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Proton exchange membrane fuel cells (PEMFCs) are crucial for the efficient utilization of hydrogen. Currently, their efficiency is mainly limited by the slow kinetics of the cathode oxygen reduction reaction (ORR) and the poisoning effect between ionomers and catalytic sites, particularly with Pt‐based catalysts. Recent works suggest that the emerging porous carbon‐supported catalysts hold promise in mitigating these challenges by ensuring fast kinetics while alleviating the poisoning. This review examines porous carbon‐supported catalysts for PEMFC cathodes, covering synthesis methods, structure and performance evaluation, and future prospects, with an emphasis on the influence of porous carbon support on PEMFC performance. On one hand, the rational design of pore structure in carbon support can help optimize the location of the active sites and enhance mass transfer. On the other hand, diverse pore structures provide a platform for gaining a deeper understanding of the mechanisms behind microscale mass transfer and reaction at the three‐phase boundaries. This review aims to inspire innovative strategies for the precise synthesis of porous carbon‐supported catalysts with various pore structures to further boost PEMFC performance. [ABSTRACT FROM AUTHOR]

Sonodynamic therapy (SDT), as a promising non‐invasive therapeutic modality combining ultrasound (US) and sonosensitizers to produce cytotoxic reactive oxygen species (ROS) for treating deep‐seated tumors, has received increasing attention in recent years. Porphyrins are multifunctional organic materials, which can be excited both by light and US to produce ROS and possess various fascinating features, including controllable synthetic processes, excellent biodegradability, low cytotoxicity without light or US. Nevertheless, their poor water solubility, skin‐photosensitive toxicity, and insufficient target specificity hinder their clinical applications as sonosensitizer. Although the target specificity issue may be improved by using nanoparticle carriers, and the SDT efficacy can be enhanced by combining with other therapeutic modalities, such combination therapy makes it more confusing about the true mechanism of SDT. This review will focus on the following points: 1) Why are porphyrin‐based sonosensitizers considered the most promising sonosensitizer for clinical applications of SDT? 2) Recent progress in the development of multifunctional porphyrin‐based sonosensitizers. 3) What new insight has been gained on the mechanism of SDT in recent years? 4) The development trend of designing more efficient multifunctional porphyrin‐based sonosensitizers and existing challenges. Finally, future perspective of practical clinical applications of SDT based on multifunctional porphyrin‐based sonosensitizers will be discussed. [ABSTRACT FROM AUTHOR]

Rechargeable aqueous zinc iodine (Zn‐I2) batteries offer benefits such as low cost and high safety. Nevertheless, their commercial application is hindered by hydrogen evolution reaction (HER) and polyiodide shuttle, which result in a short lifespan. In this study, 1‐(2‐hydroxyethyl)imidazole (HEI) organic molecules featuring pyrrole‐N groups are introduced as dually‐functional electrolyte additives to simultaneously stabilize Zn anode and confine polyiodide through ion‐dipole interactions. The pyrrole‐N groups in HEI can preserve the interfacial pH equilibrium at Zn anode by reversibly capturing H+ ions and dynamically neutralizing OH− ions, thereby suppressing the HER. Notably, the H2 evolution rate at the Zn anode is reduced to a mere 2.20 μmol h−1 cm−2. Furthermore, the pyrrole‐N moieties in HEI effectively curtail the polyiodide shuttle at I2 cathode, which show adsorption energies of −0.174 eV for I2, −0.521 eV for I3−, and −0.768 eV for I−, as indicated by density functional theory calculations. Electrochemical testing demonstrates that the Zn//Zn symmetric cell maintains stable cycling for up to 4,200 hours at 1 mA cm−2. Most strikingly, at a high I2 mass loading of 9.7 mg cm−2, the Zn‐I2 battery achieves an extraordinary cycle life of 50,000 cycles. [ABSTRACT FROM AUTHOR]

