Search

Understanding the age and dynamics of the overriding plates allows an assessment of competing subduction initiation hypotheses. The Izu‐Bonin‐Mariana margin in the Western Pacific is a key example of initiation and hence it is important to constrain the age and origin of the oldest igneous crust of the supra‐subduction Philippine Sea Plate. We present geochronological and geochemical data of igneous rocks from the oldest ocean basins of the Philippine Sea Plate: the West Philippine and Palau Basins. Basalts from these basins have enriched geochemical characteristics similar to the EM‐2‐like mantle component found in OIB‐like basalts associated with the Oki‐Daito mantle plume. Ages of basalts from the northernmost West Philippine Basin (WPB) and the Palau Basin range from 43.5 to 50.5 Ma, which is similar to the oldest samples associated with the Oki‐Daito mantle plume (48–50 Ma). This implies that the plume contributed to magmatism from the onset of basin formation. It also provides support for the proposition that rifting of the Mesozoic arc terrane and subsequent seafloor spreading of the WPB was triggered by the arrival of the Oki‐Daito mantle plume at the base of the lithosphere. The age of these Philippine Sea Basins implies that only the Mesozoic Daito Ridge Group and the Gagua Ridge existed as Philippine Sea Plate crust before subduction initiation. A major fault activity after 37 Ma in the northernmost WPB demonstrates that careful reconstruction of the Eocene Philippine Sea Plate is critical to understanding plate dynamics during subduction initiation in the Western Pacific. Plain Language Summary: This study investigates the formation of the crust beneath the Philippine Sea Plate. An outcome of this research is a clearer understanding of the plate tectonic configuration in the Western Pacific at the point when volcanic activity started. We collected rock samples from what is thought to be the oldest sections of the West Philippine Basin and the Palau Basin, and determined their age and chemical composition. These rocks were erupted between 43.5 and 50.5 million years ago, and are of a similar age and composition to the volcanic rocks known to be associated with the Oki‐Daito mantle plume (48–50 million years old). These similarities imply that the initial volcanism on the Philippine Sea Plate was triggered by the arrival of the upwelling Oki‐Daito mantle plume. A consequence of the hot and buoyant mantle plume was to stretch the existing crust and develop a new ocean basin by volcanic activity. The new ages for the oldest ocean basins in the Philippine Sea Plate reveal that only the Mesozoic arc terrane existed as the Philippine Sea Plate crust before subduction initiation. This provides new constraints on the conditions under which subduction can initiate between the two plates. Key Points: New dating indicates that a major part of the oldest Philippine Sea Plate basins formed after c. 51 MaOcean crust of the oldest Philippine Basins is affected by the Oki‐Daito mantle plumeOnset of spreading of the West Philippine Basin could have been triggered when the Oki‐Daito plume hit the base of preexisting lithosphere [ABSTRACT FROM AUTHOR]

Transanal total mesorectal excision is a relatively new approach for treating lower rectal cancer. Carbon dioxide embolism is a critical complication of this procedure. We report the case of a 69‐year‐old man with lower rectal cancer who underwent transanal total mesorectal excision followed by laparoscopic low anterior resection. He had a sudden intraoperative carbon dioxide embolism during the transanal mesorectal excision. During the ventral dissection of the rectum, end‐tidal carbon dioxide and blood oxygen saturation suddenly decreased. We stopped the insufflation of carbon dioxide and suspended the procedure. There was no circulatory collapse, and the vital signs gradually recovered; therefore, we resumed the surgery approximately 30 minutes later and completed it without additional complications. Upon reviewing the video, we found a small injured vein that would aspirate carbon dioxide. These findings suggested that careful hemostasis is essential to prevent carbon dioxide embolus during transanal total mesorectal excision. [ABSTRACT FROM AUTHOR]

