventing epilepsy. [ABSTRACT FROM AUTHOR]

Plasma jet printing, which does not require preprocessing and postprocessing, is a promising technology for manufacturing flexible electronics. The conductive properties should be confirmed to ensure the performance of the flexible electronics. In this study, the conductive properties and control mechanism of plasma jet‐printed silver patterns were investigated. Analyses show that high‐energy particles in the plasma decomposed organic solvents and induced the interconnection between silver nanoparticles. The plasma jet‐printed silver patterns had high uniformity in vertical spatial distribution. The dense packing of the silver patterns was achieved by increasing the number of printed layers, reducing the print speed, and increasing the focusing ratio. Oxidation of the silver nanoparticles was reduced and the conductivity was improved by increasing the focusing ratio. [ABSTRACT FROM AUTHOR]

This article discusses the safety and efficacy of using a paclitaxel-coated balloon (PCB) for the treatment of ureteric stenosis. Ureteric stenosis is a condition characterized by narrowing of the ureter, which can lead to obstruction and long-term complications if left untreated. Surgical reconstruction is the standard treatment, but some patients are unable or unwilling to undergo surgery. Balloon dilatation is a minimally invasive alternative, but recurrence rates are high. The PCB, which delivers paclitaxel locally, has shown promise in other medical fields but has limited use in urological diseases. This study conducted experiments on pigs and found that PCB was safe and effective in treating ureteric stenosis, resulting in improved luminal patency and reduced fibrosis. However, further clinical trials are needed to confirm these findings. [Extracted from the article]

Objective: Recently, the South China Sea has been facing a crisis of depleted fishery resources, primarily due to the impacts of illegal, unreported, and unregulated fishing activities, as well as overfishing. Accurately understanding the fishing activity intensity in the South China Sea holds significant implications for the sustainable management of fisheries resources. Methods: Leveraging the automatic identification system trajectory data from 2018, this paper employs spatial statistical methods and fishing effort indicators to comparatively analyze the spatial variations in fishing intensity between Chinese and Vietnamese fishing vessels. Result: The results of this study show that (1) in 2018, the total fishing effort of Chinese fishing vessels in the South China Sea was 7.65 times that of Vietnamese vessels, but during China's South China Sea fishing moratorium, the fishing effort exerted by Vietnamese vessels surpassed that of China and (2) the top 10 ports in China and Vietnam support approximately 30% and 55.13% of their respective fishing intensities in the South China Sea. Conclusion: The study highlights significant variations in fishing intensity between Chinese and Vietnamese vessels and the substantial support provided by major ports. These findings offer valuable insights for fisheries resource monitoring and maritime spatial planning, contributing to the sustainable management of the South China Sea's fisheries resources. Impact statementThis study sheds light on fishing by Chinese and Vietnamese vessels during the South China Sea fishing ban and the intensity of fishing by vessels supported by ports along the South China Sea. By understanding these patterns, we can better manage fishery resources in the South China Sea and ensure sustainable fishing. [ABSTRACT FROM AUTHOR]

Noninvasive pharmacological strategies like nicotinamide mononucleotide (NMN) supplementation can effectively address age‐related ovarian infertility by maintaining or enhancing oocyte quality and quantity. This study revealed that ovarian nicotinamide adenine dinucleotide levels decline with age, but NMN administration significantly restores these levels, preventing ovarian atrophy and enhancing the quality and quantity of ovulated oocytes. Improvements in serum hormone secretion and antioxidant factors, along with decreased expression of proinflammatory factors, were observed. Additionally, a significant increase in the number of ovarian follicles in aging individuals was noted. Scanning electron microscopy data indicated that NMN significantly alters the density and morphology of lipid droplets and mitochondria in granulosa cells, suggesting potential targets and mechanisms. Transcriptomic analysis and validation experiments collectively suggested that the beneficial effects of NMN on aging ovaries are mediated through enhanced mitochondrial function, improved energy metabolism, and reduced inflammation levels. Our results suggest that NMN supplementation could improve the health status of aging ovaries and enhance ovarian reserve, offering new insights into addressing fertility challenges in older women through assisted reproductive technology. [ABSTRACT FROM AUTHOR]