Real‐time monitoring of respiration plays a very important role in human health assessment, especially in monitoring and analyzing respiration during exercise and sleep. However, traditional humidity sensors still have problems in flexibility, sensitivity, and durability, so there is an urgent need to develop humidity sensors with high sensitivity, stretchability, and environmental resistance as respiratory monitoring applications. Here, based on the double network hydrogel structure of polyvinyl alcohol and polyacrylamide, a highly sensitive, highly stretchable, and environmentally stable organic hydrogel humidity sensor has been manufactured by using the synergistic effect of lithium chloride and MXene. The hydrogel humidity sensor shows rapid response in the humidity range of 40–85% RH, and has a high sensitivity of −103.4%/% RH. In addition, it exhibits more than 3000% mechanical strain and excellent environmental resistance, which is attributed to the chemical cross‐linking in the hydrogel network and the synergistic effect of multiple hydroxyl groups in glycerol forming rich hydrogen bonds with water and polymer chains. The hydrogel humidity sensor is used for real‐time monitoring of breathing and sleep processes. This work provides a new strategy for preparing high‐performance, extensibility, and environmental stability hydrogel‐based sensors for respiratory monitoring. [ABSTRACT FROM AUTHOR]

Analysis of the superconducting properties of transition metal dichalcogenides (TMDs) under high pressures offers valuable insights to guide the design and synthesis of high‐performance superconducting materials. Herein, the effect of pressure is investigated on the superconductivity of a typical van der Waals layered TMDs material, PdSSe, by measuring its transport properties. After initially increased pressure, superconductivity emerges at 10.2 GPa, with a critical superconducting temperature (Tc) of ≈5.1 K, accompanied by the diminishing charge density wave (CDW) that is originally strengthening. Then, the Tc gradually increases with increasing pressure, reaching 12.1 K at the maximum pressure. The study provides experimental evidence for the superconductivity of PdSSe, and to the best of the knowledge, this is the first report on the observation of amplified CDW phenomena under increasing pressure in nonmagnetic TMDs. The abnormal enhancement of CDW transition temperature at low pressure is consistent with the upward trend of resistance, which is related to the electron–electron interaction. Moreover, synchrotron X‐ray diffraction experiments reveal two additional structural phase transitions. [ABSTRACT FROM AUTHOR]

Aqueous Zn metal batteries hold significant promise for large‐scale energy storage owing to their high safety and low cost. Nevertheless, severe corrosion and uncontrollable dendrite growth hinder the cyclic stability of Zn metal anodes. Herein, a porphyrin‐Zn(II) (ZnTBPP) based multifunctional artificial layer to stabilize Zn anodes by suppression of hydrogen evolution reactions is designed. This hydrophobic interfacial layer repels active water molecules and facilitates the electron transfer from Zn interface to the ZnTBPP layer, thereby increasing the inherent hydrogen evolution potential of Zn anodes. Differential charge density maps reveal that the electron cloud density of the charge transfer layer within the ZnTBPP layer is delocalized due to the electron‐withdrawing effect of Br‐containing functional groups in the ZnTBPP ligands, depleting the interfacial electrons of Zn metal anodes. As a result, H* exhibits a higher Gibbs free energy (∆GH*) of 0.75 eV on Zn with a ZnTBPP coating layer in contrast to bare Zn (0.55 eV), effectively suppressing H2 production. Specifically, the H2 evolution rate of ZnTBPP@Zn (4.06 µmol h−1 cm−2) is ≈2.2 times lower than that of bare Zn. The ZnTBPP@Zn//NaV3O8·1.5H2O full cells exhibit an ultra‐long cycling life of 10 000 cycles at 10 A g−1. [ABSTRACT FROM AUTHOR]

