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Start Over Author "Kawakami, Yuka" Publisher wiley-blackwell
1 results on '"Kawakami, Yuka"'

1. Palladium‐Catalyzed Synthesis of Benzophenanthrosilines by C−H/C−H Coupling through 1,4‐Palladium Migration/Alkene Stereoisomerization.

Author

Tsuda, Tomohiro, Kawakami, Yuka, Choi, Seung‐Min, and Shintani, Ryo

Subjects
*PALLADIUM, *HECK reaction, *CATALYSIS
Abstract

A new and efficient synthesis of 8H‐benzo[e]phenanthro[1,10‐bc]silines from 2‐((2‐(arylethynyl)aryl)silyl)aryl triflates under palladium catalysis has been developed. The reaction mechanism was experimentally investigated and a catalytic cycle involving C−H/C−H coupling through a new mode of 1,4‐palladium migration with concomitant alkene stereoisomerization is proposed. [ABSTRACT FROM AUTHOR]

Published
2020
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