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The irradiation of β‐enaminones, generated in situ from cyclic 1,3‐diketones and activated alkenes leads to polyheterocyclic skeletons. The photoproduct chemoselectivity depends on the type of cyclic 1,3‐diketones employed viz., 2‐acetylcyclopentanone and 2‐acetylcyclohexanone. The observed chemoselectivity was rationalized based on the Dieckmann‐Kon rule. [ABSTRACT FROM AUTHOR]

Aryl‐maleimides undergo a novel [2+4]‐photodimerization instead of the expected [2+2]‐photodimerization under both direct irradiation with visible light and under sensitized energy transfer conditions. This new excited state reactivity in aryl‐maleimides is deciphered through photochemical, photophysical, and spectroscopic studies. The stereochemistry of the photodimer depends on the type of non‐bonding interactions prevalent during photodimerization which is in turn dictated by the substituents on the maleimide ring. More importantly, the stereochemistry of the photodimer formed is complementary to the product observed under thermal conditions. [ABSTRACT FROM AUTHOR]

Photoreaction of enamides tethered to a phenyl ketone leads to either [3+2]‐photocycloaddition or Paternò–Büchi reaction. This divergence in chemical reactivity originating from the same excited state was dependent on the reaction temperature. At low temperatures the Paternò–Büchi reaction was preferred, whereas at higher temperatures there was preference toward formation of [3+2]‐photoproduct. [ABSTRACT FROM AUTHOR]

Photoreaction of enamides tethered to a phenyl ketone leads to either [3+2]‐photocycloaddition or Paternò–Büchi reaction. This divergence in chemical reactivity originating from the same excited state was dependent on the reaction temperature. At low temperatures the Paternò–Büchi reaction was preferred, whereas at higher temperatures there was preference toward formation of [3+2]‐photoproduct. [ABSTRACT FROM AUTHOR]