N‐type ZrNiSn‐based alloys reach a record thermoelectric figure of merit zT ≈1.2 by increasing the carrier concentration to 4–5 × 1020 cm−3. In this work, It is reported that a comparable zT can also be realized in trace Ru‐doped ZrNiSn‐based alloy at even lower temperature by decreasing the carrier concentration. Compared to the previously reported Co doping, the doping of Ru results in a more effective reduction in carrier concentration, and thus higher Seebeck coefficient, lower electronic thermal conductivity, and enhanced thermoelectric performance. The electronic specific heat coefficient of the ZrNi1‐xRuxSn sample remains constant with increasing Ru content, indicating no obvious change in the density of states effective mass. Theoretical calculations show that the doping of Ru has negligible effect on the bottom of conduction band. The lattice thermal conductivity is further reduced by alloying Ti and Hf at the Zr site, and the bipolar diffusion is suppressed by doping of 0.5 at.% Sb. As a result, Ti0.25Zr0.5Hf0.25Ni0.99Ru0.01Sn0.995Sb0.005 reaches not only a zT value of 1.1 at 773 K but also a record average zT value of 0.8 in 300 to 873 K, demonstrating the effectiveness of trace Ru doping on boosting the thermoelectric performance of ZrNiSn‐based alloys. [ABSTRACT FROM AUTHOR]

Conductive hydrogels have recently attracted extensive attention in the field of smart wearable electronics. Despite the current versatility of conductive hydrogels, the balance between mechanical properties (tensile properties, strength, and toughness) and electrical properties (electrical conductivity, sensitivity, and stability) still faces great challenges. Herein, a simplified method for constructing hydrophobic association hydrogels with excellent mechanical and electrical properties is proposed. The prepared conductive hydrogels exhibit high tensile properties (≈1224%), high linearity in the whole‐strain–range (R2 = 0.999), and a wide strain sensing range (2700%). The conductive hydrogel can realize more than 1000 cycles of sensing under 500% tensile strain. As an application demonstration, an underwater communication device is assembled in combination with polydimethylsiloxane/Triton X‐100 film coating, which successfully transmits underwater signals and provides warning of potential hazards. This study provides a new research method for developing underwater equipment with excellent mechanical properties and sensing properties. [ABSTRACT FROM AUTHOR]

Among the alloying‐type anodes, elemental Sb possesses the suitable yet safe plateau, simple lithiation pathway, small voltage polarization, high conductivity, and superior cycle stability. However, challenge is that its intrinsic capacity is rather low (660 mAh g−1), <1/6 of silicon. Herein, we propose a seamless integration strategy by merging the voltage and capacity of phosphorus and antimony into a solid solution alloy. Interestingly, the enlistment of P is found greatly enlarge the capacity from 660 to 993 mAh g−1 for such Sb30P30 solid solution, while maintaining a single and stable discharge plateau (~0.79 V) similar to elemental Sb. Various experimental characterizations including XPS, PDF, Raman, and EDS mapping reveal that in such a material the P and Sb atoms have interacted with each other to form a homogenous solid solution alloy, rather than a simple mixing of the two substances. Thus, the Sb30P30 exhibits superior rate performances (807 mAh g−1 at 5000 mA g−1) and cyclability (821 mAh g−1 remained after 300 cycles). Furthermore, such Sb60‐xPx alloys can even deliver 621 mAh g−1 at −30°C, which can be served as the alternative anode materials for high‐energy and low‐temperature batteries. This unique seamless integration strategy based on solid solution chemistry can be easily leveraged to manipulate the capacity of other electrode materials at similar voltage. [ABSTRACT FROM AUTHOR]

Objectives: Observational studies suggest birth weight and childhood obesity are closely associated with age at menarche. However, the relationships between them are currently inconsistent and it remains elusive whether such associations are causal. Therefore, the aim of the study was to investigate whether there existed causal relationships between birth weight, childhood obesity and age at menarche. Design, Patients and Measurements: A two‐sample Mendelian randomization (MR) study. The standard inverse variance weighted MR analyses were adopted to evaluate the causal effects of birth weight (n = 143,677), childhood body mass index (BMI) (n = 39,620) on age at menarche (n = 182,416) with summary statistics from large‐scale genome‐wide association studies (GWASs). Meanwhile, we validated our MR results with some sensitivity analyses including maximum likelihood, weighted‐median and MR pleiotropy residual sum and outlier methods. Results: The present study showed that each one standard deviation (1‐SD) lower birth weight was predicted to result in a 0.1479 years earlier of age at menarche (β =.1479, 95% confidence interval [CI] = 0.0422–0.2535; p = 0.0061). We also found that genetically predicted 1‐SD increase in childhood BMI was causally associated with early age at menarche (β = −.3966, 95% CI = −0.5294 to −0.2639; p = 4.73E−09). Conclusions: Our MR study suggests the causal effect of lower birth weight and higher childhood BMI on the increased risk of earlier menarche. It may be the opportune time to carry out weight control intervention in prenatal and early childhood development periods to prevent early menarche onset, thus decreasing the future adverse consequences. [ABSTRACT FROM AUTHOR]

