1. Ultrathin ionic COF Membrane via Polyelectrolyte‐Mediated Assembly for Efficient CO2 Separation.
- Author
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Wang, Shaoyu, Yang, Yuhan, Liang, Xu, Ren, Yanxiong, Ma, Hanze, Zhu, Ziting, Wang, Jianyu, Zeng, Shichen, Song, Shuqing, Wang, Xuerui, Han, You, He, Guangwei, and Jiang, Zhongyi
- Subjects
POLYMERIC membranes ,FLUE gases ,NANOSTRUCTURED materials ,CARBON dioxide ,POLYETHYLENEIMINE - Abstract
Fabricating ultrathin covalent organic framework (COF) membranes toward high‐permeance molecular separations is highly desired yet challenging. Herein, a polyelectrolyte‐mediated assembly (PMA) strategy is developed to fabricate ultrathin ionic COF membrane for efficient CO2 separation. The PMA strategy allows a facile control over the assembly mode between polyethyleneimine (PEI) and TpPa‐SO3H, yielding PEI‐bridged ultra‐large COF nanosheets which are readily processed into COF membranes with thickness down to 8 nm. The resulting COF membranes exhibit a high CO2 permeances of 1371 GPU and CO2/N2 selectivity of 33 for stimulated flue gas. This PMA strategy may open up a new avenue to fabricating ultrathin 2D material membranes for diverse applications. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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