1. Pulverization-Tolerance and Capacity Recovery of Copper Sulfide for High-Performance Sodium Storage.
- Author
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Jae Yeol Park, Sung Joo Kim, Kanghoon Yim, Kyun Seong Dae, Yonghee Lee, Khoi Phuong Dao, Ji Su Park, Han Beom Jeong, Joon Ha Chang, Hyeon Kook Seo, Chi Won Ahn, and Jong Min Yuk
- Subjects
COPPER sulfide ,COPPER electrodes ,SODIUM ions ,CONVERSION disorder ,ELECTRODE reactions ,METAL sulfides - Abstract
Finding suitable electrode materials is one of the challenges for the commercialization of a sodium ion battery due to its pulverization accompanied by high volume expansion upon sodiation. Here, copper sulfide is suggested as a superior electrode material with high capacity, high rate, and long-term cyclability owing to its unique conversion reaction mechanism that is pulverization-tolerant and thus induces the capacity recovery. Such a desirable consequence comes from the combined effect among formation of stable grain boundaries, semi-coherent boundaries, and solid-electrolyte interphase layers. The characteristics enable high cyclic stability of a copper sulfide electrode without any need of size and morphological optimization. This work provides a key finding on high-performance conversion reaction based electrode materials for sodium ion batteries. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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