Glioma is a highly invasive primary brain tumour, making it challenging to accurately predict prognosis for glioma patients. Cuproptosis is a recently discovered cell death attracting significant attention in the tumour field. Whether cuproptosis‐related genes have prognostic predictive value has not been clarified. In this study, uni‐/multi‐variate Cox and Lasso regression analyses were applied to construct a risk model based on cuproptosis‐related lncRNAs using TCGA and CGGA cohorts. A nomogram was constructed to quantify individual risk, including clinical and genic characteristics and risk. GO and KEGG analyses were used to define functional enrichment of DEGs. Tumour mutation burden (TMB) and immune checkpoint analyses were performed to evaluate potential responses to ICI therapy. Ten prognostic lncRNAs were obtained from Cox regression. Based on the median risk score, patients were divided into high‐ and low‐risk groups. Either for grade 2–3 or for grade 4, glioma patients with high‐risk exhibited significant poorer prognoses. The risk was an independent risk factor associated with overall survival. The high‐risk group was functionally associated with immune responses and cancer‐related pathways. The high‐risk group was associated with higher TMB scores. The expression levels of many immune checkpoints in the high‐risk group were significantly higher than those in the low‐risk group. Differentiated immune pathways were primarily enriched in the IFN response, immune checkpoint and T‐cell co‐stimulation pathways. In conclusion, we established a risk model based on cuproptosis‐related lncRNAs showing excellent prognostic prediction ability but also indicating the immuno‐microenvironment status of glioma. [ABSTRACT FROM AUTHOR]

Vertical differential structural deformation (VDSD), one of the most significant structural characteristics of strike‐slip fault zones (SSFZs) in the Shunbei area, is crucial for understanding deformation in the SSFZ and its hydrocarbon accumulation significance. Based on drilling data and high‐precision 3‐D seismic data, we analyzed the geometric and kinematic characteristics of the SSFZs in the Shunbei area. Coupled with the stratification of the rock mechanism, the structural deformations of these SSFZs in different formations were differentiated and divided into four deformation layers. According to comprehensive structural interpretations and comparisons, three integrated 3‐D structural models could describe the VDSD of these SSFZs. The time‐space coupling of the material basis (rock mechanism stratification), changing dynamic conditions (e.g., changing stress‐strain states), and special deformation mechanism of the en echelon normal fault array uniformly controlled the formation of the VDSD in the SSFZs of the Shunbei area. The VDSD of the SSFZs in this area controlled the entire hydrocarbon accumulation process. Multi‐stage structural superimposing deformation influenced the hydrocarbon migration, accumulation, distribution, preservation, and secondary adjustments. [ABSTRACT FROM AUTHOR]

It is more and more important to analyse and process complex data for gaining more valuable knowledge and making more accurate decisions. The multigranulation decision theory based on conditional probability and cost loss has the advantage of processing decision‐making problems from multi‐levels and multi‐angles, and the neighbourhood rough set model (NRS) can facilitate the analysis and processing of numerical or mixed type data, and can address the limitation of multigranulation decision‐theoretic rough sets (MG‐DTRS), which is not easy to cope with complex data. Based on the in‐depth study of hybrid‐valued decision systems and MG‐DTRS models, this study analysed neighbourhood MG‐DTRS (NMG‐DTRS) deeply by fusing MG‐DTRS and NRS; a matrix‐based approach for approximation sets of NMG‐DTRS model was proposed on the basis of the matrix representations of concepts; the positive, boundary and negative domains were constructed from the matrix perspective, and the concept of positive decision recognition rate was introduced. Furthermore, the authors explored the related properties of NMG‐DTRS model, and designed and described the corresponding solving algorithms in detail. Finally, some experimental results that were employed not only verified the effectiveness and feasibility of the proposed algorithm, but also showed the relationship between the decision recognition rate and the granularity and threshold. [ABSTRACT FROM AUTHOR]