All‐sky radiance assimilation has been extensively developed to provide additional information for numerical weather prediction under cloudy conditions. Microwave radiances are particularly sensitive to hydrometeors, which can be used to initialize hydrometeor directly if the hydrometeor control variables (HCVs) are available. However, the effects of HCVs statistical structure and their multivariate correlation on all‐sky radiance assimilation remain unclear. In this study, five HCVs are introduced into the variational assimilation system. The characteristics of hydrometeor background errors are analyzed, and the combined effect with the observation operator is discussed. Then a 3D Variational all‐sky assimilation framework with HCVs is modified to assimilate Fengyun‐3C/D Microwave Humidity Sounder‐II radiance. It is shown that hydrometeors are initialized by radiance directly, and the thermodynamic fields are adjusted accordingly. The characteristics of multi‐variables increments are associated with both the characteristics of HCVs in background error and the Jacobians in observation operator. Furthermore, cycle assimilation and forecast experiments for three typhoon cases are conducted. It is found that the difference between observed and analyzed brightness temperatures decreases when HCVs are activated, and the hydrometeors analysis fields are more consistent with observations. Additionally, the typhoon intensity forecasts are improved with enhanced double warm‐core and the secondary circulation. This paper analyzes the characteristics of variational all‐sky assimilation framework with HCVs, and demonstrates the potential value of HCVs for variational all‐sky radiance assimilation. Plain Language Summary: Accurate forecasting of clouds and precipitation remains a challenging task in numerical weather prediction. Effective utilization of observation under cloudy conditions through data assimilation is crucial for improving the weather prediction. Current typical all‐sky assimilation methods can only indirectly assimilate cloud and precipitation in the model trajectory. In this study, the impact of enabling such direct updates is explored through the modification of the radiance assimilation framework. It is found that the enhanced radiance assimilation framework can better understand the cloud and precipitation information and further influence the thermal and dynamical processes. Typhoon cases are used to test this new assimilation framework and found that the modeled hydrometeors are closer to observations and improves typhoon intensity prediction. This study demonstrates a potential approach by directly updating hydrometeors using satellites radiance and lead to more accurate weather predictions, especially for typhoon cases. Key Points: A 3D‐Var all‐sky radiance assimilation framework for FY‐3C/D MWHS‐II with hydrometeors control variables (HCVs) is establishedHydrometeors are initialized by radiance directly, through the combined effect with background error and the observation operatorBetter analysis of hydrometeors leads to improved typhoon inner‐core structure, thus enhancing the ability of typhoon intensity prediction [ABSTRACT FROM AUTHOR]

Benzyl radical (C7H7), one of the resonantly stabilized hydrocarbon radicals, is one of the significant precursors of polycyclic aromatic hydrocarbons in interstellar media and combustion engines. The unimolecular decomposition of benzyl radical is still incompletely understood despite of its importance and relatively small molecular size. The decomposition reactions of benzyl radical were investigated in the present study by using the ab initio transition state theory (TST) and the multi‐well master equation theory. Specifically, all reaction pathways on the potential energy surface of C7H7 was calculated at the level of QCISD(T)/CBS. For the reactions with multireference characters, the CASPT2(9e,7o)/aug‐cc‐pVTZ method was used to calculate the vibrational frequencies and energies of structures along the one‐dimensional reaction coordinate of the breaking bond. The high‐pressure limits of rate constants for all the reactions were obtained by using the TST except those for C7H6 + H and C6H4 + CH3 by the variational TST. The pressure‐dependent rate constants were obtained by using the multi‐well master equation simulations. The calculated rate constants agree well with available experimental and theoretical data in the literature. Moreover, the present results identify the composition of the non‐hydrogen‐atom production observed in previous experiments, which provide new insights into the reactions of aromatic compounds. [ABSTRACT FROM AUTHOR]

