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Start Over Author "Sheng wen Liang" Publisher wiley-blackwell
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1. Tetra­aqua­bis(5-carb­oxy-2-nitro­benzo­ato-κ O)manganese(II) dihydrate: a metal–water chain complex containing cyclic water tetra­mers.

Author

Li-Qin Xiong, Chuan-Min Qi, Hui Yu, and Sheng-Wen Liang

Subjects
POLYMERIZATION, ADDITION polymerization, HYDROGEN bonding, WATER, OXYGEN, HYDROGEN
Abstract

In the title complex, [Mn(C8H4NO6)2(H2O)4]·2H2O, cyclic water tetra­mers forming one-dimensional metal–water chains have been observed. The water clusters are trapped by the co-­operative association of coordination inter­actions and hydrogen bonds. The MnII ion resides on a center of symmetry and is in an octa­hedral coordination environment comprising two O atoms from two 5-carboxy-2-nitrobenzoate ligands and four O atoms from water mol­ecules. [ABSTRACT FROM AUTHOR]

Published
2007
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