To fabricate organic solar cells (OSCs) via slot‐die coating, solvent additives are essential to induce an optimized phase‐separated and order morphology. It is critical to determine the morphological evolution from solution to solid state and understand the crystallization kinetics in slot‐die coating. Using in situ grazing‐incidence wide‐angle X‐ray scattering characterization, the morphological evolution in PM6‐ and ITIC‐based systems without or with 0.3% 1,8‐diiodooctane (DIO) as additive can be monitored in real‐time during slot‐die coating. As a result, DIO weakens the planarization of the PM6 backbone and splits the backbone ordering into fragments to form ordered crystallites. DIO also induces surface crystallization to reinforce the tie‐chain connections between the crystallites. Furthermore, in the ITIC system, DIO triggers the formation of an interconnected fibril network morphology and concurrently promotes the stacking of ITIC molecules in between the polymer network. Thus, an optimized morphology with a refined crystal structure is formed with the help of DIO. As a result, the power conversion efficiency is improved from 8.77% to 9.59% in slot‐die‐coated OSCs. These findings provide guidelines for optimizing the morphology in slot‐die‐coated OSCs and accelerate the transition of laboratory‐scale fabrication to industrial production. [ABSTRACT FROM AUTHOR]

State‐of‐health (SOH) estimation is one of the most critical battery management system (BMS) tasks. A challenge remains for the SOH prediction due to the complicated battery aging mechanism. The most common health indicator is the capacity of the lithium‐ion battery. The fluctuation of capacity caused by the capacity regeneration phenomenon can seriously affect the prediction performance. A new complete ensemble empirical mode decomposition with adaptive noise (CEEMDAN) and gate recurrent unit (GRU) based fusion prediction model for SOH estimation is proposed to solve the problem effectively. First, the CEEMDAN algorithm decomposes the original SOH into local fluctuations and global degradation trends. Then, the GRU network and autoregressive integrated moving average model are used to predict the above trends, respectively. Next, a sliding window is designed to calculate an average value of the global degradation trend prediction residuals. Then, the second GRU algorithm can be used to correct prediction residuals. Finally, the prediction results of the aforementioned parts are combined to obtain the final SOH estimation. The proposed method is verified by experimental battery data from NASA and CALCE datasets. The results show that the fusion method has both higher estimation accuracy and stronger robustness than other methods. [ABSTRACT FROM AUTHOR]

The donor/acceptor interaction in non‐fullerene organic photovoltaics leads to the mixing domain that dictates the morphology and electronic structure of the blended thin film. Initiative effort is paid to understand how these domain properties affect the device performances on high‐efficiency PM6:Y6 blends. Different fullerenes acceptors are used to manipulate the feature of mixing domain. It is seen that a tight packing in the mixing region is critical, which could effectively enhance the hole transfer and lead to the enlarged and narrow electron density of state (DOS). As a result, short‐circuit current (JSC) and fill factor (FF) are improved. The distribution of DOS and energy levels strongly influences open‐circuit voltage (VOC). The raised filling state of electron Fermi level is seen to be key in determining device VOC. Energy disorder is found to be a key factor to energy loss, which is highly correlated with the intermolecular distance in the mixing region. A 17.53% efficiency is obtained for optimized ternary devices, which is the highest value for similar systems. The current results indicate that a delicate optimization of the mixing domain property is an effective route to improve the VOC, JSC, and FF simultaneously, which provides new guidelines for morphology control toward high‐performance organic solar cells. [ABSTRACT FROM AUTHOR]