Bromine chemistry is responsible for the catalytic ozone destruction in the atmosphere. The heterogeneous reactions of sea‐salt aerosols are the main abiotic sources of reactive bromine in the atmosphere. Here, we present a novel mechanism for the activation of bromide ions (Br−) by O2 and H2O in the absence of additional oxidants. The laboratory and theoretical calculation results demonstrated that under dark conditions, Br−, O2 and H3O+ could spontaneously generate Br and HO2 radicals through a proton–electron transfer process at the air–water interface and in the liquid phase. Our results also showed that light and acidity could significantly promote the activation of Br− and the production of Br2. The estimated gaseous Br2 production rate was up to 1.55×1010 molecules cm−2 ⋅ s−1 under light and acidic conditions; these results showed a significant contribution to the atmospheric reactive bromine budget. The reactive oxygen species (ROS) generated during Br− activation could promote the multiphase oxidation of SO2 to produce sulfuric acid, while the increase in acidity had a positive feedback effect on Br− activation. Our findings highlight the crucial role of the proton‐electron transfer process in Br2 production; here, H3O+ facilitates the activation of Br− by O2, serves as a significant source of atmospheric reactive bromine and exerts a profound impact on the atmospheric oxidation capacity. [ABSTRACT FROM AUTHOR]

BiVO4 is one of the most promising candidates for photoelectrochemical water oxidation. However, the poor crystallinity and short hole diffusion length limit its charge separation. One bottleneck stems from the contradiction between high crystallinity and small particles via conventional furnace heating processes. This paper describes the design and fabrication of BiVO4 photoanodes via rapid thermal process (RTP), rather than furnace heating, to decouple the constraints between nucleation, crystallization, and growth processes of BiVO4. The higher heating ramp rate of RTP compared with furnace heating promotes the fast diffusion of reactant molecules, which elevates the nucleation rate above the particle growth rate of BiVO4, leading to small particles with high crystallinity. Moreover, the ultra‐high heating temperature makes it possible to crystallize the small BiVO4 particle within a short time. Thus, a high crystallinity can be obtained for the RTP‐treated BiVO4 while maintaining small particle size, achieving a charge separation efficiency of up to 82%, 30% higher than that of furnace‐treated BiVO4 photoanode. [ABSTRACT FROM AUTHOR]

The stereoselective cyclopropanation of olefins with “boron ylide” is disclosed for the first time, providing a modular strategy for the synthesis of stereospecific diboryl‐functionalized cyclopropanes. The chiral gem‐diborylcyclopropanes are synthesized with excellent enantioselectivity with the aid of a chiral auxiliary. Based on the powerful transformable ability of boryl group, those challenging multi‐quaternary carbon centers in cyclopropane units have been facilely constructed with excellent stereoselectivity. Control experiments indicate that the boryl groups are necessary for both chemoselectivity and stereoselectivity control. [ABSTRACT FROM AUTHOR]

The partial exposure of submarine cable may cause damage to the metal sheath, which will affect its safe and stable operation. Existing detection methods for burial depth of submarine cables are difficult to implement and have a long detection period. In this contribution, a method is proposed to calculate the burial depth of alternating current (AC) submarine cable based on surface optical fiber monitoring temperature. According to the functional relationship between the transient temperature rise of submarine cable outer sheath above the ambient temperature and the burial depth (in the IEC‐60853 standard), the burial depth of submarine cables is calculated. The optical fiber temperature, electric load and meteorological temperature data are used for 30 consecutive days in September 2020 to calculate the change of burial depth of AC 500 kV oil‐filled submarine cable. The calculation results are basically consistent with the detection conclusion of side‐scan sonar, which shows that the method can accurately calculate the burial depth of submarine cables and locate the exposed position. This provides a theoretical basis for the intelligent operation and maintenance of AC submarine cables. [ABSTRACT FROM AUTHOR]

Silicon‐based materials are regarded as the most promising negative electrode materials for next‐generation high‐energy lithium ion batteries due to their high theoretical capacity, low lithiation plateau and low cost, but they still suffer from dramatic volume variation during charge/discharge and sluggish kinetics, substantially restricting their practical applications. Recently, 2D MXenes are demonstrated to improve the electrochemical performances of Si‐based materials owing to their metallic conductivity, large surface aspect ratio, rich surface chemistry, good mechanical strength, etc. Serving as conductive host, MXenes can alleviate the volume expansion of Si during lithiation, enhance the electronic conductivity of the composite and facilitate the electron/ion transport, thus making the resultant Si/MXene composites exhibit excellent performance as negative electrodes of secondary batteries. Herein, an overview toward the recent advances of Si/MXene nanocomposites is presented for lithium storage applications. The preparation strategies and structural characteristics of the Si/MXene nanocomposites are introduced. The applications of diverse Si/MXene nanostructures such as powders, 3D architectures, films and fibers, in lithium ion batteries with corresponding structure‐performance relationships are discussed. Finally, the challenges and perspectives for the future research of Si/MXene nanocomposites are highlighted, aiming to provide a fundamental reference in designing advanced Si/MXene nanocomposites for high‐energy lithium ion batteries. [ABSTRACT FROM AUTHOR]