The southern Indian Ocean has several prominent aseismic ridges recognized as oceanic large igneous provinces (i.e., the Madagascar Ridge, Del Cano Rise, Crozet Plateau, and Conrad Rise) in the off‐axis areas of the Southwest Indian Ridge (SWIR). However, previously obtained magnetic survey lines are sparse and not correctly aligned with the seafloor spreading direction; thus, the detailed spreading history, including the formation of these aseismic ridges, remains an open question. We reconstructed the tectonic history of two segments between the Discovery II and Gallieni fracture zones in the SWIR using newly obtained magnetic data (total and vector magnetic field) and an open‐source magnetic data set. We revealed that the southern Madagascar Ridge and the Del Cano Rise once formed a single bathymetric high and separated by at least Chron 30y, which is quite different from the global age model. In addition, the rises may have formed before Chron 34y, assuming an extinct ridge south of the Del Cano Rise. The two rises have been recognized as having formed by Marion hotspot plume‐induced excess volcanism around the active spreading ridge of the SWIR, which can explain locally isostatically compensated thicker‐than‐normal crust. However, linear magnetic anomalies have not been observed across the main part of these rises, suggesting that magmatic activity controlled by seafloor spreading is unlikely. Like other aseismic ridges in the southern Indian Ocean, these two rises may possibly have been formed partly by continental fragments rather than plume‐induced excess volcanism. Plain Language Summary: The southern Indian Ocean contains several bathymetric high regions previously interpreted as oceanic large igneous provinces. Hotspot‐ridge interaction is considered as the key factor in the formation of such large volcanic structures. However, the detailed seafloor spreading history and origin of these large volcanic structures are not understood as well as those in other oceans because of the vast and remote Indian Ocean. We conducted magnetic surveys and reconstructed a new tectonic history of two segments along the Southwest Indian Ridge (SWIR). We found that the southern Madagascar Ridge and the Del Cano Rise once formed a single bathymetric high and that they separated by at least 66 million years ago. Moreover, the rises may have formed before 84 million years ago, assuming an extinct ridge south of the Del Cano Rise. The two rises might have formed by interaction between the Marion hotspot and SWIR; however, linear magnetic anomalies implying seafloor spreading are not observed in the main parts of these rises. This absence suggests that hotspot‐ridge interaction cannot fully explain the origin of these rises. We cannot exclude the possibility that the two rises are partly continental fragments rather than products of hotspot‐induced excess volcanism. Key Points: Revised seafloor ages up to Chron 31 in the Indian Ocean are obtained by new total and vector magnetic dataOur new tectonic scenario indicates that the Madagascar Plateau and Del Cano Rise once formed a single bathymetric highThe tectonics of oceanic plateaus in the Indian Ocean need to be reexamined, including continental fragment origin [ABSTRACT FROM AUTHOR]

We determined the mineralogical and petrological characteristics of ultramafic rocks dredged from two oceanic core complexes: the Mado Megamullion and 23°30′N non‐transform offset massif, which are located within the Shikoku back‐arc basin in the Philippine Sea. The ultramafic rocks are strongly serpentinized, but can be classified as harzburgite/lherzolite or dunite, based on relict primary minerals and their pseudomorphs. Strongly elongated pyroxene porphyroclasts with undulatory extinction indicate high‐temperature (≥700 °C) strain localization on a detachment fault within the upper mantle at depths below the brittle–viscous transition. During exhumation, the peridotites underwent impregnation by magmatic or hydrothermal fluids, lizardite/chrysotile serpentinization at ≤300 °C, antigorite crystallization, and silica metasomatism that formed talc. These features indicate that the detachment fault zones formed a fluid pathway and facilitated a range of fluid–peridotite interactions. [ABSTRACT FROM AUTHOR]

Discriminating magnetic minerals of different origins in natural samples is useful to reveal their associated geological and environmental processes, which can be achieved by the analysis of remanent magnetization curves. The analysis relies on the choice of the model distribution to unmix magnetic components. Three model distributions were proposed in past studies, namely, the lognormal, skew normal, and skewed generalized Gaussian distributions, which are related to the normal distribution. In this study, the Burr type XII distribution is tested and compared with existing model distributions. An automated protocol is proposed to assign parameters necessary to initiate the component analysis, which improves the efficiency and objectivity. Results show that the new model distribution exhibits similar flexibility to the skew normal and skewed generalized Gaussian distributions in approximating skewed coercivity distributions and can fit end‐member components better than the commonly used lognormal distribution. We demonstrate that the component analysis is sensitive to model distribution as well as measurement noise. As a consequence, the decomposition is subject to bias that is hard to identify due to the lack of ground‐truth data. It is therefore recommended to compare results derived from various model distributions to identify spurious components. Key Points: The Burr type XII distribution is suitable as a model distribution to statistically separate the magnetic mixture in geological samplesAn automated procedure for randomly choosing initial guesses is proposed to improve the objectivity and efficiency of decompositionComparing results derived from different model distributions is useful to assess the reliability of interpretations [ABSTRACT FROM AUTHOR]

A combination of zinc triflate and pyridine in a nitrile medium was found to act as an effective catalytic system for dehydrogenative silylation with flexible pieces of terminal alkynes and hydrosilanes, thereby producing diverse alkynylsilanes in high to excellent yields. [ABSTRACT FROM AUTHOR]

First time, alkynylsilanes are synthesized in excellent yields by dehydrogenative silylation of terminal alkynes with hydrosilanes. [ABSTRACT FROM AUTHOR]