Mixtures of nonfullerene acceptors (NFAs) are prepared to fine‐tune bulk heterojunction (BHJ) thin‐film morphologies. The acceptor phase resulting from these mixtures has unique physical properties with excellent optoelectronic processes that dictate the output of organic photovoltaic (OPV) devices. Remarkable short‐circuit current densities (JSC) and fill factors (FFs) are achieved due to the formation of better crystalline fibrils that suppress geminate recombination, leading to improved charge transport with enhanced crystallinity and aligned cascading energy levels confirm efficient exciton diffusion and dissociation, yielding more effective exciton recycling. The decreased Urbach energy and suppressed energetic disorder account for the improvement in the open‐circuit voltage (VOC). A maximum power conversion efficiency of 17.86% is obtained, underscoring the importance of using specific material interactions to produce a suitable morphology and manage energy loss, resulting in ideal organic solar cell (OSC) devices. [ABSTRACT FROM AUTHOR]

As a typical conversion‐type cathode material, CuS has shown great potential in the field of rechargeable magnesium batteries (RMBs) due to its excellent energy density, stable voltage platforms, and low cost. However, the poor phase conversion reversibility in CuS cathodes has resulted in low Coulombic efficiency and short cycling life, impeding its further development. Herein, an abundance of CS heterointerfaces is meticulously crafted by the CuS nanoparticles anchored on rGO nanosheets (CuS@G). The out‐of‐plane C─S bonds effectively reduce the activation energy of sulfur atoms within Cu‐S tetrahedrons, facilitating the formation of S─S bonds in the Cu₂S crystal structure and driving the reversible phase conversion between Cu₂S and CuS during the charge/discharge process. Furthermore, a more reversible phase conversion could diminish copper ion dissolution induced by volume expansion. Consequently, the CuS@G cathode exhibits one of the most remarkable rate performances to date (160.5 mAh g−1 at 1 A g−1), retaining 64.7% of its capacity after 1000 cycles. Additionally, a durable CuS@G||Mg pouch cell is successfully assembled, delivering a high capacity of 9.5 mAh. These fundamental insights provide valuable guidance for the design of high‐performance conversion cathode materials for next‐generation RMBs. [ABSTRACT FROM AUTHOR]

This study proposes a decentralised methodology to deal with the optimal energy flow (OEF) problem of the electricity–natural gas system (EGS). The OEF problem of EGS is formulated as a multi‐stage dynamic programming (DP) process, and the approximate DP algorithm is used to decompose it into subproblems. The independent decision of each subproblem can be made by solving Bellman's equation, requiring just a moderate interchange of information among different subproblems. Such that the information privacy and dispatch independency of subsystems (including electricity and natural gas (NG) subsystems) can be ensured. Different from most existing decentralised algorithms, the impact of one subproblem's decision on other subproblems can be estimated in the proposed algorithm, and the parameters of the proposed algorithm are not required for tuning, which makes more sense in real applications. Furthermore, an improved linear cut technique is proposed to handle the non‐convexity of the NG network model, so that the tightness of all gas flow constraints can be ensured. Case studies containing small, large and complicated EGSs validate the effectiveness of the proposed approach. [ABSTRACT FROM AUTHOR]

Polaritons in low‐dimensional materials have shown their unique capabilities to concentrate light at the deep subwavelength scale. They behave quite differently from those in conventional metals. On the one hand, the strongly confined polaritons exhibit a large tunability in wavelength following different scaling behaviors in different systems. On the other hand, they show novel reflection behaviors when they encounter topographic boundaries or electronic discontinuities. Here, recent progress on the scaling and reflection behaviors of strongly confined polaritons in three representative low‐dimensional material systems is reviewed. It is shown that the polariton wavelength changes sensitively with carrier density, thickness, and the number of conducting channels for graphene, hexagonal boron nitride, and carbon nanotubes. Also, it is demonstrated how polaritons reflect in low‐dimensional materials when encountering edges, corrugations, domain walls, strain regions, etc. [ABSTRACT FROM AUTHOR]

