1. Pt(II) and Pd(II) Complexes with β-Alanine.
- Author
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Krylova, L. F., Kovtunova, L. M., and Romanenko, G. V.
- Subjects
ALANINE ,AMINO acids ,SPECTRUM analysis ,X-ray diffraction ,PHYSICAL & theoretical chemistry - Abstract
A sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with β-aminopropionic acid (β-alanine = β-AlaH) has been studied by the
195 Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cis- and trans-bischelates of Pt(II) and Pd(II) with β-alanine as well as of the halide complexes of trans-[M(β-AlaH)2 Cl2 ] (M= Pt, Pd) and trans-K2 [Pt(β-Ala)2 I2 ] types. The NMR spectroscopy and IR spectroscopy (in the nuclei of195 Pt,13 C,1 H) and X-ray diffraction analysis have been used to examine the structures of the synthesized compounds. [ABSTRACT FROM AUTHOR]- Published
- 2008
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