Site‐selective occupation generated by ion doping into crystal lattices is an effective way to explore new matter and regulate luminescent properties. Herein, equiv. M2+ (Ca, Sr, Ba) is partially replaced each other to formulate multiple doped sites in Li2MSiO4: Eu2+ (LMSO: Eu2+). As the luminescence center, Eu2+ selectively occupies different sites to regulate luminescent color in the visible spectrum ranging from blue to orange, and ultimately functionality improvement. The Huang‐Rhys factor is quite small and the resulting phosphors display an ultrahigh thermal stability for optical thermometry. Besides, utilizing synthesized phosphors combined with the InGaN chip generates high‐quality full‐spectrum white light. Under X‐ray irradiation, LMSO: Eu2+ (M = Ca, Sr, Ba) exhibits great X‐ray imaging ability, the detection limit of X‐ray reaches 0.18, 0.075, and 0.12 µGy s−1. This work presents great potentiality of synthesized phosphors in the fields of solid‐state lighting and X‐ray imaging. [ABSTRACT FROM AUTHOR]

Background and Aims: In this study, a pediatric hospital was selected as the study setting, to investigate the effects of the environment of a pediatric operating room child‐friendly space on preschool children under anesthesia. Methods: Interviews were conducted in pediatric hospitals through anesthesia of preschool children. This study randomizing children between the ages of 1 and 7 years (seven males, five females, mean age 3.8 years, standard deviation 0.7). Twelve participants took part in this interview, which was an in‐depth interview of preschoolers' perceptions of anesthesia using generalized data analysis to assess young children's perceived preferences and sensitivity to the environment. Preschoolers' preferences for feeling under anesthesia are reflected in four main areas. Results: (1) Interesting and engaging environment. (2) Humanized design, free of fear and unfamiliarity. (3) Caring, patient, and compassionate care by healthcare professionals. (4) High cooperation of the child and good doctor–patient relationship. Conclusion: The key findings of this study may help designers and clinicians to design a toddler‐friendly built environment where pediatric hospital child‐friendly spaces are designed to benefit their health and maximize their cooperation and psychological recovery. [ABSTRACT FROM AUTHOR]

Comprehensive thermodynamic calculations and high‐temperature experiments are performed to systematically evaluate the effect of calcium and magnesium additions on the modification and control of inclusions in AH36 ship plate steel. The results show that Al2O3 or MgAl2O4 inclusions are formed under the casting temperature conditions. Calcium treatment modifies the inclusions into calcium aluminate, of which components partially fall into the liquidus region, and the aspect ratio and number density of inclusions became smaller, avoiding nozzle clogging, but the inclusions are easy to gather and grow up, which would affect the steel properties. Magnesium treatment modifies the inclusions into dispersed magnesium‐aluminum spinel with small size. However, the number density and aspect ratio of inclusions increase, as well as the melting points of inclusions are high, which would easily cause nozzle clogging. When calcium–magnesium synergistic treatment, with the increase of magnesium proportion, the inclusions types increased, and the liquidus area of inclusions became narrower until it disappeared. Synergistic treatment with more calcium and less magnesium (Ca2Mg1) is optimal since the inclusions were fine and diffuse, and the corresponding liquidus area of inclusions is wider than the calcium treatment. [ABSTRACT FROM AUTHOR]