Recently, long noncoding RNAs (lncRNAs) have been widely reported to play pivotal roles in the regulation of human cancers. Although the oncogenic property of lncRNA small nucleolar RNA host gene 3 (SNHG3) has been revealed in a variety of cancers, functions and regulatory mechanism of SNHG3 in non‐small‐cell lung cancer (NSCLC) remain to be investigated. In this study, we detected the upregulated expression of SNHG3 in NSCLC tissues as well as cells through quantitative reverse‐transcription polymerase chain reaction (qRT‐PCR) analysis. Using Kaplan–Meier analysis, we determined that a high‐level of SNHG3 was associated with a low overall survival rate of patients with NSCLC. Through gain and loss of function experiments, we demonstrated that SNHG3 had a significantly positive effect on NSCLC cell proliferation and migration. Mechanistic investigations revealed that SNHG3 was a predicted direct transcriptional target of E2F1. We observed that the transcriptional activation of SNHG3 could be induced by E2F1. To explore the mechanism, rescue experiments were carried out, which revealed that the cotreatment with SB‐431542, JSI‐124, or JSI‐124 + SB‐431542 rescued the effects brought by the overexpression of SNHG3 on NSCLC cell proliferation, migration, and epithelial‐mesenchymal transition process. Our results suggested that E2F1 activated SNHG3 and promoted cell proliferation and migration in NSCLC via transforming growth factor‐β pathway and interleukin‐6/janus‐activated kinase 2/signal transducer and activator of transcription 3 pathway, which implied that SNHG3 may be a biomarker for the treatment of patients with NSCLC. [ABSTRACT FROM AUTHOR]

It is an important subject to mine valuable knowledge from complex and massive data in the era of big data. Rough set theory is a new mathematical tool for dealing with uncertain and inaccurate data, decision-theoretic rough set model (DTRS), as an extension of classical rough set model, is used to analyze decision information systems and multi-granulation decision-theoretic rough set model (MG-DTRS) can analyze and process target concepts from different angles and levels. However, the classical DTRS model exists some limitations in dealing numerical or hybrid-valued data. Considering the different influence of numerical features and symbolic features on decision-making, the paper proposes an incomplete neighborhood multi-granulation decision-theoretic rough set model in hybrid-valued decision system through integrating MG-DTRS with neighbourhood rough sets, and two types of neighborhood multi-granulation decision-theoretic set models are emphatically analysed. Furthermore, taking pessimistic and optimistic neighborhood multi-granulation decision-theoretic rough sets as examples, the implementation algorithms and related properties of the two type of models are studied. Finally, the relationship between the proposed model and other models is analyzed through formula derivation. The model proposed in this paper can effectively solve the decision-making problem of hybrid-valued incomplete information system through multi-angle and multi-level analysis. [ABSTRACT FROM AUTHOR]

This article proposes to develop a WiFi‐controlled portable atomic force microscope (AFM). The AFM consists of a horizontal probe, controlling circuits, digital to analog (D/A) and analog to digital (A/D) interfaces, a microcomputer (Raspberry Pi, RPi), and a laptop. The proposed AFM uses a pocket‐size power supply to drive the controlling circuits, the D/A and A/D interfaces, as well as the RPi that constructs network hotspots and generates scanning signals. With special design and integration of the whole system, both of the AFM probe and electronic controlling system are portable. At a distance of 50 m from the proposed AFM, experiments in the constant height mode and the constant force mode are conducted to evaluate its performance. The results show that this WiFi‐controlled AFM has a maximum scan range of 3.6 × 3.6 μm2 with nanometer order resolution. Meanwhile, it achieves satisfactory image contrast, stability, and repeatability. Compared with conventional AFMs, the AFM proposed in this paper no longer relies on commercial AC mains supply or high‐voltage DC power supply, and realizes WiFi‐controlled AFM scanning and imaging in 50 m or farther without wire or network cable connection to a laptop or a desktop computer. Given credits to these features, WiFi‐controlled AFMs are expected to own a wider range of application, especially in isolated environments, outdoor researches, or even fieldwork investigations. [ABSTRACT FROM AUTHOR]

