1. Phase diagram of the Nd2Fe14B-Sm2Fe14B pseudo-binary system.
- Author
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Xu, Ch. F., Chen, K. H., Gu, Z. F., Cheng, L. Y., Ma, D. D., Cheng, G., Rao, G. H., and Yao, Q. R.
- Subjects
BINARY number system ,X-ray powder diffraction ,DIFFERENTIAL thermal analysis - Abstract
The phase relations in the (1− x)Nd
2 Fe14 B- xSm2 Fe14 B system over the whole concentration range have been studied by means of X-ray powder diffraction (XRD), differential thermal analysis (DTA) and scanning electron microscopy with energy-dispersive X-ray spectroscopy. Crystal structure parameters for all studied compositions of (Nd1− x Smx )2 Fe14 B have been determined by full-profile Rietveld refinements. These results revealed that all intermediate alloys of (Nd1− x Smx )2 Fe14 B are similar to the end member of the investigated system, Nd2 Fe14 B, with a tetragonal structure (space group P42 / mnm). The formation of continuous solid solutions has been found in this system. The normalized lattice parameters and unit-cell volumes of (Nd1− x Smx )2 Fe14 B solid solutions decrease linearly with increasing Sm content. The DTA measurements show that the melting temperature of (Nd1− x Smx )2 Fe14 B increases linearly with increasing Sm content and no metastable phases were detected. Based on the DTA data and XRD results, a tentative phase diagram for the pseudo-binary system Nd2 Fe14 B-Sm2 Fe14 B has been constructed. [ABSTRACT FROM AUTHOR]- Published
- 2016
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