Zn metal anodes are usually subject to grave dendrite growth during platting/stripping, which dramatically curtails the lifespan of aqueous Zn‐ion batteries and capacitors. To address above problems, in our work, a novel phosphorus‐functionalized multichannel carbon interlayer was designed and covered on Zn anodes. The results demonstrated that the multichannel structure combined with the three‐dimensional meshy skeleton can provide more sufficient space for Zn deposition, thereby effectively inhibiting the growth of zinc dendrites. Meanwhile, theoretical calculations also confirmed that the P–C and P=O functional groups from phosphorus‐functionalized multichannel carbon interlayer have the decisive influence in reducing the zinc nucleation potential and depositing uniformly zinc. Concretely, the symmetrical battery assembled with phosphorus‐functionalized multichannel carbon interlayer‐covered Zn anodes possessed a long lifetime of 3300 h at 2 mA cm−2 with 1 mAh cm−2. Furthermore, the full cell with activated carbon cathodes exhibited a high specific capacity of 80.5 mAh g−1 and outstanding cycling stability without capacity decay after 15 000 cycles at a high current density of 5 A g−1. The superior electrochemical performance exceeded that of most reported papers. Consequently, our synthesized zincophilic interlayer with the unique structure has superior prospects for application in stabilizing zinc anodes and prolonging the lifespan of batteries. [ABSTRACT FROM AUTHOR]

Fluorescent lead halide perovskite quantum dots (LH PQDs) micropatterns hold great potential for photonic applications. However, current photolithography for LH PQDs micropatterning is hindered by their incompatibility with traditional photolithography methods, which involve development processes using numerous solvents and exhibit poor stability due to the ionic characteristics of LH PQDs. Herein, a direct in situ photolithography to fabricate CsPbBr3 PQDs micropatterns based on ultraviolet‐C light‐driven debromination is developed. Using this approach, fluorescent CsPbBr3 PQDs micropatterns with high theoretical information storage capacity (up to 10750205) can be achieved in a single step, without the need for tedious development processes. Furthermore, the fabricated CsPbBr3 PQDs micropatterns show high stability, remaining undamaged even after immersion in water for 6 months. The combination of excellent optical properties, development‐free process, high stability, and low cost makes the in situ photolithography strategy very promising for patterning LH PQDs toward photonic integrations. [ABSTRACT FROM AUTHOR]

Human milk oligosaccharides (HMOs) are an evolutionarily significant advantage bestowed by mothers for facilitating the development of the infant's gut microbiota. They can avoid absorption in the stomach and small intestine, reaching the colon successfully, where they engage in close interactions with gut microbes. This process also enables HMOs to exert additional prebiotic effects, including regulating the mucus layer, promoting physical growth and brain development, as well as preventing and mitigating conditions such as NEC, allergies, and diarrhea. Here, we comprehensively review the primary ways by which gut microbiota, including Bifidobacteria and other genera, utilize HMOs, and we classify them into five central pathways. Furthermore, we emphasize the metabolic benefits of bacteria consuming HMOs, particularly the recently identified intrinsic link between HMOs and the metabolic conversion of tryptophan to indole and its derivatives. We also examine the extensive probiotic roles of HMOs and their recent research advancements, specifically concentrating on the unsummarized role of HMOs in regulating the mucus layer, where their interaction with the gut microbiota becomes crucial. Additionally, we delve into the principal tools used for functional mining of new HMOs. In conclusion, our study presents a thorough analysis of the interaction mechanism between HMOs and gut microbiota, emphasizing the cooperative utilization of HMOs by gut microbiota, and provides an overview of the subsequent probiotic effects of this interaction. This review provides new insights into the interaction of HMOs with the gut microbiota, which will inform the mechanisms by which HMOs function. [ABSTRACT FROM AUTHOR]

The segment character of polyurethanes (PUs) determines the micromorphology and properties. The effective segment regulation can customize the favorable performance of PUs. Herein, silicon covalent‐modified polyurethanes (MPUs) were prepared by incorporating diphenylmethane diisocyanate (MDI) and diphenyl silanediol (DPSD) into PU molecules as hard segments via a two‐step method. Distinctive microphase separation structures from sheet morphology to radial sheet or withered flower‐like microdomain were formed by adjusting hydrogen bonding of hard segments and post‐treatment techniques. Thus, with the addition of DPSD in hard segments, the thermo‐optic responses for MPUs occurred due to the different microphase evolution under thermal effect. And with the further addition of DPSD, the effect of thermal stimuli on the transmittance gradually weakened. It was very clear that with increasing the temperature, the transmittance of MPUs showed a gradual increase owing to melting the microcrystals or destroying the ordered accumulation of hard segments. Meanwhile, the high mechanical properties were obtained, higher 15 times tensile strength and more than 100 times elastic modulus than those of pure PU as well as the excellent thermal stability. In sum, this study was of great significance for developing new functionalized PU materials. Highlights: Polyurethanes were prepared by inducing modified silicon functionality.The distinctive microphase separation evolution of MPUs was found.Thermal stimuli responses showed a gradual decrease due to different structure.High mechanical properties and thermal stability were also obtained. [ABSTRACT FROM AUTHOR]