Ce3+, Nd3+ codoped (Sr0.6Ca0.4)3(Al0.6Si0.4)O4.4F0.6 phosphors were synthesized through the high-temperature solid-state reaction method. Luminescence spectra, absorption spectra, and decay lifetimes of these samples have been measured to prove the energy-transfer process from Ce3+ to Nd3+. Under UV and blue light excitation, (Sr0.6Ca0.4)3(Al0.6Si0.4)O4.4F0.6:Ce3+,Nd3+ phosphors exhibit near-infrared (NIR) emission, mainly peaking at 1093 nm and secondarily at 916 nm. The NIR emission matches well with the band gap of c-Si. Results of this work suggest that the (Sr0.6Ca0.4)3(Al0.6Si0.4)O4.4F0.6:Ce3+, Nd3+ phosphors have potential application as down-shifting luminescent convertor for enhancing the photoelectric conversion efficiency of c-Si solar cell. [ABSTRACT FROM AUTHOR]

This work investigated the near-infrared ( NIR) emission properties of mCe3+, xNd3+ codoped Sr3− m− x(Si1− m− xAl m+ x)O5 phosphors. Samples with various doping concentrations were synthesized by the high-temperature solid-state reaction. Al3+ ions have the ability to promote Ce3+ ions to enter into the Sr2+ sites and to improve the visible emission of Ce3+. Thus the NIR emission of Nd3+ is enhanced by the energy-transfer process, which occurred from Ce3+ to Nd3+. The device based on these NIR emission phosphors is fabricated and combined with a commercial c-Si solar cell for performance testing. Short-circuit current density of the solar cell is increased by 7.7%. Results of this work suggest that the Sr2.95Si0.95Al0.05O5:0.025Ce3+, 0.025Nd3+ phosphors can be used as spectral convertors to improve the efficiency of c-Si solar cell. [ABSTRACT FROM AUTHOR]

This work investigated the near-infrared ( NIR) emission properties of mCe3+, xNd3+ codoped Sr3− m− x(Si1− m− xAl m+ x)O5 phosphors. Samples with various doping concentrations were synthesized by the high-temperature solid-state reaction. Al3+ ions have the ability to promote Ce3+ ions to enter into the Sr2+ sites and to improve the visible emission of Ce3+. Thus the NIR emission of Nd3+ is enhanced by the energy-transfer process, which occurred from Ce3+ to Nd3+. The device based on these NIR emission phosphors is fabricated and combined with a commercial c-Si solar cell for performance testing. Short-circuit current density of the solar cell is increased by 7.7%. Results of this work suggest that the Sr2.95Si0.95Al0.05O5:0.025Ce3+, 0.025Nd3+ phosphors can be used as spectral convertors to improve the efficiency of c-Si solar cell. [ABSTRACT FROM AUTHOR]

Rechargeable magnesium batteries (RMBs) are a highly promising energy storage system due to their high volumetric capacity and intrinsic safety. However, the practical development of RMBs is hindered by the sluggish Mg2+ diffusion kinetics, including at the cathode‐electrolyte interface (CEI) and within the cathode bulk. Herein, we propose an efficient strategy to manipulate the interfacial chemistry and coordination structure in oligolayered V2O5 (L−V2O5) for achieving rapid Mg2+ diffusion kinetics. In terms of the interfacial chemistry, the specific exposed crystal planes in L−V2O5 possess strong electron donating ability, which helps to promote the degradation dynamics of C−F/C−S bonds in the electrolyte, thereby establishing the inorganic‐organic interlocking CEI layer for rapid Mg2+ diffusion. In terms of the coordination structure, the straightened V−O structure in L−V2O5 provides efficient ions diffusion path for accelerating Mg2+ diffusion in the cathode. As a result, the L−V2O5 delivers a high reversible capacity (355.3 mA h g−1 at 0.1 A g−1) and an excellent rate capability (161 mAh g−1 at 1 A g−1). Impressively, the interdigital micro‐RMBs is firstly assembled, exhibiting excellent flexibility and practicability. This work gives deeper insights into the interface and interior ions diffusion for developing high‐kinetics RMBs. [ABSTRACT FROM AUTHOR]