In situ metallization of Ag+ conductive glass was successfully achieved by applying electric and temperature fields to the glass to ensure the controlled migration of ions inside the glass. The transport and kinetic characteristics of Ag+ under the combined effect of electric field and temperature field were investigated by calculating and analyzing Ag+ diffusion coefficient. The correlations between ion transport and current were characterized with potential energy equations. The simulations and experiments of ion transport in the conducting glass were implemented, which revealed the mechanisms of ion transport and interfacial precipitation within the conducting glass. Further more, the existence of Ag+ deprivation layer was confirmed and it was clarified that the depth of the deprivation layer reached 30 µm under thermal polarization conditions of 60 V and 300°C. The microscopic morphology of in situ silver deposition layer was observed using SEM and TOF–SIMS. In addition, It was determined that the in situ metallization of conductive glass under the polarization condition of 60 V at 250°C was the best, and the thickness of deposited silver dendrites reached 1000 nm in the side of cathodically. This paper provides theoretical and experimental references for the optimization of the in situ metallization process for the ion conductive glass. [ABSTRACT FROM AUTHOR]

Due to their unique semiconducting properties, conjugated porous organic polymers (CPOPs) have garnered significant interest in various photocatalysis applications. In this study, we synthesize three thiazolo[5,4‐d]thiazole (TzTz)‐linked CPOPs with three polyaryl rigid cores of benzene (CPOP1), pyrene (CPOP2), and triazine (CPOP3). We investigated their efficacy in catalyzing visible light‐driven C−N bond formation reactions, including C−N cross‐couplings between aryl bromides and amines and amination reactions from aryl bromides and sodium azides. Among the three, only CPOP2, combined with NiCl2 or Ni(dtbbpy)Cl2, effectively facilitated these transformations. Notably, CPOP2 exhibited photocatalytic activities approximately six times higher than its small molecular counterpart C1 in both reactions. The CPOP catalyst was easily recovered through centrifugal separation and reused for five catalytic cycles with minimal loss of activity. Theoretical calculations revealed that the deliberate structural design of polyaryl moieties could effectively tune the energy gap, which is crucial for the photocatalytic activity in organic reactions. This study, therefore, demonstrates a novel application of TzTz‐linked CPOPs for heterogeneous photocatalytic organic transformations. [ABSTRACT FROM AUTHOR]

Anti‐cancer peptides (ACPs) represent a promising potential for cancer treatment, although their mechanisms need to be further elucidated to improve their application in cancer therapy. Lycosin‐I, a linear amphipathic peptide isolated from the venom of Lycosa singorensis, shows significant anticancer potential. Herein, it is found that Lycosin‐I, which can self‐assemble into a nanosphere structure, has a multimodal mechanism of action involving lipid binding for the selective and effective treatment of leukemia. Mechanistically, Lycosin‐I selectively binds to the K562 cell membrane, likely due to its preferential interaction with negatively charged phosphatidylserine, and rapidly triggers membrane lysis, particularly at high concentrations. In addition, Lycosin‐I induces apoptosis, cell cycle arrest in the G1 phase and ferroptosis in K562 cells by suppressing the PI3K‐AKT‐mTOR signaling pathway and activating cell autophagy at low concentrations. Furthermore, intraperitoneal injection of Lycosin‐I inhibits tumor growth of K562 cells in a nude mouse xenograft model without causing side effects. Collectively, the multimodal effect of Lycosin‐I can provide new insights into the mechanism of ACPs, and Lycosin‐I, which is characterized by high potency and specificity, can be a promising lead for the development of anti‐leukemia drugs. [ABSTRACT FROM AUTHOR]